• 제목/요약/키워드: Optimum Temperature

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Mordenite 촉매에서 페놀의 t-부틸화 반응 (t-Butylation of Phenol over Mordenite Catalyst)

  • 이정우;김동식;이동규
    • 한국응용과학기술학회지
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    • 제17권2호
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    • pp.113-119
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    • 2000
  • Alkylation of phenol with tert-butanol in the liquid phase on mordenite was studied. The influence of many reaction parameters such as calcination temperature, reaction temperature, t-butanol/phenol molar ratio on catalytic properties was discussed. The main products were 2,4-di-t-butylphenol, o-t-butylphenol, p-t-butylphenol, the last of these was wanted product. In order to enhance the selectivity of p-t-butylphenol, optimum conditions were recommended at $500^{\circ}C$ calcination temperature, $140^{\circ}C$ reaction temperature, 1.0 molar ratio of reactants over mordenite. P-t-butylphenol was formed with 90% isomer selectivity at optimum conditions after 4hr reaction. On the basis of the behavior obtained in the cases mentioned, optimum conditions and catalytic properties for t-butylation of phenol were provided.

Effects of Climate Change on the Occurrence of Two Fly Families (Phoridae and Lauxaniidae) in Korean Forests

  • Kwon, Tae-Sung;Lee, Cheol Min;Jie, Okyoung;Kim, Sung-Soo;Jung, Sungcheol;Park, Young-Seuk
    • 생태와환경
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    • 제54권1호
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    • pp.71-77
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    • 2021
  • Using data from flies collected with pitfall traps in 365 forests on a nationwide scale in Korea, the abundance and distribution changes of two families (Phoridae and Lauxaniidae) in Korean forests were predicted at the genus level according to two climate change scenarios: RCP 4.5 and RCP 8.5. The most suitable temperature for the 17 major genera was estimated using a weighted average regression model. Stichillus and Anevrina displayed the lowest optimum temperature with 7.6℃ and 8.5℃ in annual mean temperature, respectively, whereas Chonocephalus had the highest optimum temperature with 12.1℃. Among thirty genera, seven genera (four from Phoridae and three from Lauxaniidae), which showed their abundance in a bell-type or linear pattern along the temperature gradient, were used for predicting the distribution changes according to the future climate change scenarios. All the taxa of this study are expected to decrease in abundance and distribution as a function of temperature increase. Moreover, cold-adapted taxa were found to be more affected than warm-adapted taxa.

자색고구마 Anthocyanin 색소의 추출조건 결정 (Determination of the Conditions for Anthocyanin Extraction from Purple-Flashed Sweet Potato)

  • 이장욱;이향희;임종환;조재선
    • 한국식품영양과학회지
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    • 제29권5호
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    • pp.790-795
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    • 2000
  • To establish the optimum conditions for the extraction of anthocyanin pigment from purple-fleshed sweet potato, a suitable extraction solvent with the optimum citric acid concentration for acidification of the solvent, and the optimum extraction time and temperature were determined. Twenty percent ethanol solution acidified with citric acid was found to be a good solvent for the extraction of the pigment from purple-fleshed sweet potato. About 10 hour extraction at room temperature was appropriate for the extraction. pH of the extract was below 3 when more than 0.7% citric acid was added. The higher the concentration of citric acid added was, the higher the total optical density (TOD) of the extract was. However, the increase in TOD of the extract was insignificant when more than 1% of citric acid was added. Therefore, addition of 1% citric acid was determined for acidification of the extracting solvent. Though the initial rate of the pigment extraction increased as the extracting temperature increased, extraction at higher temperatures of 60 or 8$0^{\circ}C$ for an extended time caused a decrease in the extraction yield due to degradation of the pigment. The optimum extraction temperature for the anthocyanin pigment from purple-fleshed sweet potato with the solvent used was determined as 4$0^{\circ}C$.

