• Bulletin of the Korean Chemical Society
• /
• v.30 no.7
• /
• pp.1573-1578
• /
• 2009

A computational study of the reactions between Zn-containing species, the products of the thermal decomposition of diethylzinc (DEZn) and water was investigated. The Zn-containing species – $C_2H_5)_2,\;HZnC_2H_5,\;and\;(ZnC_2H_5)_2$ – were assumed to react with water during ZnO metal organic chemical vapor deposition (MOCVD). Density functional theory (DFT) calculations at the level of B3LYP/6-311G(d) were employed for the geometry optimization and thermodynamic property evaluation. As a result dihydroxozinc, $Zn(OH)_2$, was the most probable reaction product common for all three Zn-containing species. A further clustering of $Zn(OH)_2$ was investigated to understand the initial stage of ZnO film deposition. In experiments, the reactions of DEZn and water were examined by in-situ Raman scattering in a specially designed MOCVD reactor. Although direct evidence of $Zn(OH)_2$ was not observed, some relevant reaction intermediates were successfully detected to support the validity of the gas phase reaction pathways proposed in the computational study.

• Journal of the Korean Chemical Society
• /
• v.57 no.6
• /
• pp.712-720
• /
• 2013

Microwave assisted syntheses of Zn(II), Cd(II) and Hg(II) complexes with 3-aminopyridine (3AP) and nitrite ($NO_2{^-}$) ions have been reported. The metal complexes were characterized by elemental analyses, molar conductance, IR, Far-IR, electronic, NMR ($^1H$, $^{13}C$), thermal and electron impact mass spectral studies. The spectroscopic studies reveal the composition, the nature of nitrite ligand in the complexes, electronic transitions, chemical environments of C and H atoms thermal degradation of the complexes. On the basis of characterization data, distorted tetrahedral geometry is suggested for Zn(II), Cd(II) and Hg(II) complexes. The organic ligand (3AP) and their metal complexes were screened against gram negative pathogenic bacteria and fungi in vitro. The results are compared with our previous report J. Korean Chem. Soc. 2013, 57, 341 on 4-aminopyridine and nitrite ion complexes of the same metal ions.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.7 no.1
• /
• pp.34-46
• /
• 2004

Copper films were prepared by using ECR-MOCVD(Electron Cyclotron Resonance Metal Organic Chemical Vapor Deposition) coupled with a DC bias system. The DC bias is connected to the electrode which placed 1∼3cm above the polymer substrate. The pulse electrical field around the electrode attracts the positive charged copper ions generated from the dissociation of copper precursor, $Cu(hfac)_2$, under ECR plasma. Condensation of supersaturated copper ions in the space between the electrode and substrate, makes it possible to deposit copper film on the polymer substrate even at room temperature. In this study, optimization of the electrode configuration was carried out in order to obtain the uniform films. The uniformity of the deposited films were closely related to the parameters of electrode geometry such as electrode shape, thickness, grid size and the spacing between electrodes. The most uniform copper film was observed with the electrode that enabled uniform electrical field distribution across the whole dimension of electrode.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.222-222
• /
• 2010

Transparent semiconductor oxide thin films have been attracting considerable attention as potential channel layers in thin film transistors (TFTs) owing to their several advantageous electrical and optical characteristics such as high mobility, high stability, and transparency. TFTs with ZnO or similar metal oxide semiconductor thin films as the active layer have already been developed for use in active matrix organic light emitting diode (AMOLED). Of late, there have been several reports on TFTs fabricated with InZnO, AlZnSnO, InGaZnO, or other metal oxide semiconductor thin films as the active channel layer. These newly developed TFTs were expected to have better electrical characteristics than ZnO TFTs. In fact, results of these investigations have shown that TFTs with the new multi-component material have excellent electrical properties. In this work, we present TFTs with inverted coplanar geometry and with a novel HfInZnO active layer co-sputtered at room temperature. These TFTs are meant for use in low voltage, battery-operated mobile and flexible devices. Overall, the TFTs showed good performance: the low sub-threshold swing was low and the $I_{on/off}$ ratio was high.

• Bulletin of the Korean Chemical Society
• /
• v.21 no.9
• /
• pp.923-928
• /
• 2000

[FeIII(BBA)DBC]ClO4 as a new functional model for catechol dioxygenases has been synthesized, where BBA is a bis(benzimidazolyl-2-methyl)amine and DBC is a 3,5-di-tert-butylcatecholate dianion.The BBA complex has a structuralfeature that iron cent er has a five-coordinate geometry similar to that of catechol dioxygenase-substrate complex.The BBA complex exhibits strong absorptionbands at 560 and 820 nm in CH3CN which are assigned to catecholate to Fe(III) charge transfer transitions. It also exhibits EPR signals at g = 9.3 and 4.3 which are typical values for the high-spin FeIII (S = 5/2) complex with rhombicsymmetry. Interestingly, the BBA complex reacts with O2 within an hour to afford intradiol cleavage (35%) and extradiol cleavage (60%) products. Surprisingly, a green color intermediate is observed during the oxygenation process of the BBA com-plex in CH3CN. This green intermediate shows a broad isotropic EPR signal at g = 2.0. Based on the variable temperature EPR study, this isotropic signalmight be originated from the [Fe(III)-peroxo-catecholate] species havinglow-spin FeIII center, not from the simple organic radical. Consequently,it allows O2 to bind to iron cen-ter forming the Fe(III)-superoxide species that converts to the Fe(III)-peroxide intermediate. These present data can lead us tosuggest that the oxygen activation mechanism take place for the oxidative cleavingcatechols of the five-coordinate model systems for catechol dioxygenases.

