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니켈 폼(Ni foam)에 수열 합성법으로 제조한 수산화니켈(Ni(OH)2) 전극의 구조적 및 전기적 특성 (Structural and Electrical Properties of Nickel Hydroxide Electrode Prepared by Hydrothermal Synthesis on Nickel Foam)

  • 차현진;이석희;박정환;손영국;황동현
    • 한국표면공학회지
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    • 제56권5호
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    • pp.320-327
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    • 2023
  • In this study, the nickel hydroxide (Ni(OH)2) electrode for supercapacitor was prepared via hydrothermal method. Based on the nickel (Ni) foam, the electrode does not require any additional binder material or post-processing. Nickel nitrate (Ni(NO3)2) and hexamethylenetetramine (C6H12N4) were used for synthesis, and the synthesis condition was 12 hours at 80 ℃. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were used to analyze the structural characteristics of the electrode, and it shown that the nickel hydroxide was successfully prepared after only the one-step hydrothermal synthesis. The electrochemical properties were analyzed through the half-cell test. The prepared electrode shown a pair of oxidation/reduction peaks, indicating that the driving method included the redox reaction on the electrode surface. After the charge/discharge test, the specific capacitance was calculated as the value of 438 F/g at 3 A/g.

The Effects of Governance on Remittances: Evidence from Cross-Country Panel Data

  • Cho, Jung-Hwan
    • Journal of Korea Trade
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    • 제24권7호
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    • pp.29-37
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    • 2020
  • Purpose - This paper empirically investigates the relationship between country governance quality and worker remittances from foreign countries. Because remittances can be a source of funds for economic development and smoothing economic crises in developing countries, the related topic has been a concern for policy-makers and academic researchers. This paper divides the motives of remittances into altruistic and investment motives through existing papers, and then considers the governance quality the remittance receiving country as one of the determinants of remittances. Design/methodology - Our empirical model considers whether governance quality can affect the volume of remittances, and uses altruistic and investment factors studied in the literature. To do this, a two-step approach is taken. First, the panel data are examined via pooled OLS, random effects, and Tobit estimation. Second, the paper reduces six governance indicators into one variable, Governance, using the principal component technique (PCA) for a robustness check. Findings - The main findings can be summarized as follows. The negative governance variable in the estimation results shows a lower governance quality that induces workers to send savings to their home countries. This means that a country with poor governance quality seems to have more remittance inflows from abroad. It also reveals that poor governance quality is more relevant to an altruistic motive rather than an investment motive, in general. The positive per capita GDP variable shows the investment motive for developed countries. Originality/value - Existing papers have focused on various factors related to the motives of remittances. However, governance quality effects on remittance inflows have not been fully studied so far. This paper considers governance quality in an estimation equation explicitly as one of the determinants of remittances. This area of study is needed, in theory and empirically, in order to fully understand the relationship between governance and remittances.

미생물의 탈염소화 작용에 의한 난분해성 염화방향족 오염물질의 분해 (Biodegradation of Recalcitrant Chlorinated Aromatic Compounds via Microbial Dechlorination)

  • 채종찬;김치경
    • 환경생물
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    • 제17권2호
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    • pp.129-138
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    • 1999
  • 난분해성 유기화합물의 일종인 염화 방향족화합물은 냉각제, 소화제, 페인트, 용매, 플라스틱류, 유압제, 제초제, 농약, 그리고 화학합성에 필요한 전구물질 등에 널리 사용된다. 이들은 친지질 특성을 가지므로 생물체의 세포막에 쉽게 흡착되며 먹이사슬에 의한 생물학적 농축과정을 통해 인간을 포함하는 각종 생물체에 축적된다. 그 결과 생물체의 세포막 구조가 변화되고 기능이 저해될 뿐더러 암과 돌연변이를 유발하고 $\ulcorner$환경호르몬$\lrcorner$으로서 생물체의 내분비계 기능을 교란하는 등 심각한 보건학적 그리고 환경생물학적 문제를 일으키고 있다. 염화 방향족화합물들은 벤젠고리 구조와 벤젠고리에 염소가 치환된 탄소-염소 결합을 공통적으로 가지고 있으며 벤젠고리에 치환된 염소의 수와 같은 수의 염소라도 붙어있는 위치에 따라 난분해 특징이 결정된다. 염화 방향족화합물들의 분해를 위해서는 미생물에 의한 벤젠 구조의 개환과정과 함께 벤젠 고리구조로부터 염소 치환기를 제거하는 탈염소화 과정이 반드시 일어나야만 한다. 호기적 환경에서 미생물에 의한 탈염소화는 분해 초기단계에서 dehalogenase라는 효소에 의해 촉매되는 oxygenolytic, reductive, 그리고 hydrolytic catalysis에 의해 일어나거나, 분해 대사과정 중에 저절로 염소치환기가 떨어져 나가는 경우도 있다. 탈염소화 과정을 거쳐 분해하는 미생물들을 이용한 염화 방향족 오염물질의 생물학적 분해방법은 이미 사용되고 있는 물리ㆍ화학적 방법보다 경제적이며 2차 오염의 부작용 없이 그 오염물질들을 매우 효과적으로 처리할 수 있다. 따라서 탈염소화 기작을 포함한 분해과정의 이해는 생물학적 분해의 기본적인 정보를 제공할 뿐더러 난분해성 환경 오염물질의 분해처리를 위하여 보다 집중적으로 연구해야 할 과제라고 할 것이다.

