• Title/Summary/Keyword: One-pot

Search Result 565, Processing Time 0.029 seconds

New Synthetic Method of Perfluoro-Silanes for the Stable Electrolyte of Lithium Ion Battery Application

  • Koh, Kyungkuk;Sohn, Honglae
    • Journal of Integrative Natural Science
    • /
    • v.10 no.3
    • /
    • pp.171-174
    • /
    • 2017
  • Non-hydrolyzable fluorinated organosilicon compounds as an eletrolyte for the application of lithium-ion batteries (LIB) are synthesized. New synthetic method for the perfluorinated organosilicon compound containing spacer such as ethyl and propyl group with cyano moiety instead of ethylene glycol to prevent hydrolysis and to promote conductivity are developed in one pot reaction with moderately high yield. Air-sensitive boron trifluoride etherate is no longer required in this reaction. The products are characterized by spectroscopic analysis.

Stereoselective Transformation of Phytosphingosine to Safingol

  • Kim, Na-Ri;Lee, Sun-Hee;Namgoong, Sung-Keon
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.3
    • /
    • pp.695-699
    • /
    • 2009
  • A short and efficient synthesis of (2S,3S)-safingol from commercially available D-ribo-(2S,3S,4R)-phytosphingosine is described. The highlights of the synthesis are a stereoselective one-pot transformation of a diol into an epoxide under phase transfer catalytic conditions and a regioselective epoxide-opening reduction with a hydride reagent.

Syntheses and Characterizations of Lactam Cyclophanes. Attempted Synthesis of a Lactam Catenane Using Hydrogen Bonds

  • 주경미;임혜재;백경수
    • Bulletin of the Korean Chemical Society
    • /
    • v.16 no.11
    • /
    • pp.1079-1084
    • /
    • 1995
  • New cyclophanes having multilactam linkages were synthesized and characterized. One-pot coupling reaction of 2,6-pyridinedicarbonyl dichloride and a diamine gave a tetralactam, a hexalactam, and a octalactam in good yields. The TLC behaviour, the molecular symmetry shown by 1H NMR spectrum, and the fragmentation patterns shown by FAB mass spectrum of the octalactam support its monocyclic structure.

Synthesis of POSS-Functionalized Imidazole

  • Choi, Kyung-Min;Jang, Hee-Jae;Shin, Dong-Soo
    • Journal of the Korean Chemical Society
    • /
    • v.63 no.1
    • /
    • pp.51-55
    • /
    • 2019
  • The synthesis of N-substituted POSS-imidazole in one pot typically prepared using the condensation method from diketone and aminopropylisobutyl-POSS. A wide variety of functional groups and substitution patterns were tolerated under the present procedure. The resulting compounds can be used as valuable products allowing for the elaboration to OLED, DSSC building block.

Stereoselective Total Synthesis of (-)-Cytoxazone

  • Kim, Ji-Duck;Hoon, Jung-Young
    • Proceedings of the PSK Conference
    • /
    • 2003.10b
    • /
    • pp.179.2-179.2
    • /
    • 2003
  • We have developed the novel one-pot synthetic method for regioselective and stereoselective N-protected amines through the reaction of various ethers with chlorosulfonyl isocyanate (CSI). Also, we found a novel technique to compare directly the stability of carbocations in the solution phase and established the stability order of the various carbocations. And we reported the cleavage of benzyl and p-methoxybenzyl protecting groups of alcohols and phenols in the presence of other functional groups using CSI. (omitted)

  • PDF

Effects of Amo-1618 on the Yield, Behavior of Mineral Nutritions and Uptake Ratio Employing P-32 Labelled Double Calcium Super-phosphate in Rice Plants (水稻(수도)에 대한 질소(窒素) 및 인산효율증진(燐酸效率增進)에 관한 연구(硏究) -(수도(水稻)에 대한 Amo-1618 처리(處理)가 수량(收量), 무기영양요소(無機營養要素)의 동태(動態) 및 $P^{32}$ 표식중과석(標識重過石)의 이용율(利用率)에 미치는 영향(影響))-)

