• Title/Summary/Keyword: Organic pollutant removal

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Behavior of Organic Matter, Chlorine Residual and Disinfection By-Products (DBPs) Formation during UV Treatment of Wastewater Treatment Plant Effluents (하수처리장 방류수의 UV 처리시 유기물질, 잔류염소 및 소독부산물 생성 거동)

  • Han, Jihee;Sohn, Jinsik
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.1
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    • pp.61-72
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    • 2014
  • Study on effluent organic matter (EfOM) characteristic and removal efficiency is required, because EfOM is important in regard to the stability of effluents reuse, quality issues of artificial recharge and water conservation of aqueous system. UV technology is widely used in wastewater treatment. Many reports have been conducted on microbial disinfection and micro pollutant reduction with UV treatment. However, the study on EfOM with UV has limited because low/medium pressure UV lamp is not sufficient to affect refractory organics. The high intensity of pulsed UV would mineralize EfOM itself as well as change the characteristics of EfOM. Chlorine demand and DBPs formation is affected on the changed amounts and properties of EfOM. The objective of this study is to investigate the effect on EfOM, chlorine residual, and chlorinated DBPs formation with low pressure and pulsed UV treatment. The removal of organic matter through low pressure UV treatment is insignificant effect. Pulsed UV treatment effectively removes/transforms EfOM. As a result, the chlorine consumption is changed and chlorine DBPs formation is decreased. However, excessive UV treatment caused problems of increasing chlorine consumption and generating unknown by-products.

Pollutant Removal in Variable HRT Using the Aerobic Biofilm (호기성 생물막을 이용한 HRT 변화에 따른 오염물질 제거)

  • Ahn, Kwang-Ho;Ko, Kwang-Baik;Kim, I-Tae;Kim, Kwang-Soo
    • Journal of Environmental Science International
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    • v.21 no.12
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    • pp.1495-1501
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    • 2012
  • In this study, an experiment was conducted on influent water with low concentrations of organic matter, such as river water or secondary treatment water of a sewage treatment plant, according to HRT changes by using aerobic biofilm. In the biofilm process, as the biofilm increases in thickness, the inner membrane can be low in oxygen transfer rate and become anaerobic conditions, while the detachment of biomass from biofilm occurs. To overcome these limitations in the detachment of microorganisms in biofilm, the yarn, which was made from poly propylene(PP), was weaved and manufactured into a tube. Then, a test was carried out by injecting air so that the interior of the biofilm could create aerobic conditions. The results of the experiment showed that the removal efficiency of $TCOD_{cr}$ reached 66.1~81.2% by HRT 2hr, and 50.9 ~61.8% after HRT 1 hr. The removal efficiency of $SCOD_{cr}$ was 45.9 to 55.1% by HRT 1hr, and 26.1% in HRT 0.5hr, showing the highest removal efficiency in HRT 1hr. The SS removal efficiency was at 81.8 to 94.6%, and the effluent SS concentration was very low, indicating less than 2.2 mg/L in all HRT's. As a result, the $SCOD_{cr}$ and $NH_4{^+}$-N that were removed per specific surface area and attached to microbial biofilm showed the highest efficiency in HRT 1hr with 8.37 $gSCOD_{cr}/m^2{\cdot}d$, 2.93 $gNH_4{^+}-N/m^2{\cdot}d$. From the result of reviewing the characteristics of biofilm growth, microorganisms were found to be attached, and increased by 36 days. Later, they decreased in number through detachment, but showed a tendency to increase again 41 days later due to microbial reproduction.

A Study on the Reduction Process of VOCs Emission from Paint Booth - A Hybrid Process of Biotrickling Filter and Activated Sludge Reactor

  • Lim Gye-Gyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E2
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    • pp.41-48
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    • 2005
  • A novel hybrid system composed of a biotrickling filter and an activated sludge reactor was investigated under the conditions of four different SRTs (sludge retention times). The performance of the hybrid reactor was found to be directly comparable among the four different sludge ages. Discernible differences in the removal performance were observed among four different SRTs of 2, 4, 6, and 8 days. High removal efficiency was achieved by continuous circulation of activated sludge over the immobilized mixture culture, which allowed on pH control, addition of nutrients, and removal of paint VOCs (volatile organic compounds). The results also showed that the removal efficiency for a given pollutant depends on the activity of microorganisms based on the SRT. As the SRT increased gradually from 2 to 8 days, the average removal performance decreased. The highest removal rate was achieved at the SRT of 2 days at which the highest OUR (oxygen uptake rate), $6.1mg-O_2/liter-min$ was measured. Biological activity in the recycle microbes decreased to a much lower level, $3.6mg-O_2/liter-min$ at a SRT of 8 days. It is thus believed that young microorganisms were more active and more efficient for the VOCs removal of low concentrations and high flow rates. The apparent correlation of $R^2=0.996$ between the average removal efficiency and the average OUR at each SRTs suggests that VOCs degradation by young cells significantly affected the overall removal efficiency for the tested SRTs.

