• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.1135-1139
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• 2017

화염 내 화학종의 공간적 분포는 화염의 구조 및 연소 특성을 이해하는데 중요한 지표가 되며, 그 계측을 위해 발광분광법 (Optical emission spectroscopy)은 간단하고 비침투적인 진단 방식으로 인해 널리 활용되고 있다. 본 연구에서는 측정 line-of-sight 방향의 공간 분해 계측 목적으로 개발된 발광분광기를 이용한 로켓 플룸 내 화학종 (OH radical) 분포 계측의 가능성을 제시하였다. 발광분광기의 측정 신호로부터 바닥 상태의 화학종 농도를 예측하기 위해 화염 내 열적 여기와 화학적 여기 기작을 고려하였으며, 열적으로 여기된 종에 대해서 열적 평형 상태를 가정하였다. 또한 발광분광기의 공간 분해 성능 및 공간에 따른 수광 특성을 보정하기 위한 방법론을 제시하였다.

• 천문학논총
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• 제15권spc1호
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• pp.61-71
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• 2000

The emission line objects such as planetary nebulae, symbiotics, gaseous nebulae, HII regions, novae, supernovae, SNRs, nearby spiral galaxies, dIrr, dE, and nearby active galactic nuclei, would be goldmines for us to dig with the 1.8m bohyunsan optical (BOAO) telescope. We discussed the importance of strategically important diagnostic lines and atomic constant calculation for a study of Galactic and extragalactic emission objects. The scientific background on a spectrometer development history is briefly presented and spectroscopic research areas other than the emission objects are also summarized.

• 한국광학회:학술대회논문집
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• 한국광학회 1990년도 제5회 파동 및 레이저 학술발표회 5th Conference on Waves and lasers 논문집 - 한국광학회
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• pp.172-176
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• 1990

A high resolution picosecond absorption kinetic spectrometer utilizing dye emission and a streak camera is presented and compared with other methods of picosecond transient absorption measurements. Typical transient absorption and bleach recovery kinetics measured with this spectrometer are shown. Single wavelength transient absorption or ground state bleach recovery kinetics are determined on the basis of a single laser shot, so that the samples are relatively free frm decomposition by irradiation. Excellent kinetics may be obtained from the near UV to the near IR and are not subject to interference from luminescence of samples. The sensitivity of this spectrometer is very high and it is reasonably easy and convenient to set up and use.

• 천문학논총
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• 제15권spc1호
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• pp.127-132
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• 2000

The purposes of spectroscopy in astronomy are to measure the radiation flux of the spectroscopic emission or absorption line and to measure the dynamical parameters of the line profile. In order to use an appropriate instrument for the scientific purpose, we need to understand the characteristics of various spectrometers, e.g., a prism spectrometer, a grating spectrometer, and a Fabry-Perot spectrometer (FPS), which are being used in ultra-violet, optical, and infrared bands. The Fabry­Perot spectrometer is not very popular compared to the grating spectrometer, because of its complex and tricky operations. The Fabry-Perot spectrometer, however, can get a two-dimensional image at one exposure, so we can study radiation mechanisms and dynamical properties of extended sources, e.g., clusters, nebula, and galaxies.

• 분석과학
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• 제6권3호
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• pp.275-282
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• 1993

지르콘사 광물에서 지르코니아를 회수하기 위하여 지르콘사를 분해 반응시킨 소성산물 중의 $SiO_2$와 $ZrO_2$를 DC arc source를 이용한 직독식 분광기로 동시 분석하였다. 순수한 금속산화물을 혼합하여 합성표준시료를 만들고 완충제(흑연)와 융제($Li_2B_4O_7$)의 혼합비를 조절하면서 최적의 들뜸조건을 선정하였다. 완충제와 흑연의 비를 0.22:1로 하고 시료와의 혼합비를 40배로 하였을 때 가장 좋은 들뜸조건을 얻을 수 있었다. 분석 결과의 표준편차는 $SiO_2$는 1.3%, $ZrO_2$는 4.9%였다.

• 한국결정학회:학술대회논문집
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• 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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• pp.5-6
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• 2002

