• 제목/요약/키워드: Organic pollutant

검색결과 307건 처리시간 0.024초

염색폐수 중의 유기오염물질 분석 (Determination of Organic Pollutants in Dyeing Wastewater)

  • 육근성
    • 분석과학
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    • 제10권5호
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    • pp.332-342
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    • 1997
  • 15종의 휘발성 유기오염물질을 blank water에 $20{\mu}g/L$의 농도로 첨가하여 Purge and Trap과 Gas Chromatograph/Mass Spectrometer(GC/MS)로 분석하였다. 그 결과 100%의 총평균 회수율과 3.6%의 평균상대표준편차를 얻었으며, 검출한계는 $1.9{\sim}3.3{\mu}g/L$를 나타내어 분석법이 적합함을 알 수 있었다. 반월염색단지 공동폐수처리장의 폐수를 분석한 결과 15종의 유기물이 검출되었으며, 이 중 미국 EPA에서 규제하는 priority pollutant는 trichloroethylene, tetrachloroethylene, toluene, ethylbenzene 등 4종이었다. 한편, 환경부가 폐수 중에서 규제하는 trichloroethylene과 tetrachloroethylene의 농도는 각각 34.6과 $75.6{\mu}g/L$로 배출허용기준 이하로 검출되었다.

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Trace Organic Contaminants in Sediments from Deep-sea Basin near Dokdo, Korea

  • Yim, Un-Hyuk;Oh, Jae-Ryoung;Hong, Sang-Hee;Li, Dong-Hao;Shim, Won-Joon;Choi, Hye-Kyung;Kim, Eun-Soo;Shim, Jae-Hyung
    • Ocean and Polar Research
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    • 제24권4호
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    • pp.391-398
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    • 2002
  • Trace organic contaminants in deep-sea sediments near Dokdo were analyzed. Total PAMs concentration ranged 14.8-314 ng/g dry weight and high molecular weight PAHs were dominant. The highest PAHs concentration was detected at A19 which located at Ulleung Basin. Most of organochlorines were under detection limit. Among the detected organochlorines, DDT compounds were dominant and followed by HCHs and HCB. Butyltin compounds and most of organophosphorus pesticides were not detected. Vertical distribution of PAHs showed typical sub-surface maximum and decreasing trends depending on depth. The highest PAHs concentration reached 454ng/g. Some organochlorines, DDT, HCH was detected and also showed decreasing trends. Other target organic pollutants were not detected in core sediments. Abnormally high level of PAHs concentration in A19 was discussed and the input sources were inferred to be the transport of sludge derived pollutant dumped at dumping site 'Byung' by deep current.

하수처리장 방류수의 UV 처리시 유기물질, 잔류염소 및 소독부산물 생성 거동 (Behavior of Organic Matter, Chlorine Residual and Disinfection By-Products (DBPs) Formation during UV Treatment of Wastewater Treatment Plant Effluents)

  • 한지희;손진식
    • 상하수도학회지
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    • 제28권1호
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    • pp.61-72
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    • 2014
  • Study on effluent organic matter (EfOM) characteristic and removal efficiency is required, because EfOM is important in regard to the stability of effluents reuse, quality issues of artificial recharge and water conservation of aqueous system. UV technology is widely used in wastewater treatment. Many reports have been conducted on microbial disinfection and micro pollutant reduction with UV treatment. However, the study on EfOM with UV has limited because low/medium pressure UV lamp is not sufficient to affect refractory organics. The high intensity of pulsed UV would mineralize EfOM itself as well as change the characteristics of EfOM. Chlorine demand and DBPs formation is affected on the changed amounts and properties of EfOM. The objective of this study is to investigate the effect on EfOM, chlorine residual, and chlorinated DBPs formation with low pressure and pulsed UV treatment. The removal of organic matter through low pressure UV treatment is insignificant effect. Pulsed UV treatment effectively removes/transforms EfOM. As a result, the chlorine consumption is changed and chlorine DBPs formation is decreased. However, excessive UV treatment caused problems of increasing chlorine consumption and generating unknown by-products.

