• Plant Resources
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• v.6 no.1
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• pp.27-35
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• 2003

In this study, as preliminary research for the development of natural estrogen supplement the chemical properties of Iranian black pomegranate juice concentrate and seeds were evaluated. Proximate compositions of pomegranate juice concentrate and seeds were as follows; crude lipid 0.4% and 8.2%, moisture 39.9% and 6.6%, crude protein 0.9% and 12.2%, ash 1.4% and 1.7%, and carbohydrate 42.0% and 84.5% respectively. Major amino acids are glutamic acid (1310.0ppm) and aspartic acid (896.2ppm) in juice concentrate, and glycine (611.1ppm) and arginin (401.6ppm) in seeds. Ascorbic acid has the highest concentration of 20.0mg/l00g in juice concentrate and 0.23mg/l00 in seeds. The compositions of unsaturated fatty acids such as linoleic acid and linolenic acid were higher than those of saturated fatty acids such as stearic palmitic acid. Major minerals were potassium, calcium and sodium, potassium was highest in both juice concentrate and seeds. Vitamins were composed of ascorbic acid (20.0mg/l00g), vitamin B$_1$(0.12mg/100g) and niacin (0.80mg/l00g) in juice concentrate, and only ascorbic acid(0.23mg/l00g) in seeds. Organic acids such as citric and L-malic acid were detected only in pomegranate juice concentrate. The contents of total polyphenols were 4.55g/L in juice concentrate and 3.5mg/l00g in seeds, respectively. Phytoestrogens detected in pomegranate juice concentrate and seeds were daidzein, quercetin, genistein and 17 $\beta$-estradiol.

• Journal of the Korean Chemical Society
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• v.27 no.1
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• pp.31-37
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• 1983

The consumption of atmospheric carbon monoxide by soil was measured under laboratory conditions in different types of soils. Laboratory experiments were performed with humus containing high proportion of organic matter, roadside soils, and humus and roadside soils previously exposed to high concentration of CO by reusing in the experiment. CO concentrations in the 18.2 l-reaction vessel were varied from 2,000 ppm to 24,000ppm to estimate the effectiveness of CO consumption at high level of CO. The uptake of CO by soil was measured by gas chromatography using a TCD detector. The control experiments conducted along with the soil experiments evidently indicated that the potting soil is responsible for CO consumption. Humus showed much higher CO uptake rates compared with the soil taken from roadside. The humus reused in the experiment showed somewhat higher rates(15%) of uptake than the fresh one. The soil's ability to remove CO from the test atmosphere reached a maximum near the CO concentration of 13,000 ppm in the range of $9,000~24,000ppm$. The addition of streptomycin did not influence the removal capacity of soil significantly, whereas 10% saline solution remarkably prevented CO uptake of the humus sample.

• Journal of the Korean Chemical Society
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• v.9 no.1
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• pp.61-65
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• 1965

Metal distribution in the reaction products and system of reactions between organo chloro acid or ester and zinc, silicon, magnesium, and tin under acetonitrile, dioxane, and toluene solvent were determined by means of radioactive tracer prepared by means of a (n, ${\gamma}$) reaction. It was found that the solubility of the organo halogen metal complex was markedly increased in a hydrophilic solvent and was decreased in a nonpolar solvent which resulted in an increased metal distribution in the recovered metal or water washing of the recovered metal mixture. This was also true in the case of the reaction conducted in the presence of a carbonyl compound. The relative increase of the solubility of the metal complex in a hydrophilic solvent was in order of zinc, silicon, tin and magnesium, and in a nonpolar solvent, it was in order of silicon, tin, magnesium, and zinc. There was no formation of organo metallics throughout the reaction sequence. The result was discussed and the observed solvent influence on the present reaction path was criticized.

• Korean Journal of Agricultural Science
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• v.46 no.4
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• pp.857-868
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• 2019

