• Title/Summary/Keyword: Organic Substances

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Case Studies for the Ratification of Stockholm Convention on Persistent Organic Pollutants with Specific Exemption in South Korea (Stockholm 협약 비준 대비 잔류성유기오염물질의 특정면제를 위한 국내 실태조사)

  • Kim, H.H.;Lee, J.Y.;Yang, J.Y.;Lee, J.S.;Shin, D.C.;Jung, H.W.;Lim, Y.W.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.12 no.1
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    • pp.63-75
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    • 2010
  • United Nations Environment Program adopted a global binding agreement to regulate the production and distribution for the persistent organic pollutants (POPs) in May 22, 2001. The agreement took its effectuation with the ratification of 59 countries from the approval of 151 countries in May 17, 2004. After the approval on the binding agreement in October 4, 2001, South Korea performed systematic investigation for the ready of ratification on the convention with country-specific exemption for some chemical substances. Case study with documentary examination and fact-finding survey found some potential problem for 5 chemical substances such as chlordane, dichloro diphenyl trichloroethane (DDT), hexachlorobenzenes (HCB), heptachlor, polychlorinated biphenyls (PCBs). However, subsequent investigation with more detailed degree showed the possibility for the ratification with no country-specific exemption.

Utilizing method for Bioenergy (바이오에너지의 극대활용방안)

  • 진수웅
    • Journal of the Korean Professional Engineers Association
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    • v.34 no.5
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    • pp.63-68
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    • 2001
  • The terminology of bioenergy means the biomass. The urge to make biomass more Quantitative has led to the wide spread Inclusion of plants, grains and all organic substances. Biomass for nonelectrical uses In the our country accounts for approximately 2∼3% of the total energy consumption In 1999. Biomass also generally produces lower gas pollutant omission than fossil energies and to attractive because It's a renewable energy source .

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Humic Substances Act as Electron Acceptor and Redox Mediator for Microbial Dissimilatory Azoreduction by Shewanella decolorationis S12

  • Hong, Yi-Guo;Guo, Jun;Xu, Zhi-Cheng;Xu, Mei-Ying;Sun, Guo-Ping
    • Journal of Microbiology and Biotechnology
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    • v.17 no.3
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    • pp.428-437
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    • 2007
  • The potential for humic substances to serve as terminal electron acceptors in microbial respiration and the effects of humic substances on microbial azoreduction were investigated. The dissimilatory azoreducing microorganism Shewanella decolorationis S12 was able to conserve energy to support growth from electron transport to humics coupled to the oxidation of various organic substances or $H_2$. Batch experiments suggested that when the concentration of anthraquinone-2-sulfonate (AQS), a humics analog, was lower than 3 mmol/l, azoreduction of strain S12 was accelerated under anaerobic condition. However, there was obvious inhibition to azoreduction when the concentration of the AQS was higher than 5 mmol/l. Another humics analog, anthraquinone-2-sulfonate (AQDS), could still prominently accelerate azoreduction, even when the concentration was up to 12 mmol/l, but the rate of acceleration gradually decreased with the increasing concentration of the AQDS. Toxic experiments revealed that AQS can inhibit growth of strain S12 if the concentration past a critical one, but AQDS had no effect on the metabolism and growth of strain S12 although the concentration was up to 20 mmol/l. These results demonstrated that a low concentration of humic substances not only could serve as the terminal electron acceptors for conserving energy for growth, but also act as redox mediator shuttling electrons for the anaerobic azoreduction by S. decolorationis S12. However, a high concentration of humic substances could inhibit the bacterial azoreduction, resulting on the one hand from the toxic effect on cell metabolism and growth, and on the other hand from competion with azo dyes for electrons as electron acceptor.