Photocatalytic activity enhancement of TiO2 with adding Zn particles

  • Seo, Hyeon Jin;Boo, Jang Heon;Jang, Hyun Woo;Kim, Mi Jeong;Boo, Jin-Hyo
    • Applied Science and Convergence Technology
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    • 제25권6호
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    • pp.162-165
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    • 2016
  • APhotocatalysis process uses ambient oxygen from air and irradiation, fundamentally UV light, to generate oxidation and reduction which can degrade almost all harmful organic and inorganic compounds to nontoxic substances. This study was focused on enhancement of photocatalytic activity which improves the photocatlytic efficiency with $TiO_2$ particle by mixing of certain amounts of Zn particles. We analyzed degradation of organic pollutant materials such as toluene and phenol with the mixed photocatalysis by using UV-visible spectrophotometer and obtained a result that photocatalytic activity is increased with increasing amount of Zn particle. Especially, in the case of $TiO_2$ (1 mmol) and Zn (0.1 mmol) mixture photocatalyst, we obtained at least 2 times higher photocatalytic activity compared with the commercially available $TiO_2$ photocatalyst (Degussa P-25), indicating that our mixed photocatalyts (Zn-doped $TiO_2$) is very effective of removing both organic dye and pollutants and the conversion rate of toluene is much faster than that of phenol.

TCE, PCE 측정을 위한 바이오센서의 특성

  • 류두현;김용미;최상일
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.388-391
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    • 2004
  • A sol-gel fiber-optic biosensor with encapsulated pH-sensitive fluorophore and immobilized genetically modified toluene-o-xylene monooxygenase was developed to detect TCE and PCE, which are carcinogenic chlorinate organic compounds prevailing in ground water. The sensitivity was characterized for the composition of sol-gel, and manufacturing procedure. The intensity curve reveals a linear range of intensity for pollutant concentration range of 0.01ppm and 1ppm. The change in intensity was appeared to be larger at each of L for same condition, and, therefore, the wavelength of λ was chosen for the analytical measurement.

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미국 주 정부 실천계획의 현황 및 추진방향 (The Status and Direction of State Implementation Plans to Improve Air Quality of the United States)

  • 신태주
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2000년도 춘계학술대회 논문집
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    • pp.49-51
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    • 2000
  • 오존은 온도가 높고 태양 빛이 강한 여름철에 휘발성 유기화합물(Volatile Organic Compounds)과 질소화합물(NOx)의 광 화학 반응으로 생성되는 이차적 공해물질(Secondary Air Pollutant)이다. 성층권에 존재하는 오존은 피부암을 유발시키는 강한 자외선을 차단하고 흡수하는 고마운 존재이지만, 급속한 산업발달로 다량의 공해물질유출로 인해 생성된 지표면상의 오존은 대단히 유독해서 높은 농도에서 장시간 호흡 시 호흡기관의 장애는 물론이고 치사까지 이르게 하는 것으로 알려져 있다. (중략)

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소규모 축산농가에 의한 담수호의 수질오염특성 (The Wate Quality Characterics of Fresh Water Lake by Small-Scale Dairy Farm)

  • 김선주;이석호
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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    • pp.727-733
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    • 1999
  • In general ,wastes of livestock are covered 1% in the total wastes in Korea. But, actual pollutant loading rates by an organic material are 18% which will be serious problem in fresh water lake. An aim of this study is analyzing water quality in Bo-Ryeoung fresh water lake which are arounded by a lot of small livestock area, so that look for how to manage water quality of fresh waterlake.