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고온초전도 테이프를 이용한 다단 전류 도입선의 최적설계 (Optimal Design of Multi-Step Current Leads Using HTS Tapes)

  • 김민수;나필선;설승윤
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2001년도 학술대회 논문집
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    • pp.84-88
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    • 2001
  • The optimum cross-sectional area Profile of gas-cooled high-temperature superconductor (HTS) current lead is analyzed to have minimum helium boil-off rate. The conventional constant area HTS lead has much higher helium consumption than the optimum HTS lead considered in this study. The optimum HTS lead has variable cross-sectional area to have constant safety factor. An analytical formula of optimum shape of lead and temperature profile are obtained. For multi-step HTS current leads, the optimum tape lengths and minimum heat dissipation rate are also formulated. The developed formulations are applied to the Bi-2223 material, and the differences between constant area, constant safety-factor, and multi-step current leads are discussed.

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저순도 알루미나 세라믹 가소결재의 피삭성

  • 이재우
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1995년도 춘계학술대회 논문집
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    • pp.33-38
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    • 1995
  • In this study, unsistered, pre-sintered and sintered low purity alumina ceramics were machined with various tools to clarify the machniability, the optimum tool materials and the optimum tool materials and the optimum cutting conditions. The maon conclusions obtained were as follows. (1) Machined withalloy steel tool, the machinabilty of te pre-sintered ceramics becomes better with the decrease of pre-sintering temperature, but that of unsintered ceramics(white body) was extremely poor. (2) In the case of carbide tool K01, the tool life in machining white body was the longest, and the machinabilty of pre-sintered ceramics becomes poorer with the increase of the pre-sintering temperature. (3) In the case of ceramic tool, the 10000-1100 .deg. C pre-sintered ceramics showed te best machinability within a certain cutting speed range. So far as dry machining, the above combination and conditions showed the highest productivity. (4) When the pre-sintered ceramics were wet machined withsintered diamond tool, the tool life becomes extremelylong, and higher cutting speed can be can be used than in the case offull-sintered ceramics. The productivity of wet cutting is much higher than that ofdry cutting.

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Collins 내동기의 최적 설계조건 (Optimum Design Condition of the Collins Cryocooler)

  • 이상원;김수연;정평석
    • 설비공학논문집
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    • 제4권3호
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    • pp.183-190
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    • 1992
  • The Collins cryocooler is numerically analysed with the optimization technique, and the optimum operating and design conditions are searched. This paper shows that liquefied helium quantity has an external maximum w.r.t. the total mass flow rate, the mass flow rates through expander and the capacities of heat exchangers. The liquefied helium quantity increases as the compressor exit pressure of the cryocooler does. The maximum quantity of liquefied helium and the maximum coefficient of performance have been found to exist in extremum, depending on the ratios of each heat exchanger capicities to the total one. At the optimum condition, the capacity of heat exchanger in high temperature region is larger than that in low temperature region.

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Optimum Water Potential, Temperature, and Duration for Priming of Rice Seeds

  • Lee, Suk-Soon;Kim, Jae-Hyeun;Hong, Seung-Beom;Kim, Min-Kyeong;Park, Eui-Ho
    • 한국작물학회지
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    • 제43권1호
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    • pp.1-5
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    • 1998
  • Experiments were carried out to find out the optimum water potential, temperature, and duration for the priming of rice seeds, Oryza sativa L. (cv. Ilpumbyeo) for better germination at sub-optimal temperatures. Seeds were primed in 0, -0.2, -0.4, -0.6, -0.8, and -1.0 MPa PEG (polyethylene glycol) solutions at $25^{\circ}C$. The optimum water potential for seed priming, the highest water potential at which rice seeds did not germinate, was -0.6 MPa. To find out optimum priming temperature and duration rice seeds were primed in -0.6 MPa PEG solution and 0 MPa (water as a control) for various durations at 15 and $25^{\circ}C$ and the seeds were germinated at 17, 20, and $25^{\circ}C$. Considering germination rate and speed, the optimum priming time in water (0 MPa) was 4 days at 15$^{\circ}C$ and 1 day at $25^{\circ}C$, while 4 days was the optimum priming time in a -0.6 MPa PEG solution, regardless of the priming temperature. Priming reduced the actual time of germination, especially at sub-optimal temperatures. Priming did not affect germination rate in -0.6 MPa PEG solution at 15$^{\circ}C$, but overpriming reduced the final germination rate in water at 15$^{\circ}C$ and in -0.6 PEG solution at $25^{\circ}C$. Total sugars and $\alpha$-amylase activity induced during the seed priming were negatively correlated with the final germination rate and there was no noted relationship with the speed or uniformity of germination.