  • Ahn, Hak-Soo
    • Applied Biological Chemistry
    • /
    • v.11
    • /
    • pp.173-184
    • /
    • 1969
  • To elucidate the effect of Amo-1618(4-hydroxyl-5-isopropyl-2-methlphenyl trimethyl ammonium chloride, 1-piperidine carboxylate) known as a kind of growth retardant, on the growth, grain yield, increasing the efficiency of nitrogen fertilizer, behavior of mineral nutritions and the rate of phosphorus utilization, this experiment was conducted pot culture method in a vinyl house. Two nitrogen level, namely, practical nitrogen level(1 N) and three times nitrogen level(3 N) was made and labelled double-calcium-superphosphate $Ca(H_2P^{32}O_4)_2.\;2H_2O)$ as a source of radioactive phosphorus(P-32) was employed $80\;{\mu}c/pot$, respectively. Rice seedlings, variety 'Suwon No. 82', was transplanted to a 1/50,000 a china pot on June 13 in 1968. For treatment, at early stage of tillering, 10,000 ppm solution of Amo-1618 was foliar sprayed only one time. The Duncan's new mutiple-range test was adopted for statistical analysis evaluating experimental data at 5% level significance. The results obtained may be summarized as follows; 1) No significant difference was found among the treatments in plant height, but in plot of Amo-1618 treatment and 3 N level, number of tillers was significantly increased than that of others. 2) Weight of 10,000 kernels and seed-setting rate was also remarkably increased in same treatment above. 3) Grain yield per pot was significantly increased in Amo-1618 and 3 N level application. This results seemed to be due to the increased the factors on the yield. 4) Contents of nitrogen and phosphorus per cent in the grain was likewise increased in Amo-1618 and 3 N application. There is, however, no difference among treatments in the content of nitrogen and phosphorus in the leaves and culms of rice plants. 5) On the other hand, the contents of potassium and magnesium, no distinctly tendeny showed among treatments. 6) The rate of phosphorus utilization was significantly increased in the plot of Amo-1618 and 3 N application.

  • PDF

Recommendation of Optimum Amount of Fertilizer Nitrogen Based on Soil Organic Matter for Chinese Cabbage and Cabbage in Volcanic Ash Soils of Cheju Island (제주도 화산회토양의 배추와 양배추에 대한 질소의 시비추천식 설정)

  • Song, Yo-Sung;Kwak, Han-Kang;Yeon, Byeong-Yeal;Lee, Choon-Soo;Yoon, Jung-Hui;Moon, Doo-Young;Lee, Shin-Chan
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.35 no.2
    • /
    • pp.105-111
    • /
    • 2002
  • To find out the optimum nitrogen fertilization levels for the leafy vegetables in volcanic ash soils of Cheju island, fertilization effects on chinese cabbage chinese and cabbage were investigated through pot and field experiments. In pot experiment conducted with two volcanic ash soils of Cheju island, optimum rates of nitrogen fertilizer was ranged from 294 to $331kg\;ha^{-1}$ for chinese cabbage. At field experiment with one volcanic soil, the optimum N fertilizer was $331kg\;ha^{-1}$. On the basis of soil organic matters, fertilizer recommendation formula for cabbage, could be established by using 1.03 of comparison factors (F) compared with chinese cabbage : y=344.54-0.285x for chines cabbage, y= 354.88-0.294x for cabbage, where y is the recommendation amount of nitrogen fertilizer with x g $kg^{-1}$ of organic matter in soil. Actual optimum rate of nitrogen fertilizer for chinese cabbage under field condition was much more similar to the value caluculated by the revised nitrogen recommendation formula than the amount of nitrogen fertilizer recommended by the current formula in volcanic ash soil.