• Title/Summary/Keyword: Organic pollutant removal

검색결과 80건 처리시간 0.03초

실내공기질 모델을 이용한 환기 시스템의 공기 정화 효율성 평가 (Evaluation of Ventilation System Performance Using Indoor Air Quality Model)

  • 최성우
    • 한국환경보건학회지
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    • 제23권4호
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    • pp.57-66
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    • 1997
  • Successful energy conservation and good indcfor air quality (IAQ) are highly dependent on ventilation system. Air filtration is a primary solution of indoor air control strategies in terms of reducing energy consumption and improving ihdoor air quality. A conventional system with bypass filter, as it is called variable-air-volume/bypass filtration system (VAV/BPFS), is a variation of the conventional variable air volume (VAV) systems, which is designed to eliminate indoor air pollutant and to save energy. Bypass filtration system equipped with a high-efficiency particulate filter and carbon absorbent provides additional cleaned air into indoor environments and maintain good IAQ for human health. The objectives of this research were to compare the relative total decay rate of indoor air pollutant concentrations, and to develop a mathematical model simulating the performance of VAV/BPFS. All experiments were performed in chamber under the controlled conditions. The specific conclusions of this research are: 1. The VAV/BPFS system is more efficient than the VAV system in removing indoor air pollutant concentration. The total decay rates of aerosol, and total volatile organic compound (TVOC) for the VAV/BPFS system were higher than those of the conventional VAV system. 2. IAQ model predictions of each pollutant agree closely with the measured values. 3. According to IAQ model evaluation, reduction of outdoor supply air results in decreased dilution removal rate and on increased bypass filtration removal rate with the VAV/BPFS. As a results, we recommends the VAV/BPFS as an alternative to conventional VAV systems.

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Efficient use of ferrate(VI) for the remediation of wastewater contaminated with metal complexes

  • Sailo, Lalsaimawia;Pachuau, Lalramnghaki;Yang, Jae Kyu;Lee, Seung Mok;Tiwari, Diwakar
    • Environmental Engineering Research
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    • 제20권1호
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    • pp.89-97
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    • 2015
  • Remediation of wastewater contaminated with metal(II)-complexed species (Cu(II)-NTA (NTA: nitrilotriacetic acid), Cu(II)-EDTA (EDTA: ethylenediamine tetraacetic acid) and Cd(II)-EDTA is attempted using the potential applicability of ferrate(VI). Kinetics of pollutant degradation is obtained with the removal of ferrate(VI) studied at wide range of pH (8.0-10.0) and the concentration of metal(II)-complexed species (0.3 to 15.0 mmol/L) employing a constant dose of ferrate(VI) i.e., 1.0 mmol/L. Pseudo-first-order and pseudo-second-order rate constants were obtained in the reduction of ferrate(VI) which was then employed to obtain the overall rate constants of the pollutant degradation. The mineralization of NTA and EDTA was obtained with the change in TOC (total organic carbon) values collected by the ferrate(VI) treated pollutant samples. Decrease in pH and molar pollutant concentrations was greatly favored the percent mineralization of NTA or EDTA by the ferrate(VI) treatment. The treated pollutant samples were filtered and subjected for AAS (atomic absorption spectrophotometric) analysis to assess the simultaneous removal of copper and cadmium from aqueous solutions at the studied pH as well at the elevated pH 12.0. Results show that an enhanced removal of cadmium or copper was achieved at pH 12.0. Overall, ferrate(VI) possesses multifunctional application in wastewater treatment as it oxidizes the degradable impurities and removes metallic impurities by coagulation process.

Acclimation of magnetic activated sludge with 1,4-dioxane and analysis of bacterial flora in the sludge

  • Toshiyuki Nikata;Hayato Ogihara;Yasuzo Sakai
    • 한국초전도ㆍ저온공학회논문지
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    • 제25권3호
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    • pp.7-12
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    • 2023
  • Isolation of pollutant-degrading bacteria is important in bioaugmentation, one of the methods for biological degradation of environmental contaminants. We focused on the magnetic activated sludge (MAS) process as a culture method that efficiently concentrates degrading bacteria, and cultured activated sludge with 1,4-dioxane as a model pollutant. After 860 days of operation, MLVSS, which indicates the amount of sludge, increased from 390 mg/L to 10,000 mg/L, and the removal rate of organic matter including 1,4-dioxane, tetrahydrofuran, and glucose in the artificial wastewater reached up to 97%. Based on these results, the MAS process was successfully used to acclimate activated sludge with 1,4-dioxane. Bacterial flora analysis in the MAS showed that bacteria of the genus Pseudonocardia, already reported as 1,4-dioxane degrading bacteria, play an important role in the degradation of this pollutant. The MAS process is a suitable culture method for acclimation of environmental pollutants, and the findings indicate that it can be used as an enrichment unit for pollutant-degrading bacteria.

