• 제목/요약/키워드: Organic material removal

검색결과 182건 처리시간 0.029초

축제식 대하양식장에서 수차의 순환기능 (Effects of Paddle Wheel on Water Circulation in Shrimp Culture Ponds)

  • 강윤호
    • 한국양식학회지
    • /
    • 제14권1호
    • /
    • pp.43-50
    • /
    • 2001
  • To study the effect of paddle wheel on water circulation, velocity components were measured in shrimp ponds both along the longitudinal direction from a single paddle wheel and at 25 grid points of two ponds, which have mean water depth of 1.2m and aspect ratio (length/width) 1.05 and 0.68, respectively. An analysis of factors related to water quality and circulation showed that I) a single paddle wheel has an effective distance of 33m for de-stratification, 16m for particulate suspension and 25m for removal of organic material, dispersion of DO and prevention of bed sediment disturbance and ii) with doubling the number of paddle wheels at the pond corners, the flow speed increased by 13% over the ponds, while it reduced by 8.5% around the pond centres. Contrary to expectation, increasing the number of paddle wheel did not generate strong circulation around the pond centre and improve water quality.

  • PDF

나노프로브 응용 기계-화학적 나노리소그래피 기술 (Nanoprobe-based Mechano-Chemical Scanning Probe Lithography Technology)

  • 성인하;김대은;신보성
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2003년도 춘계학술대회
    • /
    • pp.1043-1047
    • /
    • 2003
  • With the advancement of micro-systems and nanotechnology, the need for ultra-precision fabrication techniques has been steadily increasing. In this paper, a novel nano-structure fabrication process that is based on the fundamental understanding of nano-scale tribological interaction is introduced. The process, which is called Mechano-Chemical Scanning Probe Lithography (MC-SPL), has two steps, namely, mechanical scribing for the removal of a resist layer and selective chemical etching on the scribed regions. Organic monolayers are used as a resist material, since it is essential for the resist to be as thin as possible in order to fabricate more precise patterns and surface structures. The results show that high resolution patterns with sub-micrometer scale width can be fabricated on both silicon and various metal surfaces by using this technique.

  • PDF

Pervaporation Separation of Trace VOCs from Water Through PDMS Membranes

  • Rhim, Ji-Won;Kwon, Young-Mann
    • Korean Membrane Journal
    • /
    • 제1권1호
    • /
    • pp.73-80
    • /
    • 1999
  • The removal of trace chlorinated and aromatic hydrocarbons from water by a pervaporation technique has been carried out through poly (dimethylsiloxane) membrane which had been fabricated by the addition crosslinking reaction. This study dealt with the swelling and permeation behaviors of the PDMS membranes with dichloroethane trichloroethane and toluene aqueous solutions. The swelling ratio in the toluene aqueous solution was much higher than those in the chloroethane solutions at all of the operating temperatures and concentrations. The solubility parameter theory was introduced to interpret the affinity between permeates and a membrane material and in all cases this approach seemed to be proper. It was suggested that the existence of water clusters in the membrane due to the hydrophobic characteristics of the membrane made the size of the permeating water larger resulting in suppressing water permeation and increasing enrichment of the organic components. The permeation behaviors at different membrane thicknesses were indirectly interpreted in terms of the effect of concentration polarization.

  • PDF

동물뼈로부터 재활용된 hydroxylapatite를 이용한 Cu(II) 제거 (Removal of Cu(II) with the Recycled Hydroxylapatite from Animal Bones)