• Journal of Korean Society of Forest Science
• /
• v.90 no.4
• /
• pp.450-457
• /
• 2001

This study aimed to clarify the influencing site factors of the mesopore ratio on a pore geometry of surface soil in deciduous stands as an index of the water retention capacity. Fifteen factors including site conditions and soil properties were analyzed by spss/pc+ for the data collected during March to October of 1994. The factors influencing the mesopore ratio(pF2.7) on the surface soil were as follows; tree height, under vegetation coverage and organic matter contents of soil. And influencing factor on the ratio of mesopore in the soil surface was correlated with surface soil hardness shows high negative significance. Also, multiple regression equations for mesopore ratios of surface soil hardness, organic matter contents of soils show high significance($R^2=0.84$). In deciduous stands, it is effective in promoting development on the ratio of mesopore that forest practice for enhancing of the water resource retention capacity should be carried out when the under vegetation coverage rates of stands are maintained from 30 to 80 percentages.

• Journal of Mechanical Science and Technology
• /
• v.18 no.9
• /
• pp.1680-1688
• /
• 2004

The information indicating device plays an important part in the information times. Recently, the classical CRT (Cathod Ray Tube) display is getting transferred to the LCD (Liquid Crystal Display) one which is a kind of the FPDs (Flat Panel Displays). The OLED (Organic Light Emitting Diodes) display of the FPDs has many advantages for the low power consumption, the luminescence in itself, the light weight, the thin thickness, the wide view angle, the fast response and so on as compared with the LCD one. The OLED has lately attracted considerable attention as the next generation device for the information indicators. And also it has already been applied for the outside panel of a mobile phone, and its demand will be gradually increased in the various fields. It is manufactured by the vapor deposition method in the vacuum state, and the uniformity of thin film on the substrate depends on the temperature distribution in the point-cell source. This paper describes the basic concepts that are obtained to design the point-cell source using the computational temperature analysis. The grids are generated using the module of AUTOHEXA in the ICEM CFD program and the temperature distributions are numerically obtained using the STAR-CD program. The temperature profiles are calculated for four cases, i.e., the charge rate for the source in the crucible, the ratio of diameter to height of the crucible, the ratio of interval to height of the heating bands, and the geometry modification for the basic crucible. As a result, the blowout phenomenon can be shown when the charge rate for the source increases. The temperature variation in the radial direction is decreased as the ratio of diameter to height is decreased and it is suggested that the thin film thickness can be uniformed. In case of using one heating band, the blowout can be shown as the higher temperature distribution in the center part of the source, and the clogging can appear in the top end of the crucible in the lower temperature. The phenomena of both the blowout and the clogging in the modified crucible with the nozzle-diffuser can be prevented because the temperature in the upper part of the crucible is higher than that of other parts and the temperature variation in the radial direction becomes small.

• Journal of Korean Society of Forest Science
• /
• v.90 no.3
• /
• pp.314-323
• /
• 2001

This study aimed to clarify the influencing factors of mesopore ratio on a pore geometry of surface soil in coniferous stands as an index of the water retention capacity. Twenty three factors including site conditions and soil properties were analyzed by spss/pc + for the data collected during March to October of 1993. The factors influencing the mesopore ratio(pF2.7) on the surface soil were as follows; macropore ratio(pF1.6), slope, crown-cover rates, thickness of F layer, organic matter contents, and the growing stock. And influencing factor on the ratio of mesopore in the soil surface was correlated with percentage of amount of clay, soil surface, A and B horizon soil hardness shows high negative significance. Also, multiple regression equations for mesopore ratios of surface soil and surface soil hardness, clear length, growing stock, B horizon of soil hardness, organic matter contents show high significance($R^2$; 0.80). In coniferous stands, it is effective in promoting development on the ratio of mesopore that forest practice for enhancing of the water resource retention capacity should be carried out when the crown-cover rates of stands are more than 80 percentages.

• Journal of Educational Research in Mathematics
• /
• v.25 no.2
• /
• pp.225-240
• /
• 2015

In this study, we investigated the representativeness of proofs in school mathematics, based on the extension of the midpoint connector theorem for the quadrilateral. To this end, we considered a variety of quadrilateral and proved their extensions of the midpoint connector theorem, and identified the relationships between them, therefore seemed that the proof in school mathematics has a representativeness. On the other hand, in the survey based on this information, students were found only some types of quadrilateral and completed easily the proofs for each quadrilateral they found, but students tended to use other proof or mathematical concepts, if the target figures changes in despite of proving the same mathematical fact. Thus, students were more difficult to figure out the relationship between the proofs. From these facts, we know that students are poorly understood the representativeness of proofs to understand the relationship between concrete proofs and to generalize it, though they are able to proof to the specific figures. Therefore it can be seen that the proof activity needs to be done with organic and semantic.

• The KSFM Journal of Fluid Machinery
• /
• v.19 no.6
• /
• pp.50-54
• /
• 2016

The performance of a scroll expander is the most important factor for the efficiency of small scale Organic Rankine cycle waste heat power generation systems. In this research, a scroll compressor was purchased and operated in reverse to function as a scroll expander. With air as a working fluid, a series of performance test were conducted on this expander by varying the inlet and outlet pressure. Secondly, We have tested through 2000 to 3500 rpm rotational speed to find the maximum power and efficiency of the expander. And last, It was observed in the initial experiments that the design of the expander's orbiting scroll wrap partially blocked the fluid intake which may have caused unnecessary flow resistance. To verify this theory, a small part of the scroll wrap was removed and the performance test was redone. It was observed that the lower back pressure assure the higher efficiency and power of expander and the rotational speed that shows maximum adiabetic efficiency of scroll expander is 69% at 2500 rpm. And by modified wrap of the scroll, we could get volume flow rate for 13% to 19% and power for 5% to 18% increased. But the maximum efficiency of the modified scroll was decreased 8%.