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인산 일수소칼슘의 최적합성조건 (Optimal Synthesis Conditions of Calcium Hydrogen Phosphate)

  • 신화우;김윤설;김준희
    • 약학회지
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    • 제42권2호
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    • pp.153-158
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    • 1998
  • Calcium hydrogen phosphate was synthesized by reacting calcium chloride and sodium hydrogen phosphate solution in this study. It is well known that the particle size and yield o f calcium hydrogen phosphate produced is greatly affected by the synthetic conditions such as the reactant concentration, reaction temperature, reacting fine, mole ratio and drying temperature, etc. The purpose of this study is to investigate the optimum synthesis condition from the viewpoint of yield and sedimentation volume of the prepared calcium hydrogen phosphate powder according to a randomized complete block design proposed by G.E.P. Box and K.B. Wilson. It was found that the optimum synthetic conditions of calcium hydrogen phosphate were as follows: It was found that optirnum temperature range of reactant solutions was $28-38^{\circ}C$ and $32-42^{\circ}C$ respectively, on the viewpoint of yield and sedimentation volume. The optimum concentration range of reactant solutions was 5.5-10.0% and 6.9-7.4% respectively, on the viewpoint of yield and sedimentation volume. The optimum mole ratio of $CaCl_2$ to $Na_2HPO_4$ was in the range of 1.2-2.0 and the optimum reacting time range was 8.5-11.0 minutes. The optimum drying temperature range was $39-41^{\circ}C$ from the viewpoint of yield, but it was $39-43^{\circ}C$ on the basis of sedimentation volume. Crystallographic analysis to X-ray diffraction patterns of commercially available ecalcium hydrogen phosphate and calcium hydrogen phosphate samples prepared in this study suggested that all samples tested belonged to monoclinic crystal system characteristic of $CaHP0_4{\cdot}2H_20$ crystals.

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A Study on the Optimum Mix Proportion of the Mass Concrete Designed as Massive and Deep Structure

  • Kwon Yeong-Ho;Lee Hwa-Jin
    • 콘크리트학회논문집
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    • 제17권2호
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    • pp.293-302
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    • 2005
  • This study describes data from determination of the optimum mix proportion and site application of the mass concrete placed in bottom slab and side wall having a large depth and section as main structures of LNG in-ground tank. This concrete requires low heat hydration, excellent balance between workability and consistency because concreting work of LNG in-ground tank is usually classified by under-pumping, adaptation of longer vertical and horizontal pumping line than ordinary pumping condition. For this purpose, low heat Portland cement and lime stone powder as cementitious materials are selected and design factors including unit cement and water content, water-binder ratio, fine aggregate ratio and adiabatic temperature rising are tested in the laboratory and batch plant. As experimental results, the optimum unit cement and water content are selected under $270kg/m^3$ and $l55{\~}l60 kg/m^3$ separately to control adiabatic temperature rising below $30^{\circ}C$ and to improve properties of the fresh and hardened concrete. Also, considering test results of the confined water ratio($\beta$p) and deformable coefficient(Ep), $30\%$ of lime stone powder by cement weight is selected as the optimum replacement ratio. After mix proportions of 5cases are tested and compared the adiabatic temperature rising($Q^{\infty}$, r), tensile and compressive strength, modulus of elasticity, teases satisfied with the required performances are chosen as the optimum mix design proportions of the side wall and bottom slab concrete. $Q^{\infty}$ and r are proved smaller than those of another project. Before application in the site, properties of the fresh concrete and actual mixing time by its ampere load are checked in the batch plant. Based on the results of this study, the optimum mix proportions of the massive concrete are applied successfully to the bottom slab and side wall in LNG in-ground tank.