[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.4191/KCERS.2002.39.5.427

A Study on the Synthesis of Organophilic [TEACOOH]-Montmorillonite Intercalations Complex and its Swelling Properties

Cho, Sung-Jun (Division for Advanced Matrials Engineering, Paichai University)

Publication Information

Journal of the Korean Ceramic Society / v.39, no.5, 2002 , pp. 427-432 More about this Journal

Abstract

In this research an organic cation, [TEACOOH] Br, with a long alkyl chain was synthesized which will replace the metal ion between the layers of Na-Montmorillonite and an organophilic [TEACOOH]-Montmorillonite intercalations complex was formed by the cation exchange reaction between the Na-Montmorillonite and the synthesized [TEACOOH] Br. After drying of this intercalations complex in high vacuum we have tried to experiment on the probability whether it will form complexes with various swelling solutions such as dist. water, methano, ethanol, toluene, acetonitrile and propionitrile and the corresponding basal sp acings measured were $17.41{\AA}$ , $31.90{AA}$ , $34.42{AA}$ , $30.52{AA}$ and $32.36{AA}$ , respectively.

Keywords

Na-Montmorillonite; Organic cation; Intercalations complex; Cation exchange reaction; Swelling solutions;

Citations & Related Records

Reference

1	K. Kuhn and A. Weiss, 'Investigations of the Capability of Solvents by the Organophilic Bentonites(in Ger.),' Schrift-enreihe Angew. Geol. Karlsruhe 4 141-59 (1988)
2	S. J. Cho and J. O. Kim, 'A Study of Intercalations-com-plexes of Montmorillonite as Model-systems (I)(in Kor.),' The J. of Nat'l Sci., Pai Chai Uniniversity, 5 [1] 77-86 (1992)
3	S. J. Cho, Y. S. Ko, I. G. Kim and W. C. Oh, 'A Study of Intercalations-complexes of Montmorillonite as Model-sys-tems (II)(in Kor.),' J. Kor. Ceram. Soc., 30 [4] 269-64 (1993)
4	S. J. Cho, 'A Study of Intercalations-complexes of Montmo-rillonite as Model-systems (III)(in Kor.),' J. Kor. Ceram. Soc., 38 [5] 431-37 (2001)
5	Z. Wang and T. J. Pinnavaia, 'Hybrid Organic-inorganic Nanocomposites: Exfoliation of Magadiite Nanolayers in an Elastomeric Epoxy Polymer,' Chem. Mater., 10 1820-26 (1998) DOI ScienceOn
6	X. Fu and S. Qutubuddin, 'Synthesis of Polystyrene-clay Nanocomposites,' Mater. Latte., 42 12-5 (2000) DOI ScienceOn
7	Organikum, 2. berichtigter Nachdruck der 15. bearbeiteten Auflage, Veb Deutscher Verlag der Wissenschaften Berlin (1981), s. 499
8	J. O. Kim, T. N. Kim and S. J. Cho, 'A Study on the Syn-thesis of Organophilic [RC00H]-Montmorillonite and on Its Swelling Behavior(in Kor.),' J. Kor. Ceram. Soc., 31 [3] 282-90 (1994)
9	C. J. Pouchert, 'The Aldrich Library of Infared Spectra,' Edition 3, Band 1
10	H. Messe u. H. Meier u. B. Zeeh, 'Spekroskopische Meth-ode in der Organ. Chemie,' 2nd Edition, Georg Thieme Ver-lag, 1984
11	H. Guenzler u. H. Boeck, 'IR-spektroskopische Chemie,' $Physi\kappa$ Verlag, 213-17 (1975)
12	J. X. Li, J. Wu and C. M. Chan, 'Thermoplastic Nanocom-posites,' Polymer, 41 6935-37 (2000) DOI ScienceOn
13	U. Hofmann, 'From the Chemistry of Clays,' Angew. Chem., 80 [18] 736-47 (1968) DOI
14	M. I. Rozengart, G. M. Vyunova and G. V. Isagulyants, 'Layered Silicates as Catalysts,' Russian Chem. Reviews, 57 [2] 115-28 (1988) DOI ScienceOn
15	A. Weiss, 'Organic Derivatives of Mica-type Layer-sili-cates(in Ger.),' Angew. Chem., 75 113-48 (1963) DOI
16	J. W. Gilman, 'Flammability and Thermal Stability Stud-ies of Polymer Layered-silicate (Clay) Nanocomposites,' Applied Clay Sci., 15 31-49 (1999) DOI ScienceOn
17	X. Kornmann, H. Lindberg and L. A. Berglund, 'Synthesis of Epoxy-clay Nanocomposites,' ANTEC '99, 1623-27
18	H. Wiberg, 'Textbook of Inorganic Chemistry(in Ger.),' pp91-100, Berlin; New $Yor\kappa ;$ de Gruyter, 1985
19	G. Lagaly and A. Weiss, 'Arrangement and Orientation of Cationic Tenside on Silicate Surfaces (IV. Arrangement of n-Alkylammonium Ions in Case of Low Loaded Layer Sili-cates(in Ger.)),' Kolloid-Z. u. Z. Polymere, 243 48-55 (1971) DOI
20	U. Hofmann, 'From the Chemistry of High Swellable C1ays(in Ger.),' Angew. Chem., 68 [2] 53-80 (1956) DOI
21	K. Kuhn, 'Influence on Sorption Properties of Organophilic Bentonites(in Ger.),' Diplomarbeit, University of Munich 1985