A flooded rice field is one of the significant sources of anthropogenic methane (CH₄) with the intensity of the emissions dependent on management practices. Incorporation of rice straw, which is one of the organic amendments, induces the increase of methane emissions during the flooding season. In this study, we measured of methane emission according to applications of rice straw in different soil textures during a cultivation period in 2017 and 2018. The fallow treatments were non application of rice straw (NA), spring plowing after spring spreading of rice straw (SPSA), spring plowing after previous autumn spreading of rice straw (SPAA), and autumn plowing after previous autumn spreading of rice straw (APAA). The SPSA treatment emitted the highest total methane from loam soil in both 2017 (596.7 CH₄ kg ha^-1) and 2018 (795.4 CH₄ kg ha^-1). The same trend was observed in silt clay loam soil; the SPSA treatment still emitted the highest amount of methane in both 2017 (845.9 CH₄ kg ha^-1) and 2018 (1,071.7 CH₄ kg ha^-1). The lowest emission among the rice straw incorporated plots came from the APAA treatment for both soil texture types in all the seasons. The conversion factors of the SPAA were 0.79 and 0.65 from the loam and silt clay loam soils, respectively. Relatedly, the conversion factors of the APAA were 0.71 and 0.43 from the loam and silt clay loam soils, respectively. The above observations mean therefore that incorporation of rice straw early in the fallow reduces methane emissions in the main rice growing season.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2765-2770
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• 2011

Organic dye-doped glasses, viz., ruthenium (II) tris(4,7'-diphenyl-1,10'-phenanthroline) $[Ru(dpp)_3]^{2+}$ incorporated into thin silica xerogel films produced by the sol-gel method, were prepared and their $O_2$ quenching properties investigated as a function of the $[Ru(dpp)_3]^{2+}$ concentration (3-400 ${\mu}M$) within the xerogel. The ratio of the luminescence from the $[Ru(dpp)_3]^{2+}$-doped films in the presence of $N_2$ and $O_2$ ($I_{N2}/I_{O2}$) was used to describe the film sensitivity to $O_2$ quenching. ($I_{N2}/I_{O2}$ changed three-fold over the $[Ru(dpp)_3]^{2+}$ concentration range. Time-resolved intensity decay studies showed that there are two discrete $[Ru(dpp)_3]^{2+}$ populations within the xerogels (${\tau}_1$ ~ 300 ns; ${\tau}_2$ ~ 3000 ns) whose relative fraction changes as the $[Ru(dpp)_3]^{2+}$ concentration changes. The increased $O_2$ sensitivity that is observed at the higher $[Ru(dpp)_3]^{2+}$ concentrations is a manifestation of a greater fraction of the 3000 ns $[Ru(dpp)_3]^{2+}$ species (more susceptible to $O_2$ quenching). A model is presented to describe the observed response characteristics resulting from $[Ru(dpp)_3]^{2+}$ distribution within the xerogel.

• Korean Chemical Engineering Research
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• v.54 no.6
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• pp.723-733
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• 2016

Intensive researches have been focused on the 3-dimensional packaging technology using through silicon via (TSV) to overcome the limitation in Cu interconnection scaling. Void-free filling of TSV by the Cu electrodeposition is required for the fabrication of reliable electronic devices. It is generally known that sufficient inhibition on the top and the sidewall of TSV, accompanying the selective Cu deposition on the bottom, enables the void-free bottom-up filling. Organic additives contained in the electrolyte locally determine the deposition rate of Cu inside the TSV. Investigation on the additive chemistry is essential for understanding the filling mechanisms of TSV based on the effects of additives in the Cu electrodeposition process. In this review, we introduce various filling mechanisms suggested by analyzing the additives effect, research on the three-additive system containing new levelers synthesized to increase efficiency of the filling process, and methods to improve the filling performance by modifying the functional groups of the additives or deposition mode.

• Ceramist
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• v.22 no.3
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• pp.281-300
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• 2019

Surface enhanced Raman scattering (SERS) was first discovered in 1974 by an unexpected Raman signal increase from Pyridine adsorbed on rough Ag electrode surfaces by the M. Fleishmann group. M. Moskovits group suggested that this phenomenon could be caused by surface plasmon resonance (SPR), which is a collective oscillation of free electrons at the surface of metal nanostructures by an external light source. After about 40 years, the SERS study has attracted great attention as a biomolecule analysis technology, and more than 2500 new papers and 500 review papers related to SERS topic have been published each year in recently. The advantages of biomaterials analysis using SERS are as follows; ① Molecular level analysis is possible based on unique fingerprint information of biomolecule, ② There is no photo-bleaching effect of the Raman reporters, allowing long-term monitoring of biomaterials compared to fluorescence microscopy, ③ SERS peak bandwidth is approximately 10 to 100 times narrower than fluorescence emission from organic phosphor or quantum dot, resulting in higher analysis accuracy, ④ Single excitation wavelength allows analysis of various biomaterials, ⑤ By utilizing near-infrared (NIR) SERS-activated nanostructures and NIR excitation lasers, auto-fluorescence noise in the visible wavelength range can be avoided from in vivo experiment and light damage in living cells can be minimized compared to visible lasers, ⑥ The weak Raman signal of the water molecule makes it easy to analyze biomaterials in aqueous solutions. For this reason, SERS is attracting attention as a next-generation non-invasive medical diagnostic device as well as substance analysis. In this review, the principles of SERS and various biomaterial analysis principles using SERS analysis will be introduced through recent research papers.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.4
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• pp.325-338
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• 2009

