• Title/Summary/Keyword: Organic geometry

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A Study of the Dielectric Characteristics of the Low-k SiOCH Thin Films by Ellipsometry (Ellipsometry를 이용한 Low-k SiOCH 박막의 유전특성에 관한 연구)

  • Yi, In-Hwan;Hwang, Chang-Su;Kim, Hong-Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1083-1089
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    • 2008
  • We studied the dielectric characteristics of low-k SiOCH thin films by Ellipsometry. The SiOCH thin films were prepared by deposition of BTMSM precursors on p-Si wafer by CCP-PECVD method. The nano-porous structural organic/inorganic hybrid-type of SiOCH thin films correlated directly to the formation of low dielectrics close to pore(k=1). The structural groups including highly dense pores in SiOCH thin films originated the anisotropic geometry type of network structure directing to complex refractive characteristics of SiOCH single layer on the p-Si wafer. The linearly polarized beam of Xe-ramp in the range from 190 nm to 2100 nm introduced to the surface of SiOCH thin film, and the reflected beam was Elliptically polarized by complex refractive coefficients of SiOCH dipole groups. The amplitude variation $\Psi$ and phase variation $\Delta$ of the relative reflective coefficients between perpendicular and parallel components to the incident plane were measured by Ellipsometry. The complex optical constants n and k as well as the dielectric constant and thickness of SiOCH thin films were driven by the measured value of $\Psi$ and $\Delta$.

A Study on Formative Features of Fashion Design in Digital Era (디지털 시대의 패션 디자인 조형성에 관한 연구)

  • Chun, Jae-Hoon;Har, Ji-Soo
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.11 s.158
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    • pp.1560-1571
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    • 2006
  • The purpose of this study is to analyze relations between digital characteristics and formative features of fashion design in digital era, to find out the best way to make desirable clothes in the future affected by digital characteristics. The methods of this study are documentary research of previous studies and case study. For the study of formative features of fashion design, 100 kinds of pictures have been selected from photographs in fashion magazines, professional books and internet sites. In the theoretical study, digital characteristics are limitless repetition, compressibility, interactivity, ease of deformation and mobility. And formative features of digital design are plasticity & geometry, assemblage, joints & connections, transparency and deformation. The results of analysis are as follow. Formative features of fashion design in digital era are classified nonlinearity, variability and hybrid. There are organic relations between digital characteristics and formative features of fashion design as well as between digital characteristics and formative features of digital design. Also, there is significant similarity between formative features of digital design and formative features of fashion design in digital era.

The Characteristics of Bioremediation for VOCs in Soil Column (VOCs처리를 위한 미생물의 토양복원화 특성)

  • 손종렬;장명배
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.9-12
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    • 2002
  • Diffusive transport of volatile organic compounds(VOCs) and their degradation by bacteria in unsaturated soils are couple by poorly understood mass transfer kinetics at the gas/water interface. Determination of the fate of VOCs in unsaturated soil is necessary to evaluate the feasibility of natural attenuation as a VOC remediation strategy. The objective of this study was to develop a mechanistically based mathematical model that would consider the interdependence of VOC transport, microbial activity, and sorptive interaction in a moist, unsaturated soil. Because the focus of the model was on description of natural attenuation, the advective VOC transport that is induced in engineered remediation processes such as vapor extraction was not considered. The utility of the model was assessed through its ability to describe experimental observations form diffusion experiments using toluene as a representative VOC in well-defined soil columns that contained a toluene degrading bacterium, Pseudomonas Putida, as the sole active microbial species. The coefficient for gas-liquid mass-transfer, K$\sub$LA/, was found to be a key parameter controlling the ability of bacteria to degrade VOCs. This finding indicates that soil size and geometry are likely to be important parameters in assessing the possible success of natural attenuation of VOCs in contaminated unsaturated soils.

