• Title/Summary/Keyword: Organic acids addition

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The Solubility Characteristics of Organic Compounds in Urban Aerosol Samples

  • Kim, Young-Min;Peter Brimblecombe;Tim Jickells;Baek, Sung-Ok
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.E
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    • pp.27-40
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    • 1998
  • The solubility characteristics of organic compounds were studied in terms of the extraction efficiency as a function of the polarity of the organic solvent, and the acidity of water in urban aerosol samples collected in University of East Anglia (UEA), Norwich, England. The extraction efficiency of organic compounds were evaluated with respect to the organic carbon, -nitrogen and -hydrogen by means of a wide range of solvent which include polar and nonpolar organic solvents as well as acids and alkaline water. In addition, after being dissolved in aqueous solution, the aqueous chemistry of organic compounds were studied in terms of the organic metal complexes in aerosol, which were studied with oxalic acid, copper, and zinc. The results of this study indicate that solubility characteristics of organic compounds depend on the polarity of the solvents and the acidity of the solvents. In particular, some organic compounds are water soluble, even though they are much smaller than acetone soluble fractions. In the comparison between polar organic solvent extraction and non- polar organic solvent extraction, it can be thought that significant fraction of organic compounds analysed in the aerosol samples, are polar organic compounds because of the higher extraction efficiencies of organic compounds in polar organic solvent extraction than in nonpolar organic solvent extraction. Regarding the study of the oxalic -metal complexes, it can be thought that most oxalic acids are present in the form of oxalic -copper complexes in the aerosols collected at UEA.

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The Effect of Organic Acids on Mineral Extraction from Chicken Thigh Bone Stock (유기산 첨가가 닭뼈(대퇴골) 스톡(stock)에 용출되는 무기질량에 미치는 영향)

  • 이승언;남출항구;대곡귀미자;최석현;한재숙
    • Journal of the East Asian Society of Dietary Life
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    • v.12 no.5
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    • pp.379-387
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    • 2002
  • The focus of this study was the influence of organic acids such as acetic, citric and malic acid on the dissolution of calcium (Ca), magnesium (Mg), and phosphorus (P) on chicken thigh bone. As the concentration (0, 0.5, 1, 2, 4%) of acetic, citric, and malic acid increased, the resultant contents of calcium, magnesium, and phosphorus were higher than that of the control. When the boiling time (2, 4, 6, 8, 12 hours) was increased, dissolved amounts of several minerals from the chicken thigh bone increased. Calcium dissolved the most when chicken stock was boiled for 12 hours with 4% of malic acid added. In addition to minerals, amino acids and proteins were further extracted by adding organic acids. The soup stock which contains minerals such as calcium, can be obtained by boiling the chicken thigh bone for 12 hours with an organic acid.

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Enbancement of Treatement Efficiency in a Biological Nutrient Removal Process by addition of Volatile Fatty Acids (휘발성 지방산의 주입을 통한 생물학적 영양염류 제거공정의 효율증진에 관한 연구)

  • Choung, Yoon Kyoo;Ko, Kwang Baik;Kim, Sue Jin;Yim, Seong Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.3
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    • pp.73-82
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    • 1996
  • The removal efficiencies of organic substrates, nitrogen and phosphorus in the anaerobic-aerobic biological phosphorus removal process were investigated by addition of acetic acid, propionic acid and butyric acid which are normal volatile fatty acids contained in anaerobic digester supernatants. Substrate utilization coefficients for the phosphorus release and uptake were also estimated. The effect of a VFA, which showed higher phosphorus removal efficiency than the other VFAs did, was also studied in an anaerobic-aerobic-anoxic biological nutrient removal process. For the anaerobic-aerobic process added by VFA, the phosphorus removal efficiencies were up to about 68%, 55% and 61% for the reactors of acetic acid, propionic acid and butyric acid added, respectively, which indicates the efficiencies were increased by about 8-21%, comparing to that of 47% for the reactor with no VFA added. There were no significant difference in removal efficiencies for organic substrate and $NH_3-N$ without regard to addition of VFA. However, the removal efficiency of total nitrogen was increased in the case of VFA added, since $NO_3-N$ was less produced. For the anaerobic-aerobic-anoxic process added VFA, the removal efficiencies for $NH_3-N$ and $PO{_4}^{3-}-P$ were increased by 5% and 13%, respectively, comparing with them in the reactors not added VFA.

