• 제목/요약/키워드: Organic complex

검색결과 1,011건 처리시간 0.027초

대기중 복합물질의 돌연변이원성과 인체 위해도 (Health Risk of Airborne Complex Mixtures Based on their Mutagenicity)

  • 박성은;정용
    • 한국대기환경학회지
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    • 제12권3호
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    • pp.269-278
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    • 1996
  • Airborne suspended particulates were collected by an Andersen high volume air sampler in a traffic area of Seoul from September 1990 to August 1991. Origanic matter extracted from particulates, their fractions, namely acidic, basic, neutral and carcinogenic subfractions (PAHs, nitroarenes) in neutral fractions were assayed for mutagenicity on TA98, TA100 and TA98NR deficient Salmonella strains, use of the pre-incubation method. The relative contribution to total mutanenicity of organic matters was highest in neutral fraction and was lowest in basic fraction. Among subfractions, that of neutral fraction was higher nitroarenes subfraction compared to PAHs subfraction. While the carcinogenic effect of benzo[a]pyrene was calculated as 0.96 persons/million persons based on unit risk estimates by extrapolation method, life time excess cancer risk estimate of EOM, neutral, PAH fraction based on their mutagenicity was calculated as 52, 42, 3.8 persons/million persons, respectively. These findings indicate that the mutagenic hazard of the partciculate, air organic complex mixture, may be dependent upon the mutagen composition in the particulate and interactions each of them. Therfore, health risk from air organic complex mixtures based on mutagenicity might be useful indicator for evaluation of actual risk.

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복합 유기혼합물체로부터 휘발성이 서로 다른 세 유기화합물 그룹의 분리 농축방법의 연구 (Isolation and Concentration of Organic Components from a Complex Matrix into Three Fractions of Different Volatilities)

  • 김경례
    • 대한화학회지
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    • 제25권1호
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    • pp.30-37
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    • 1981
  • 복합 유기혼합체로부터 휘발성이 다른 세 그룹을 분리 농축할 수 있는 간단한 소형장치가 고안되었다. 이 장치를 사용하여 휘발성이 높은 유기성분들은 테넥스지씨에 헤드스페이스 트랩핑하고 남은 시료를 유기용매로 용출하여 얻어진 용출들을 휘발성 및 비휘발성 그룹으로 분리 농축할 수 있었다. 얻어진 휘발성 성분그룹은 고성능 캐리러리 가스크로마토그래피로 분석하였고, 비휘발성 성분그룹은 고성능 액체크로마토그래피에 의해서 분석하였다. 상세한 실험방법 및 유기 혼합물질인 잎담배를 시료로 사용하여 얻어진 분석 결과가 언급되어 있다.

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Ir 착화합물을 이용한 유기발광소자의 특성연구 (The study on the characteristics of organic light emitting devices using Ir)

  • 김준호;표상우;정래영;하윤경;김영관;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.214-217
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    • 2002
  • The internal quantum efficiency of organic light emitting devices(OLEDs) using fluorescent organic materials is limited within 25% because of the triplet excitons which can hardly emit light. So there has been considerable interest in finding ways to obtain light emission from triplet excitons. One approach has been to add phosphorescent compounds to one of the layers in OLEDs. Then triplet excitons can transfer to these phosphorescent molecules and emit light. In this study, multilayer OLEDs with phosphorescent emitter, Iridium complexes were prepared. The devices with a structure of ITO/TPD/Ir complex doped in the host material/Alq3/Li:Al/Al were fabricated, and its electrical and optical characteristics were studied. Using various Ir complexes and the host materials, we fabricated several devices and investigated the device characteristics.

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유기 발광 소자의 바이어스 전압에 따른 유전 특성 (Dielectric Properties depending on Bias Voltage in Organic Light-emitting Diodes)

  • 오용철;이준웅
    • 한국전기전자재료학회논문지
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    • 제18권11호
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    • pp.1038-1042
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    • 2005
  • We have investigated dielectric properties depending on bias voltage in organic light-emitting diodes using 8-hydroxyquinoline aluminum $(Alq_3)$ as an electron transport and emissive material. We analyzed the dielectric properties of organic light-emitting diodes using impedance of characteristics. Impedance characteristics was measured complex impedance Z and phase $\theta$ in the frequency range of 40 Hz to $10^8$ Hz. We obtained complex electrical conductivity, dielectric constant, and loss tangent $(tan\delta)$ of the device at room temperature. From these analyses, we are able to interpret a conduction mechanism and dielectric properties contributed by an interfacial and orientational polarization.

