• Journal of the Korea Organic Resources Recycling Association
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• v.8 no.2
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• pp.60-70
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• 2000

The swine wastewater from slurry feedlot has been a social problem in Korea since the proper treatment is very difficult. Therefore, a practical study on the Solid-Liquid separation of swine wastewater from slurry feedlot was carried out as a pan of pretreatment for the successful biological treatment. The appropriate type of coagulant and optimum dosage were proposed for the most efficient Solid-Liquid separation and the best Solid-Liquid separation methods for different size of feedlot were determined through the tests with field-scaled Solid-Liquid separation equipment. The appropriate coagulant for the conditioning of dewatering property was E-851, which is a cationic polyelectrolyte made of polyacrylamide, and the optimum dosage was 0.24~0.6% of unit solids weight. Mesh Screen, Drum Screen, Cyclone Drum Filter, Screw Press, High-speed Screw Decanter, Low-speed Screw Decanter, and Dissolved Air Flotation Process had been investigated in this study. According to the results, the Screw Press was the best dewatering equipment for the small & medium size for feedlot and low-speed Screw Decanter was the best for the large size feedlot & public owned treatment facilities for the primary Solid-Liquid separation, and the most suitable secondary treatment process was DAF. On the other hand, reductions for the requirement of bulking agent and organic loading by Solid-Liquid separation process were 94.8% and 84.7%, respectively Therefore, the Solid-Liquid separation process must be required for the successful treatment of swine wastewater from slurry feedlot.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.581-589
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• 2005

Recently, membrane processes have been replacing the conventional processes for waste water treatment to produce better quality of effluent and to meet more stringent regulations because of water shortage. However, using membrane processes for water treatment has confronted with fouling and difficulty in treating dissolved organic pollutants. In this study, membrane process equipped with crossflow microfiltration is combined with coagulation process using alum and PAC to improve permeability and treatment efficiency. The effects of coagulant dosage and optimum membrane operating conditions were investigated from measurement of permeate flow, cumulative volume, total resistance, particle size, dissolved organic pollutant, dissolved aluminium and quality of effluent. Characteristic of PAC coagulation was compared with that of alum coagulation. PAC coagulation reduced membrane fouling because of forming larger particle size and increased permeate velocity and cumulative volume. Less dissolved organic pollutants and dissolved aluminum made decreasing-rate of permeate velocity being lowered. At using $0.2\;{\mu}m$ membrane, cake filtration observed. At using $0.45\;{\mu}m$ membrane, there was floc breakage due to shear stress occurred born circulating operation. It made floc size smaller than membrane pore size, which subsequently to decrease permeate velocity and to increase total resistance. The optimum coagulation dosage was $300{\pm}50\;mg/L$ for both alum and PAC. PAC coagulation was more efficiently used with $0.2\;{\mu}m$ membrane, and the highest permeate flux was in using $0.45\;{\mu}m$membrane. The greatest efficiency of treatment was as follows; turbidity 99.8%, SS 99.9%, $BOD_5$ 94.4%, $COD_{Cr}$ 95.4%, T-N 54.3%, T-P 99.8%.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.7
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• pp.1307-1318
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• 2000

The purpose of this study is to investigate the degradation characteristics of oxalic acid and citric acid by $UV/H_2O_2$ oxidation. For this purpose, the effects of pH, $H_2O_2$ dosage and the concentration of each compounds on the degradation of oxalic acid and citric acid by $UV/H_2O_2$ were investigated. Oxalic acid was effectively degraded at the wavelength of 254 nm, while the degradation efficiency of citric acid was very low at the same wavelength. It was also found that both organic substances were not degraded by the injection of $H_2O_2$ only. The optimum pH of degradation of oxalic acid and citric acid was 4 and 4 to 6, respectively. In the case of $UV/H_2O_2$ oxidation, the degradation efficiency was increased by increasing $H_2O_2$ dosage. The degradation efficiency decreased when the dose of $H_2O_2$ exceeds 200 mg/L. From these results, it can be concluded that the optimum reaction conditions for the degradation of oxalic acid and citric acid by $UV/H_2O_2$ oxidation were pH 4 and 200mg/L of $H_2O_2$.

