• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2737-2742
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• 2011

Ring-opening metathesis polymerization (ROMP) of an ethyl-substituted tetracyclododecene (8-ethyltetracyclo[$4.4.0.1^{2,5}.1^{7,10}$] dodec-3-ene, Et-TCD) was carried out in the presence of a ternary catalyst system consisting of $WCl_6$, triisobutyl aluminium (iso$Bu_3Al$), and ethanol. The optimal molar ratio of Et-TCD/$WCl_3$/iso-$Bu_3Al$/ethanol was found as 500/1/3/2 at which the yield of ring-opened polymer was 100%. 1-Hexene was shown to be an effective molecular weight controlling agent for ROMP reaction of Et-TCD. The hydrogenation of the ring opened polymer (p-Et-TCD) was conducted successfully using Pd(5 wt %)/${\gamma}$-$Al_2O_3$ at $80^{\circ}C$ for 1 h. Chemical structures of p-Et-TCD and its hydrogenated product($H_2$-p-Et-TCD) were characterized using 2D NMR techniques ($^1H-^1H$ COSY and $^1H-^{13}C$ HSQC). The changes of physical properties such as thermal stability, glass transition temperature and light transmittance after the hydrogenation were also investigated using TGA, DSC, and UV.

• 콘크리트학회논문집
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• 제22권3호
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• pp.427-435
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• 2010

인장 균열은 콘크리트의 가장 취약한 특성으로 수화열 및 건조수축 등으로 인해 초기재령에서 발생되는 경우가 많다. 초기의 균열을 정확히 예측하기 위해서는 응력-균열 개구 관계가 시간에 따라 어떻게 변화하는 지를 파악해야 한다. 이 연구에서는 기존에 수행되었던 쐐기형 쪼갬 실험결과에 대한 역해석을 수행하였으며, 측정된 하중-균열 개구 변위를 최적으로 모사하는 응력-균열 개구 관계에 대한 쌍선형 연화곡선을 구하였다. 파괴에너지의 시간에 따른 변화에 관한 분석이 이루어졌으며, 분석 결과를 바탕으로 초기재령에서의 응력-균열 개구 관계에 대한 모델을 제안하였다. 최대 하중, 최대 하중에서의 균열 개구 변위, 파괴에너지에 대하여 실험 측정값, 역해석 결과, 모델로부터 계산된 결과들을 비교해 보았으며, 이를 통해 제안된 모델을 검증하였다.

• Nuclear Engineering and Technology
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• 제54권3호
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• pp.849-859
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• 2022

Feed-water valves (FWVs) are used to regulate the flow rate of water entering steam generators, which are very important devices in nuclear power plants. Due to the working environment of relatively high pressure and temperature, there is strength failure problem of valve body in some cases. Based on the thermo-fluid-solid coupling model, the valve body stress of the feed-water valve in the opening process is investigated. The flow field characteristics inside the valve and temperature change of the valve body with time are studied. The stress analysis of the valve body is carried out considering mechanical stress and thermal stress comprehensively. The results show that the area with relatively high-velocity area moves gradually from the bottom of the cross section to the top of the cross section with the increase of the opening degree. The whole valve body reaches the same temperature of 250 ℃ at the time of 1894 s. The maximum stress of the valve body meets the design requirements by stress assessment. This work can be referred for the design of FWVs and other similar valves.

• 한국공간구조학회논문집
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• 제8권3호
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• pp.65-73
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• 2008

본 연구에서는 음향적으로 결합된 공간에서 개구부의 크기변화에 따른 주관적 잔향감의 평가를 청취실험을 통해 실시하고 주관적 잔향감을 예측할 수 있는 새로운 물리적 지표를 제시하고자 하였다. 대상공간의 물리적 음향특성은 물론 주관적 음향평가를 위하여 1/10 스케일의 모형을 제작하여 실험에 사용하였다. 주관적 잔향감평가를 위해 바이노럴 임펄스 리스펀스(binaural impulse response)를 더미헤드(dummy head)를 이용해 녹음하여 가청화작업(auralization)을 거쳐 청취실험에 음원으로 제시하였다. 청취실험결과, 주실이 흡음력이 낮은 잔향부실과 음향적으로 결합할 경우 개구율이 12.5%(주실면적대비 1.97%)일 때 주관적 잔향감이 가장 큰 것으로 나타났으며 개구율이 25%(주실면적대비 3.94%)이상일 때 주관적 잔향감이 감소하는 것으로 나타났다 주실이 흡음력이 높은 흡음부실과 음향적으로 결합할 경우 개구율이 $0%{\sim}6.25%$까지(주실면적대비 $0%{\sim}0.99%$)는 주관적 잔향감이 변화하지 않다가 개구율이 12.5%에서부터 점차적으로 감소하는 것으로 나타났다. 이중감쇠현상을 나타내는 물리적 지표 T30/T15는 개구율의 변화에 따른 주관적 잔향감과 상관도가 거의 없는 것으로 나타났으며 저자들이 제시한 새로운 지표 T30/Tbp이 주관적 잔향감과 높은 상관도를 보였다. 또한 개구율 변화에 따른 이중감쇠현상은 초기나 중기감쇠부분에서보다 후기감쇠부분에서 에너지가 현저하게 증가하는 것으로 나타나 T30/T15에 비해 LDT/EDT나 T3/T1가 주관적 잔향감과의 상관성이 높은 것으로 나타났다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.56.2-56.2
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• 2010