Assessment of Performances of Low Impact Development (LID) Facilities with Vegetation (식생이 조성된 LID 시설의 효율 평가)

  • Hong, Jung Sun;Kim, Lee-Hyung
    • Ecology and Resilient Infrastructure
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    • v.3 no.2
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    • pp.100-109
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    • 2016
  • Low impact development (LID) facilities are established for the purpose of restoring the natural hydrologic cycle as well as the removal of pollutants from stormwater runoff. Improved efficiency of LID facilities can be obtained through the optimized interaction of their major components (i.e., plant, soil, filter media, microorganisms, etc.). Therefore, this study was performed to evaluate the performances of LID facilities in terms of runoff and pollutant reduction and also to provide an optimal maintenance method. The monitoring was conducted on four LID technologies (e.g., bioretention, small wetlands, rain garden and tree box filter). The optimal SA/CA (facility surface area / catchment area) ratio for runoff reduction greater than 40% is determined to be 1 - 5%. Since runoff reduction affects the pollutant removal efficiency in LID facilities, SA/CA ratio is derived as an important factor in designing LID facilities. The LID facilities that are found to be effective in reducing stormwater runoff are in the following order: rain garden > tree box filter > bioretention> small wetland. Meanwhile, in terms of removal of particulate matter (TSS), the effectiveness of the facilities are in the following order: rain garden > tree box filter > small wetland > bioretention; rain gardens > tree box filter > bioretention > small wetland were determined for the removal of organic matter (COD, TOC), nutrients (TN, TP) and heavy metals (Cu, Pb, Cd, Zn). These results can be used as an important material for the design of LID facilities in runoff volume and pollutant reduction.

Retreatment of Arificial Wastewater by using Microalgae (조류를 이용한 인공하수의 재처리)

  • Lee, Young-Joon;Lee, Soo-Hyung
    • Korean Journal of Ecology and Environment
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    • v.35 no.2 s.98
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    • pp.133-140
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    • 2002
  • This study was performed in lab scaled oxidation pond. The removal efficiency of pollutant on the influence of changes of hydraulic retention time and pond style was investigated. The correlation between organic removal efficiency and dissolved oxygen concentration on algal photosynthesis showed the light time revealed a higher relationship more than the dark time, and the squares of the correlation coefficient of 15 days retention time were higher than that of 5 days in single pond. The variation of dissolved oxygen concentration of a series pond was from 4.2 to 19.8 mg/l under 5 days retention time, the concentration of dissolved oxygen increased with increasing step of series pond. Between the single pond and a series of pond system, a series of pond system showed better organic removal efficiency. Average removal efficiency range of $TBOD_5$ and $SBOD_5$ was $49{\sim}83%$ and $87{\sim}92%$, respectively. Algae should be removed appropriately to increase the removal efficiency of organic matter.

Effect of the Presence of Soil on the Ferrous Catalyzed Sodium Persulfate Oxidation of Naphthalene (과황산나트륨과 제일철 촉매를 이용한 나프탈렌 산화 시 토양이 미치는 영향 평가)

  • Han, Dai-Sung;Yun, Yeo-Bog;Ko, Seok-Oh
    • Journal of Soil and Groundwater Environment
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    • v.15 no.1
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    • pp.29-38
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    • 2010
  • Batch tests were carried out to examine the influence of the presence of soil and Fe(II) sorption capacity of soil on the ferrous catalyzed sodium persulfate oxidation for the destruction of organic pollutants in the application of in-situ chemical oxidation. Laboratory column tests were also conducted to investigate the transport of oxidant and catalyst in contaminated groundwater. Test results proved that Fe(II) was adsorbed on soil surface, and thus soil behaved as a heterogeneous catalyst, enhancing the naphthalene removal rate up to 50%. Column tests that were conducted with and without dissolved Fe(II) showed that naphthalene removal ratio were 24% and 25%, respectively. The removal efficiency was not enhanced with dissolved Fe(II), since the dissolved Fe(II) flew out of the column as the oxidant progressively injected into the column saturated with Fe(II). It indicates that the injected oxidant could not interact with dissolved Fe(II). But target organic pollutant was degraded in soil column system, implying that sulfate radical was produced by the reaction of dissolved persulfate with Fe(II) adsorbed on soil.

Development of tree box filter LID system for treating road runoff (LID 시설로서 도로에 적용 가능한 수목여과시설 개발)

  • Choi, Jiyeon;Son, Younggyu;Lee, Soyoung;Lee, Yuhwa;Kim, Lee Hyung
    • Journal of Wetlands Research
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    • v.15 no.3
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    • pp.407-412
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    • 2013
  • The aim of this study was to develop a tree box filter system, an example of Low Impact Development technology, for treating stormwater runoff from road. Monitoring of storm events was performed between June 2011 and November 2012 to evaluate the system performance during wet day. Based on the results, all runoff volume generated by rainfall less than 2 mm was stored in the system. The minimum volume reduction of 20% was observed in the system for rainfall greater than 20 mm. The greatest removal efficiency was exhibited by the system for total heavy metals ranging from 70 to 73% while satisfactory removal efficiency was exhibited by the system for particulate matters, organic matters and nutrients ranging from 60 to 68%. The system showed greater pollutant removal efficiency of 67 to 83% for rainfall less than 10 mm compared to rainfall greater than 10 mm which has 39 to 75% pollutant removal efficiency. The system exhibited less pollutant reduction for rainfall greater than 10 mm due to the decreased retention capacity of the system for increased rainfall. Overall, the system has proved to be an option for stormwater management that can be recommended for on-site application. Similar system may be designed based on several factors such as rainfall depth, facility size and pollutant removal efficiency.