The new spectrometer for X-ray Induced Electron Emission Spectroscopy (XIEES) .has been recently developed in KRISS in collaboration with PTI (Russia). The spectrometer allows to perform research using the XAFS, SXAFS, XANES techniques (D.C.Koningsberger and R.Prins, 1988) as well as the number of techniques from XIEES field(L.A.Bakaleinikov et all, 1992). The experiments may be carried out with registration of transmitted through the sample x-rays (to investigate bulk samples) or/and total electron yield (TEY) from the sample surface that gives the high (down to several atomic mono-layers in soft x-ray region) near surface sensitivity. The combination of these methods together give the possibility to obtain a quantitative information on elemental composition, chemical state, atomic structure for powder samples and solids, including non-crystalline materials (the long range order is not required). The optical design of spectrometer is made according to Johannesson true focusing schematics and presented on the Fig.1. Five stepping motors are used to maintain the focusing condition during the photon energy scan (crystal angle, crystal position along rail, sample goniometer rail angle, sample goniometer position along rail and sample goniometer angle relatively of rail). All movements can be done independently and simultaneously that speeds up the setting of photon energy and allows the using of crystals with different Rowland radil. At present six curved crystals with different d-values and one flat synthetic multilayer are installed on revolver-type monochromator. This arrangement allows the wide range of x-rays from 100 eV up to 25 keV to be obtained. Another 4 stepping motors set exit slit width, sample angle, channeltron position and x-ray detector position. The differential pumping allows to unite vacuum chambers of spectrometer and x-ray generator avoiding the absorption of soft x-rays on Be foil of a window and in atmosphere. Another feature of vacuum system is separation of walls of vacuum chamber (which are deformed by the atmospheric pressure) from optical elements of spectrometer. This warrantees that the optical elements are precisely positioned. The detecting system of the spectrometer consists of two proportional counters, one scintillating detector and one channeltron detector. First proportional counter can be used as I/sub 0/-detector in transmission mode or by measuring the fluorescence from exit slit edge. The last installation can be used to measure the reference data (that is necessary in XANES measurements), in this case the reference sample is installed on slit knife edge. The second proportional counter measures the intensity of x-rays transmitted through the sample. The scintillating detector is used in the same way but on the air for the hard x-rays and for alignment purposes. Total electron yield from the sample is measured by channeltron. The spectrometer is fully controlled by special software that gives the high flexibility and reliability in carrying out of the experiments. Fig.2 and fig.3 present the typical XAFS spectra measured with spectrometer.

• 한국재료학회지
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• 제15권3호
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• pp.209-215
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• 2005

Titanium dioxide films $(TiO_2)$ doped cobalt transition metal were prepared on titanium metal by water spray pyrolysis technique. Micro-morphology, crystalline structure, chemical composition and binding state of sample groups were evaluated using field emission scanning microscope(FE-SEM), X-ray diffractometer(XRD), Raman spectrometer, X-ray photoelectron spectrometer(XPS). $TiO_2$ films of rutile structure were predominately formed on all sample groups and $Ti_2O_3$ oxide was coexisted on the surface of cobalt doped-sample groups. The optical absorption peaks measured by using UV-VIS-NIR spectrophotometer were observed at specific wavelength region in sample groups doped cobalt ion. This result could be analyzed by introducing crystal field theory.

• 한국표면공학회지
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• 제38권2호
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• pp.73-78
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• 2005

A real-time monitoring of ICP(inductively coupled plasma) assisted magnetron sputtering of MgO was carried out using a QMS(quadrupole mass spectrometer), an OES(optical emission spectrometer), and a digital oscilloscope with a high voltage probe and a current monitor. At the time of ICP ignition, the most distinct impurity was OH emission (308.9 nm) which was dissociated from water molecules. For reactive deposition oxygen was added to Ar and the OH emission intensity was reduced abruptly When the discharge voltage was regulated by a PID controller from 240V(metallic mode) to 120V(oxide mode), the emission intensity from Mg (285.2 nm) changed proportionally to the discharge voltage, but the intensity of Ar I(811.6 nm) was constant. At 100V of discharge voltage, Mg sputtering was almost stopped. Emissions from Ar I(420.1 nm) and Mg I were dropped down to 1/10, but Ar I(811.6 nm) didn't change. And the emission from atomic oxygen (O I, 777.3 nm) was increased to 10 times. These results are compatible with those from QMS study.

• 한국전자파학회논문지
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• 제12권6호
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• pp.1009-1017
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• 2001

우주전파의 신호를 관측하기 위한 1 GHz대역의 음향광학 전파분광기를 설계.제작하였다. 이 전파분광기는 다중채널 방식의 신호의 세기가 미약한 우주 전파신호를 분석하기 위한 초고감도의 전파 분광기로, 관측되는 스펙트럼의 모양을 상세히 측정할 수 있는 전파분광기이다. 주파수 분해능과 광대역 주파수 성분을 포함하는 이 음향광학 전파분광기의 광원(optical source)으로는 He-Ne 레이저를 사용하였고, 1 GHz에서 2 GHz까지의 대역폭을 갖는 광대역 GaP 광펼향 소자를 사용하였으며, 광신호 검출을 위해 2,048 채널의 CCD를 사용하였다. 전파망원경을 통해 우주전파신호인 CRL 2688, IRC 10216 그리고 NGC 5005 은하 중심의 12CO(J= 1 ~0) 분자선(molecular line)을 관측한 결과, 광대역의 특성을 가지며 주파수 분해능이 양호함을 확인하였다.

• 한국광학회지
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• 제17권5호
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• pp.391-395
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• 2006

본 논문에서는 온도 제어가 가능한 blackbody를 이용하여 수동형 FTIR 분광계의 radiometric calibration을 수행하고 타당성을 살펴보았다. Radiometric calibration은 분광계로 입사되는 radiance의 온도 변화에 대한 광 검출기의 파장 별 응답특성과 기기 내부에서 발생되는 온도 및 반사율에 의해 발생되는 측정 오차를 보정하여 Planck radiance로 변환하는 기법이다. 시료에 대한 calibration 과정을 수행한 스펙트럼을 spectral library와 비교한 결과, 흡수 스펙트럼의 파장 별 선폭과 상대적인 intensity가 매우 유사하게 나타났으며 입사 광원의 온도차와 비례하여 spectral intensity가 일정하게 증가됨을 확인할 수 있었다.