• Title/Summary/Keyword: Organic Solution

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Solution Processable Ionic p-i-n OLEDs (습식 이온 도핑 p-i-n 구조 유기 발광 소자)

  • Han, Mi-Young;Oh, Seung-Seok;Park, Byoung-Choo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.11
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    • pp.974-979
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    • 2009
  • We studied solution-processed single-layered phosphorescent organic light-emitting diodes (PHOLEDs), doped with ionic salt and treated with simultaneous electrical and thermal annealing. Because the simultaneous annealing causes the accumulation of salt ions at the electrode surfaces, the energy levels of the organic molecules are bent by the electric fields due to the adsorbed ions, i.e., the simultaneous annealing can induce the proper formation of an ionic p-i-n structure. As a result, an ionic p-i-n PHOLED with a peak luminescence of over ${\sim}35,000\;cd/m^2$ and efficiency of 27 cd/A was achieved through increased and balanced carrier-injections.

Dependence of Electrical Resistance in Porous Silicon Layer for Detecting Organic Vapors (유기 가스 검지를 위한 다공질 실리콘층의 전기 저항 의존성)

  • Park, Kwang-Yeol;Kim, Seong-Jeen;Lee, Sang-Hoon;Choi, Bok-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.792-796
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    • 2002
  • In this work, porous silicon(PS) layer is used as a sensing material to detect organic gases. To do this, PS sensors with membrane structure are fabricated. The sensors were made by applying the technologies of membrane formation by anisotropic etching of silicon, and PS layer formation by anodization in HF solution. From fabricated sensors, current-voltage (I-V) curves were measured against ethanol (called alcohol), methanol and acetone gases evaporated from 0.1 to 0.5% solution concentrations at $36^{\circ}C$. As the result, all curves showed rectifying behavior due to a diode structure between Si and PS, and the conductance of sensor devices increased largely with the organic solution concentration at high voltage of 5V.

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Analysis of Post Cleaning Solution After Wet Cleaning of Shadow Mask Used in OLED Process (OLED공정에서 사용되는 섀도마스크의 습식 세정 후 세정표면 및 세정용액 분석에 관한 연구)

  • Cui, Yinhua;Pyo, Sung Gyu
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.7-10
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    • 2016
  • The post cleaning method for clean the shadow mask using in OLED (organic light emitting diode) emitter layer is always reforming. The cleaning solution and analysis method of shadow mask is still lack and not optimized. We use the simple and useful analytical method to determine the quantity and quality of organic and inorganic residue on surface of shadow mask. Finally analyze the cleaning solution using Raman spectroscopy efficiently.

Effects of Fused Thiophene Bridges in Organic Semiconductors for Solution-Processed Small-Molecule Organic Solar Cells

  • Lee, Jae Kwan;Lee, Sol;Yun, Suk Jin
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2148-2154
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    • 2013
  • Three push-pull organic semiconductors, TPA-$Th_3$-MMN (1), TPA-ThTT-MMN (2), and TPA-ThDTT-MMN (3), comprising a triphenylamine donor and a methylene malononitrile acceptor linked by various ${\pi}$-conjugated thiophene units were synthesized, and the effects of the ${\pi}$-conjugated bridging unit on the photovoltaic characteristics of solution-processed small-molecule organic solar cells based on these semiconductors were investigated. Planar bridging units with extended ${\pi}$-conjugation effectively facilitated intermolecular ${\pi}-{\pi}$ packing interactions in the solid state, resulting in enhanced $J_{sc}$ values of the SMOSCs fabricated with bulk heterojunction films.

Synthesis and Optical Properties of Poly(hydroxyphenylbenzoxazole): A Colorimetric and Fluorescent Sensor for Ionic Species

  • Lee, Jin-Koo;Kim, Tae-Hyun;Kim, Young-shin;Gang Li;Park, Won-Ho;Lee, Taek-Seung
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.23-24
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    • 2003
  • We synthesized a poly[2-(2'-hydroxyphenyl) benzoxazole] under the two step procedures of Suzuki coupling polymerization with corresponding monomers followed by the deprotection of benzyl group. The polymer in DMF solution is applicable to colorimetric sensing fluoride anion, which shows a color change from colorless to yellow. High sensitivity to fluoride anion compared to other anions such as phosphate, chloride, and sulfate is ascribed to the high coordination ability of the 2-(2'-hydroxy phenyl)benzoxazole moiety in the polymer chain. Emission shift by metal cations, which can be applied to fluorescent sensing w as also observed in the polymer solution.

