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Sequential Extraction을 이용한 Fly ash의 Cd 흡착 양상 평가

  • 이광헌;이승학;이아라;명동일;박준범;김형석
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.376-379
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    • 2004
  • pH has been regarded as a master variable governing the heavy metal sorption on fly ash. However, the chemical constituents in the fly ash could also suggest a potential sorption site for heavy metals. So, in this study sequential extraction method is employed to evaluate the sorption behavior of fly ash for cadmium. Two different fly ashes (S-fly ash, T-fly ash) were obtained from different power plants in Korea. First, cadmium is adsorbed under four different initial pHs. And, Cd sorbed in fly ash was sequentially desorbed following the sequential extraction method suggested by Tessier. In test results, the effect of pH increase was differently exerted in two fly ash. In S-fly ash, exchangeable fraction was dominated in low initial pH, however, as increasing initial pH, the fraction bound to carbonate increased. In the T-fly ash, regardless of initial pH the fraction bound to carbonate was major part of sorption estimated. The fraction bound to Fe/Mn oxide was about 10% in T-fly ash, and 5% in S-fly ash at high pH.

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미연탄서를 제거한 플라이애쉬의 특성 (Propoerties of Beneficated Fly Ashes)

  • 이승헌;;;박정수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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    • pp.613-618
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    • 1999
  • This paper discuss the chemical, physical and mineral properties of classified fly ashes by electrostatic precipitator and calcinated fly ashes at 50$0^{\circ}C$. The electrostatic precipitator in coal fired power plant has a number of hopper in the direction of flue gases. The properties of fly ashes collected at each hopper in the electrostatic precipitator are different. Superfine, fine and ordinary fly ashes can be collected respectively at each hopper. The carbon content in fly ash is influenced on the viscosity of paste. By calcination, the carbon content in fly ash is decreased and the fluidity of paste is improved.

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플라이 애시 시멘트 페이스트의 유동성에 미치는 플라이 애시의 인자 (A Factor of Fly Ash on Fluidity of Fly Ash Cement Paste)

  • 이승헌;김홍주
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.153-158
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    • 2000
  • This study was carried out in order to investigate the relationship roundness of fly ashes and fluidity of fly ash cement paste. electrostatic precipitator system in coal-fired power plant have many successive collection fields in the direction of flue gas travel. In experiment, the roundness of fly ashes collected from the same location had similar values regardless of the load or boiler, and they increased going from the 1st collection filed to third collection filed in the direction of gas movement. In considering the relation between roundness of fly ashes and fluidity of fly ash cement paste, it has a high correlation.

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석탄회 시용이 연초 생육과 토양중 중금속 함량에 미치는 영향 (Effects of Application of Fly Ash on Tobacco Growth and on Accumulation of Heavy Metal in Soil)

  • 홍순달;석영선;송범헌
    • 한국연초학회지
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    • 제20권1호
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    • pp.5-12
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    • 1998
  • Pot experiment was conducted to investigate the effects of fly ash on growth responses and on accumulation of the heavy metals in soil. Two kinds of fly ash, anthracite and bituminous coal, were treated with different levels of 0, 0.4, 0.8, and 1.2 kg/pot(20L). Tobacco growth was better by application of fly ash than that by the control. However, the early stage of growth by application of bituminous coal, 1.2 kg/pot, was decreased due to the boron toxicity occurred by fly ash. Generally, tobacco yield was significantly increased with applying fly ash, showing the highest yield at 1.2 kg/pot for anthracite and at 0.8 kg/pot for bituminous coal. The content of total nitrogen in leaves was higher with fly ash than that of the control, while the content of calcium in leaves was low, Contents of heavy metal and the other minerals were not significantly different between the control and the treatment of fly ash. Soil pH after experiment was linearly increased with application level of fly ash, indicating that the application of bituminous coal was more effective than that of anthracite. Contents of available phosphate, exchangeable $Ca^{2+}$+ and $Mg^{2+}$ in soil were increased by application of fly ash, especially with bituminous coal. Contents of Cu, Cr, and Ni were increased with application level of bituminous coati even if the contents were still lower than critical levels for farming land. The other heavy metals were similar between the control and the application of fly ash.

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플라이애쉬를 다량 사용한 시멘트 경화체의 강도증진에 관한 실험적연구 (A Study on Strength of Cement Mortar with Micro Grinding High Volume Fly-Ash)

  • 정재동
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2001년도 학술논문발표회
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    • pp.82-87
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    • 2001
  • The purpose of this study is for the active use of the fly ash, which is a by-product of the combustion pulverizes coal thermal power plants, to compensate for the lack of landfill and for conservation of energy, by using fly ash as the supplementary cementitious material, and to prove its possibility as the related products of the cement. First of all, the ordinary fly ash is grinded in a special method and its fineness is controlled from 6000$\textrm{cm}^2$/g to 8000$\textrm{cm}^2$/g, then replaced it with the 10% to 80% of the cement mortar in order to test physics characteristics. The first experiment conducts on the strength development in fly ash replacing content and fineness. and the changes of the flow values, incorporating fly ash into cement. The second one is about the slow development of the strength of the fly ash mortar in early ages, and improves its strength with the activator $Na_{2}SO_{4}$, using high volume fly ash.

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Fly Ash를 사용한 수중불분리 콘크리트의 유동성에 관한 연구 (A Study on the Fluidity of Antiwashout Underwater Concrete Containing Fly Ash)

  • 권중현;배기성
    • 한국해양공학회지
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    • 제12권1호
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    • pp.153-161
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    • 1998
  • This paper is to investigate the Fluidity of Antiwashout Underwater Concrete containing Fly Ash. The results of study are concluded as follows: the increase in Slump Flow value did not happen in the plain concrete which was replaced cement by Fly Ash; however, the maximum value could reach in the replacement of 30% of Fly Ash by weight of cement in the Fly Ash replaced concrete. On the condition of Fly Ash-Antiwashout Underwater Concrete in expecting 50 cm of the Slump Flow, it was necessary that the usage amount of Superplasticizer be around 1% of unit Binder, and 1.5% in 60 cm of the Slump Flow, respoectively.