Determination of Goitrogenic Metabolites in the Serum of Male Wistar Rat Fed Structurally Different Glucosinolates

  • Choi, Eun-Ji;Zhang, Ping;Kwon, Hoonjeong
    • Toxicological Research
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    • v.30 no.2
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    • pp.109-116
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    • 2014
  • Glucosinolates (GLSs) are abundant in cruciferous vegetables and reported to have anti thyroidal effects. Four GLSs (sinigrin, progoitrin, glucoerucin, and glucotropaeolin) were administered orally to rats, and the breakdown products of GLSs (GLS-BPs: thiocyanate ions, cyanide ions, organic isothiocyanates, organic nitriles, and organic thiocyanates) were measured in serum. Thiocyanate ions were measured by colorimetric method, and cyanide ions were measured with CI-GC-MS. Organic isothiocyanates and their metabolites were measured with the cyclocondensation assay. Organic nitriles and organic thiocyanates were measured with EI-GC-MS. In all treatment groups except for progoitrin, thiocyanate ions were the highest among the five GLS-BPs. In the progoitrin treated group, a high concentration of organic isothiocyanates (goitrin) was detected. In the glucoerucin treated group, a relatively low amount of goitrogenic substances was observed. The metabolism to thiocyanate ions happened within five hours of the administration, and the distribution of GLSs varied with the side chain. GLSs with side chains that can form stable carbocation seemed to facilitate the degradation reaction and produce a large amount of goitrogenic thiocyanate ions. Because goitrogenic metabolites can be formed without myrosinase, the inactivation of myrosinase during cooking would have no effect on the anti-nutritional effect of GLSs in cruciferous vegetables.

Distribution of Heavy Metal Contents in Sediment of the Lower Kumho River (금호강하류의 저니중 중금속 함량분포)

  • 권오억
    • Journal of Environmental Health Sciences
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    • v.20 no.4
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    • pp.45-52
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    • 1994
  • This study was performed to investigate the contents of six heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) with respect to the particle sizes and depths in sediment collected at nine sites of the lower Kumho river. The mean Cd, Cr, Cu, Ni, Pb and Zn contents in sediment of all sites ranged from 1.59~5.32 mg/kg, 17.4~301.7 mg/kg, 23.2~399.9 mg/kg, 9.48~116.8 mg/kg, 31.1~294.1 mg/kg and 74.2~964.3 mg/kg, respectively. The highest heavy metal contents was generally found to be Zn and lowest was Cd. The mean contents of heavy metal by particle sizes (1.0~0.5, 0.5~ 0.25, <0.25 mm)was the highest in particle sizes less than 0.25 mm, but the coefficients of variation was lowest in particle sizes less than 0.25 mm. Mean contents and coefficient of variation by depths (0~5 cm, 5~10 cm, 10~15 cm) were generally found to be higher in the upper parts of sediment than in the lower parts of sediment. Organic substances were found to be higher as the particle sizes become more small. Moreover, contents of heavy metal increased with the amounts of organic substances in sediment.

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Evaluation of membrane fouling by MBR operation conditions in MBR-RO (MBR-RO 공정에서 MBR 운전조건에 따른 막오염 특성 및 RO 공정 막오염 평가)

  • Park, Kitae;Park, Jungwoo;Park, Junghoon;Kang, Heeseok;Kim, Jihoon;Kim, Hyungsoo
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.5
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    • pp.545-551
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    • 2016
  • This study compares characteristic of membrane fouling in MBR-RO systems. In lab. scale MBRs test, MBRs were operated at different Flux(10, 20, 30 & 40 LMH) and temperature(10, 15, 20, 25 & $30^{\circ}C$). The results show that MBR permeate was measured lower amounts of organic substances in Higher flux and lower temperature and led to lower RO fouling rates. The main cause was that due to cake fouling formed on membrane surfaces in MBRs. Under both cases, Cake layer of membrane surfaces formed in MBRs removed RO fouling factors, polysaccharide and protein, because of cake layer attached on membrane surfaces greater amounts of organic substances. This study implies that optimization of MBR with operating conditions is a crucial strategy to RO membrane fouling control.

