• Journal of the Korean Vacuum Society
• /
• v.10 no.2
• /
• pp.194-200
• /
• 2001

In this study, the optical properties of diamond-like carbon(DLC) films, which was synthesized by 13.56 MHz rf plasma enhanced chemical vapor deposition system(PECVD), were investigated. We observed the variation of the transmittance and optical band gap with respect to deposition condition. The change of the transmittance and optical band gap of the DLC films were investigated as a function of RF power, working pressure, and additional gas. The optical band gap decreased with the increase of RF power and working pressure. We could verify the bond structures change of DLC films by observing the content of hydrogen using FT-IR spectroscopy. And the addition of hydrogen and nitrogen decreased the optical band gap by the breakage of C-H bond of DLC films during the deposition.

• Electrical & Electronic Materials
• /
• v.9 no.5
• /
• pp.445-449
• /
• 1996

Structural and optical characteristics in Se thin film fabricated by EBE method had been studied. Se thin film was deposited with noncrystalline until substrate temperature of >$100^{\circ}C$ Color of its surface had red genealogy, and its optical energy band gap was about 2.45 eV. But Se film was grown with monoclinic at substrate temperature of over >$150^{\circ}C$ Also, color of its surface had gray genealogy, and its optical energy band gap was about 2.31 eV. Finally, after heat-treatment at >$150^{\circ}C$ for 15 min with substrate temperature of >$100^{\circ}C$ noncrystalline Se was proved to be hexagonal, and color of its surface had dark gray genealogy, and its optical energy band gap was about 2.06 eV. From the results, it was known that Se thin film for photoelectric device with the lowest optical energy band gap was accepted from hexagonal structure.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.11 no.9
• /
• pp.693-699
• /
• 1998

In this work $Cd_4GeS_6:Co^{2+}$(0.5mole%) single crystals were grown by the chemical transporting reactiov(CTR) method using high purity(6N) elements. The grown single crystals crystallized in a monoclinic structure(space group Cc). The direct optical energy gap of this single crystals was found to be 2.445eV at 300K and the temperature dependence of optical energy gap was fitted well to Varshni equation. But at temperatures lower than 70K an anomalous temperature dependence of the optical energy gap was obtained. This anomalous temperature dependence accored well with the anomalous temperature dependence of the unit cell volume. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gaps.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2004.05a
• /
• pp.888-893
• /
• 2004

This paper proposed a dual actuator using bimorph PZT for information storage device based on prove array NSOM(Near-field Scanning Optical Microscopy). The gap between the media and the optical head should be maintained within the optical tolerance. Therefore, a new actuator having high sensitivity is required. Bimorph PZT, which has fast access time and high sensitivity characteristic, is suitable for this precise actuating system. This paper is focused on derivation of mathematical model of dual bimorph PZT actuator and control algorithm. Hamilton's principle was used for mathematical model. The model is verified by FEA(Finite Element Analysis), and compared with experimental results. Different control algorithms were used f3r two bimorph PZT actuating same direction and opposite direction. The gap between recording media and optical head was controlled within 20nm in experiment.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.5
• /
• pp.1523-1528
• /
• 2014

Silicon quantum dots (Si QDs) were synthesized by etching silicon nanopowder with aqueous hydrofluoric acid (HF) and nitric acid ($HNO_3$). Then, the hydride-terminated Si QDs (H-Si QDs) were functionalized by 1- octadecene (ODE). By only controlling the etching time, the maximum luminescence peak of octadecylterminated Si QDs (ODE-Si QDs) was tuned from 404 nm to 507 nm. The average optical gap was increased from 2.60 eV (ODE-Si QDs-5 min) for 5 min of etching to 3.20 eV (ODE-Si QDs-15 min) for 15 min of etching, and to 3.40 eV (ODE-Si QDs-30 min) for 30 min of etching. The electron affinities (EA), ionization potentials (IP), and quasi-particle gap (${\varepsilon}^{qp}_{gap}$) of the Si QDs were determined by cyclic voltammetry (CV). The quasi-particle gaps obtained from the CV were in good agreement with the average optical gap values from UV-vis absorption. In the case of the ODE-Si QDs-30 min sample, the difference between the quasi-particle gap and the average optical gap gives the electron-hole Coulombic interaction energy. The additional electronic levels of the ODE-Si QDs-30 min and ODE-Si QDs-15 min samples determined by the CV results are interpreted to have originated from the Si=O bond terminating Si QD.

