• 제목/요약/키워드: Organic complex

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유기전하이동착체 랭뮤어-블로젯 초박막의 광전도 특성 (Photoelectric Properties of Organic Charge Transfer Complex Langmuir-Blodgett Ultra Thin Films)

  • 정순욱
    • 한국응용과학기술학회지
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    • 제18권1호
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    • pp.49-54
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    • 2001
  • Ultra-thin films of organic charge transfer complex were prepared on a hydrophilic substrate by Langmuir-Blodgett(LB) technique. In this study, the photoelectric properties of a LB film consisting of (N-docosyl quinolinium)-TCNQ(1:2) complex was investigated. The visible light(${\lambda}$ : 700 nm) of xenon lamp was illuminated on the LB films and light absorptivity and photoconductivity were observed. The photocurrent increased linearly and was saturated at the light intensity of 23 ${\mu}W/cm^{2}$.

난각칼슘의 제조 조건 및 유기산이 칼슘의 이온화에 미치는 영향 (Preparation of Calcium Powder from Eggshell and Use of Organic Acids for Enhancement of Calcium Ionization)

  • 신형순;김공환
    • Applied Biological Chemistry
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    • 제40권6호
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    • pp.531-535
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    • 1997
  • 폐기물로 버려지고 있는 난각에 다량으로 포함되어 있는 칼슘을 효율적으로 회수하고, 이온화 정도를 높일 수 있는 방법을 조사하였다. Ball mill을 이용해 난각을 분쇄해 물속에서 비중의 차이를 이용하여 난각분을 얻었고, 회전속도 30 rpm, 체류시간 30분, volume fraction 0.08에서 가장 높은 난막 제거 효과를 보였다. 난각분을 전기로에서 회화시켜 얻은 난각칼슘분의 백색도를 측정해 L값이 90이상에 도달하는 시간은 전기로 온도 850, 900, $1000^{\circ}C$에서 각각 14, 9, 3시간이 소요 되었으며, 난각칼슘분의 Hausner ratio는 1.43으로 조사되었다. 난각칼슘분은 물, 초산, 구연산, 젖산$(0.05{\sim}3%)$ 용액에서 각각 990, 3500, 3900, 4200 ppm의 이온화 정도를 나타내었다. Calcium-citrate-malate complex(CCM), calcium-citric acid complex(CC), calcium-malic acid complex(CM)는 물에서 이온화 정도가 난각칼슘분에 비해 약 4-5배 증가 하였다.

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Preparation and Characterization of Electrospun TiO2-Activated Carbon Complex Fiber as Photocatalyst

  • Jung, Min-Jung;Jeong, Eui-Gyung;Jang, Jeen-Seok;Lee, Young-Seak
    • Carbon letters
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    • 제11권1호
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    • pp.28-33
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    • 2010
  • In this study, $TiO_2$-Activated carbon (AC) complex fibers were prepared by electrospinning for the synergetic effect of adsorption and degradation of organic pollutant. The average diameter of these fibers increased with increasing the amount of AC added, except for 1AC-TOF (AC$/TiO_2$ =1/40 mass ratio). After calcinations at $500^{\circ}C$, long as-spun fibers were broken and their average diameter was slightly decreased. The resultant fibers after calcination had rough surface and sphere shapes like a peanut. From XRD results, it was confirmed that as-spun fibers were changed to anatase $Ti_O2$ fiber after calcinations at $500^{\circ}C$. The prepared $TiO_2$-AC complex fibers could remove procian blue dyes by solar light irradiation with high removal property of 94~99%. The PB dye was rapidly removed by adsorption during the initial 5 minutes. But after 5 minutes, dye removal was occurred by photodegradation. In this study, the most efficient AC/$TiO_2$ ratio of $TiO_2$-AC complex fibers was 5/40, showing the synergetic effect of adsorption and photodegradation. It is expected that the $TiO_2$-AC complex fibers can be used to remove of organic pollutants in water system.

Korean consumers' attitudes towards organic labels and country-of-origin of organic foods