An overview of functionalised carbon nanomaterial for organic pollutant removal

  • Jun, Lau Yien;Mubarak, N.M.;Yee, Min Juey;Yon, Lau Sie;Bing, Chua Han;Khalid, Mohammad;Abdullah, E.C.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.175-186
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    • 2018
  • Carbon nanomaterials (CNMs), particularly carbon nanotube and graphene-based materials, are rapidly emerging as one of the most effective adsorbents for wastewater treatment. CNMs hold great potential as new generation adsorbents due to their high surface to volume ratio, as well as extraordinary chemical, mechanical and thermal stabilities. However, implementation of pristine CNMs in real world applications are still hindered due to their poor solubility in most solvents. Hence, surface modification of CNMs is essential for wastewater treatment application in order to improve its solubility, chemical stability, fouling resistance and efficiency. Numerous studies have reported the applications of functionalized CNMs as very promising adsorbents for treating organic and inorganic wastewater pollutants. In this paper, the removal of organic dye and phenol contaminants from wastewater using various type of functionalized CNMs are highlighted and summarized. Challenges and future opportunities for application of these CNMs as adsorbents in sustainable wastewater treatment are also addressed in this paper.

Removal of Heavy Metal and Organic Substance in Contaminated Soils by Electrokinetic and Ultrasonic Remediation (동전기 및 초음파 복원기술에 의한 오염지반내의 중금속 및 유기오염물질 제거)

  • Chung, Ha-Ik
    • Journal of the Korean Geotechnical Society
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    • v.19 no.3
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    • pp.83-91
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    • 2003
  • The electrokinetic technique has been applied to remove mainly the heavy metal and the ultrasonic technique to remove mainly organic substance in contaminated soil. In this study, the combined electrokinetic and ultrasonic remediation technique was studied far the removal of heavy metal and organic substance in contaminated soils. This study emphasized the coupled effects of electrokinetic and ultrasonic techniques on migration as well as remediation of contaminants in soils. The laboratory soil flushing tests combining electrokinetic and ultrasonic technique were conducted using specially designed and fabricated devices to determine the effect of both of these techniques. A series of laboratory experiments involving the simple, electrokinetic, ultrasonic, and electrokinetic & ultrasonic flushing test were carried out. A soil admixed with sand and kaolin was used as a test specimen, and Pb and ethylene glycol were used as contaminants of heavy metal and organic substance. An increase in out flow, permeability and contaminant removal rate was observed in electrokinetic and ultrasonic flushing tests. Some practical implications of these results are discussed in terms of technical feasibility of in situ implementation of electrokinetic ultrasonic remediation technique.

A study on pollutants removal characteristics of domestic riverbed filtration and riverbank filtration intake facilities (국내 복류수 및 강변여과수 취수시설의 오염물질 제거특성에 관한 연구)

  • Chan-woo Jeong;Sun-ick Lee;Sung-woo Shin;Chang-hyun Song;Bu-geun Jo;Jae-won Choi
    • Journal of Korean Society of Water and Wastewater
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    • v.37 no.5
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    • pp.281-288
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    • 2023
  • This study was performed to evaluate the pollutants removal characteristics of two types of RBFs(Riverbank filtration, Riverbed filtration) intake facilities installed in Nakdong River and in Hwang River respectively. The capacity of each RBF is 45,000 m3/d for riverbank filtration intake facility and 3,500 m3/d for riverbed filtration intake facility. According to data collected in the riverbank filtration site, removal rate of each pollutant was about BOD(Biochemical Oxygen Demand) 52%, TOC(Total Organic Carbon) 57%, SS(Suspended Solids) 44%, Total coliforms 99% correspondingly. Furthermore, Microcystins(-LR,-YR,-RR) were not found in riverbank filtered water compared to surface water in Nakdong River. DOC(Dissolved Organic Carbon) and Humics which are precursors of disinfection byproduct were also reported to be removed about 59% for DOC, 65% for Humics. Based on data analysis in riverbed filtration site in Hwang River, removal rate of each contaminant reaches to BOD 33.3%, TOC 38.5%, SS 38.9%, DOC 22.2%, UV254 21.2%, Total coliforms 73.8% respectively. Additionally, microplastics were also inspected that there was no obvious removal rate in riverbed filtered water compared to surface water in Hwang River.