국부적 후면 전극(LBC)형성은 결정질 실리콘 태양전지에서 고효율과 저가화를 동시에 달성할 수 있는 기술이다. 후면 표면 passivation과 국부적 후면 전극 형성을 통해서 후면 재결합 속도를 낮출 수 있고 이를 통해 효율향상을 기대해볼 수 있다. 본 연구에서는 PECVD를 이용한 LBC(local back contact) cell의 후면 passivation 박막을 형성하였고 접합면적에 따른 전기적 특성을 분석해 보았다. LBC cell을 위한 후면 passivation 박막은 PECVD를 이용한 ONO박막을 사용하였고, 후면 opening 형성에 etching paste를 이용하였다. Opening size는 0.4mm,0.5mm,0.7mm로 형성하여 cell을 제작하고 효율을 분석하였다. 실험결과 opening size가 0.4mm일때 전극의 접촉면적이 15.96%, 0.5mm일때 10.22%, 0.7mm일때 5.17%로 형성됨을 확인할 수 있었다. Opening size가 0.4mm일 때 cell의 효율이 가장 우수함을 IQE 및 LIV 결과를 통해 확인 할 수 있었다. 결과적으로 접촉면적이 증가함에 따라 전극에서 수집되는 carrier의 양이 증가하고 셀 효율역시 향상됨을 확인 할 수 있었다.

• 설비공학논문집
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• 제16권11호
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• pp.1092-1100
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• 2004

This paper presents the effect of opening configuration on the thermal behavior and air pattern of earth tube system. The earth tube system is a fresh air load reduction system by using underground double floor space for air-conditioning. In order to analyze the effect of opening configuration on thermal performance of this system and air pattern in underground double floor space quantitatively, we used a model dealing with tree-dimensional profile of wind velocity and temperature in underground double floor space. In conclusion, it is confirmed that heat exchange of a fresh air is mainly performed with upper and lower wall in underground double floor space, and that heat exchange area increased by installing the opening near the wall.

• 설비공학논문집
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• 제16권4호
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• pp.390-396
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• 2004

A double-inlet pulse tube refrigerator was fabricated as a U-shape with $\Phi$19.0 mm${\times}$125 mm regenerator packed by #200 stainless steel mesh and $\Phi$12.7 mm${\times}$125 mm pulse tube. A pressure sensor was installed at the inlet of the regenerator and a differential pressure sensor was installed across the bypass. Amplitude of the pulsating pressure was independent of the opening of the orifice and the bypass valves. Helium flow through the orifice and the bypass was calculated based on the measured pressure. Energy loss through the orifice and the bypass was evaluated with the measured pressure and the calculated helium flow rate. The energy loss, which is equivalent to the refrigeration capacity at the cold end of the ideal pulse tube refrigerator, was mainly generated through the orifice. It was proportional to the opening of the orifice valve, but the real refrigerator displayed the best performance at the optimized opening of the orifice valve. This optimized performance of the tested pulse tube refrigerator can be explained by additional refrigeration losses. As an example, the shuttle heat transfer loss of the pulse tube was calculated from the measured experimental data.

• 한국수소및신에너지학회논문집
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• 제26권4호
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• pp.386-392
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• 2015

Flow characteristics inside a 10 inch ball valve have been analyzed using three-dimensional numerical analysis and experiments. Continuity and three-dimensional Reynolds-averaged Navier-Stokes equations have been used as governing equations for the numerical analysis. The numerical model has been constructed through the grid dependency test and validation with the results of experiments to ensure reliability and numerical effectiveness. The shear stress transport (SST) model has been used as the turbulence closure. The experimental test-rig has been constructed to measure pressure, temperature and flow rate along the pipeline. Some valve opening angles have been tested to evaluate the flow characteristics inside the ball valve and pipeline. The results show that the rapid pressure variations is observed while the valve opening angle decreases, which caused by flow separation at the downstream of the ball valve.

• International Journal of Naval Architecture and Ocean Engineering
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• 제5권3호
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• pp.478-491
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• 2013

Natural vibration analysis of plates with openings of different shape represents an important issue in naval architecture and ocean engineering applications. In this paper, a procedure for vibration analysis of plates with openings and arbitrary edge constraints is presented. It is based on the assumed mode method, where natural frequencies and modes are determined by solving an eigenvalue problem of a multi-degree-of-freedom system matrix equation derived by using Lagrange's equations of motion. The presented solution represents an extension of a procedure for natural vibration analysis of rectangular plates without openings, which has been recently presented in the literature. The effect of an opening is taken into account in an intuitive way, i.e. by subtracting its energy from the total plate energy without opening. Illustrative numerical examples include dynamic analysis of rectangular plates with rectangular, elliptic, circular as well as oval openings with various plate thicknesses and different combinations of boundary conditions. The results are compared with those obtained by the finite element method (FEM) as well as those available in the relevant literature, and very good agreement is achieved.

• 한국수소및신에너지학회논문집
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• 제21권2호
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• pp.98-103
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• 2010

In order to develop two-stroke free-piston hydrogen engine to obtain high thermal efficiency and low emission, backfire occurrence have to be prevented. In this research, backfire characteristics are analyzed as functions of the intake valve opening timing and compression chamber pressure under piston by using RICEM (Rapid Intake Compression Expansion Machine) that has reverse uni-flow scavenging. As the result, reverse uni-flow scavenging is advantage about back fire. but, it exists suitable intake valve opening timing and its timing become known that equivalence ratio 1 retard until the piston rises. Also, To rise chamber pressure of lower piston, this does not cause backfire occurs in equivalent ratio 0.6 observed back fire. Therefore, 2cycle hydrogen fueled free-piston engine is undesirable scavenging compression by compressing the piston.