National parks provide recreation, health, and science to human being. The provision of beautiful landscape view of the national park improves an economic and social phase of a nation. However, visibility impairment frequently occurred in the national park area of Gyeongju. The purpose of this study is to investigate the physical and the chemical characteristics of visibility reduction observed at the national park area of Gyeongju. Optical, chemical, meteorological characteristics and scenic monitoring were performed at the visibility monitoring station of Gyeongju University located at the Seoak section of Gyeongju national park from April 28 to May 9, 2008. Light extinction, light scattering, and light absorption coefficients were continuously measured using a transmissometer, a nephelometer, and an aethalometer, respectively. In order to investigate the impact of aerosol chemistry on visibility impairment, size-resolved aerosols were collected at intervals of 2-hour (from 8 A.M. to 6 P.M.) and 14-hour (from 6 P.M. to 8 A.M.) interval each sampling day. The average light extinction coefficient and the average visual range were measured to be $270{\pm}135\;Mm^{-1}$ and $14.5{\pm}6.3\;km$ during the intensive monitoring period, respectively. It was revealed that sulfate particle was the largest contributor to the light extinction under hazy condition. Organic mass accounted for about 26% of the average light extinction. The mass extinction efficiencies for $PM_{1.0}$, $PM_{2.5}$, and $PM_{10}$ were estimated to be 9.0, 4.7, and $2.7\;m^2\;g^{-1}$ under the consideration of water growth function of hygroscopic aerosols, respectively.

• Journal of Korean Society of Forest Science
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• v.97 no.3
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• pp.285-290
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• 2008

This study was carried out to obtain an optimal liquid culture condition for Sarcodon aspratus mycelia. Among various basal culture media the GYS (glucoe-yeast extract-soytone) medium was the best for mycelial growth. The appropriate temperature was $25^{\circ}C$. Starch, maltose or glucose was excellent carbon sources for the mycelial culture, compared to others tested. As nitrogen nutrients, soytone and $NH_4-N$ were the best organic and inorganic nitrogen sources, respectively. Moreover, the optimal concentration of soytone was 3 g per one-liter medium. In addition, we also found that alanine, $(NH_4)H_2PO_4$, and nicotinic acid were the best aminoacid, phosphorus salt, and vitamin, respectively. When all optimal conditions described above were applied to culture medium, we were able to produce 5.7 g dry weight of S. aspratus mycelia per one-liter liquid medium within 20 days.

• Advances in Traditional Medicine
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• v.10 no.2
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• pp.103-110
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• 2010

The seed powder of Abrus precatorius L. has traditionally been used as oral contraceptive agent by the women in some rural areas in Bangladesh. The present study aimed to examine the antifertility activity of A. precatorius seed extracts in experimental female rats. Finely ground seeds were extracted with aqueous acetone followed by successive partitioning with n-hexane, ethyl acetate (EtOAc), methanol (MeOH) and water. Water suspended crude seed powder, organic fractions of acetone extract and a standard contraceptive drug ($Nordette^{(R)}28$) were separately administered orally to the female rats for 30 days. n-Hexane, EtOAc and MeOH solubles at the doses of 2, 4 and 6 mg/rat/day, respectively and crude seed powder at 100 mg/rat/day exhibited 100% antifertility activity with lowest levels of serum luteinizing hormone (LH), follicle stimulating hormone (FSH) and $17{\beta}$-estradiol. Histological study of ovary and uterus of these rats exhibited reduced number of developing follicles and increased number of atretic follicles in the ovary, and fewer uterine glands with shrunken morphology, reduced endometrial height, poor vascularity and compact stroma in uterus. However, the activities of serum glutamate oxaloacetate transaminase and serum glutamate pyruvate transaminase and the body weight of the rats remained almost unaffected in all the seed extract treated rats compared to control. These results suggest that A. precatorius seed extracts reduced the levels of serum FSH, LH and $17{\beta}$-estradiol probably by affecting hypothalamic-pituitary-gonadal axis. The reduced levels of these hormones might have affected the oestrous cycle, follicular development, and subsequently the establishment of pregnancy in treated rats.