액체 레이저 매질로서의 신물질 Yb(HFA-D)$_3$착물의 개발 (Development of Yb(HFA-D)$_3$Complexes for Liquid Laser Material)

  • 김정호;박용필
    • 한국전기전자재료학회논문지
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    • 제13권12호
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    • pp.1045-1050
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    • 2000
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(HFA-D)$_3$]complexes were synthesized by the keto-enol tautomerism reaction of Yb(HFA-H$_3$) in methanol-d$_4$in rder to reduct the radiationless transition to the ligands. The luminescence properties of Yb(HFA-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescnce in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(HFA-D)$_3$complex.complex.

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A Study on the Synthesis of Organophilic [TEACOOH]-Montmorillonite Intercalations Complex and its Swelling Properties

  • Cho, Sung-Jun
    • 한국세라믹학회지
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    • 제39권5호
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    • pp.427-432
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    • 2002
  • In this research an organic cation, [TEACOOH] Br, with a long alkyl chain was synthesized which will replace the metal ion between the layers of Na-Montmorillonite and an organophilic [TEACOOH]-Montmorillonite intercalations complex was formed by the cation exchange reaction between the Na-Montmorillonite and the synthesized [TEACOOH] Br. After drying of this intercalations complex in high vacuum we have tried to experiment on the probability whether it will form complexes with various swelling solutions such as dist. water, methano, ethanol, toluene, acetonitrile and propionitrile and the corresponding basal sp acings measured were $17.41{\AA}$, $31.90{AA}$, $34.42{AA}$, $30.52{AA}$ and $32.36{AA}$, respectively.

온도에 따른 유기발광소자의 임피던스 분석 (Impedance spectrosocpy depending on temperature in Organic Light-Emitting Diodes)

  • 안준호;정동회;장경욱;송민종;이성일;이준웅;김태완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.543-546
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    • 2004
  • Bias and frequency-dependent impedance is a technique for the investigation of complex conductivity. At low frequency, complex impedance is dominated by resistive component, and at high frequency by capacitive component. We are going to present the results of the bias and frequency-dependent complex impedance in the device structure of $ITO/Alq_3/Al$ in the temperature range between 10K and 300k. And we will show to change radius of Cole-Cole plot. It will be decrease resistance by temperature. Also equivalent electrical circuit and dielectric relaxation can be accomplished by using the complex impedance analysis.

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농업.농촌의 미래발전모델 연구 (A Study on Developing Model of Agriculture in Korea)

  • 윤성이
    • 한국유기농업학회지
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    • 제18권4호
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    • pp.511-526
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    • 2010
  • We need fundamental plan to develop Environment-friendly agriculture which has essential effect to agriculture and rural community. It should be avoided the structural problem that the farming corporations has gone through in present. Firstly, it needs to be systematized and constructed farming complex for the priority. The government initiated Environment-friendly agriculture business and expanded agriculture business as the part of the policy. There are some researches which have been studied the systematization and the construction of farming complex. It is suggested and mentioned various kinds of policies and directions so far. But, it is not mentioned any practical models. That means it seems to be various differences between each farming corporations in the structural cases. This research suggests the most optimized model of Environment-friendly agriculture by analyzing structural differences between 'Natur' farming Corp and 'Sancheong-gun' expanded Environment-friendly farming complex.

Alum과 PACl을 이용한 응집처리 (Chemical Coagulation Treatment Using Alum and PACl in Complex Wastewater)

  • 성일화
    • 한국환경보건학회지
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    • 제35권1호
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    • pp.53-57
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    • 2009
  • In order to treat the complex wastewater containing organic compound and solids, pre-treatment system associated with molecular separation process were investigated. The reductions of COD and turbidity were obtained after coagulation processes using Alum (Aluminium sulfate, $Al_2(SO_4)_2{\cdot}18H_{2}O$) and PACl (poly aluminium chloride as 17% $Al_{2}O_{3}$). The results of study were as follows: using variable dosage of Alum, COD removal was highest at 4,000 mg/l, and the reduction of COD and turbidity was 42% and 92%, respectively. The optimum coagulation would be effective at pH 7.3 than pH 9.0 by the addition of alum at a concentration of 6,000 mg/l and PACl was add at 4.25% in raw complex wastewater with 2,000 mg/l alum at pH 7.3, the reduction of COD was reduced by 32%. But coagulation aid experiments indicated that PACl would be more effective in sludge separation ability than COD removal efficiency.

고출력, 고효율 실현을 위한 새로운 레이저매질 개발 (Development of New Laser Material for High Power and High Efficiency)

  • 김정호;박용필
    • 한국전기전자재료학회논문지
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    • 제14권11호
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    • pp.928-933
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL-D)$_3$] complexes are synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$ in methanol-d$_4$ in order to reduce the radiationless transition to the ligands for the high power solid state laser material. The luminescence properties of Yb(SOL-D)$_3$ complex are measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$ and DMSO-d$_{6}$. The Luminescence intensity, lifetime and quantum efficiency in DMSO-d$_{6}$ are superior to those in other deuterated solvents. It is suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the laser material of Yb(SOL-D)$_3$ complex.complex.

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