슬릿 유전체 장벽을 갖는 선대 평판형 방전장치의 방전 및 오존 발생특성 (Discharge and Ozone Generation Characteristics of a Wire-Plate Discharge System with a Slit Barrier)

  • 문재덕;정재승
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제54권9호
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    • pp.421-426
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    • 2005
  • A wire-plate discharge system with a slit barrier has been proposed and investigated experimentally by focusing on the discharges on the slit barrier and ozone generation characteristics. This wire-plate discharge system with a slit barrier can generate an intensive corona discharges, and produce corona discharge twice, once from the corona wire electrode and second time from the surface and the slits of the slit dielectric barrier. As a result this propose wire-plate discharge system with the slit barrier can produce greatly increased ozone than without the slit barrier. This type of wire-plate discharge system with the slit barrier could be used for effective ozone generation as a means with retard to the removal of pollutant gas

PDMS (Polydimethylsilioxane)-Coated Silica Nanoparticles for Selective Removal of Oil and Organic Compound from Water

  • Cho, Youn Kyoung;Kim, Dae Han;Yoon, Hye Soo;Jeong, Bora;Kim, Young Dok
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.257-257
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    • 2013
  • In order to selectively remove oil and organic compound from water, silica nanoparticles with hydrophobic coating was used. Since silica nanoparticles are generally hydrophilic, removal efficiency of oil and organic compound, such as toluene, in water can be decreased due to competitive adsorption with water. In order to increase the removal efficiency of oil and toluene, hydrophobic polydimethylsiloxane (PDMS) was coated on silica nanoparticles in the form of thin film. Hydrophobic property of the PDMS-coated silica nanoparticles and hydrophilic silica nanoparticles were easily confirmed by putting it in the water, hydrophilic particle sinks but hydrophobic particle floats. PDMS coated silica nanoparticles were dispersed on a slide glass with epoxy glue on and the water contact angle on the surface was determined to be over $150^{\circ}$, which is called superhydrophobic. FT-IR spectroscopy was used to check the functional group on silica nanoparticle surface before and after PDMS coating. Then, PDMS coated silica nanoparticles were used to selectively remove oil and toluene from water, respectively. It was demonstrated that PDMS coated nanoaprticles selectively aggregates with oil and toluene in the water and floats in the form of gel and this gel remained floating over 7 days. Furthermore, column filled with hydrophobic PDMS coated silica nanoparticles and hydrophilic porous silica was prepared and tested for simultaneous removal of water-soluble and organic pollutant from water. PDMS coated silica nanoparticles have strong resistibility for water and has affinity for oil and organic compound removal. Therefore PDMS-coated silica nanoparticles can be applied in separating oil or organic solvents from water.

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Preparation and Characterization of Electrospun TiO2-Activated Carbon Complex Fiber as Photocatalyst

  • Jung, Min-Jung;Jeong, Eui-Gyung;Jang, Jeen-Seok;Lee, Young-Seak
    • Carbon letters
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    • 제11권1호
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    • pp.28-33
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    • 2010
  • In this study, $TiO_2$-Activated carbon (AC) complex fibers were prepared by electrospinning for the synergetic effect of adsorption and degradation of organic pollutant. The average diameter of these fibers increased with increasing the amount of AC added, except for 1AC-TOF (AC$/TiO_2$ =1/40 mass ratio). After calcinations at $500^{\circ}C$, long as-spun fibers were broken and their average diameter was slightly decreased. The resultant fibers after calcination had rough surface and sphere shapes like a peanut. From XRD results, it was confirmed that as-spun fibers were changed to anatase $Ti_O2$ fiber after calcinations at $500^{\circ}C$. The prepared $TiO_2$-AC complex fibers could remove procian blue dyes by solar light irradiation with high removal property of 94~99%. The PB dye was rapidly removed by adsorption during the initial 5 minutes. But after 5 minutes, dye removal was occurred by photodegradation. In this study, the most efficient AC/$TiO_2$ ratio of $TiO_2$-AC complex fibers was 5/40, showing the synergetic effect of adsorption and photodegradation. It is expected that the $TiO_2$-AC complex fibers can be used to remove of organic pollutants in water system.

강우시 인공습지를 이용한 유기물관리 (Management of Organic Matters by Constructed Treatment Wetlands during Rainfall Events)

  • 이상팔;박제철
    • 한국환경과학회지
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    • 제26권3호
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    • pp.401-410
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    • 2017
  • This study analyzed the changes in the concentrations of organic matters in constructed treatment wetlands, coming from discharge water from a sewage treatment plant and non-point pollutant sources during rainfall events. At the beginning of a rainfall event, a massive amount of particulate organic matter flowed in, and was removed from the sedimentation basin (S1, S2); dissolved organic matter was removed after passing through stepwise treatment processes in the wetland. During dry period in the wetland, the removal efficiency rate for COD and TOC was -21 and -7%, respectively; during the rainfall event, the removal efficiency rate for COD and TOC were 47 and 43%, respectively. The highly-concentrated organic matters that flowd in at the beginning of the rainfall event was stabilized by various structures in the wetland before water discharge. Cyanobacteria blooms annually at the confluence of the So-ok stream and Daecheong Lake. Therefore, it is expected that the wetland will contribute significantly to reducing cyanobacteria and improving water quality in the area.