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소규모 시험포에서의 비료처리별 오염배출 농도 특성 비교 (Comparison of Pollutant Load Discharge Characteristics with Fertilizer Treatments from Small Scale Plot)

  • 류창원;신용철;허성구;한윤수;임경재;최중대
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2006년도 학술발표회 논문집
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    • pp.997-1001
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    • 2006
  • Organic compost has been widely applied to the cropland because it has been thought as Environmentally Sound Agriculture (ESA) in Korea. In this study, two-year indoor rainfall experiments were performed. Surface runoff and groundwater volume from 10% and 20% slope plots were measured and water quality samples were collected and analyzed for BOD, COD, T-P and T-N. Flow weighted mean concentration (FWMC) values were computed to assess effects of various fertilizer treatments. FWMC BOD values for organic compost treated plots were higher than chemical fertilizer treated plots. FWMC BOD values for 20% slope plots were higher than those from those for 10% slope plots. The similar trends were found for COD and T-P. FWMC T-N values for chemical fertilizer treated plots were higher than organic compost treated plots. FWMC T-N values for 10% slope plots were higher than those for 20% slope plots. In Korea, excessive use of organic compost has caused extremely high levels of organic matter contents at the cropland. Since organic compost is very slow in releasing its nutrients to the soil, farmers usually apply excessive organic compost for immediate effects and maximum crop yields, which has been causing soil and water quality degradations. Therefore, thorough investigations for better nutrient management plans are needed to develop the ESA strategy in Korea.

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유기물오염도 지표를 이용한 하천수질영향평가 - 산업폐수의 방류수질을 기준으로 - (Impact Assessment of River Water Quality using Organic Pollutant Index - Industrial Waste Water -)

  • 조수현;강미아;추용엽;정교철;정동희;이준흥
    • 지질공학
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    • 제16권4호
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    • pp.373-379
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    • 2006
  • 우리나라에서 하천에 유입되는 유기물부하의 많은 부분을 차지하는 산업폐수를 대상으로 유기물 오염지표간의 상관성을 조사하였다. 기존 사용되고 있던 COD와 BOD를 현재 많은 국가에서 도입하고 있는 TOC와의 관계를 규명하였다. 업종별 업체별로 그 상관계수에는 큰 차이가 있었으며, 최고의 상관계수는 음식료품 생산업체의 방류수 중에 함유된 COD/BOD/TOC와의 관계에서 나타났다. 각각의 상관계수는 COD/BOD: 0.997, COD/TOC : 0.969, BOD/TOC: 0.990이었다. 상관계수가 낮은 경우도 많았으며, 동일업종이라 하더라도 상관도에는 일관성이 없었다. 그러므로 수질기준 책정 또는 하천수질 모니터링 등에 기존의 유기물질지표의 대체지표로써 TOC를 사용하는 것은 불가능할 것으로 사료된다. 그러나 이들의 상관도가 높은 방류수의 관리에 있어서는 유용하게 사용될 수 있으므로 이들 유기물질 인자간의 상관성을 검토하여 개별적으로 사용하여야 할 것이다.

Photo and Electrocatalytic Treatment of Textile Wastewater and Its Comparison

  • Singaravadivel, C.;Vanitha, M.;Balasubramanian, N.
    • Journal of Electrochemical Science and Technology
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    • 제3권1호
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    • pp.44-49
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    • 2012
  • Electrochemical and photochemical techniques have been proved to be effective for the removal of organic pollutants in textile wastewater. The present study deals with degradation of synthetic textile effluents containing reactive dyes and assisting chemicals, using electro oxidation and photo catalytic treatment. The influence of various operating parameters such as dye concentration, current density, supporting electrolyte concentration and lamp intensity on TOC removal has been determined. From the present investigation it has been observed that nearly 70% of TOC removal has been recorded for electrooxidation treatment with current density 5 mA/$dm^2$, supporting electrolyte concentration of 3 g/L and in photocatalytic treatment with 250 V as optimum lamp intensity nearly 67% of TOC removal was observed. The result indicates that electro oxidation treatment is more efficient than photocatalytic treatment for dye degradation.