• 제목/요약/키워드: Organic Cation

검색결과 487건 처리시간 0.028초

e-beam 증발법으로 제조된 비정질 WO3박막과 전해질 계면으로 삽입되는 리튬의 층간 반응에 관한 전기화학적 특성 (Electrochemical Characteristic on Lithium Intercalation into the Interface between Organic Electrolyte and Amorphous WO3 Thin Film Prepared by e-beam Evaporation Method)

  • 민병철;손태원;주재백
    • 공업화학
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    • 제8권6호
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    • pp.1022-1028
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    • 1997
  • 본 연구에서는 1M $LiClO_4/PC$ 유기 용액 중에 존재하는 리튬 이온의 층간 반응에 의하여 전기 발색 현상을 나타내는 전자-선 증발법으로 제조된 비정질의 텅스텐 산화물 박막과 전해질 계면에서의 전기화학적 특성들을 연구하기 위하여 음극 Tafel 분극법, 순환 전류-전위법 및 전기량 적정법 등의 전기화학 측정법과 X선 회절 분석법을 이용한 박막의 결정 상태 조사 등이 수행되었다. 특히 다중 순환 전류-전위 곡선으로부터 리튬 이온의 층간 반응은 발색 반응에 대한 인가 과전압이 약 1.0V 이내에서는 안정된 소 발색의 가역적 현상을 나타내었으나, 발색 반응에 대한 인가 과전압이 1.5V일 때는 발색 시 삽입된 박막 내부의 리튬이 소색 시 완전히 빠져 나오지 못하여, 박막 내부에 리튬이 축적되는 현상을 나타내었으며, 적은 순환 횟수임에도 불구하고 소 발색의 전류 밀도가 감소되는 것이 조사되어 발색에 필요한 인가 과전압의 한계가 존재함을 알 수 있었다.

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다양한 상대 양이온을 갖는 Cy3 염료의 제조 및 특성 연구 (Preparation and Characterization of Cy3 Dye with Various Counter Cations)

  • 이상동;현동균;정연태
    • 한국전기전자재료학회논문지
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    • 제28권5호
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    • pp.314-319
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    • 2015
  • In this research, we focused on the development of cy3 dye with high thermal stability and good solubility for LCD color filter. Cy3 dyes were prepared through the synthetic procedure of two steps. The synthesized cy3 dyes were characterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed maximum absorption wave length (${\lambda}_{max}$) in the range of 549~555 nm in UV/Vis spectrum. And we confirmed that solubility characteristics and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with methyl counter cation and ethyl counter cation have good solubility in organic solvents such as chloroform, ethanol, and PGME. Moreover, Cy3 dye with ethyl counter cation gave excellent thermal stability in TGA thermograms. And Cy3 dye with ethyl counter cation showed good result in photoresist film test.

신축성사 개발 및 물성평가 : 코어(core)사와 장식(effect)사간의 동색성 및 염색성 평가 (Preparation and Characterization of Stretch Fabric : Dyeing Properties of Core Yarn and Effect Yarn)

  • 강기혁;김영성;손영아
    • 한국염색가공학회지
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    • 제22권2호
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    • pp.140-144
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    • 2010
  • In this study, we investigated the clean appearance and good stretch properties. Usually, clean appearance concerned with the dyeing properties of core and effect yarns. The dyeing properties between core yarn (conjugate yarn) and effect yarn were determined by the build-up and the color differences using the four different yarns of SDY FD(spindraw yarn full dull), SDY CD(spindraw yarn cation dyeable), POY FD( partially-oriented yarn full dull) and POY CD(partially-oriented yarn cation dyeable). We used the single color dye of C. I. Disperse Blue 79 and mixed colors made by C. I. Disperse Red 60, C. I. Disperse Blue 56, and C. I. Disperse Yellow 54.