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Adsorption of Hydrophobic Organic Compounds from Aqueous Solution with CTAB Coated Silicate (CTAB가 코팅된 Silicate을 이용한 소수성 유기물질의 흡착)

  • 김학성;정영도;한훈석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.78-84
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    • 1995
  • Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

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Corrosion Resistance by Organic/Inorganic Hybrid Solution for Cold Rolled Steel of SPCC and SPFC590 for Automobile (자동차용 냉연강판 SPCC와 냉연고장력강판 SPCF590의 유/무기 하이브리드 용액에 의한 내식특성)

  • Lee, So-Young;Lee, Kwang-Ho;Jeong, Hee-Rok;Nam, Ki-Woo
    • Journal of Power System Engineering
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    • v.19 no.5
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    • pp.38-44
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    • 2015
  • The cold-rolled steel sheet for automobile is liable to corrosion, and will be painting in a variety of ways for the anticorrosive. This paper was coated on cold rolled steel (SPCC and SPFC590) for automobiles using five kinds of organic/inorganic hybrid solution. This was evaluated corrosion resistance and so on by the salt spray. Corrosion area was less according to increasing of curing time in 2 types of steel plate with 5 types of the coating solution. No.1 solution was showed the best corrosion resistance regardless of the kinds of the steel sheet. It is judged that the melamin hardner had the role of bridge between $SiO_2$ polysilicate and urethan resin. Other properties were excellent in all solution.

Regeneration of $FeCl_3$ from a Spent Etching Solution Containing Nickel by Solvent Extraction (니켈 함유 에칭폐액으로부터 용매추출에 의한 $FeCl_3$의 재생)

  • Lee, Kyoung-Joo;Lee, man-Seung;Oh, Young-Joo
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.218-226
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    • 2004
  • Solvent extraction and stripping experiments were conducted to separate iron from a spent $FeCl_3$ etching solution containing nickel. In the extraction, PC88A, MIBK and Alamine336 were tested as an extractant in various diluents. Alamine336 salt in toluene led to the highest extraction percentage of iron. Stripping percentage of iron from the loaded organic by Alamine336 increased with decreasing HCl conentration of stripping solution and with increasing volume ratio of aqueous to organic. In the operation of bench scale mixer-settler, 7 extraction stage with 1.0M Alamine336 salt in toluene and 10 stripping stage with 0.01M HCl solution resulted in a stripped solution with 133g/L of iron and in a raffinate with most of nickel together with a small amount of iron when the flow rate ratio of organic to aqueous was 7.

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Corrosion Resistance of Degraded STS310S and STS347H by Cr-free Modified Si Organic/Inorganic Hybrid Coating Solution (Cr-free Si 변성 유/무기하이브리드 코팅액에 의한 열화된 STS310S 및 STS347H의 내식성)

  • Lee, So-Young;Kim, Young-Soo;Jeong, Hee-Rok;Kim, Gui-Shik;Nam, Ki-Woo
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.12-18
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    • 2015
  • Austenitic stainless steels generally experience the occurrence of chromium-depleted zones at the boundaries, known as sensitization, caused by the carbide precipitation that takes place due to a welding process or heat treatment. Normally, the depleted zones become the focus of the intense corrosion. In this study, the Cr-free organic/inorganic hybrid solution was developed, and the artificially degraded STS316S and STS347H with the solution-coating investigated the corrosion resistance by salt spray test. Both the OIBD-1 and OIBD-2 solutions improved the corrosion resistance of STS310S and STS347H. The corrosion resistance with the OIBD-1 solution was better than that of OIBD-2 solution. Additionally, Both solutions have been proven excellence in adhesion ability, boiling water resistance and flexibility. However, a problem of rubbing after the boiling was found out to be overcome.

Solution-processible corrugated structure and scattering layer for enhanced light extraction from organic light-emitting diodes

  • Hyun, Woo Jin;Im, Sang Hyuk;Park, O Ok;Chin, Byung Doo
    • Journal of Information Display
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    • v.13 no.4
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    • pp.151-157
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    • 2012
  • A simple method of fabricating out-coupling structures was demonstrated via solution-processing to enhance light extraction from organic light-emitting diodes (OLEDs). Scattering layers were easily obtained by spin-coating an $SiO_2$ sol solution that contained $TiO_2$ particles. By introducing the scattering layer and the solution-processible corrugated structure as internal and external extraction layers, the OLEDs showed increased external quantum efficiency without a change in the electroluminescence spectrum compared to conventional devices. Using these solution-processible out-coupling structures, nearly all-solution-processed OLEDs with enhanced light extraction could be fabricated. The light extraction enhancement is attributed to the suppression by the out-coupling structures of the light-trapping that arose at the interface of the glass substrate and the air.