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The Components of the Fermented Soy Sauce from Gorosoe and Bamboos SaP (고로쇠 및 대나무 수액간장의 성분조성)

  • 정미자;조종수;김행자;성낙주
    • The Korean Journal of Food And Nutrition
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    • v.14 no.2
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    • pp.167-174
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    • 2001
  • Soy sauce was prepared with the addition of Gorosoe and bamboos sap instead of tap water to make ordinary soy sauce, respectively. The changes of such compounds during fermentation as minerals, free sugars, organic acids and free amino acids were analyzed. Total mineral contents in the 90 days fermented soy sauce from Gorosoe and bamboos sap were increased by 2.0 and 4.4 times as compared with those of control samples, respectively. Especially the increase of calcium, potassium and magnesium in soy sauce of sapes were derived from those of saps. The sugars were found to be only glucose and galactose in control samples, but they were detected not only above sugar but also fructose and sucrose in soy sauce of saps. Butyric acid in detected organic acid were dominant in all stray sauce samples. In the free amino acid composition of control samples, leucine, phenylalanine, isoleucine, lysine and glutamic acid were abundant amino acids. Amino acid such as isoleucine, leucine and phenylalanine were decreased, the rest 11 kinds of amino acids containing phosphoserine were increased during the fermentation of control samples. Increasing and decreasing patterns of free amino acids during fermentation of sap soy sauce were similar to control samples. Total nitrogen, amino acid nitrogen and ammonia nitrogen were increased during their fermentation.

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Effects of Humic Acids on Growth of Herbaceous Plants in Soil Contaminated with High Concentration of Petroleum Hydrocarbons and Heavy Metals (고농도 유류와 중금속으로 복합 오염된 토양에서 식물성장에 미치는 부식산의 영향)

  • Kim, Ki-Seob;Sung, Ki-June
    • Journal of Soil and Groundwater Environment
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    • v.16 no.1
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    • pp.51-61
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    • 2011
  • Germination tests were conducted to determine the practical concentration levels at which plants can reproduce naturally during the phytoremediation of soils contaminated with a high concentration of petroleum hydrocarbons and heavy metals. The effects of humic acids on plant growth and soil physicochemical properties were also investigated. The results show that phytoremediation can be applied in soils contaminated by multiple contaminants at the former soil contamination potential level of Korean soil quality standards considering successful natural reproduction. It was observed that germination rates of Helianthus annuus and Festuca arundinacea were high after all treatments, and transplantation was more appropriate for Phragmites communis in phytoremediation. Humic acids had a positive effect on the growth of both aboveground and belowground biomass of herbaceous plants. Growth inhibition by multiple contaminants is more severe in the case of aboveground biomass. Germination and growth tests suggest that Helianthus annuus is a suitable phytoremediation plant for soils contaminated with a high concentration of petroleum hydrocarbons and heavy metals. The addition of humic acids also caused changes in the physicochemical properties of contaminated soils. An increase in the carbon and nitrogen content due to the addition of humic acids and a correlation between cation exchange capacity(CEC) and the organic matter content were observed.

Behavior of Hydrogen and Organic Acids in Anaerobic Digestion of Food Wastewater (음폐수의 혐기성 소화 시 수소 및 유기산의 거동)

  • Cho, Kyungmin;Oh, Saeeun
    • New & Renewable Energy
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    • v.18 no.2
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    • pp.9-17
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    • 2022
  • In this study, we used the Flux Balance Analysis (FBA) program to examine the behavior of hydrogen and organic acids according to seasonal changes in food wastewater collected from D city. The results showed that average hydrogen conversion rates in spring, summer, autumn, and winter were 1.06, 0.71, 1.21, and 1.13 mol H2/mol of hexoseadded, respectively, indicating a significantly lower hydrogen conversion rate in summer than in other seasons. This phenomenon is believed to occur because the carbohydrate concentration of the incoming food wastewater is low. In addition, Lactobacillus, the lactic acid-producing bacterium, was 21.3% in spring, 27.2% in summer, 17.5% in autumn, and 22.6% in winter. The most distinctive feature of the microbial community in summer was that 15.3% of the Ilyobacter was analyzed. It was confirmed that Ilyobacter, which is involved in the production of acetic acid and propionic acid, is closely associated with the tendency of increasing acetic acid and propionic acid and thus contributes to organic acid change. Clostridium, a hydrogen-producing bacterium, was 76.2%, 50.8%, 78.3%, and 74%, in spring, summer, autumn, and winter, respectively. It was confirmed that Clostridium dominates the microbial community by approximately 70% or more in all seasons except summer.

Induction of ethanol tolerance on the production of 17-ketosteroids by mutant of mycobacterium sp.