• Membrane Journal
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• v.23 no.1
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• pp.12-23
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• 2013

On the subject of river bed water in Seomjin river, it had accomplished the verifying experiment of membrane filtration pilot plant for evaluating the applicability of its process throughout the prediction of membrane fouling as a function of the pore size of membrane and the determination of optimum coagulant dosage. On the result of the experiment for the evaluation of the membrane fouling as a function of the pore size, a increasing rate of irreversible resistance of membrane pore size $0.1{\mu}m$ and $0.01{\mu}m$ was measured each $0.44{\times}10^{12}/m^2$ and $0.42{\times}10^{12}/m^2$, respectively. And on the result of Flux-test, it showed that the optimum coagulant dosage was measured lower than the it of the Jar-test. The result to be operated in a condition of a permeate flux $1.0{\sim}1.5m^3/m^2{\cdot}day$ without coagulation and a permeate flux $1.0{\sim}2.0m^3/m^2{\cdot}day$ with coagulation was maintained at stable trans-membrane pressure (TMP) value for 6 months up to. Therefore it showed that the stable operation without the coagulation was possible on permeate flux $1.0{\sim}1.5m^3/m^2{\cdot}day$ in the operation of membrane filtration process.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.7
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• pp.697-703
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• 2005

Iron-coated sand(ICS) was prepared with variation of particle size of Joomoonjin sand, primary and secondary coating temperature, coating time, and dosage of initial Fe(III). An optimum condition of the preparation ICS was selected from the coating efficiency, stability of coated Fe(III), and removal efficiency of As(V). Coated amount of Fe(III) increased as primary coating temperature increased with smaller particle size of sand. Coating efficiency was quite similar over the investigated secondary coating temperature and time, while adsorption efficiency of As(V) onto ICS was severely reduced with ICS prepared at higher secondary coating temperature. By considering these results, an optimum secondary coating temperature and time for the preparation of ICS was selected as $150^{\circ}C$ and 1-hr, respectively. Coating efficiency increased us the dosage of initial Fe(III) up to 0.8 Fe(III) mol/kg sand and then no distinct increase was noted. Maximum As(V) adsorption was observed at 0.8 Fe(III) mol/kg sand. Secondary coating temperature and time were important parameters affecting stability of ICS, showing decreased dissolution of Fe(III) from ICS prepared at higher coating temperature and at longer coating time. From anionic type adsorption of As(V) onto ICS, it is possible to suggest the application of ICS for the removal of As(V) contaminated in acidic water system.

• Journal of the Korean Chemical Society
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• v.64 no.5
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• pp.249-258
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• 2020

The potential use of egg shell and calcined egg shell as adsorbent was evaluated and compared to remove Cd²⁺ from aqueous solution. The samples were characterized using Thermogravimetry and Differential Thermal Analysis (TG/DTA), Scanning Electron Microscope (SEM), X-ray Diffractometer (XRD), Energy Dispersive X-ray Spectrometer (EDX) and BET Surface Analyzer. The batch-type adsorption experiment was conducted by varying diverse variables such as contact time, pH, initial Cd²⁺ concentrations and adsorbent dosage. The results showed that, under the initial Cd²⁺ concentrations ranged from 25 to 200 mg g^-1, the removal efficiencies of Cd²⁺ by egg shell powder (ESP) were decreased steadily from 96.72% to 22.89% with increase in the initial Cd²⁺ concentration at 2.5 g of dosage and 8 h of contact time. However, on the contrary to this, calcined egg shell powder (CESP) showed removal efficiencies above 99% regardless of initial Cd²⁺ concentration. The difference in the adsorption behavior of Cd²⁺ may be explained due to the different pH values of ESP and CESP in solution. Cd²⁺ seems to be efficiently removed from aqueous solution by using the CESP with a basicity nature of around pH 12. It was also observed that an optimum dosage of ESP and CESP for nearly complete removal of Cd²⁺ from aqueous solution is approximately 5.0 g and 1.0 g, respectively. Consequently, Cd²⁺ is more favorably adsorbed on CESP than ESP in the studied conditions. Adsorption data were applied by the pseudo-first-order and pseudo-second-order kinetics models and Freundlich and Langmuir isotherm models, respectively. With regard to adsorption kinetics tests, the pseudo-second-order kinetics was more suitable for ESP and CESP. The adsorption pattern of Cd²⁺ by ESP was better fitted to Langmuir isotherm model. However, by contrast with ESP, CESP was described by Freundlich isotherm model well.

