• 제목/요약/키워드: Organic Pollutants

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남해 연안 해역에 있어서 미량유기오염물질의 정량적 평가 (Quantitative Assessment of Micropollutants in the Southern Coastal Waters of Korea)

  • 한상국;박지영;이종삼
    • 한국해양환경ㆍ에너지학회지
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    • 제8권4호
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    • pp.213-219
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    • 2005
  • 본 연구는 310종 다성분 동시분석 법을 활용하여 남해 연안 해역 중 광양만, 여자만, 가막만에서의 미량유기오염물질에 의한 오염특성을 규명하고자 하였다. 채수지점에서 검출된 주요 미량유기오염물질은 aliphatic, polycyclic compounds 와 같은 CH기의 화학물질과 aromatic ammines, nitro compounds와 같은 CHN(O)기의 화학적 구조를 갖는 물질이었다. 미량유기오염물질의 농도는 겨울철보다는 여름철에 높게 나타났으나 검출된 물질 종수와 계절적 상관성은 뚜렷하게 나타나지 않았다. 남해 연안 해역에서 검출된 농약의 총량은 $ND{\sim}9.11$ 이었으며 광양만과 가막만에서 살충제와 제초제의 검출이 집중적으로 관찰되었다. 또한 남해 연안 해역에서 환경호르몬성 물질은 총 6종이 검출되었다. 이러한 결과로부터 남해연안해역의 주요오염인자는 살충제와 제초제, 그리고 수종의 환경호르몬성 물질로 판단된다.

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이포보 상류 용존 유기물의 공간적 분포 분석 (Spatial Distribution of Dissolved Organic Matter Compositions Upstream of Ipobo)

  • 윤상미;최정현
    • 한국물환경학회지
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    • 제34권4호
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    • pp.399-408
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    • 2018
  • This research investigated the effects of weir (Ipobo) construction on the dynamics and the related spatial distributions of pollutants inflowing from tributaries (Yanghwacheon and Bokhacheon). Conductivity measurements and water sampling were conducted longitudinally, horizontally, and vertically in the waterbody upstream of the area located in Ipobo. Additionally, collected water samples were used for the dissolved organic carbon (DOC) analysis and fluorescence analysis which results in the SUVA, HIX, BIX, and FI calculation and parallel factor analysis (PARAFAC). Consequently, the results of the Conductivity, DOC, SUVA, and HIX showed that high concentration of pollutants that were flowing from the area of Bokhacheon which was mixed along the flow of the main river. The results of the BIX and FI did not show significant difference along the river flow which represented that allochthonous and terrestrial DOM, and for this reason was dominated in the whole waterbody rather than just the autochthonous DOM. The PARAFAC results showed that the two fluorescence components, humic-like and protein-like, constituted the fluorescence matrices of the water samples. The prevailing discipline notes that the two components were inflowing from the tributaries, however, a refractory component, humic-like substances, was relatively accumulated near the weir. From the results, the dynamics and spatial distributions of the DOM are dependent on the DOM characteristics, which induces the application of a specialized DOM analysis method to investigate the effects of a subsequent weir construction on the dynamics and spatial distributions of pollutants inflowing from the tributaries.

ACE-Asia 집중관측기간에 제주고산에서 측정한 대기오염물질의 농도 분포특성 (Concentrations of Air Pollutants Measured at Kosan during ACE-Asia Intensive Observation Period)

  • 신혜정;김지영;최병철;오성남
    • 한국대기환경학회지
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    • 제18권6호
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    • pp.487-501
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    • 2002
  • The concentrations of gaseous (NO$_{x}$, SO$_2$, and $O_3$) and particulate (Elemental Carbon, EC and Organic Carbon, OC) pollutants were measured to evaluate the air quality of Kosan. Samples were taken at Kosan during ACE-Asia (Asian Pacific Regional Aerosol Characterization Experiment) IOP (Intensive Observation Period) (2001. 3. 21~2001. 5. 5). The mean concentrations of $O_3$(46.3$\pm$10.4 ppb) is higher than those at urban area such as Seoul and Busan in Korea. On the other hand, the mean concentrations of other gaseous species, NO$_{x}$(4.73$\pm$3.42 ppb) and SO$_2$(0.62$\pm$0.63 ppb) are lower than those at great cities. So we concluded that there are a few primary sources emitting atmospheric pollutants. The concentration of EC is higher and the concentration of OC is similar with or higher than those at other background sites. The recent EC concentration is higher than those measured before at Kosan. We concluded that there are more primary sources than other background sites and the amount of primary source have increased recently in Jeju. Backward trajectory and co..elation analysis were used to study where the air masses originated and distinguish the source of pollutants. While NO$_{x}$ and $O_3$ were mainly emitted and formed from Jeju inland area, concentrations of SO$_2$, OC and EC were affected by Asian Dust from China. Using the mean relative standard deviation of ozone, cleanness coefficient was obtained. The cleanness coefficient value, is 1.6 times larger than the value in 1992. Recently, the air quality of Kosan has been contaminated because of the Asian Dust events since spring and the rapid industrialization development.pment.

