• 펄프종이기술
• /
• 제46권3호
• /
• pp.37-43
• /
• 2014

Kinetics of holocellulose hydrolysis in concentrated sulfuric acid was analyzed using $^1H$-NMR spectroscopy with different reaction time, temperature and acid concentration in secondary hydrolysis. In this work, reaction condition of secondary hydrolysis was similar to concentrated sulfuric acid process with electrodialysis or simulated moving bed chromatography process for sulfuric acid recycling. By $^1H$-NMR spectroscopy, acid hydrolyzates from higher secondary acid hydrolysis (25-35% acid concentration) was successfully analyzed without any difficulties in neutralization or adsorption of acid hydrolyzate to solid salt. Higher acid concentration, higher temperature and longer reaction time led to more cellulose for glucose conversion but accompanied with glucose to galactose isomerization, glucose to unknown compounds and degradation of glucose to organic acid via furans.

• 생약학회지
• /
• 제47권3호
• /
• pp.217-221
• /
• 2016

Endophytic fungi have yielded a variety of secondary metabolites so far. In the course of the project to find bioactive secondary metabolites from cultures of endophytic fungi, an isolate of Arthrinium phaeospermum (JS 0567) was selected for chemical investigation. A large scale culture of this strain in rice media was extracted with an organic solvent and the extract was subjected to a serious of chromatography, which led to six metabolites. Their chemical structures were elucidated as 2,3,6,8-tetrahydroxy-1-methylxanthone(1), 2,3,4,6,8-pentahydroxy-1-methylxanthone(2), 3,4,6,8-tetrahydroxy-1-methylxanthone(3), 3,6,8-trihydroxy-1-methylxanthone(4), 2,4,2',4',6'-pentahydroxy-6-methylbenzophenone(5), and 5,7-di hydroxy-3-methylphthalide(6) on the basis of spectroscopic data. To the best of our knowledge, this is the first study on the secondary metabolites from Arthrinium phaeospermum.

• Transactions on Electrical and Electronic Materials
• /
• 제5권5호
• /
• pp.173-179
• /
• 2004

The influence of heavily Si impurity doping in the GaN barrier of InGaN/GaN multi-quantum well structures of blue light emitting diodes were investigated by growing samples in metal-organic chemical vapor deposition. The delta-doped sample was compared to the sample with the undoped barrier. The delta-doped sample shows the tunneling behavior and forms the energy level of 0.32 eV for tunneling and the photoemission of the 450-nm band. The photo-luminescence shows the blue-shifted broad band of the radiative transition due to the inclusion of Si delta-doped layer indicating that the delta doping effect acts to form the higher energy level than that of quantum well. The dislocation may provide the carrier tunneling channel and plays as a source of acceptor. During the tunneling of hot carrier, there was no light emission.

• 반도체디스플레이기술학회지
• /
• 제3권4호
• /
• pp.39-43
• /
• 2004

The parallel multi-quantum well structures of blue and amber lights were designed and grown in metal-organic chemical vapor deposition by utilizing integration process on epitaxial layers. Samples were deposited for 5 periods-InGaN multi-quantum well layers for blue light emission and partially etched in order to regrow the 3 periods-InGaN multi-quantum wells for amber light. The blue and amber photoluminescence spectra were observed at the peak wavelengths of 475 and 580 nm, respectively. The chromatic coordinates of the white emitting diode were 0.31 and 0.34.

• Bulletin of the Korean Chemical Society
• /
• 제32권3호
• /
• pp.1007-1010
• /
• 2011

$Ir(dpq/dpqx)_2$(przl-R) complexes were prepared and their electrochemical properties were investigated, where dpq, dpqx and przl-R represent 2,3-diphenylquinoline, 2,3-diphenylquinoxaline and N-phenyl-R-pyrazolonate derivatives, respectively. The iridium complexes containing dpq and dpqx as main ligands were reported to show red phosphorescence, and involvement of a pyrazolonate ancillary ligand in the iridium complexes led to high luminous efficiency for organic light-emitting diodes. In this study, we synthesized red phosphorescent iridium complexes containing a new pyrazolonate ancillary ligand and investigated the HOMOs, LUMOs and resulting electrochemical gaps of $Ir(dpq/dpqx)_2$(przl-R) by cyclic voltammetry. The emission wavelengths of the complexes at 600 - 640 nm were consistent with the gaps of 1.95 - 2.03 eV measured from reduction and oxidation potentials of the complexes.