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Recurrent Neural Network Modeling of Etch Tool Data: a Preliminary for Fault Inference via Bayesian Networks

  • Nawaz, Javeria;Arshad, Muhammad Zeeshan;Park, Jin-Su;Shin, Sung-Won;Hong, Sang-Jeen
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.239-240
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    • 2012
  • With advancements in semiconductor device technologies, manufacturing processes are getting more complex and it became more difficult to maintain tighter process control. As the number of processing step increased for fabricating complex chip structure, potential fault inducing factors are prevail and their allowable margins are continuously reduced. Therefore, one of the key to success in semiconductor manufacturing is highly accurate and fast fault detection and classification at each stage to reduce any undesired variation and identify the cause of the fault. Sensors in the equipment are used to monitor the state of the process. The idea is that whenever there is a fault in the process, it appears as some variation in the output from any of the sensors monitoring the process. These sensors may refer to information about pressure, RF power or gas flow and etc. in the equipment. By relating the data from these sensors to the process condition, any abnormality in the process can be identified, but it still holds some degree of certainty. Our hypothesis in this research is to capture the features of equipment condition data from healthy process library. We can use the health data as a reference for upcoming processes and this is made possible by mathematically modeling of the acquired data. In this work we demonstrate the use of recurrent neural network (RNN) has been used. RNN is a dynamic neural network that makes the output as a function of previous inputs. In our case we have etch equipment tool set data, consisting of 22 parameters and 9 runs. This data was first synchronized using the Dynamic Time Warping (DTW) algorithm. The synchronized data from the sensors in the form of time series is then provided to RNN which trains and restructures itself according to the input and then predicts a value, one step ahead in time, which depends on the past values of data. Eight runs of process data were used to train the network, while in order to check the performance of the network, one run was used as a test input. Next, a mean squared error based probability generating function was used to assign probability of fault in each parameter by comparing the predicted and actual values of the data. In the future we will make use of the Bayesian Networks to classify the detected faults. Bayesian Networks use directed acyclic graphs that relate different parameters through their conditional dependencies in order to find inference among them. The relationships between parameters from the data will be used to generate the structure of Bayesian Network and then posterior probability of different faults will be calculated using inference algorithms.

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범주형 자료에서 경험적 베이지안 오분류 분석 (Empirical Bayesian Misclassification Analysis on Categorical Data)

  • 임한승;홍종선;서문섭
    • 응용통계연구
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    • 제14권1호
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    • pp.39-57
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    • 2001
  • 범주형 자료에서 오분류는 자료를 수집하는 과정에서 발생될 수 있다. 오분류되어 있는 자료를 정확한 자료로 간주하여 분석한다면 추정결과에 편의가 발생하고 검정력이 약화되는 결과를 초래하게 되며, 정확하게 분류된 자료를 오분류하고 판단한다면 오분류의 수정을 위해 불필요한 비용과 시간을 낭비해야 할 것이다. 따라서 정확하게 분류된 표본인지 오분류된 표본인지를 판정하는 것은 자료를 분석하기 전에 이루어져야할 매우 중요한 과정이다. 본 논문은 I$\times$J 분할표로 주어지는 범주형 자료에서 두 변수 중 하나의 변수에서만 오분류가 발생되는 경우에 오분류 여부를 검정하기 위해서 오분류 가능성이 없는 변수에 대한 주변합은 고정시키고, 오분류 여부를 가능성이 있는 변수의 주변합을 Sebastiani와 Ramoni(1997)가 제안한 Bound와 외부정보로 표현되는 Collapse의 개념, 그리고 베이지안 방법을 확장하여 자료에 적합한 모형과 사전정보를 고려한 사전모수를 다양하게 설정하면서 재분류하는 연구를 하였다. 오분류에 대한 정보를 얻기 위해서 Tenenbein(1970)에 의해 연구된 이중추출법을 이용하여 오분류 검정을 위한 새로운 통계량을 제안하였으며, 제안된 오분류 검정통계량에 관한 분포를 다양한 모의실험을 통하여 연구하였다.