• Journal of the Korean Vacuum Society
• /
• v.3 no.4
• /
• pp.420-425
• /
• 1994

메탄을 원료가스로 하여 PECVD에 의해 다이아몬드성 탄소(DLC) 박막을 형성하였으며 이때 인 가전력의 크기 및 주파수 그리고 보조가스의 종류가 optical band gap의 크기에 미치는 영향에 대학여 연구하였다. DLC 박막의 optical band gap 은 증착되는 이온의 에너지가 증가할수록 감하였으며 불활성 기체를 보조가스로 사용하는 경우 인가전력에 따른 optical band gap의 크기가 큰폭으로 감소하였다. 소 소를 보조가스로 사용한 경우는 높은 인가전력(100W 이상)에서 optical band gap이 증가하는 것으로 밝 혀졌으며 본 연구에서 제안된 증착 기수의 모델에 의해 적절한 설명이 가능하였다.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.28 no.3
• /
• pp.245-250
• /
• 2004

This paper proposes a new method of measuring an air interface distance between a solid immersion lens(SIL) applied magneto-optic technology and the disk surface. For applying near-field recording (NFR) technology to the magneto-optic storage devices for the next generation, it is positively necessary to maintain the small air gap under about 100㎚. We design an apparatus that consists of some optical components such as a prism, a polarizer and an analyzer. By using the Fresnel reflection coefficient equation, Jones matrices calculation and Malus's law, we establish a mathematical model for understanding the characteristics of the system. The simulations are based on the mathematical model and through the simulation results which is made with various cases we can estimate the performance of the new optical gap sensor system. Experimental results, which are also based on the mathematical model for specific cases, are in good agreement with simulated ones and demonstrate the possibility as the new optical gap sensor.

• Proceedings of the Optical Society of Korea Conference
• /
• 2001.02a
• /
• pp.142-143
• /
• 2001

Cell gap은 LCD(Liquid Crystal Display)의 중요한 파라미터들 중의 하나이다. cell gap이 LCD의 광학적인 성능에 영향을 주기 때문에 정확한 cell gap 측정방법은 제조공정을 향상시키는데 중요하다 특히 최근 고속 영상 디스플레이를 제공할 수 있는 장점 때문에 낮은 cell gap의 LCD가 요구되고 있는 시장 추세에 따라 낮은 cell gap을 측정할 수 있는 기술이 요구되고 있다. LCD의 cell gap 측정 방법들 가운데 가장 보편화되어 있는 것으로 회전편광자법(rotating polarizer method)[1, 2]과 위상보상법(phase compensation method)[3,4]을 들 수 있는데 낮은 셀갭을 정확히 측정하기가 어려우며 주기적인 해가 발생한다는 단점이 있다. (중략)

• The Transactions of the Korean Institute of Electrical Engineers P
• /
• v.51 no.3
• /
• pp.137-141
• /
• 2002

CdS and $CdS:Co^{2+}$ single crystals were grown by CTR method using iodine as transport material. The grown single crystals have defect chalcopyrite structure with direct band gap. The optical energy band gap was decreased according to add of Co-impurity. We can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.261-261
• /
• 2010

Photonic band gap (PBG) materials have been of great interest due to their potential applications in science and technology. Their applications can be further extended when PBG becomes tunable against various chemical and electrical stimuli. In recent, it was found that tunable photonic band gap materials can be achieved by incorporating stimuli-responsive smart gels into PBG materials. For example, the characteristic volume phase transition of gels in response to the various external stimuli including temperature, pH, ionic strength, solvent compositions and electric field were recently combined with the unique optical properties of photonic crystals to form unprecedented highly responsive optical components. Since these responsive photonic crystals are capable of reversibly converting chemical or electrical energy into characteristic optical signals, they have been considered as a good platform for label-free chemical or biological detection, actuators or optical switches as well as a model system for investigating gel swelling behavior. Herein, we report block copolymer photonic gels self-assembled from polystyrene-b-poly (2-vinyl pyridine) (PS-b-P2VP) block copolymers. In this talk, we are going to demonstrate that selective swelling of lamellar structure can be effectively utilized for fabricating PBG materials with extremely large tunability. Optical properties and their applications will be discussed.