충청지역 농업용수 중 농약 유래 POPs의 모니터링 연구 (Pesticide-Originated Persistent Organic Pollutants in Agricultural Waterways in Chungcheong Province, Korea)

  • 이화성;전황주;이회선;이성은
    • Journal of Applied Biological Chemistry
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    • 제58권4호
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    • pp.291-294
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    • 2015
  • 잔류성유기오염물질(POPs)은 현재 사용이 금지된 유기염소계 농약을 포함하고 이들은 국내 농업환경 중 발견이 되며 이들의 작물로의 이동 또한 보고되고 있다. 본 연구는 충청도 지역 15곳의 농업용수를 채취하여 이들 시료 중 POPs를 모니터링 하고자 하였으며 이들 시료는 액액분배를 통한 추출 및 정제컬럼을 이용한 정제과정을 거쳐 기체크로마토그래피에 의하여 분석되었다. 농약유래 POPs 중 ${\alpha}$-endosulfan이 0.01-1.13 ng/mL 수준에서 검출되었으며, ${\beta}$-endosulfan과 endosulfan sulfate는 각각 0.01-0.55 ng/mL 및 0.13-1.13 ng/mL 수준에서 검출되었다. 총 endosulfan 검출량은 0.38-1.18 ng/mL이었다. 현재 사용중인 농약 중 triadimefon 은 2.03-2.05 ng/mL 수준에서, tolyfluanid은 0.26-0.33 ng/mL 수준에서, chlorpyrifos는 1.34-3.85 ng/mL 수준에서 검출되었다. 농약계 POPs 중 endosulfan류의 물질들의 잔류가 확인되었고 이들의 환경 중 지속적인 모니터링이 필요하다.

CTAB가 코팅된 Silicate을 이용한 소수성 유기물질의 흡착 (Adsorption of Hydrophobic Organic Compounds from Aqueous Solution with CTAB Coated Silicate)

  • 김학성;정영도;한훈석
    • 환경위생공학
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    • 제10권3호
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    • pp.78-84
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    • 1995
  • Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

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축산에서 기후변동 관련 기체의 발생원과 방지대책 (Possibilities for Reduction and the Emissions of Trace Gases from Livestock System)

  • 류종원
    • 한국축산시설환경학회지
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    • 제4권1호
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    • pp.37-45
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    • 1998
  • There are a lot of trace gas of gaseous pollutants produced from farm animals. CO2 and CH4 are gases produced directly by the animal. NH3, N2O are produced from animal waste. Most of the effects of these gaseous pollutants on the farm animals have not been investigated in detail. CO2 emission from animal is very little. CH4 release from ruminant is also considered to be a significant factor in potential global warming. Nitrous oxide (N2O) emissions could be avoided by using organic or mineral fertilizer only as much as is needed by plant growing. This paper gives an overview about problems and solving strategies for possibilities for reduction of gaseous pollutants. The way to reduce the gaseous pollution risks from livestock systems are discussed.

Viologen 유도체를 이용한 항만오염물질의 전기화학적 센싱 특성 연구 (Study on Electrochemical Sensing Property of Harbor Pollutants using Viologen Derivative)

  • 박상현;이동윤;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
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    • pp.119-120
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    • 2008
  • In this paper, viologen derivative is used as charge transfer material to develop sensors for detecting the organic pollutants which are the main reason of harbor pollution. We fabricated self-assembled monolayers of viologen derivative on gold electrode of QCM and investigated an electrochemical behavior property. We also determined electrochemical sensing property about environmental pollution materials such as bezene, phosphate and surfactant through quantitative and qualitative analysis of charge transfer using intrinsic property of viologen derivative by temperature and concentration change. From the achieved results, we can apply and develope the detecting sensors for harbor pollutants.

