• 제목/요약/키워드: Organic electroluminescence

검색결과 175건 처리시간 0.025초

PVK 유기 EL에서 Stibenequinone 유도체의 광학적 특성 (Optical properties of Stibenequinone derivatives in PVK organic electroluminescence)

  • 조종래;유정이;양종헌;신상식;손세모;정수태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1047-1049
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    • 2003
  • Stibenequinone(SQ) derivative which was electronic transportation materials in Poly(N-vinylcarbazole) (PVK)-based on organic EL and an optical characteristic of organic EL which is mentioned previously was investigated. The Photoluminescence highest pick with blending TBSQ with PVK was shifted from 439nm to 517nm. This result indicates that an energy gap of a PVK/TBSQ blended sample is less than an energy gap of PVK. According to the electrochemistry characteristic, the ionization energy(Ip) and the electro affinity(Ea) decreased from 5.79eV to 5.63eV and 2.23eV to 2.63eV, respectively.

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New Conjugated Polymer Based on Dihydroindoloindole for LEDs

  • Jin, Yeong-Eup;Kim, Kwang-hyun;Song, Su-hee;Kim, Jin-woo;Kim, Jae-hong;Park, Sung-Heum;Lee, Kwang-hee;Suh, Hong-suk
    • Bulletin of the Korean Chemical Society
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    • 제27권7호
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    • pp.1043-1047
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    • 2006
  • New electroluminescence polymer, poly(5,10-dihexyl-5,10-dihydroindolo[3,2-b]indole-2,7-diyl) (PININO) was synthesized by Yamamoto conditions with Ni(0) catalyst. The full characterization of structures and properties as well as the performances of the electroluminescence devices of the new polymer are presented. The resulting polymer, which exhibits good solubility in common organic solvents, was used as the electroluminescence layer for the light-emitting diodes (LEDs) (ITO/PEDOT/polymer/Al). PININO shows turn-on voltage of 2.5 V, and electroluminescence (EL) with maximum peak at 490 nm, maximum brightness of 40 cd/$m^{2}$ at 8 V, and efficiency of 0.002 cd/A at 350 mA/$cm^{2}$.

가변입사각 분광타원 법을 이용한 유기 발광 박막의 광학상수 및 두께 결정 (Determination of optical constants and thickness of organic electroluminescence thin films using variable angle spectroscopic ellipsometry)

  • 김상열;류장위;김동현;정혜인
    • 한국광학회지
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    • 제12권6호
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    • pp.472-478
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    • 2001
  • 가변입사각 분광타원법(Variable Angle Spectroscopic Ellipsometry)을 사용하여 유기발광소자(OLED)의 발광층인 유기박막 의 광학상수와 두께를 결정하였다. 광투과영역에서 모델링분석으로 박막의 평균두께와 굴절률 분산식을 결정하고, 광흡수영역으로 확장하여 유기막의 다층구조, 각 층의 두께와 밀도 그리고 각 파장에서의 복소굴절률을 결정하였다. 분광광도계를 사용하여 구한 투과율 스펙트럼을 가변입사각 분광타원법을 사용하여 결정한 다층구조 및 복소굴절률로 계산한 투과율 스펙트럼과 비교하여 분석의 정확성을 확인하였다.

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Alq$_3$ 박막의 전기전도와 발광특성 (Electroluminescence Characteristics and Electrical Conduction of Alq$_3$ thin film)

  • 이청학;유선규;이종찬;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.439-442
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    • 1998
  • In this paper, organic thin film LED(light emitting diode) having ITO glass/Alq$_3$/Al structure using an Alq$_3$ was fabricated by the vacuum evaporation and the absorbance, wave length, I-V characteristics were investigated, Electroluminescence of green and wavelength of 510[nm] were observed in this device. We observed absorbance form 320[nm] to 430[nm] and knew unstability of Alq$_3$ material as light emitting device.