• Microbiology and Biotechnology Letters
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• v.26 no.3
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• pp.257-263
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• 1998

Alcaligenes eutrophus was successfully recovered from high cell density broth by pre-treatment with Fe-based coagulants. An inorganic coagulant, Fe$_2$(SO$_4$)$_3$, and a polymerized coagulant, Ferix-3, were used. Good coagulation was observed in broad pH range of 3 to 13, the floe size was increased with increasing pH of culture broth. The optimum pH of fermentation broth for cell recovery was 10 to 13. The optimum coagulant dosages to recover cells with 95% cell recovery were increased with increasing cell concentration. Optimal coagulant dosage was lower when the polymerized coagulant was used rather than the inorganic coagulant. The coexistence of NH$_4$$\^$+/ was increased coagulant requirement, and the coagulant requirement was 0.066g Fe$_3$$\^$+//g NH$_4$$\^$+/.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.8
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• pp.823-830
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• 2008

The feasibility study for the application of the photoelectrocatalytic decolorization of Rhodamine B(RhB) was performed in the slurry photoelectrochemical reactor with powder TiO$_2$. The photoelectrocatalytic process was consisted of powder TiO$_2$, Pt electrode and three 8 W UV-C lamps. The effects of operating conditions, such as current, electrolyte, air flow rate and electrode material were evaluated. The experimental results showed that optimum TiO$_2$ dosage and current in photoelectrocatalytic process were 0.4 g/L and 0.02 A, respectively. It was found that the RhB could be degraded more efficiently by this photoelectrocatalytic process than the sum of the two individual oxidation processes(photocatalytic and electrolytic process). It demonstrated a synergetic effect between the photo- and electrochemical catalysis. Photoelectrocatalytic process was affected to air flow rate and optimum air flow rate was 2 L/min. The electrode material and NaCl effect of decolorization of RhB were not significant within the experiment conditions.

• Journal of Environmental Science International
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• v.21 no.12
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• pp.1523-1528
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• 2012

This study was carried out to develop pilot plant Net3FM(Net Fit Fiber Filter Module) system and to suggest optimum operating condition for municipal wastewater reuse. SS concentration of biologically treated sewage effluent was reduced from 1.5~5.4mg/L to 0.4~1.0mg/L without coagulant injection in Net3FM system, and the SS removal efficiency was average 84.7%. And also, the removal efficiencies of COD and T-P were decreased slightly due to the SS removal by filtration. Coagulation-Filtration test was conducted to enhance the removal efficiencies of SS and T-P. The optimum dosage of coagulant was injected automatically by auto-controlling system, which is controlled by detecting value of turbidity of secondary sewage effluent. SS, COD and T-P concentrations in filtrated effluent were 0.21~0.57, 1.6~6.2 and 0.137~0.392mg/L with coagulant injection by in-line mixer in Net3FM system, respectively. The removal efficiencies of SS and T-P were highly increased to 92.8% and 89.8%, respectively. It was due to the combined the processes of coagulation and filtration. Net3FM system was evaluated that the removal efficiency of pollutants in secondary sewage effluent and the utilization potential as reclaimed water technology were very high.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.2 no.2
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• pp.47-59
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• 1982

It is well practised in the field of concrete engineering that the effort of improving the low slumped concrete and uplifting the quality of the soft concrete by adopting the superplasticizer. In this paper, an attempt is made to find out the optimum mix design of the superplasticized concrete with an unit weight of cement 400 kg and the range of $19{\pm}1cm$ of slump by variatlng the sand percentage, unit water content and the dosage of superplasticizer. As a result, the author obtained the basic idea on the optimum mix design and strength of superplasticized concrete. On the other hand, it is also considered during the research the method of preventing the slump loss of the superplasticized concrete due to the delayed time after concrete mixing.