  • 김무늬;김원기;이승목;양재규
    • 대한환경공학회지
    • /
    • 제31권9호
    • /
    • pp.735-742
    • /
    • 2009
  • 척추동물의 뼈는 hydroxylapatite [$Ca_{10}(PO_4)_6(OH)_2$, HAp]로 이루어져 있어서 용액중에 존재하는 중금속이온들의 훌륭한 이온교환제로서 잘 알려져 있다. 본 연구에서는 하소시켜 얻은 소뼈, 돼지뼈, 생선뼈를 이용한 회분식 반응조에서의 구리이온의 제거성능을 조사하였으며 이러한 결과로부터 중금속이온을 제거하기 위한 흡착제로서의 재이용성을 평가하였다. 온도를 달리하여 하소시켜 얻은 세 종류의 뼈 시료들의 표면특성은 SEM, XRD 및 FT-IR 분석을 통하여 측정하였다. SEM 촬영결과 하소온도가 높아질수록 표면이 불규칙해졌으며 작은 기공이 발달하였다. XRD 분석에서는 하소 온도가 높아질수록 피크가 발달되는 경향을 보였는데 이와 같은 현상은 HAp가 열처리에 의해 무정형 형태에서 결정형으로 바뀌었음에 기인한 것으로 여겨진다. FT-IR 분석결과 하소온도가 높아질수록 흡착된 물과 골격 내 유기물의 흡수밴드의 강도는 점차 감소되는 것을 알 수 있었다. 구리이온 제거 결과 뼈를 넣지 않은 바탕실험에서는 15% 이하의 제거율을 보였는데 하소된 뼈를 사용한 경우에는 제거율이 부가적으로 40% 이상 상승하였다. 세 종류의 동물뼈 모두에서 하소온도를 높일수록 구리에 대한 제거율은 감소하였다. 용액의 pH가 상승할수록 양이온 교환 및 침전반응을 형성할 수 있는 유리한 조건에 의해 구리이온의 제거율이 상승하였다.

TREATMENT OF FOODWASTE AND POSPHORUS REMOVAL USING STRUVITE CRYSTALLIZATION IN HYBRID ANAEROBIC REACTOR WITH SAC MEDIA

  • Park, In-Chul;Kim, Dong-Su;Kim, Sung-Man;Lee, Jung-Jun
    • 한국자원리싸이클링학회:학술대회논문집
    • /
    • 한국자원리싸이클링학회 2001년도 정기총회 특별강연 및 춘계학술연구발표회(2)
    • /
    • pp.129-132
    • /
    • 2001
  • The purpose of this research was to understand possibility of foodwaste treatment by hybrid anaerobic reactor(HAR). The Possibility of methane utility and applicability of hybrid reactor system using foodwaste as substrate was investigated. The maximum loading rate and optimized operational conditions were determined. Hybrid anaerobic reactor was filled with packing material 50% of its total volume between the tube and the outer surface. The packing material used was randomly packed open-pore synthesis activated ceramic(SAC) media as support media for microbial attachment, growth, and chemical stability protected bacteria from effect of organic acid accumulation. In this research, although foodwaste has high concentrations C $l^{[-10]}$ and S $O_{4}$$^{2-}$ concentration the possibility of foodwaste anaerobic treatment was when foodwaste is treated by anaerobic digestion, this study focused on the possibility using C $H_4$ gas made under the anaerobic treatment as an alternative energy source. Other objective of this research is to study struvite formation and crystal forms in anaerobic digester. HAR is used to investigate phosphate crystallization without the addition of chemicals.

  • PDF

염료감응형 태양전지의 고효율화를 위한 $Alq_3$가 코팅된 FTO기판 제작 (Optimization of $Alq_3$-coated FTO substrate for high efficient of DSSC)

  • 박아름;박경희;구할본;박복기
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
    • /
    • pp.241-241
    • /
    • 2010
  • Recently high and persistent spontaneous buildup of a surface potential (SP) upon vacuum deposition of tris (8-hydroxyquinolinato) aluminum (III) ($Alq_3$), which is widely used for organic light emitting devices. The removal of the giant surface potential by visible light irradiation has also been reported. In this study, we coated $Alq_3$ on the FTO substrate and raise the capacity for absorbing sun light. The $Alq_3$ which is green light emitting diode emits light at wavelengths between 500 and 550nm. If we apply one's FTO/$Alq_3$ substrate in one's DSSC, we could get higher energy conversion efficiency because the N719 dye that we used for fabricating the DSSC emits light just at near 540nm. The energy conversion efficiency of approximately 4.8 % at the condition of irradiation of AM 1.5 (100 mW/$cm^2$) simulated sunlight, and the $J_{sc}$ is 12.0 mA/$cm^2$, $V_{oc}$ is 0.71 V, FF is 0.56, respectively.