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Friction and Wear of the Vane/Roller Surfaces Depending on Several Sliding Condition for Rotary Compressor (미끄럼 조건에 따른 로터리 압축기 베인/롤러 표면의 마찰 마멸 특성)

  • Oh Se-Doo;Cho Sung-Oug;Lee Young-Ze
    • Tribology and Lubricants
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    • v.20 no.6
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    • pp.337-342
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    • 2004
  • One of the serious challenges in developing rotary compressor with HFC refrigerant is the prediction of scuffing times and wear amounts between vane and roller surfaces. In this study, the tribological characteristics of sliding surfaces using vane-roller geometry of rotary compressor were investigated. The sliding tests were carried out under various sliding speeds, normal loads and surface roughness. During the test, friction force, wear depth, time to failure and surface temperature were monitored. Because severe wear occurred on vane surface, TiN coating was applied on sliding surfaces to prolong the wear life of vane-roller interfaces. From the sliding test it was found that there was the optimum initial surface roughness to break in and to prolong the wear life of sliding surfaces. Depending on the load and speed, the protective layers, which were composed of metallic oxide and organic compound, were formed on sliding surfaces. Those would play an important role in the amounts of friction and wear between roller and vane surfaces.

A Study on Architectural Expressive Characteristic of 'Structure & Skin Integration' Type in Contemporary Architecture - Focused on the Architecture cases after 2000 - (현대건축에서 구조와 표피 일체화 유형의 건축적 표현특성 - 2000년 이후 건축 사례를 중심으로 -)

  • Lee, Sang-Ho;Ban, Ja-Yuen
    • Korean Institute of Interior Design Journal
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    • v.25 no.4
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    • pp.43-50
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    • 2016
  • This study tries to categorize trends of "structure and skin integration" and understand the expressive characters of each architectural type. To do so, we listed up 8 architects who are quoted twice or more in related researches, then analyzed their 25 contemporary buildings which integrated structure and skin since 2000. As a result, this study defined four types based on the way of building tectonic system of structure and skin. Key feature of "linear structure-two dimensional skin" type is the communication with the surroundings as a result of .geometric architectural forms, patterned surface and reflection. Characters of "linear-three dimensional" type are organic architectural forms, sculptural skin, and the mysterious space. "Planar-two dimensional" type is a transformational geometry form to express the dramatic images through the skin, therefore gives a sense of rhythm and dynamics to space. "Planar structure-three dimensional" type highlights the texture, and exposes boundary of the inside and outside. In architectures we studied, the structure is the way to make a creative forms and space, and the skin to express various meanings. That said, the "structure and skin integration" is the means of aggressive design expression.

A Review of Porous Media Theory from Woltmans Work to Biots Work

  • Park, Taehyo;Jung, Sochan
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.2
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    • pp.93-104
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    • 2003
  • Porous media consist of physically and chemically different materials and have an extremely complicated behavior due to the different material properties of each of its constituents. In addition, the internal structure of porous materials has generally a complex geometry that makes the description of its mechanical behavior quite complex. Thus, classical continuum mechanics cannot explain the behavior of materials with pore spaces, such as concrete, soils and organic materials in waste landfill. For these reasons, porous media theory has been developed in the nineteenth century. Biot had the greatest influence on the development of porous media theory. Biot's work has been referred by many authors in the literature. Development of numerous fundamental equations in porous media theory were made possible due to Biot's work. His contributions made the greatest influence on porous media theory. Therefore, it is highly advantageous to review Biot's publications. This work presents a review of Biot's work. It shows how porous media theory has been developing so far and provides a chance to discuss the contribution of his work to the modern porous media theory.

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Iron(III) removal from aqueous solution using MCM-41 ceramic composite membrane

  • Basumatary, Ashim Kumar;Kumar, R. Vinoth;Pakshirajan, Kannan;Pugazhenthi, G.
    • Membrane and Water Treatment
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    • v.7 no.6
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    • pp.495-505
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    • 2016
  • Mesoporous MCM-41 was deposited on an inexpensive disk shaped ceramic support through hydrothermal technique for ultrafiltration of $Fe^{3+}$ from aqueous solution. The ceramic support was fabricated using uni-axial compaction technique followed by sintering at $950^{\circ}C$. The characteristics of MCM-41 powder as well as the composite membrane were examined by X-ray diffraction (XRD), thermogravimetric analysis (TGA), field emission scanning electron microscope (FESEM), porosity and pure water permeation test. The XRD result revealed the good crystallinity and well-resolved hexagonally arranged pore geometry of MCM-41. TGA profile of synthesized MCM-41 zeolite displayed the three different stepwise mechanisms for the removal of organic template. The formation of MCM-41 on the porous support was verified by FESEM analysis. The characterization results clearly indicated that the accumulation of MCM-41 by repeated coating on the ceramic disk directs to reduce the porosity and pore size from 47% to 23% and 1.0 to $0.173{\mu}m$, respectively. Moreover, the potential of the fabricated MCM-41 membrane was investigated by ultrafiltration of $Fe^{3+}$ from aqueous stream at various influencing parameters such as applied pressure, initial feed concentration and pH of solution. The maximum rejection 85% was obtained at applied pressure of 276 kPa and the initial feed concentration of 250 ppm at pH 2.

