• Title/Summary/Keyword: Optimum Temperature

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Characteristics of Concrete Sidewalk Block Manufactured Using Stone Powder Sludge and photocatalytic agent (석분슬러지와 광촉매제를 사용한 콘크리트 보도블록의 특성)

  • Jung, Yong-Wook;Lee, Seung-Han;Choi, Jong-Oh
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.6
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    • pp.4237-4244
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    • 2015
  • This study examined the efflorescence characteristics of a concrete sidewalk block manufactured using recycled stone powder sludge and photocatalytic generated by surface polishing during the sidewalk block manufacturing process. The study evaluated the characteristics of the sidewalk block in terms of its quality, based on the amount of stone powder sludge used, efflorescence, and further based on the mixing ratio and number of applications of the photocatalytic. The experimental results indicated that heavy metals such as lead, hexavalent chrome, cadmium, and mercury were not present in the concrete sidewalk block, thereby confirming the effectiveness of the recycled stone powder sludge. The optimum mixing ratio of used in the concrete sidewalk block (for satisfying KS standard values such as water absorption ratio and flexural strength) was found to be 20%. The concrete sidewalk block incorporating the stone powder sludge and photocatalytic exhibited a water absorption ratio of 5.4% and flexural strength of 5.2 MPa, thereby satisfying the quality standards. Additionally, when the photocatalytic was used, efflorescence did not occur even at the low temperature of $-5^{\circ}C$, and the by the sidewalk block was found to be 70% under normal conditions and 68% when subjected to an accelerated weathering test.

Dismantlement of Spent Lithium Primary Batteries for Recycling (폐(廢)리튬일차전지(一次電池)의 안정적(安定的) 해체(解體)를 위한 연구(硏究))

  • Yoo, Kyoung-Keun;Kim, Myoung-Hwa;Shin, Shun-Myung;Yang, Dong-Hyo;Kang, Jin-Gu;Sohn, Jeong-Soo
    • Resources Recycling
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    • v.16 no.4
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    • pp.3-9
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    • 2007
  • Dismantlement of lithium primary batteries without explosion is required to recycle the lithium primary batteries which could be exploded by heating too much or crushing. In the present study, the optimum discharging condition was investigated to dismantle the batteries without explosion. When the batteries were discharged with $0.5kmol{\cdot}m^{-3}$ sulfuric acid, the batteries became inert after 4 days at $35^{\circ}C$ and after 1 day at $50^{\circ}C$, respectively. This result shows that higher temperature accelerates inert of the batteries. Because loss of metals recycled increases when the batteries are discharged only with the sulfuric acid, discharging process using acid solution and water was newly proposed. When the batteries were discharged with water during 24 hours after discharging with $0.5kmol{\cdot}m^{-3}$ sulfuric acid during 6 hours, the batteries discharged were dismantled without explosion. Because decrease in loss of metals was accomplished by new process, the recycling process of the batteries could become economic by the 2-step discharging process.

Analysis of Trench Slope Stability in Permafrost Regions According to the Vertical and Horizontal Angle of Slope (동토지반에서 종방향 및 횡방향 사면의 경사에 따른 트렌치 안전성 분석)

  • Kim, Jong-Uk;Kim, Jung-Joo;Jafri, Turab H.;Yoo, Han-Kyu
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.27-33
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    • 2017
  • In this study, the stability of trench slope was analysed in summer and winter seasons for the construction of pipelines in permafrost regions. The construction standards of Korea, Russia and UK were compared for obtaining an optimum trench shape for a pipeline of 30 in. diameter. Using the geotechnical properties of soil in Yakutsk (Russia), the stability of trench slope was analysed using Strength Reduction Method (SRM) according to the horizontal slope angle values of $0^{\circ}$, $10^{\circ}$, $20^{\circ}$ and $30^{\circ}$ and vertical slope angle values of $20^{\circ}$, $30^{\circ}$ and $40^{\circ}$. In both seasons, an increase in the slope angle results in a decrease in the factor of safety. The results show that horizontal slope angle of $30^{\circ}$ was not safe in summer season. At the vertical slope angle of $20^{\circ}$, trench side failure was observed, whereas, ground slope failure was observed at the vertical slope angles of $30^{\circ}$ and $40^{\circ}$. Due to the solidification of pore water at temperatures below $0^{\circ}C$, cementation of soil particles take place. Therefore, the trench slope was found to be stable in the winter season at all vertical and horizontal slop angles, except for special load cases and abrupt temperature changes.