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플라이애시를 대량 사용한 콘크리트의 배합설계를 위한 기초적 연구 (A Fundamental Study on the Mix Design in High Volume Fly-Ash Concrete)

  • 심재형;김재환;최희용;강석표;최세진;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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    • pp.641-646
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    • 2001
  • Generally, when Fly-Ash was used as replacement material of cement in concrete, it might occur retardation of setting and hardening. So, it is unable to use a large amount of Fly-Ash as replacement for cement. However, if it is used as replacement material of fine aggregate in concrete, we can use a large amount of Fly-Ash and settle a problem of natural-aggregate exhaustion. Furthermore, engineering properties of High Volume Fly-Ash Concrete Is better than that of plain concrete But, the larger Fly-Ash is replaced, the more fluidity of High Volume Fly-Ash Concrete decrease, because porous organization of Fly-Ash adsorb water and Superplasticizer. In this study, after appending additional water to High Volume Fly-Ash Concrete in proportion to weight of Fly-Ash, we intend to find proper ratio which doesn't affect strength and satisfy fluidity As a result of this study, it was found that fluidity of mortar with 25~28 percentage of additional water was satisfied with fluidity of plain mortar, and compressive strength of that was similar to plain mortar's

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주물공장 플라이애쉬를 혼화재로 사용한 콘크리트의 기초적 성질 (Fundamental Properties of Concrete Using Casting Foundry Fly Ash as an Admixture)

  • 김희성;진치섭
    • 콘크리트학회논문집
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    • 제12권3호
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    • pp.87-94
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    • 2000
  • Disposal of casting foundry fly ash generally depends on reclamation up to the present. This is the great loss from a standpoint of saving resources and utilizing industrial wastes. Therefore, a study on the reuse of fly ash as a substitute material for construction is necessary in order to utilize industrial wastes, to reduce cost and improve quality in producing concrete products, and to protect environment from pollution. In this study, methods for the reuse of the casting foundry fly ash, industrial wastes products, as an admixture for concrete are discussed. For this purpose, fly ash was extracted from casting foundry and tests of physical and chemical properties are executed. Also, various characteristics of concrete using fly ash as an admixture are experimented. Finally, the reuse methods for casting foundry fly ash are presented.

Experimental Investigation of Clay Fly Ash Bricks for Gamma-Ray Shielding

  • Mann, Harjinder Singh;Brar, Gurdarshan Singh;Mann, Kulwinder Singh;Mudahar, Gurmel Singh
    • Nuclear Engineering and Technology
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    • 제48권5호
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    • pp.1230-1236
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    • 2016
  • This study aims to determine the effect of fly ash with a high replacing ratio of clay on the radiation shielding properties of bricks. Some interaction parameters (mass attenuation coefficients, half value layer, effective atomic number, effective electron density, and absorption efficiency) of clay fly ash bricks were measured with a NaI(Tl) detector at 661.6 keV, 1,173.2 keV, and 1,332.5 keV. For the investigation of their shielding behavior, fly ash bricks were molded using an admixture to clay. A narrow beam transmission geometry condition was used for the measurements. The measured values of these parameters were found in good agreement with the theoretical calculations. The elemental compositions of the clay fly ash bricks were analyzed by using an energy dispersive X-ray fluorescence spectrometer. At selected energies the values of the effective atomic numbers and effective electron densities showed a very modest variation with the composition of the fly ash. This seems to be due to the similarity of their elemental compositions. The obtained results were also compared with concrete, in order to study the effect of fly ash content on the radiation shielding properties of clay fly ash bricks. The clay fly ash bricks showed good shielding properties for moderate energy gamma rays. Therefore, these bricks are feasible and eco-friendly compared with traditional clay bricks used for construction.

열병합발전소 플라이애쉬의 특성 및 활용방안에 관한 실험적 연구 -고강도 콘크리트를 중심으로- (AN EXPERIMENTAL STUDY ON THE PROPERTIES & APPLICATION FOR FLY ASH OF CONBINED HEAT POWER PLANT - FOCUSSED HIGH STRENGTH CONCRETE -)

  • 권영호;백명종;이보근;박칠림
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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    • pp.211-216
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    • 1994
  • This study dealt with the properties for fly ash of conbined heat power plant and application for concrete industry. For this purpose, fly ash sampled Ulsan conbined heat power plant and analyzed for physical and chemical properties. As analyzed results of fly ash, contents of $SiO_ and Al_O_ $in the fly ash of Ulsan were less than those of Thermo-electric power plant(Boryuing), but contents of CaO were tem times as much as those of Boryung, because of these differences, it is expected that pozzolanic activity of concrete using fly ash of Ulsan will be different from another fly ash. Concrete specimens were tested to evaluate concrete preformance when 10 to 50 percent of the portland cement by weight in the concrete mix was replaced with fly ash of conbined heat power plant. As test results, workability and consideration in the fresh concrete were increased and concrete strength was showed more than 400kg/$\textrm{cm}^2$ for the required age. This study would be provided valuable data for the practical utilization of fly ash(conbined heat power plant). In the future, properties of fly ash concrete including long term strength, elapsed time, pozzolanic activity, modulus of elasticity, sulfate resistance, shrinkage, freeze-thaw durability and so on will be studied.

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