Fabrication of Superoleophobic Surface with Anisotropic Wettability Using Silicon Wafer (실리콘 웨이퍼를 이용한 이방성의 젖음성을 가지는 초소유성 표면 제작)

  • Lee, Dong-Ki;Lee, Eun-Haeng;Cho, Younghak
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.23 no.6
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    • pp.533-538
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    • 2014
  • We fabricated grooved mushroom structures with anisotropic wettability on silicon substrates using basic MEMS processes. The geometry of these grooved mushroom structures could be changed by controlling the additional IPA solution during Si etching by TMAH solution. To understand anisotropic wettability, contact angles (CAs) of hexadecane droplets were measured in the orthogonal and parallel directions to grooved lines. The CA measurement results displayed anisotropic wetting on the grooved mushroom structures. However, specimens with $80{\mu}m$ distance between top layers displayed isotropic and superoleophobic wetting. This study demonstrates that the thickness of the top layer is more critical than the width or height of the ridge when determining the wettability of organic solvent. Despite the wide distance between top layers ($80{\mu}m$), the specimen with a thin top layer (100 nm) showed highly anisotropic wetting and low CA due to the pinning of droplets at the edge of the top layer.

Track Deterioration Prediction and Scheduling for Preventive Maintenance of Railroad (궤도 유지보수를 위한 틀림진전 예측 및 일정최적화)

  • Kim, Dae-Young;Lee, Seong-Geun;Lee, Ki-Woo;Woo, Byoung-Koo;Lee, Sung-Uk;Kim, Ki-Dong
    • Proceedings of the KSR Conference
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    • 2008.06a
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    • pp.1359-1370
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    • 2008
  • In the track geometry such as rails, sleepers, ballasts and fastener, track deterioration occurs by repetitive train weight and the high-speed railway takes a trend faster than normal. Track deterioration of over threshold value harms ride comfort and furthermore affect in trains safety seriously. An organic and systematic track maintenance system is very important because a trend of the track deterioration effects on track life-cycle and running safety. Also costs of the railway track permanent way and its maintenance are extremely large, forming a significant part of the total infrastructure expenditure. Therefor reasonable and efficient track maintenance has to be planed on a budget. It is required to carry out not only corrective maintenance but preventive maintenance for the track maintenance. In order to perform maintenance jobs in the boundary of the machines and resources given regarding the type and amount jobs, it is necessary to determine feasible or optimal scheduling considering the priority. In this study, the system organization and required functions for the development of track maintenance system supported track deterioration prediction and optimal scheduling are proposed.

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Origin of Multiple Conductance Peaks in Single-Molecule Junction Experiments

  • Park, Min Kyu;Kim, Hu Sung;Kim, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.654-654
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    • 2013
  • One of the most important yet unresolved problems in molecular electronics is the controversy over the number and nature of multiple conductance peaks in single-molecule junctions. Currently, there are three competing explanations of this observation: (1) manifestation of different molecule-electrode contact geometries, (2) formation of gauche defects within the molecular core, (3) involvement of different electrode surface orientations [1]. However, the exact origin of multiple conductance peaks is not yet fully understood, which indicates our incomplete understanding of the scientifically as well as techno-logically important organic-metal contacts. To theoretically resolve this problem, we previously applied a multiscale computational approach that combines force fields molecular dynamics (FF MD), density functional theory (DFT), and matrix Green's function (MGF) calculations [2] to a thermally fluctuating haxanedithiol (C6DT) molecule stretched between flat Au(111) electrodes, but could observe only a single conductance peak [3]. In this presentation, using DFT geometry optimizations and MGF calculations, we consider molecular junctions with more realistic molecule-metal contact conformations and Au(111) electrode surface directions. We also conduct DFT-based molecular dynamics for the highly stretched junction models to confirm our conclusion. We conclude that the S-Au coordination number should be the more dominant factor than the electrode surface orientation.

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