A design guide to minimize frost heave in unbound pavement layers over box culverts (저토피부 암거상부 포장의 도상피해 예방을 위한 단명설계)

  • Seo, Young-Guk
    • International Journal of Highway Engineering
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    • v.9 no.3
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    • pp.111-121
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    • 2007
  • During the whole month of December in 2005, Korea experienced both heavy snowfall and freezing temperature in southeast regions, which had caused frost related damages to many pavements laid on top of box culverts. In-situ observation revealed that the formation of ice lenses in subgrade and subsequent unbound layers led to upward heaving and transverse cracks in concrete and asphalt pavements. This has affected the long-term performance of pavements, as well as has threatened drivers' safety for a while. Recently, Korea Expressway Corporation has proposed a design guide to better protect newly constructed unbound pavement layers over culverts from frost heave. A trench drainage system has been selected to effectively draw off water and to alleviate pore-water pressure in soils during the coldest season. This paper presents experimental and analytical backgrounds behind this new design guide. Soil specimens retrieved from the sites are tested to quantify clay content and to estimate the permeability of subgrade. A 2-D ground seepage analysis has been conducted to better understand the changes in pore water pressures as a function of grain size. Finally, an optimum size of trench drainage is determined based on numerical analysis and workability in the field.

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Synthesis of Sulfonated PET-g-GMA Fine Ion-exchange Fibers for Water Treatment by Photopolymerization and Their Adsorption Properties for Metal Ions (광중합법을 이용한 수처리용 설폰산형 PET-g-GMA 극세 이온 교환 섬유의 합성 및 금속 이온 흡착 특성)

  • Kwak Noh-Seok;Hwang Taek-Sung;Kim Sun-Mi;Yang Yun-Kyu;Kang Kyung-Seok
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.397-403
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    • 2004
  • The sulfonated PET-g-GMA ion-exchange fine fibers were synthesized by UV radiation-induced graft copolymerization using a photoinitiator, and their chemical structure and adsorption properties were investigated. The optimum values for synthetic conditions - UV intensity, reaction time, and reaction temperature were 450 W, 60 min, and $40^{\circ}C$, respectively. Maximum values of the degree of sulfonation and ion exchange capacity were 8.12 mmol/g and 3.25 meq/g, respectively. Tensile strength of sulfonated PET-g-GMA fine ion exchange fibers was lower than that of PET trunk polymer as the grafting reaction rates increased. It was shown that as for the adsorption rate of $Ca^{2+}$ and $Mg^{2+}$ by the sulfonated PET-g-GMA fine ion exchange fibers, magnesium ion is slower than calcium ion in the solution. However, in the mixture of the calcium and magnesium ions, the adsorption rate of calcium ion was much slower than that of magnesium ion.

Occurrence of Rhizopus Soft Rot on Apple Fruit Caused by Rhizopus stolonifer in Korea (Rhizopus stolonifer에 의한 사과 무름병 발생)

  • Kwon, Jin-Hyeuk;Jee, Hyeong-Jin
    • Research in Plant Disease
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    • v.14 no.1
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    • pp.57-60
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    • 2008
  • A rhizopus soft rot caused by Rhizopus stolonifer occurred sporadically on apple fruits (Malus pumila var. dulcissima Koidz.) at a wholesale market of agricultural products in Jinju, Korea in 2006 and 2007. Infected fruits were rapidly water-soaked, softened and rotted. The symptoms were initiated mainly from wounds or cracks occurred at harvest time. Sporangiophores were $950{\sim}1,900\;{\mu}m$ in length and $12{\sim}22\;{\mu}m$ in width. Sporangia were globose or hemispheric and $82{\sim}185\;{\mu}m$ in size. The color of sporangia was white and cottony at first and gradually turned to brownish black, bearing abundant spores when matured. Columella were hemispheric and $70{\sim}85\;{\mu}m$ in size. Sporangiospores were irregular round or oval, brownish-black streaked and $8{\sim}18{\times}7{\sim}8\;{\mu}m$ in size. Optimum temperature for mycelial growth of the fungus on PDA was $25^{\circ}C$. On the basis of mycological characteristics and pathogenicity to apple the causal fungus was identified as Rhizopus stolonifer (Ehrenb.) Vuill. This is the first report of Rhizopus soft rot by R. stolonifer on Fuji apple in Korea.

Synthesis and Characteristics of Partially Fluorinated Poly(vinylidene fluroide)(PVDF) Cation Exchange Membrane via Direct Sulfonation (직접술폰화반응에 의한 부분불소화 Poly(vinylidene fluroide)(PVDF) 양이온교환막의 합성 및 특성)

  • Kang, Ki Won;Hwang, Taek Sung
    • Membrane Journal
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    • v.25 no.5
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    • pp.406-414
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    • 2015
  • In this study, partially fluorinated cation exchange membranes were prepared by direct sulfonation of Poly(VDF-co-hexafluoropropylene) copolymers (PVDF-co-HFP) followed by a casting method for application in the Membrane capacitive deionization (MCDI). The structure of sulfonated PVDF-co-HFP (SPVDF) was confirmed by Fourier-transform infrared (FT-IR) and $^1H$ Nuclear magnetic resonance ($^1H$ NMR) analysis. For quantitative analysis of the chemical composition, the X-ray Photoelectron Spectroscopy (XPS) was used. The membrane properties such as water uptake, ion exchange capacity and electrical resistance were measured. It was suggested that the optimum direct sulfonation condition of PVDF-co-HFP ion exchange membranes was $60^{\circ}C$ and 7 hours for temperature and duration of sulfonation, respectively. The water uptake of the SPVDF ion exchange membrane was 21.5%. The ion exchange capacity and electrical resistance were 0.89 meq/g and $3.70{\Omega}{\cdot}cm^2$, respectively. It was investigated that if it is feasible to apply these membranes in MCDI at various cell potentials (0.9~1.5 V) and initial flow rates (10~40 mL/min). In the MCDI process, the maximum salt removal rate was 62.5% in repeated absorption-desorption cycles.