  • Kim, Mal-Nam;Kim, Eun-Mi
    • Journal of Microbiology
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    • v.33 no.4
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    • pp.322-327
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    • 1995
  • Tolerance of Mycobacterium sp. against organic solvents has been induced for the cholesterol side chain degradation by adding chemicals associated with synthesis of fatty acids or alcohols. Biotin of 300 .mu.g/1 and 0.5% aqueous ethanol solution were optima for the enhancement of ethanol tolerance of the microorganism. The induction of ethanol tolerance by biotin was found to be due to increase of degree of unsaturation of the fatty acids in membranous phospholipid of the cell, especially due to increase of oleic acid content. However when 0.5% of ethanol was added for the ethanol tolerance induction, there was an ambiguous correlation between ethanol tolerance and degree of unsaturation of the fatty acids, in spite of the fact that the induction increased the content of unsaturated fatty acids. Addition of 0.5% of ethanol induced several ethanol shock proteins having molecular weight similar to that of heat shock proteins.

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Modification of Hydroxyapatite-gelatin Nanocomposite using Side Group Reaction of Ca2+-RCOO-

  • Chang, Myung-Chul;Yang, Hae-Kwon
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.72-77
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    • 2012
  • In the preparation of a hydroxyapatite [HAp]/gelatin [GEL] nanocomposite, the GEL matrix in aqueous solution of $H_3PO_4$ was modified by the introduction of aspartic acid [Asp], asparagine [Asn], and glycine [Gly]. The addition of Asp, Asn and Gly greatly affected the slurry formation of HAp/GEL nanocomposite and the resulting dry body showed variations in toughness with the addition of the different amino acids. The introduction of Asn into HAp/GEL nanocomposite was effective for producing the organic-inorganic interaction between HAp and GEL, and caused the increase of toughness. The formation reaction of the modified HAP/GEL nanocomposites was investigated by using XRD and FT-IR. The organic-organic interaction between the GEL matrix and the additives of Asp, Asn and Gly was confirmed from FT-IR analysis, and the organic-inorganic interaction between HAp nanocrystallites and the modified GEL matrix was also discussed, using FT-IR spectra patterns. Nanocrystallites of HAp were covalently bound with the GEL macromolecules and differently influenced by the modification species of Asp, Asn, and Gly.

Effect of Addition of Ethanol and Organic Acids on the Quality of Mul-kimchi (Ethanol과 유기산의 첨가가 물김치의 품질에 미치는 영향)

  • 김도희;한영숙
    • Journal of the East Asian Society of Dietary Life
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    • v.13 no.4
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    • pp.305-312
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    • 2003
  • The effect of addition of ethanol and/or organic acid on slowing down the fermentation of Mul-kimchi was tested by measuring the changes in pH, acidity and counting the number of microorganisms in kimchi fermentation, and sensory evaluation were carried out. The addition of 0~5% ethanol to kimchi delayed the decrease of pH and the delaying effect during kimchi fermentation was dependent on the ethanol concentration used. The pH of kimchi without ethanol decreased from 5.7 to 4.13, however, the pH of the kimchi added with 5% ethanol only from 5.8 to 5.14. The increase of acidity in kimchi with 5% ethanol was only 0.5~0.6%, while that without ethanol was 0.7~0.8%. Among the organic acids tested, adipic acid was found to be most effective on the prevention of kimchi souring. The Mul-kimchi added 2% ethanol together with 0.1% organic acid showed similar effect to that of organic acid alone in the change of pH and acidity. By the sensory evaluation, Mul-kimchi with 0.1% adipic acid and 2% ethanol was selected the most desirable one except control without any addition. And the numbers of total microbes, lactic bacteria and yeast count, showed the most effective inhibition in Mul-kimchi with 0.1% adipic acid and 2% ethanol.

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Extraction and Stabilization of Anthocyanin Pigments from Morus alba Fruits (오디 anthocyanin 색소의 추출 및 저장 안정성)

  • Seo, Kyeong-Hwa;Lee, Dae-Young;Jeong, Rak-Hun;Kim, Young-Eon;Kim, Young-Rae;Hong, Eock-Kee;Bang, Myun-Ho;Baek, Nam-In
    • Journal of Applied Biological Chemistry
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    • v.57 no.1
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    • pp.29-32
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    • 2014
  • This study was initiated to search for the most effective method for extraction of anthocyanins from Morus alba Fruits using organic acids and to evaluate the stability of the pigments at various storage environments. The anthocyanins were effectively extracted by addition of organic acids such as citric acid, malic acid and fumaric acid. The anthocyanins were not degraded at $25^{\circ}C$ and under a fluorescent light with 183 lux, but sharply degraded at $60^{\circ}C$.