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흡착 소재별 도로 노면 유출 오염원의 저감성 비교 연구 (Feasibility Study with Several Sorption Materials to Treat Road Runoff Pollutions)

  • 박상우;오재일;최영화
    • 상하수도학회지
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    • 제20권5호
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    • pp.709-717
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    • 2006
  • This research was conducted to figure out the feasibility of several sorption materials to treat various pollutants in road runoff. In advance of the major feasibility test with various sorption materials, the separation process with $1.2{\mu}m$ filter was conducted and showed that slight portion of pollutants was removed(Orgamic pollutant - 20%, Nutrient salt - 50%, Heavy metals - 0~30%). To remove dissolved pollutants in runoff, various materials were tested through an isotherm sorption experiment. As a result, GAC showed most effective material among them to lessen most contaminants such as organic compounds and nutrients. On the other hand, ion-exchange resin and Zeolite showed limited usefulness on the some heavy metals. Freundlich model was most suitable for the current experiment data, and the amount of adsorbent (GAC) could calculated based on this model.

서울시 대기중 유기오염물질의 농도와 돌연변이원성에 대한 연구 (Atmospheric concentration and mutagenicity of organic pollutants of suspended particulate in Seoul)

  • 신동천;정용;문영한;노재훈
    • Journal of Preventive Medicine and Public Health
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    • 제23권1호
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    • pp.43-56
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    • 1990
  • To evaluate the difference of concentration and mutagenicity of organic pollutants between residential and traffic area of Seoul, air samples were collected in Bulkwang (residential) and Shinchon (traffic) area. Samples were analyzed to measure the concentration of extractable organic matters (EOM) and their subfractions and mutagenicities were tested using Salmonella typhimurium TA 98. The concentrations of polycyclic aromatic hydrocarbons (PAHs) were also measured by gas-chromatography and compared between two areas. The results were as follows ; 1. While the concentration of total suspended particulate (TSP) in residential area was below the environmental standard in annual average, the concentration in traffic area was above the standard and was up to its maximum $256{\mu}g/m^3$ in November. The difference of TSP concentrations in both areas of each month was statistically significant (P<0.05). 2. The concentration of fine particle in traffic area was significantly higher compare to that in residential area and showed statistically significant monthly difference in both areas (P<0.05). The proportion of concentration of fine particle to TSP was 55-68%. 3. Mean concentrations of EOM in residential and traffic areas were $4.3{\mu}g/m^3\;and\;5.3{\mu}g/m^3$ respectively. The proportion of amount of EOM from fine particle to EOM from TSP was 70-88%. 4. While the percentage of polar neutral organic compounds (POCN) of fine particle in Bulkwang's sample was higher compare to Shinchon's sample, the percentage of aliphatic compounds of fine particle in Shinchon's sample was higher compare to Bulkwang's sample. The percentages of PAH fraction were as low as 6-10% in both areas. 5. The mutagenic activity of nit concentration of organic matters extracted from fine particle was higher compare to that of coarse particle and was increased when metabolically activated with S9. Mutagenicities with metabolic activation calculated by unit air volume were significantly different between residential and traffic area, $17\;revertants/m^3$\;and\;22\;revertants/m^3$ respectively. 6. The concentrations of benzo(a)pyrene in fine particle of traffic and residential areas were $3.10ng/m^3\;and\;2.02ng/m^3$ respectively. Sixteen PAHs were higher in samples of traffic area compare to residential area and also concentrations of PAHs in fine particle were higher compare to coarse particle.

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버섯 다원적 기능의 접근 (Approach on the multifunctionality of mushroom)

  • 장현유;구창덕;박윤식;고인수;김양식
    • 한국버섯학회지
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    • 제8권1호
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    • pp.1-5
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    • 2010
  • 버섯의 다원적 기능은 생리활성 기능, 가축 사료생산 기능, 유기질 비료 생산 기능, 생태계 분해자로서의 기능, 환경 오염물질 정화 기능, 식품 영양학적, 기호 식품적, 생리활성 기능 이다. 이 중 생리활성 기능, 가축 사료생산 기능, 유기질 비료 생산 기능과 생태계 분해자로서의 기능은 정량화를 하였고 그 나머지 기능은 정량화하는 연구가 더 필요하였다. 정량화된 버섯의 다원적 기능을 경제적 가치로 환산하면 112조 922억원이며 정량화하지 못한 부분까지 합하면 이의 2배 이상될 것으로 추정한다. 이렇게 추정할 경우 쌀의 다원적 기능 약 100조원의 경제적 가치에 비해 버섯은 거의 비슷한 가치가 있다고 볼 수 있다. 버섯의 생리활성물질 베타글루칸의 산업적 가치는 약 112조원, 가축 사료생산 기능은 약 618억원, 유기질 비료생산 기능은 약 56억원, 생태계 분해자로서의 기능은 약 360억원으로 나타났다.

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