상토로서 지렁이 분립이 엽채류의 생육에 미치는 영향

  • 김인수;김성진;이지영;이주삼
    • 한국유기농업학회:학술대회논문집
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    • 한국유기농업학회 2005년도 하반기 학술대회 발표 논문집
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    • pp.55-64
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    • 2005
  • 1. 지렁이 분립량이 증가할수록 용적비중(bulk density), 유효수분함량(available water content), pH, 전기전도도(electrolytic conductivity), 무기물(ash), 전질소(total nitrogen), 양이온치환능력(cation exchange capcaity), 유효인산(available $P_{2}O_{5}$), 치환성양이온(exchangeable cation)이 증가하였다. 2. 근대는 분립 40${\sim}$100%의 혼합비율에서 초장(PL), 엽면적(LA), 엽수(NL), 엽면적(LA), 지상부 건물중(SHW), 근중(RW), 줄기두께(SD), 근중(RW) 및 생물학적수량(BY)이 다른 처리구보다 유의하게 높았다. 3. 열무는 분립 40${\sim}$60%의 혼합비율에서 초장(PL), 지상부 건물중(SHW), 근중(RW), 생물학적수량(BY)이 다른 처리구보다 유의하게 높았다. 3. 시금치와 상추는 40%의 혼합비율에서 지상부중(SHW), 근중(RW), 생물학적수량(BY)이 다른 처리구에 비해 유의하게 높았다(p${\leq}$0.05).

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Synthesis and Characterization of Molecular Composite Prepared from Layered Perovskite Oxide, $HLa_2Ti_2NbO_{10}$

  • 홍영식;김시중
    • Bulletin of the Korean Chemical Society
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    • 제18권6호
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    • pp.623-628
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    • 1997
  • A layered perovskite oxide, $RbLa_2Ti_2NbO_{10}$, was prepared and investigated for proton exchange and intercalation behaviors. Its protonated form, $Hla_2Ti_2NbO_{10}$, exhibits the Bronsted acidity and reacts with organic amines. Polyoxonuclear cation, 4Al_{13}$, was then introduced into the interlayer by refluxing octylamine-intercalated compound with an $Al_{13}$ pillaring solution. These layered oxides were characterized by X-ray diffractometer, thermogravimeter, FT-infrared spectrometer and elemental analyzer. It is observed that the polyoxonuclear cation-pillared material exhibits a bilayer structure and is thermally more stable than organic counterpart at higher temperatures. The surface area of the pillared material annealed at 400 ℃ was the value of 25.1 m²/g.

식재기반 복원을 위한 유기질계 토양개량재의 효용성 (Effects of Soil Organic Amendment as Plant Growing Media Component for Restoration of Planting Ground)

  • 주진희;인다영;김원태;윤용한;최은영
    • 한국환경과학회지
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    • 제24권11호
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    • pp.1363-1370
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    • 2015
  • This study was aimed to determine effects of soil organic amendment as plant growing media component on restoration of planting ground. The changes of soil physical and chemical properties and germination and growth of kentucky bluegrass (Poa pratensis L.) were investigated. For treatments, soil was excavated at depth of 0-50 cm (referred as $S_1$) and at depth of 50-100 cm (referred as $S_2$). Then the half amount of $S_1$ soil was mixed with the soil organic amendment (coir dust 40% (v/v), bottom ash 25%, leaf mold 25%, vermiculite 5%, carbonized rice hull 5%) at a rate of 6% (v/v) (referred as $S_1CC$) and also the half amount of $S_2$ soil was mixed with the soil organic amendment at a rate of 6% (v/v) (referred as $S_2CC$) on pot in a 16 cm diameter and 14 cm height. The experiment was replicated 3 times with 3 pots per replication in randomized block design, and 100 seeds were planted per pot. In results, there was no significant difference in soil pH among the treatments with a slight decrease in soil hydraulic conductivity. However, in the $S_1CC$ treatment, positive increases in soil chemical properties, including electrical conductivity, organic matter, phosphoric acid, total nitrogen, exchangeable cation, and cation exchange capacity. Also, the germination rate, plant height, and number of leaves were higher in the $S_1CC$ treatment than those in other treatments. These results suggest that the addition of organic amendment to the soil at depth of 0-50 cm might be proper for restoring planting ground.

Donepezil, Tacrine and $\alpha-Phenyl-n-tert-Butyl Nitrone$ (PBN) Inhibit Choline Transport by Conditionally Immortalized Rat Brain Capillary Endothelial Cell Lines (TR-BBB)