  • Lee, Hye-Kyoung;Cho, Young-Sang
    • 유통과학연구
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    • 제9권1호
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    • pp.49-59
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    • 2011
  • Although the South Korean organic food market is in the infancy compared to other industrialized countries, Korean consumers'interest in organic food and retail stores devoting space to organic products have been rapidly increasing. Despite the fact of organic food popularity, the term "organic" is interpreted differently by individuals. As opposed to the US, Japan and the EU where have operated an integrated organic food labelling system, Korea has adopted complex organic labelling systems regulated by several different government bodies. As a result, complicated food labelling standards make consumers confused when purchasing organic foods. Furthermore, in terms of country of origin (COO), it is argued by a lot of researchers that COO effects vary from product to product and from country to country; moreover, other informational cues such as brand and price can influence COO effects. In modern society, COO labelling has been complicated, due to the sourcing, manufacturing and market locations of merchandise spread over the world. Accordingly, the evaluation of COO effects has become complex. In order to examine these issues, a quantitative research was selected to classify the commonfeatures of organic food consumers and construct statistics such as the extent to which people are aware of organic food and COO labellingvia a questionnaire which took place in two cities in Korea with a cluster sample of 161 organic food purchasers. As for the data analysis, one-way analysis of variance (ANOVA), T-tests, bivariate crosstatulations with Cramer's V were conducted,depending on the characteristics of variables and the assumptions the research data need to fit. It has been concluded that in general, Korean organic consumers comprehend the term "organic"in a closer way to the general concept rather than technical term, thus people do not appreciate environmentally labels which include organic food labels, although marital status influence the degree of label awareness, regardless of gender, age, education level and so on. Regarding COO effects on organic food, home organic products were Korean consumers'first choice over those from industrialized countries and developing nations. Specifically, in processed organic product category, domestically cultivated and processed organic products were absolutely preferred to leading national brands produced with imported ingredients and international brands. However, due to a lack of checks of ingredients' COO, consumers tend to purchase a leading national organic food brand, believing that it is a pure organic food sourced domestically. As a consequence, this research has suggested some important managerial implications and future research directions. In order to prevent consumer confusion when buying organic foods, it should be noted that consumers do not comprehend the organic food certifications, due to complicated labelling systems for organic produce and processed organic foods. Therefore, government bodies related to organic food distribution have to know consumers' perception of organic food labels and the significance of customer-oriented labels and reestablish labelling standards. Similarly, public advertising should be followed to raise public awareness of the labelling to enable customers to have the correct information. In addition, not only international marketers but also domestic marketers need to understand COO images and also the influence COO of ingredients has on the image of an organic product.

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산화물 표면의 U(VI) 흡착에 미치는 살리실산과 피콜린산의 영향 (Effect of Salicylic and Picolinic Acids Acids on the Adsorption of U(VI) onto Oxides)

  • 박경균;정의창;조혜륜;송규석
    • 방사성폐기물학회지
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    • 제7권4호
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    • pp.219-227
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    • 2009
  • 세 종류의 산화물($TiO_2$(아나타제), $SiO_2$(비결정성) 및 $Al_2O_3$(비결정성)) 표면에 U(VI)이 흡착될 때 유기산이 미치는 영향을 연구하였다. 유기산으로는 살리실산과 피콜린산을 사용하였다. 유기산의 존재 여부에 따라 달라지는 U(VI)의 흡착률 변화를 pH 함수로 측정하였다. 또한 U(VI)의 존재 여부에 따라 달라지는 유기산의 흡착량을 pH 함수로 측정하였다. $TiO_2$의 경우, 살리실산과 피콜린산이 U(VI)과 수용성 착물을 형성함으로써 U(VI)의 흡착률을 저하시킨다. $SiO_2$의 경우, 살리실산은 U(VI) 흡착에 영향을 주지 않지만, 피콜린산은 오히려 U(VI) 흡착을 증가시킨다. 이 현상을 삼성분 표면착물(ternary surface complex) 생성으로 해석하였으며 U(VI) 흡착에 의존하는 피콜린산의 흡착량 변화, 그리고 흡착된 U(VI)의 형광 특성 변화로 이를 확인하였다. $Al_2O_3$의 경우, 살리실산과 피콜린산 모두 U(VI) 흡착과 무관하게 높은 흡착량을 보였으나 U(VI) 흡착을 감소시키지는 않았다. 따라서 삼성분 표면착물 생성을 배제할 수 없으나 이를 확인하기 위해서는 분광 분석과 같은 추가 연구가 필요하다.

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부분과 전체 : 근대 지역지리 방법론의 고찰 (The Part and the Whole : The Ontological Assumptions of Modern Geographical Thought about the Regional Geography)

  • 권정화
    • 한국지역지리학회지
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    • 제7권4호
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    • pp.81-92
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    • 2001
  • 근대 지리학 방법론 논쟁에서 가장 주요한 쟁점은 지역 지리학의 학문적 성격에 대한 논란이었다. 그러나 대부분의 논의는 지역 연구의 절차를 제시하기보다는 지역 지리학을 형이상학적으로 정당화하는 데 머물렀다. 본 연구에서는 이러한 견해를 비판적으로 검토하기 위하여 지역 지리학 방법론에 내재하는 전제들 가운데에서도 부분과 전체의 관계에 대한 존재론적 가정을 가장 중요한 준거로서 설정하였다. 대부분의 논의는 유기체론에 근거하여 지역을 복합적 존재로서 인식하고, 생명체와의 비유를 통해 지역의 속성을 파악해야 한다고 주장하였다. 그러나, 단위 지역이라는 전제의 한계와 더불어 단순히 요소들을 열거하는 데에 머물렀으며, 지역의 복합성을 포착하지 못하였다. 이러한 한계는 생활양식이라는 전제 위에서 출발한 데에서 오는 당연한 귀결이었다.

