• Korean Journal of Materials Research
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• v.3 no.6
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• pp.678-683
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• 1993

Atomic arral1gement of ordered phase in $GaAs_{0.5}Sb_{0.5}$ epilayer was studied by observation of selected area diffraction patterns and high resolution images. The epilayer was grown on untilted (001) GaAs substrate at $580^{\circ}C$ by molecular beam epitaxy(MBE). A 1/2(111) type long-range ordered phase is formed in the epilayer. Atomic arrangement of the ordered phase is described as an alternative stacking of As-rich and Sb-rich {111} planes in group V sublattice. Space group of the ordred structure belongs to R3m, and unit cell of the ordered structure is rhombohedral.

• Korean Journal of Metals and Materials
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• v.48 no.12
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• pp.1070-1077
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• 2010

The creep rates of polycrystalline $L1_2$-ordered $Co_3Ti$ and B2-ordered NiAl-Hf intermetallics decrease appreciably with the fine precipitation of the coherent disordered fcc Co-rich phase and $Ni_2AlHf$ phase. With B2-ordered NiAl containing $L2_1-Ni_2AlHf$ precipitates, transmission electron microscope observations of the interaction between dislocations and spherical precipitates revealed that the dislocations tend to be strongly attracted to the particle interfaces during the creep deformation. On the other hand, with $L1_2$-ordered $Co_3Ti$, the significance of the threshold stress is discussed based upon the transmission electron microscope observations of the interaction between dislocations and precipitates. The superdislocations produced during deformation tend to be strongly attracted and dissociated as they meet the coherent disordered precipitates because the anti-phase boundary energy in the disordered phase was zero. An extra force required to pull the dislocations out of the disordered particles during the creep deformation establishes the threshold stress which is beneficial for improving creep strength under lower stresses.

• Korean Journal of Metals and Materials
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• v.49 no.2
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• pp.137-144
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• 2011

Strengthening mechanisms in an ordered intermetallic compound containing coherent precipitates of lower antiphase boundary energy than the matrix were investigated on the basis of the interaction between the deformation induced dislocations and the disordered precipitates in an $Ll_2$ ordered $Ni_3Al$-based alloy. Extra work was needed to pull out the dislocations from the precipitate, which was dependent on the difference in the antiphase boundary energy between the matrix and the precipitate, as well as the size and volume fraction of the precipitate. The strength of the $Ll_2$ ordered ${\gamma}^{\prime}$ phase containing fine precipitates of the disordered ${\gamma}$ phase was examined using the proposed model. The model can explain almost quantitatively the age hardening behavior of the $Ll_2$ ordered ${\gamma}^{\prime}$ phase.

• Journal of the Korean Society for Heat Treatment
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• v.19 no.5
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• pp.249-256
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• 2006

Structural studies have been performed on precipitation hardening found in $L1_2$ ordered ${\gamma}^{\prime}-Ni_3(Al,Ti)$ alloys using transmission electron microscopy. A uniform solid solution of ${\gamma}^{\prime}-L1_2$ ordered phase supersaturated with Ni can be obtained by solution annealing in a suitable temperature range. The ${\gamma}^{\prime}$ phase hardens appreciably by the fine precipitation of disordered ${\gamma}$. The shape of ${\gamma}$ precipitates formed during aging is initially spherical or round-cubic and grow into platelets as aging proceeds. High resolution electron microscopy revealed that the ${\gamma}$ precipitates are perfectly coherent with the matrix ${\gamma}^{\prime}$ as long as the ${\gamma}$-precipitates are plates. The loss of coherency initiates by the introduction of dislocations at the ${\gamma}/{\gamma}^{\prime}$ interface followed by the step formation at the dislocations. The ${\gamma}$ precipitates become globular after the loss of coherency. The strength of ${\gamma}^{\prime}-Ni_3(Al,Ti)$ increases over the temperature range of experiment by the precipitation of fine ${\gamma}$ particles. The peak temperature where a maximum strength was obtained shifted to higher temperature.