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상압 공정을 이용한 침상형 5Mg(OH)2·MgSO4·3H2O 합성에 대한 MgSO4/MgO 효과 (Effect of MgSO4/MgO on the Synthesis of 5Mg(OH)2·MgSO4·3H2O Whiskers using One-step Ambient Pressure)

  • 유리;피재환;김형태;김유진
    • 한국세라믹학회지
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    • 제50권3호
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    • pp.201-205
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    • 2013
  • Magnesium hydroxide sulfate hydrate ($5Mg(OH)_2.MgSO_4{\cdot}3H_2O$, abbreviated 513 MHSH) whiskers were synthesized using MgO and $MgSO_4.7H_2O$ as reactants without addition of basic solution. Previously, MHSH whiskers were prepared by hydrothermal method using $MgSO_4$ in aqueous ammonia. In this work, for the first time, we synthesized a high purity MHSH via ambient pressure. In addition, a high molar ratio of $MgSO_4$ : MgO is an important key to the formation of high purity MHSH. Also, it was possible to prepare whiskers with high aspect ratio using an increasing reaction time in the reaction between the remaining $SO_4^{2-}$ ions and the ${Mg(OH)_6}^{4-}$ fragment, finally producing one-dimensional whiskers.

The Comparative Analysis of 3D Software Virtual and Actual Wedding Dress

  • Yuan, Xin-Yi;Bae, Soo-Jeong
    • 패션비즈니스
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    • 제21권6호
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    • pp.47-65
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    • 2017
  • This study is intended to compare an actual wedding dress being made completely through 3D software, and compare it with an actual dress of a real model by using collective tools for comparative analysis. The method of the study was conducted via a literature review along with the production of the dresses. In the production, two wedding dresses for the small wedding ceremony were designed. Each of the design was made into both 3D and an actual garment. The results are as follows. First, the 3D whole body scanner reflects the measure of the exact human body size, however there were some difficulties in matching what the customer wanted, because the difference of the skin color and the hair style. Second, the pattern of the dress is much more easily altered than it was in the real production. Third, the silhouette of the virtual and the actual person with the dress was nearly the same. Fourth, textile tool was much more convenient because of the use of real-time rendering on the virtual dresses. Lastly, the lace and biz decoration were flat, and the luster was duller than in reality. Prospectively, the consumer will decide their own design of variety through the use of the avatar without wearing the actual dresses, and they would demand what the another one desired, different from the presented ones by making the corrections by themselves. Through this process, the consumer would be actively participating in the design, a step which would finally lead to the two way designing rather than the one way design of present times.

염석법을 이용한 비공유 기능기화된 그래핀 나노플레이트렛의 분리 공정 연구 (Separation of Non-covalently Functionalized Graphene Nanoplatelets via Salting-out Process)

  • 김준희;유승찬;차재민;류호진;홍순형
    • Composites Research
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    • 제32권3호
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    • pp.134-140
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    • 2019
  • 그래핀 나노플레이트렛(GNP)은 현시점에서 가장 산업화 적용에 가까운 그래핀으로 알려져 있다. 하지만 현재 GNP는 그 우수한 생산량에도 불구하고 응집현상과 물리화학적 불균질성으로 인해 복합재에서의 강화재로 사용되기에는 제한이 존재한다. 본 연구에서는 이러한 GNP의 문제 해결을 위해 산업화 레벨의 대량생산 공정으로 확장 가능한 비공유 기능기화공정을 이용하여 GNP를 기능기화하였다. 본 기능기화 공정은 저렴한 물질로 알려진 멜라민을 사용하여 GNP의 응집현상을 방지하는 동시에 극성 용매내에서의 분산성을 향상시켰다. 뿐만 아니라 기능기화된 GNP의 분산성의 차이를 이용한 염석법 공정을 적용, GNP를 크기 별로 정제하였다. 이처럼 본 연구는 언급한 기능기화와 분리 공정을 기반으로 하여 GNP의 복합소재/부품 산업 응용을 위한 전략을 제시하였다.

『황제내경(黃帝內經)』의 체질론(體質論) (The Constitutional Ideas in the 『Huangdi Neijing』)