소규모 오수발생지역의 고도처리시설을 위한 상.하 흐름형 인공습지 개발 (Development of Up- and Down-flow Constructed Wetland for Advanced Wastewater Treatment in Rural Communities)

  • 김형중;윤춘경;권태영;정광욱
    • 한국농공학회논문집
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    • 제48권6호
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    • pp.113-124
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    • 2006
  • The feasibility of the up- and down-flow constructed wetland was examined fur rural wastewater treatment in Korea. Many constructed wetland process was suffered from substrate clogging and high plant stresses because of long term operation. The up- and down-flow constructed wetland process used porous granule materials (charcoal pumice : SSR=10:20:70) for promoting intake rate of nutrient to plant, and especially flow type was designed continuously repeating from up-flow to down-flow. $BOD_5$ and SS was removed effectively by the process with the average removal rate being about 75% respectively. The wetland process was effective in treating nutrient as well as organic pollutant. Removal of TN and TP were more effective than other wetland system and mean effluent concentrations were approximately 7.5 and $0.4mg\;L^{-1}$ which satisfied the water quality standard for WWTPs. The treatment system did not experience any clogging or accumulations of pollutants and reduction of treatment efficiency during winter period because constructed polycarbonate glass structure prevented temperature drop. Considering stable performance and effective removal of pollutant in wastewater, low maintenance, and cost-effectiveness, the up- and down-flow constructed wetland was thought to be an effective and feasible alternative in rural area.

대청호 유역 비점오염원 제어를 위한 생태습지의 오염물질 제거효율 평가 (Evaluation of Removal Efficiency of Pollutants in Constructed Wetlands for Controlling Nonpoint Sources in the Daechung Reservoir Watershed)

  • 박별님;조영철
    • 생태와환경
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    • 제56권2호
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    • pp.127-139
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    • 2023
  • 대청호는 유역에 있는 비점오염원으로부터 유입되는 오염물질로 인해 남조류 과다증식에 기인한 녹조가 빈번하게 발생하고 있다. 이에 녹조 관리 대책 중 하나로 인공습지를 설치하여 호소에 유입되는 오염물질을 저감하고 있다. 본 연구에서는 비점오염원의 관리방법으로 인공습지의 적용 가능성을 평가하기 위해 대청호 상류에 설치된 서화천 생태습지를 대상으로 2014년부터 2020년까지 유입수 및 유출수의 BOD, COD, SS, T-N, T-P 등 오염물질 농도를 분석하였다. 분석 결과 대체적으로 인공습지에서의 처리를 통해 오염물질의 농도가 감소하는 것이 확인되었으며, 특히, 유기물질보다 질소, 인과 같은 영양염류에 있어 높은 처리효율이 확인되었다. 유입수의 오염물질 농도에 따른 처리효율을 구간을 나누어 분석한 결과 대체적으로 고농도에서 처리효율이 높은 경향을 나타내었다. 설치 및 운영 경과에 따른 연도별 인공습지 처리효율을 분석한 결과, T-P에서 큰 변화가 확인되었다. 이는 인공습지 조성 초기에는 식생의 성장에 따라 높은 처리효율을 보였지만, 식생이 안정화되고 습지 퇴적층이 포화됨에 따라 처리효율이 점진적으로 감소한 결과로 판단된다. 본 연구의 결과는 초기 강우 등 높은 농도의 오염물질 유입 및 주기적인 퇴적토 준설 등의 관리가 이루어진다면 인공습지가 유역면적이 넓고, 비점오염원의 영향을 크게 받는 댐 저수지의 부영양화 억제에 유용한 수단이 될 수 있음을 보여준다.

다단 생물반응기에 의한 질소제거 (Nitrogen Removal from Wastewater by a Multi-stage Bio-reactor)

  • 최규철;정일현
    • 환경위생공학
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    • 제13권1호
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    • pp.91-103
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    • 1998
  • Design data for COD and nitrogen removal from wastewater were collected from Pilot's Multi-stage Bio-reactor. Hyraulic conditions and pollutant loadings were varied in order to optimize the biological and operational parameters. Pilot's experimental results summarize as followings. 1. T-N removal efficiency in the organic volumetric loading 0.2 kgCOD/m$^{3}$·d was obtained as maxium of 85% at internal recycle ratio 2.5 and in more ratio than this it was decreased. Organic removal efficiency was about 91% under the overall experimental conditions and not influenced by recycle ratio.. 2. Nitrification reaction was shown as maxium in the SCOD$_{cr}$/NH$^{+}$-N ratio of 6.5 and in more ratio than this it was decreased. Denitrification rate was the maxium as 85% in more than 7.5 of SCOD$_{cr}$/NO$_{x}$-N ratio and in the ratio over this ratio it becomes constant. 3. By utilizing an applied new model of Stover-Kincannon from Monod's kinetic model, concentration of T-N in the effluent according to flow quanity in the influent was estimated as 8.74 and -67.5 respectively. The formula for estimating T-N concentration of effluent was obtained like this: N$_e$=N$_0$(1- $\frac{8.74}{(QN$_0$/A)-67.05}$)

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