• Journal of the Mineralogical Society of Korea
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• v.10 no.2
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• pp.97-104
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• 1997

Based on the method of determination for relative stability of each phase from the difference among the interaction parameters of the phases consisting the mixed layer, the types of interactions between layers were specified and interaction parameter between layers in ordered domain was analytically derived as a function parameter between layers in ordered domain was analytically derived as a function of not only temperature and mole fraction of layers but also ordering parameter. Interaction parameter between the different layers in ordered phase, L is as follows:{{{{ {L }_{1 } (X,Q,T)= { C} over { Q} -4(1-2Q) { L}^{2 } - { RT} over {2} ln { 1} over {2 } - { 2RT} over { { X}_{ s} } ln { { 4QX}`_{s } ^{2 } } over {(1- { X}_{s }- { QX}_{s })( { X}_{s }- {QX }_{s } ) } }}}}L2 is the interaction parameter between ordered and disordered phase in domain and is the mole fraction of the domain which represent the infinite length of mixed layer mineral and Q and C are the reaction progress parameter and arbitrary constant, respectively. This equation was used for the I/S mixed layer clay minerals to infer the relative stability of R1 type I/S mixed layer in the temperature range from 373K to 450K. The result of calculation suggest that, owing to the decrease in interaction parameter with increasing temperature. The interaction parameter decreases more rapidly with decreasing mole fraction of smectite in domain, which is consistent with the fact that the probability of finding the series smectite layer is lo in the domain with small mole fraction of smectite layers in natural system.

• Journal of the Korean Society for Heat Treatment
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• v.21 no.5
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• pp.251-258
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• 2008

A transmission electron microscope investigation has been performed on the morphology of dislocations in deformed ${\gamma}^{\prime}-Ni_3(Al,Ti)$ alloys containing fine dispersion of disordered ${\gamma}$ particles. Superlattice dislocations dissociate into fourfold Shockley partial dislocations in a uniform supersaturated solid solution of the ${\gamma}^{\prime}$ phase. Dislocations are attracted into the disordered ${\gamma}$ phase and dissociate further in the particles. At any stage of aging, dislocations cut through the particles and the Orowan bypassing process does not occur even in the over-aged stage of this alloy system. The work necessary to pull the dislocation away from the disordered particles into the ordered matrix should mainly contribute to increase the strength of the ${\gamma}^{\prime}$ phase containing fine dispersion of the disordered ${\gamma}$ phase.

• Journal of the Korean Ceramic Society
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• v.36 no.7
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• pp.762-766
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• 1999

The crystal structure of A2+(Mg1/3Nb2/3)O3,(A2+=Sr2+ and Ca2+)ceramics was studied usig X-ray diffraction (XRD) and high resolution transmission electrion microscopy(HRTEM). Ba(Mg1/3Nb2/3)O3 (SMN) has the 1:2 ordered monoclinic structure which has the anti-phase tilt of octahedra. The type of tilting in SMN was considered to be a$^{\circ}$a$^{\circ}$c- or a­a­c$^{\circ}$ Ca(Mg1/3Nb2/3)O3 (CMN) also has the 1:2 ordered monoclinic structure which was distorted by the anti-phase tilt or in-phsae tilt of octahedra. A unit cell containing both the in-phase tilt axis and anti-phase tilt axis was not observed in the CMN. Therefore CMN has the mixed phase consisting of the 1:2 ordered monoclinic phase with anti-phase tilt of octahedra and the one with in -phase tilt of ocatahedra,. The anti-parallel shift of cation was also observed in the CMN.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.11a
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• pp.158-158
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• 1998

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.11a
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• pp.283-287
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• 2003

Crystal structure of $(Ba_{1-x}La_x)[Mg_{(1+x)/3}Nb_{(2-x)/3}]O_3$ (BLMN) ceramics with $0{\leq}x{\leq}1$ was investigated using synchrotron X-ray powder diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). When La content, x, is above 0.1, the 1:2 ordered hexagonal structure found in $Ba(Mg_{1/3}Nb_{2/3})O_3$ (BMN) was transformed into 1:1 ordered cubic structure. The 1:1 ordered cubic structure was maintained up to x=0.7. However, when x exceeded 0.7, BLMN was transformed 1:1 ordered structure which has cation displacement and in-phase and anti-phase tilt of octahedra.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.7
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• pp.718-723
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• 2004

Crystal structure of $(Ba-{1-x}La_x)[Mg_\frac{1+x}{3}}Nb_\frac{{2-x}{3}}]O_3$ (BLMN) ceramics with 0\leq1x \geq was investigated using synchrotron X-ray powder diffraction (XRD) and high reso(B $a_{l-x}$L $a_{x}$)[M $g_{(1+x)}$3/N $b_{(2-x)/3}$］ $O_3$lution transmission electron microscopy (HRTEM). When the La content, x, is above 0.1, the 1:2 ordered hexagonal structure found in Ba($Mg_\frac{1}{3}Nb_\frac{2}{3}})O_3$(BMN) was transformed into 1:1 ordered cubic structure. The 1:1 ordered cubic structure was maintained up to x=0.7. When x exceeded 0.7, however, BLMN was transformed into 1:1 ordered structure which has cation displacement and in-phase and anti-phase tilt of octahedra.