CHARACTERIZATION OF RECALCITRANT DISSOLVED ORGANIC MATTER IN LAKE AND INFLOW RIVER WATERS

  • Kim, Yong-Hwan;Lee, Shun-Hwa;Kim, Jung-Ho;Park, Jong-Woong;Choi, Kwang-Soon
    • Environmental Engineering Research
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    • v.11 no.4
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    • pp.181-193
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    • 2006
  • The hydrophilic or hydrophobic characteristics of dissolved organic matter (DOM) from different origins in lake and river waters were investigated using spectrometric and chromatographic analyses of water samples. DOM in a deep, mesotrophic lake (Lake Unmun) was fractionated using three types of ion exchange resins and classified into aquatic humic substances (AHS), hydrophobic neutrals (HoN), hydrophilic acids (HiA), hydrophilic neutrals (HiN), and bases (BaS). The DOM fractionation provided insight into the understanding of the nature of heterogeneous DOM molecules present in different water sources. The UV/DOC ratios were determined for samples from the influent river and lake waters during DOM fractionation and incubation. AHS prevailed over DOM in the lake and river waters. After biodegradation, the relative contribution of AHS in the total DOM became more significant. It indicates that the AHS fraction would increase while water stay long time in the lake.

Sludge solubilization using sono-activated persulfate (활성 과황산염을 이용한 슬러지 가용화)

  • Moon, Sang-Jae;Nam, Se-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.3
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    • pp.35-40
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    • 2021
  • In order to investigate the degree of solubilization of sewage sludge using sono-activated persulfate(UV/PP), VSS reduction rate, solubilization rate and extracellular polymeric substances were measured. Ultrasonic(US) and alkali·ultrasonic method using sodium hydroxide(US/SH) were compared. Under the persulfate·ultrasonic conditions, the VSS reduction rate and the solubilization rate increased to 27.6% and 58.9%, respectively. TB-EPS as Carbohydrate and Protein were extracted by 770 mg/L and 2,162 mg/L. Compared to the other methods, US and US/SH, the VSS reduction rate and solubilization rate were higher. And also, according to the TB-EPS values, cell wall destruction was more efficient.

A Study on the Accumulation Phenomena of Oxidized Starch in White Water in Closed Fine Papermaking Process (Part 1) -Effect of Papermaking system closure- (백상지 공정 폐쇄화에 따른 백수 내 산화전분의 축적 현상에 관한 연구 (제1보) -공정 폐쇄화의 영향-)

  • Ahn, Hyun-Kyun;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.3
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    • pp.15-34
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    • 2004
  • Diverse benefits such as reduction of fresh water consumption and effluent discharge, efficient use of raw materials and energy savings can be obtained by papermaking system closure. Closure of papermaking processes, however, causes many problems including reduction of the efficiency of additives, decrease of retention and dewatering, felt plugging, poor Paper quality, generation of slime and odor, poor vacuum efficiency, etc, and it has been recognized that accumulation of Inorganic and organic substances in the process white water is the prime cause of these problems. Therefore, technological developments for preventing accumulation of these detrimental substances are urgently required for Implementing papermaking system closure. Understanding of the accumulation phenomena of the inorganic and organic substances in the papermaking process white water is prerequisite for papermaking system closure. In this study a process simulation method was used to analyze the accumulation phenomena of anionic starch In the process white water as the closure level of a fine paper making process is increased. A pilot paper machine was used as a model process. Starch adsorption and desorption models were developed based on the concept of starch adsorption ratio, which was not considered in previous studies. Steady state simulation studies were carried out based on this model using a commercial simulator. In steady state simulation, the variation of dissolved starch concentration in each process unit was monitored as a function of white water usage for wire shower. The result of the steady state simulation showed that dissolved starch concentration and its increase ratio in Process units increased as white water usage ratio for wire shower increased.