  • 최승훈
    • 사상체질의학회지
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    • 제10권2호
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    • pp.15-28
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    • 1998
  • One's constitution is formed congenitally and is also acquired, and is relatively stable in its individually manifested function, structure and temperament. It has characteristics of universality, complexity, generality and continuity. It is also manifested in physiological responses and expresses pathologic tendencies including susceptibility. Attempts at understanding constitution has had a long history throughout the world. In Oriental Medicine, the constitution had been acknowledged from the "Huangdi Neijing", which has been a bible in Oriental Medicine for about two thousand years. In many aspects, the "Huangdi Neijing" provides the basis for both basic and practical fields. In order to derive the ideal structure from the "Huangdi Neijing" to Lee Je-ma's(Lee Jayma's) Sasang Constitutional ideas, which can strengthen the understanding of ideal core of Oriental Medicine's constitutional characteristics, the author launched his analysis of the constitutional understandings in the "Huangdi Neijing" as a first step and came to the following: 1. The constitutional understanding in the "Huangdi Neijing" was done both via the physiological responses to heat, pain and acupuncture treatment and the pathologic tendencies via body structure, strength, body heat, courage and obesity. 2. It was recognized that the constitution was formed congenitally and also acquired factors like living conditions including food customs, residents and geographical conditions were explained in detailed. 3. The constitutional typology was suggested both by the general and systematic criterion according to the Yin-yang and the Five phase theories and by single criterion such as obesity, courage and the response to acupuncture treatment. 4. As diagnosis is related to the constitution, courage was adopted for the disease caused by emotions, obesity was for its manifestations of qi and blood, the quantities of qi-blood and Yin-yang in the typology by the Yin-yang and Five phase theories were suggested. 5. In the case of obesity, Yin-yang and Five phase theory, treatment according to the constitutional ideas was mentioned, and their goals were concluded as "being the balancing between Yin and Yang" which means the Yin-yang theory is more practical than the Five phase theory in Oriental Constitutional Medical field. According to the above understandings, the author would like to suggest that the constitutional ideas in the "Huangdi Neijing" based on the Yin-yang theory blossomed via the practical spirit of Zhang Zhong-jing's "Shanghanlun" and at last from Lee Je-ma's(Lee Jayma's) Sasang Constitutional Medicine which realized "the balancing between Yin and yang" through the practical applications of herbal treatments.

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Gonadotropins, Prostaglandin $F_{2{\alpha}}$ 및 Ouabain이 황체막의 $Ca^{++}-ATPase$ 활성도에 미치는 영향 (Effects of Gonadotropins, Prostaglandin $F_{2{\alpha}}$, and Ouabain on the $Ca^{++}-ATPase$ Activity in Luteal Membranes)

  • 구본숙;김인교
    • The Korean Journal of Physiology
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    • 제21권1호
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    • pp.47-58
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    • 1987
  • It has been reported that the luteal function may be regulated by the intracellular $Ca^{++}$ level which may be adjusted partially by the high affinity $Ca^{++}-ATPase$ in luteal cell membranes. Then, one may expect that luteotropic and/or luteolytic agents, such as gonadotropins, prostaglandin $F_{2{\alpha}}\;(PGF_{2{\alpha}})$ and ouabain, affect the intracellular $Ca^{++}$ level. In this present study, therefore, we examined the effects of luteinizing hormone (LH, or human chorionic gonadotropin, hCG), $PGF_{2{\alpha}}$ and ouabain on the kinetic properties of the high affinity $Ca^{++}-ATPase$ in light membrane, heavy membrane, and microsomal fractions from the highly luteinized ovary. LH (or hCG) increased the affinity and the Vmax for $Ca^{++}$ both in light membrane and heavy membrane. $PGF_{2{\alpha}}$ increased the Vmax in light membrane and decreased the Km in heavy membrane for $Ca^{++}$ at low concentration $(5\;{\mu}g/ml)$. At higher concentration, however, $PGF_{2{\alpha}}$ oppositly affected on kinetic properties, that shown at low concentration. Ouabain, a potent inhibitor of $Na^+-K^+-ATPase$, increased the Km at high concentration $(10^{-4}\;M)$, however, decreased the Vmax for $Ca^{++}$ in light membrane at low concentration $(10^{-6}\;M)$. Also, ouabain increased the Km for $Ca^{++}$ in heavy membrane without changes in the Vmax at both concentrations. It seems that LH and low dose of $PGF_{2{\alpha}}$ increase the intracellular $Ca^{++}$ level and cause in activation of $Ca^{++}-ATPase$, however, higher dose of $PGF_{2{\alpha}}$ and ouabain inhibit directly $Ca^{++}-ATPase$ activity and result in increase in intracellular $Ca^{++}$ level. According to the above results, we suggest that luteotropic and/or luteolytic agents regulate the luteal progesterone $(P_4)$ production through two different pathways; one is cyclic adenosine monophosphate (cAMP)-dependent and another is $Ca^{++}-dependent$. Intracellula. $Ca^{++}$ level regulated by the high affinity $Ca^{++}-ATPase$ may affect both pathways in a time-dependent fashion. LH (or hCG) acts on the luteal $P_4$ production via both pathways. The initial step is $Ca^{++}$ dependent, and the late step is cAMP dependent. $PGF_{2{\alpha}}$ and ouabain increase the intracellular $Ca^{++}$ concentration so that basal luteal $P_4$ production is increased and LH-stimulated $P_4$ production is inhibited by the inhibiting LH-dependent adenylate cyclase activity.

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