• 한국세라믹학회지
• /
• 제54권6호
• /
• pp.449-469
• /
• 2017

The development of quantum dots (QDs) has had a significant impact on various applications, such as solar cells, field-effect transistors, and light-emitting diodes (LEDs). Through successful engineering of the core/shell heterostructure of QDs, their photoluminescence (PL) quantum yield (QY) and stability have been dramatically enhanced. Such high-quality QDs have been regarded as key fluorescent materials in realizing next-generation display devices. Particularly, electrically driven (or electroluminescent, EL) QD light-emitting diodes (QLED) have been highlighted as an alternative to organic light-emitting diodes (OLED), mostly owing to their unbeatably high color purity. Structural optimizations in QD material as well as QLED architecture have led to substantial improvements of device performance, especially during the past decade. In this review article, we discuss QDs with various semiconductor compositions and describe the mechanisms behind the operation of QDs and QLEDs and the primary strategies for improving their PL and EL performances.

• 반도체디스플레이기술학회지
• /
• 제4권2호
• /
• pp.21-24
• /
• 2005

Ink-jetting characteristics of pulse width and pulse amplitude for a piezoelectric ink jet printer driver have been mapped with various polymer EL ink. In this study, the jetting characteristics have been classified into 4 regime; no Jetting, unstable jetting, stable jetting, and spraying, and the importance of fluid viscosity on the scope of the stable jetting regime has been emphasized. The relation between jetting speed and the width and amplitude of driving signal has also been investigated and the effect of the speed on the jetting characteristics has been discussed.

• Journal of Forest and Environmental Science
• /
• 제29권2호
• /
• pp.125-130
• /
• 2013

An attempt was made on pulp production from the fast growing plant, Acacia hybrid to determine the total yield, screened yield, Kappa number, and fibre morphology of organosolv Acacia hybrid pulp. Uniform-sized chips were taken to undergo pulping in a digester with five different concentrations of ethanol, 50%, 60%, 70%, 80% and 90% (v/v) with 1 M of sodium hydroxide as catalyst. All chips were digested in a temperature-controlled digester with constant amount of water added and temperature of $185^{\circ}C$ with the duration of three hours cooking time and correspond pressure 1.1-1.2 MPa. It was observed that increasing of ethanol concentration has led to pulp yield increment and decreased in the degree of delignification at the same time. This study was aimed to focus on the effect of the varied concentration of organic solvent towards the pulp yield and its relationship with Kappa number and pulp yield.

• Journal of Information Display
• /
• 제12권2호
• /
• pp.85-87
• /
• 2011

The contrast ratio is one of the most important performance parameters for display devices. The general method of measuring the contrast ratio is to determine the ratio of the full-screen white pattern to the full-screen black pattern, according to the Video Electronics Standards Association standard. Real TV images seldom have these images, however, and the conventional method does not reflect the true performance of the display in actual use. In this paper, a new contrast ratio measurement method that uses image patterns is proposed, to demonstrate that active matrix organic light-emitting diode TVs have a higher contrast than LED (LCD) TVs.

• Journal of Microbiology and Biotechnology
• /
• 제16권4호
• /
• pp.637-638
• /
• 2006

Bioassay-guided fractionation of an organic extract of the culture broth from an unidentified marine-derived fungus led to the isolation of a new metabolite, N-[2-(4-hydroxyphenyl) acetyl]formamide (1), along with four known polyketides, 4-hydroxyphenyl acetamide (2), 4-hydroxyphenyl acetic acid (3), 3,4-dihydroxyphenyl acetic acid (4), and N-[2-(4-hydroxyphenyl)ethenyl]formamide (5). The structures of 1-5 were elucidated by spectral data analyses. Among them, compounds 1, 4, and 5 exhibited significant radical scavenging activity against 1, 1-diphenyl-2-picrylhydrazyl (DPPH) with $IC_{50}$ values of 8.4, 11.9, and $0.2{\mu}M$, respectively.