  • Kang Young-Sook;Lee Kyeong-Eun;Lee Na-Young;Terasaki Tetsuya
    • Archives of Pharmacal Research
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    • 제28권4호
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    • pp.443-450
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    • 2005
  • In the present study, we have characterized the choline transport system and examined the influence of various amine drugs on the choline transporter using a conditionally immortalized rat brain capillary endothelial cell line (TR-BBB) in vitro. The cell-to-medium (C/M) ratio of $[^3{H}]choline$ in TR-BBB cells increased time-dependently. The initial uptake rate of $[^3{H}]choline$ was concentration-dependent with a Michaelis-Menten value, $K_{m}$, of $26.2\pm2.7{\mu}M$. The $[^3{H}]choline$ uptake into TR-BBB was $Na^{+}-independent$, but was membrane potential-dependent. The $[^3{H}]choline$ uptake was susceptible to inhibition by hemicholinium-3, and tetraethy-lammonium (TEA), which are organic cation transporter substrates. Also, the uptake of $[^3{H}]choline$ was competitively inhibited with $K_{i}$ values of $274 {\mu}M, 251 {\mu}M and 180 {\mu}M$ in the presence of donepezil hydrochloride, tacrine and $\alpha-phenyl-n-tert-butyl nitrone$ (PBN), respectively. These characteristics of choline transport are consistent with those of the organic cation transporter (OCT). OCT2 mRNA was expressed in TR-BBB cells, while the expression of OCT3 or choline transporter (CHT) was not detected. Accordingly, these results suggest that OCT2 is a candidate for choline transport at the BBB and may influence the BBB permeability of amine drugs.

포도 '거봉' 품질에 미치는 토양이화학성의 상대적 기여도 (Contribution Rate on Soil Pysico-Chemical Properties Related to Fruit Quality of 'Kyoho' Grapevines)

  • 김승희;최인명;한점화;조정건;박서준;임태준;윤해근
    • 한국토양비료학회지
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    • 제43권6호
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    • pp.782-788
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    • 2010
  • Detail management standard on soil conditions in 'Kyoho' grapes were not yet made. Therefore, this study was carried out to investigate the optimum soil environmental conditions on production of high fruit quality in 'Kyoho' grapes. We established using correlation between fruit quality and soil condition. These results were used to develop soil management guideline with promoting efficiency and minuteness in grape vineyard. Soil conditions were analyzed at total 80 vineyards in major grape producing areas such as Ansung, and Cheonan (40 orchards an area). The soil environmental factors affected fruit weight were soil pH of 36.6%, cultivation layer depth of 23.3%, and cation of 17.8%. The soil condition factors affected sugar content were soil hardness of 24.4%, cation of 24.1% and organic matter content of 22.1%. Cultivation layer depth, soil texture, and phosphate content were low as relative contribution. Coloring was involved with organic matter content, CEC (cation exchange capacity), and saturated hydraulic conductivity. while soil pH, cultivation layer depth, and phosphate content showed low contribution. Finally, relative contribution on fruit quality related with sugar content, fruit weight, and coloring were soil hardness of 28.0%, organic matter content of 25.0%, soil pH of 12.9%.

우리나라 토양(土壤)의 물리화학적(物理化學的) 특성(特性) 상호관계(相互關係)에 관(關)한 연구(硏究) (A Study on the Correlations among the Physical and Chemical Properties of Soils in Korea)

  • 조인상;허봉구;김리열;조성진
    • 한국토양비료학회지
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    • 제18권2호
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    • pp.134-139
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    • 1985
  • 정밀토양조사(精密土壤調査) 결과(結果) 밝혀진 315개(個) 토양(土壤)(제주도(濟州道) 60개(個) 토양(土壤) 제외(除外))에 대한 14개(個) 토양특성(土壤特性)을 수집(蒐集)하여 토지이용별(土地利用別), 토심별(土深別), 배수등급별(排水等級別)로 단순상관(單純相關)과 다중상관(多重相關)을 분석(分析)하였다. 토양물리화학적(土壤物理化學的) 성질(性質) 상호관계(相互關係)가 밝혀졌으며 점토함량(粘土含量)과 유기물함량(有機物含量)을 가지고 양(陽)이온 치환용량(置換容量)(CEC)을 계산(計算)할 수 있는 회귀식(回歸式)을 구(求)하였는데 우리나라 점토(粘土)의 CEC는 22me/100g, 유기물(有機物)의 CEC는 103.3me/100g이었다. 보수력(保水力)은 점토함량(粘土含量) 및 유기물(有機物)과 고도(高度)의 유의성(有意性)이 있는 회귀관계(回歸關係)가 성립(成立)되었으며 점토함량(粘土含量)의 회귀계수(回歸係數)는 배수(排水)가 불량(不良)할수록 증대(增大)되었으며 유기물(有機物)의 계수(係數)는 배수(排水)가 약간 양호한 경우가 가장 높았다. 유기물함량(有機物含量)은 토성(土性)과 pH를 가지고 계산(計算)할 수 있었으며 pH가 증가(增加)될수록 유기물함량(有機物含量)은 낮아졌고, pH를 가지고 염기포화도(鹽基飽和度)를 계산(計算)할 수 있었다.

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