  • PDF

Effect of Pressure on Edge Delamination in Chemical Mechanical Polishing of SU-8 Film on Silicon Wafer

  • Park, Sunjoon;Im, Seokyeon;Lee, Hyunseop
    • Tribology and Lubricants
    • /
    • 제33권6호
    • /
    • pp.282-287
    • /
    • 2017
  • SU-8 is an epoxy-type photoresist widely used for the fabrication of high-aspect-ratio (HAR) micro-structures in micro-electro-mechanical systems (MEMS). To fabricate highly integrated structures, chemical mechanical polishing (CMP) has emerged as the preferred manufacturing process for planarizing the MEMS structure. In SU-8 CMP, an oxidizer decomposes organic impurities and particles in the CMP slurry remove the chemically reacted surface of SU-8. To fabricate HAR microstructures using the CMP process, the adhesion between SU-8 and substrate material is important to avoid the delamination of the SU-8 film caused by the mechanical-dominant material removal characteristic. In this study, the friction force during the CMP process is measured with a CMP monitoring system to detect the delamination phenomenon and investigate the delamination of the SU-8 film from the silicon substrate under various pressure conditions. The increase in applied pressure causes an increase in the frictional force and wafer-edge stress concentration. The frictional force measurement shows that the friction force changes according to the delamination phenomenon of the SU-8 film, and that it is possible to monitor the delamination phenomenon during the SU-8 CMP process. The delamination at a high applied pressure is explained by the effect of stress distribution and pad deformation. Consequently, it is necessary to control the pressure of polishing, which can avoid the delamination in SU-8 CMP.

Cu ECMP 공정에 사용디는 전해액의 최적화 (Optimization of Electrolytes on Cn ECMP Process)

  • 권태영;김인권;조병권;박진구
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
    • /
    • pp.78-78
    • /
    • 2007
  • In semiconductor devices, Cu has been used for the formation of multilevel metal interconnects by the damascene technique. Also lower dielectric constant materials is needed for the below 65 nm technology node. However, the low-k materials has porous structure and they can be easily damaged by high down pressure during conventional CMP. Also, Cu surface are vulnerable to have surface scratches by abrasive particles in CMP slurry. In order to overcome these technical difficulties in CMP, electro-chemical mechanical planarization (ECMP) has been introduced. ECMP uses abrasive free electrolyte, soft pad and low down-force. Especially, electrolyte is an important process factor in ECMP. The purpose of this study was to characterize KOH and $KNO_3$ based electrolytes on electro-chemical mechanical. planarization. Also, the effect of additives such as an organic acid and oxidizer on ECMP behavior was investigated. The removal rate and static etch rate were measured to evaluate the effect of electro chemical reaction.

  • PDF

Ag:CNT 인쇄박막 액체 센서의 위험유해물질 검출 특성 (HNS Detection Properties of Printed Ag:CNT Film as Liquid Sensor)

  • 고동완;최준석;이상태;장지호
    • 한국전기전자재료학회논문지
    • /
    • 제32권3호
    • /
    • pp.223-228
    • /
    • 2019
  • We fabricated a printed Ag:CNT film as a liquid sensor for the detection of HNS (hazardous and noxious substances) in seawater. The paste required for printing was prepared using Ag powder, MWCNTs (multi-walled carbon nanotubes), and an organic binder. The heat treatment process for binder removal was optimized. In order to confirm that the sensor was operational, the resistance change characteristics in brine (3.5%) and methanol (99.8%) were assessed at $20^{\circ}C$. EDL (electrical double layer) formation and redox reactivity were confirmed as the most important reactions affect each electrical property of sensor in brine and methanol. From these results, it was determined that printed Ag:CNT film can be applied as a sensor to detect HNS in seawater.

Degradation and mineralization of violet-3B dye using C-N-codoped TiO2 photocatalyst

  • Putri, Reza Audina;Safni, Safni;Jamarun, Novesar;Septiani, Upita;Kim, Moon-Kyung;Zoh, Kyung-Duk
    • Environmental Engineering Research
    • /
    • 제25권4호
    • /
    • pp.529-535
    • /
    • 2020
  • The present study investigated the photodegradation of synthetic organic dye; violet-3B, without and with the addition of C-N-codoped TiO2 catalyst using a visible halogen-lamp as a light source. The catalyst was synthesized by using a peroxo sol-gel method with free-organic solvent. The effects of initial dye concentration, catalyst dosage, and pH solution on the photodegradation of violet-3B were examined. The efficiency of the photodegradation process for violet-3B dye was higher at neutral to less acidic pH. The kinetics reaction rate of photodegradation of violet-3B dye with the addition of C-N-codoped TiO2 followed pseudo-first order kinetics represented by the Langmuir-Hinshelwood model, and increasing the initial concentration of dyes decreased rate constants of photodegradation. Photodegradation of 5 mg L-1 violet-3B dye achieved 96% color removal within 240 min of irradiation in the presence of C-N-codoped TiO2 catalyst, and approximately 44% TOC was removed as a result of the mineralization.