Activation Mechanism of Protease in the Germination of Mulberry Seeds (뽕나무 종자 발아시의 Protease 발현기구)

  • 배계선
    • Journal of Sericultural and Entomological Science
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    • v.35 no.1
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    • pp.1-6
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    • 1993
  • The activity change of mulberry seeds protease was compared during germination for 5 days at 28$^{\circ}C$ in the dark place after daily hormone injection of different concentration. The protease from germinated mulberry seeds for 4 days was partially purified and the enzyme characteristics was investigated. The protease activity of mulberry seeds treated by hormone was highest with 10 $\mu$m GA3 followed by 10 $\mu$M zeatin and 10 $\mu$M kinetin. The protease activity of mulberry seeds was increased by 14% with 10ml agar culture that control at 4th day of germination. The protease from mulberry seeds was purified 313 fold by DEAE-Toyo-pearl 650M, Butyl-Toyopearl, Hydrozylapatite and Toyopearl HW 55M. After purification, the specific activity of the enzyme was 175 units/mg. Optimum pH and temperature of protease from mulberry seeds was 5.0 and 37$^{\circ}C$, respectively. The protease was stable below 37$^{\circ}C$ and the enzyme activity was decreased by 50%, when incubated at 52$^{\circ}C$ for 10minutes. The protease activity of mulberry seeds was inhibited by metal ions such as mercury, iron, zinc, copper, but activited by magnesium, choromium, aluminium ions. The Km value of the protease was 0.89mM with azocasein as a subscribe.

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Growth of Vicia tetrasperma and V. hirsuta as Affected by Seeding Condition and Estimated N Production (피복식물용 얼치기완두와 새완두의 생장에 미치는 파종조건과 질소공급량 추정)

  • Cho, Jung-Lai;Choi, Hyun-Sug;Lee, Youn;Kim, Chang-Seok;Lee, In-Yong
    • Korean Journal of Weed Science
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    • v.31 no.1
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    • pp.84-88
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    • 2011
  • This study was established to investigate the effects of seeding depth and seeding time on the emergence, growth, and N production of Vicia tetrasperma and V. hirsuta in 2007 and 2008. All seeds of both species were gathered from Dangjin, Chungnam in late June of 2005 and stored for two year at room temperature. Both V. species began to germinate at the end of June, passed the winter with the seedling stage, rapidly increased their height in April and May, were in full bloom in May, and then withered after entering mid-June. V. hirsuta had higher emergence rate and growth compared to those of V. tetrasperma. The optimum seeding time and seeding depth for a cover cropping was from late August to early September and from 1 to 5 cm, respectively. V. tetrasperma and V. hirsuta had a satisfactory growth and provided 43.8 and $55.4kg\;ha^{-1}$of N, respectively.

Molecular Cloning and Expression of a Cellulolytic Xylanase Gene from Bacillus circulans in Escherichia coli (Bacillus circulans 기원의 Cellulolytic Xylanase 유전자의 대장균에서의 클로닝 및 발현)

  • 이동석;김지연;김한복
    • Korean Journal of Microbiology
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    • v.36 no.3
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    • pp.196-202
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    • 2000
  • A gene for cellulolytic xylanase of Bacillus circulnns ATCC21365 was cloned on pUC 19 in Eschwichia coli. The recombinant plasniid pXLI80 contained an 1.8 id, inselt composed of0.5 kb and 1.3 kb PslI fragments derived from B, circulans. The 0.5 kh fragment in the upstream region of 1.3 kb one was confirmed lo be indispensable for not only expression but also hyperexpression of the cloned gene. The transformant overproduced the xylanase 135 times greater than that produced by the orlginal B circulnns. The optimum pH and temperature of the cloned enzyme we]-e pH 5.2 and $60^{\circ}C$, respectively. Heal pretl-eatment at TEX>$55^{\circ}C$C for 1 Indid not cause inhibition of the activity of this enzyme. The elm.ynie could hydl-olyre CMC and lichenan as well as xylan to produce xylose(or GI), xylohiose(or G2) and xylolnose(or G3) as inah products. Hence We defined the cloned enzyme as a cellulolytic xylanase. The SDS-PAG electrophoretic mobility and zyiiogram of this enzyme derived from whole cell extracts or c~~lture supematants or E. coli(pXL180) indicated a molecular weight of 45,000 and nonprocessing of the enzyme in the peilplasln of E. coli.

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