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다층구조를 갖는 유기박막의 발광 및 전자물성 (Electroluminescence and Electronic properties of multi1ayer organic Thin Film)

  • 이청학;김정태;박복기;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.792-794
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    • 1998
  • The TPD and the $Alq_3$ film are widely used as a hole transport layer and an emitter layer respectively, in organic electroluminescent(EL) device (ITO Glass/TPD/$Alq_3$/metal). In this structure, we fabricated two models. Model(1) having ITO glass/$Alq_3$/Al structure and model(2) having ITO Glass/TPD/$Alq_3$/Al structure were fabricated by the vacuum evaporation. The comparison between model(1) and model(2) was made about the absorbance, the wave length, the current-voltage characteristic and the ln I - $V^{(1/2)}$characteristic respectively. Electroluminescence of green and wavelength of 510[nm] were observed in both model. We observed absorbance from 320[nm] to 430[nm] in $Alq_3$ material and from 250[nm] to 400[nm] in TPD material.

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LB법에 의해 제작된 유기소자의 녹색 발광특성에 관한 연구 (A Study on the Green Emission Characteristics of Organic Device Produced by LB Method)

  • 전동규;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.506-509
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    • 2002
  • In this paper. we give pressure stimulation into organic ultra thin films and detected the induced displacement current proper ties, and then manufacture a device under the accumulation condition. In processing of a device manufacture. And electroluminescence(EL) from conjugated polymers has recently received great attention because polymer light-emitting diodes(LEDs) clealy have potential for applications such as large-area displays. The operation of polymer LEDs is based on double injection of electrons and holes from the elextrodes. followed by formation of excitons whose radiative decay results in light emission at wavelength characteristic to the material. In this paper, we fabricated the single layer EL device using $Alq_3$ as emitting material. According as turn on voltage could know about 5.5V in voltage-current characteristics and voltage rise, current could see that increase as non-linear, Current and ruminance can see that express similar relativity in voltage, and could know that ruminance is expressing current relativity.

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유기 EL용 청색 발광 히드라존 유도체의 합성 (Synthesis of Blue Emission Hydrazone Derivatives for Organic Electroluminescence)

  • 정평진;임회득
    • 한국재료학회지
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    • 제13권8호
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    • pp.514-518
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    • 2003
  • As a fundamental study on organic electroluminescence(EL), blue emitting materials were synthesized and characterized. Individual blue colored hydrazone derivatives were synthesized from the reaction of aldehydes (phthalaldehyde, isophthalaldehyde) with the corresponding amnios (1-methyl -1-phenylhydrazine, 1,1-diphenylhydrazine hydrochloride). Recrystallization of hydrazones from chloroform revealed the melting temperature within $142∼156^{\circ}C$. Photoluminescence(PL) analysis on each hydrazone showed that emission range were blue(458∼478 nm). The structure of obtained hydrazones were elucidated by FT-IR, $^1$H-NMR and C, H, N elemental analyzer.

전기발광고분자의 양자효율 측정 (Determination of photo- and electroluminescence quantum efficiency of semiconducting polymers)

  • 이광희;박성흠;김진영;진영읍;서홍석
    • 한국광학회지
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    • 제13권2호
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    • pp.128-133
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    • 2002
  • 최근 주목을 받고 있는 고분자 발광다이오드의 개발에 있어서, 발광고분자의 Photoluminescence(PL)와 Electroluminescence (EL) 양자효율 측정은 소자의 성능개선 연구 등에 있어서 가장 핵심적인 요소 중 하나로 여겨진다. 이러한 이유에서 본 연구에서는 잘 알려진 발광고분자인 Poly(2-methoxy-5(-(2-ethyl-hexyloxy)- 1,4-phenylenevinylene) (MEH- PPV)를 이용하여 시편을 제작하고, 적분구 측정법을 이용하여 이의 P교라 EL 양자효율을 구하였다. 그 결과 본 연구진이 개발한 MEH-PPV의 PL 양자효율은 8$\pm$2%로 측정되었는데, 이는 세계적으로 알려져 있는 ~9%의 결과에 거의 접근함을 보였다. 한편, 이 물질을 이용하여 고분자 발광다이오드를 제작한 결과, 이의 EL양자효율은 0.02 1m/W로 측정되었다. 본 연구를 통하여 확립된 발광고분자의 양자효율 측정법은 국내의 유기발광소자 연구에 큰 기여를 하리라 기대된다.