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Inorganic and Organic Nano Materials and Devices

  • Li, G.P.;Bachman, Mark
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.4.1-4.1
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    • 2009
  • The dream of futurists andtechnologists is to build complex, multifunctional machines so small that theycan only be seen with the aid of a microscope. The unprecedented technologyadvancements in miniaturizing integrated circuits on semiconductors, and theresulting plethora of sophisticated, low cost electronic devices demonstratethe impact that micro/nano scale engineering can have when applied only to thearea of electrical and computer engineering. Emerging research efforts indeveloping organic and inorganic nano materials together with using micro/nanofabrication techniques for implementing integrated multifunctional devices hopeto yield similar revolutions in other engineering fields. By cross linking theindividual engineering fields through micro/nano technology, various organicand inorganic materials and miniaturized system devices can be developed thatwill have future impacts in the IT and life science applications. Yet to buildthe complex micromachines and nanomachine of the future, engineering will needto develop the technology capable of seamlessly integrating these materials andsubsystems together at the micro and nano scales. The micromachines of thefuture will be “integrated nanosystems,” complex devices requiring the integration of multiple materials,phenomena, technologies, and functions at the same platform. To develop thistechnology will require great efforts in materials science and engineering, infundamental and applied sciences. In this talk, we will first discuss thenature of micro and nanotechnology research for IT and life sciences, and thenintroduce selected current activities in micro and nanotechnology research fororganic and inorganic materials and devices. The newly developed micro/nanofabrication processes and devices, combined with in-depth scientificunderstandings of materials, can lead to rapid development of next generationsystems for applications in IT and life sciences.

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석유화학단지의 휘발성 유기화합물로 인한 인체 위해도 평가에 관한 연구 (A Study on the Health Risk Assessment of Volatile Organic Compounds in a Petrochemical Complex)

  • 이진홍;김윤신;류영태;유인석
    • 한국대기환경학회지
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    • 제13권4호
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    • pp.257-267
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    • 1997
  • This study focuses on the health risk assessment of airborne volatile organic compounds (VOCs) in a petrochemical complex, with several emphases on a risk assessment method. The first emphasis is on the importance of hazard identification to determine the likely carcinogenic potential of a VOC. Without considering this type of information, a direct comparison of the carcinogenic risks of two pollutants is meaningless. Therefore, wer suggest that this type of information be prepared and be listed with the estimate of cancer risk in parallel. The second emphasis is on the selection of a better dose-response model to estimate unit risk or cancer potency factor of a carcinogenic VOC. Finally, probilistic risk assessment method is discussed and recommended to use within a comparison of conventional point-estimate method. A health risk assessment has also been carried out. For non-carcinogenic risk, even the highest hazard index for carbon tetrachloride is estimated to be less than 1 with the other VOCs less than 0.03. However, the lifetime cancer risk from the inhalation of airborne VOCs is estimated to be about $2.6 \times 10^{-4}$ which is higher than the risk standard of $10^{-6}$ or even $10^{-5}$. Therefore, the investigation into domestic petrochemical complexes should be strengthened to obtain more fine long-term airborne VOC data.

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항 히스타민제의 흡광광도정량법 (Spectrophotometric Determination of Antihistamines by Using Metal Indicators NN, EBT and Calcon as Color Developing Agents.)

  • 옥지원
    • 약학회지
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    • 제18권2호
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    • pp.133-144
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    • 1974
  • The metal indicator, acidic azo dyes NN, EBT and Calcon are utilized to analyse quantitatively chlorpheniramine, tripelenamine and diphenhydramine forming insoluble ion pair in aqueous solution at proper pH values between the acidic azo dyes and the sample molecules, these compexes are extracted by organic polar solvents, and organic layer is determined spectrophotometrically. Generally, the absorption maxima of the complexes are shifted to longer wavelengths compare to the absorption maxima of the dyes themselves. The binding ratio of the ion pair forming complex molecules in chloroform soln, are as follows ; NN-antihistamines (chlorpheniramine, tripelennamine, diphenhydramine) are NN-1 to antihisamine-1, EBT-antihistamines are EBT-2 to antithistamines a and Calcon-antihistamines are Calcon-3 to antithistamines-1. These coomplexes in chloroform soln. are very stable, and show higher absorbance than the other organic polar solvents. The binding state of complexes were presumed intermolecular hydrogen bond by their infrared spectra. In the mixture solution of three samples, the aqueous phase is buffered at pH 1.0, and benzene is used to extract ion pair of diphenhydramine EBT complex selectively. At pH 1.0 of aqueous layer, Calon-diphenhydramine complex is also extracted selectively by benzene. However, in this case very small amount of chlorpheniramine-calcon calcon simultaneously. The binding state of diphenhydramine-EBT and diphenhydramine-calcon in benzene are smae as the complexes in chloroform. But the absorption maxima of the complexes in benzene are shifted to shorter wavelenlgths than the complexes in chloroform.

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