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Influence of Chemical Activators on Cement-Fly ash Paste and Strength Development of Concrete

  • Song, Jong-Taek;Yun, Sung-Dae;Kim, Jae-Young;Lee, Chin-Yong
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.103-106
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    • 2000
  • The effects of replacement level, curing method and chemical admixtures were investigated in the cement-fly ash paste. The strength of cement-fly ash paste is lower than that of controlled cement paste only and the differences increase with replacement level. However, in steam curing, strength of cement-fly ash pastes is improved, especially, at early ages. In order to improve early strength, the use of $Na_2SO_4$in cement-fly ash paste increases the quality of concrete. In addition, improvement of strength of concrete including 30% of fly ash can be obtained and achieves the highest strength compared to other concrete mixtures.

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The Content of Chlorobenzenes and Chlorophenols and Their Isomer in MSWI Fly Ash (소각잔사 중의 클로로벤젠과 클로로페놀의 함량 및 이성체 분포특성)

  • Lee, U-Geun;Sim, Yeong-Suk;Kim, Jin-Beom
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.3
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    • pp.209-218
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    • 1998
  • Chlorobenzenes (CBs) and chlorophenols (CPs) in fly ashy discharged from several municipal solid waste incinerators (MSWI) were investigated in terms of total content and isomer distribution. The content of CBs and CPs was highest in the fly ash from S incinerator, which were 1040.7ng CB/g-fly ash and 1156.4 ng CP/g-fly ash. According to the experimental results, while all samples contained a large amount of the higher chlorinated CBs, was almost constant regardless of season. The quantities of CBs and CPs depended closely on the chemical composition of MSW. while the isomer distribution of CBs and CPs was constant throughout all the year round.

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An experimental study on strength of hybrid mortar synthesis with epoxy resin, fly ash and quarry dust under mild condition

  • Sudheer, P.;Muni Reddy, M.G.;Adiseshu, S.
    • Advances in materials Research
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    • v.5 no.3
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    • pp.171-179
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    • 2016
  • Fusion and characterization of bisphenol-A diglycidyl ether based thermosetting polymer mortars containing an epoxy resin, Fly ash and Rock sand are presented here for the Experimental study. The specimens have been prepared by means of an innovative process, in mild conditions, of commercial epoxy resin, Fly ash and Rock sand based paste. In this way, thermosetting based hybrid mortars characterized by a different content of normalized Fly ash and Rock sand by a homogeneous dispersion of the resin have been obtained. Once hardened, these new composite materials show improved compressive strength and toughness in respect to both the Fly ash and the Rock sand pastes since the Resin provides a more cohesive microstructure, with a reduced amount of micro cracks. The micro structural characterization allows pointing out the presence of an Interfacial Transition Zone similar to that observed in cement based mortars. A correlation between micro-structural features and mechanical properties of the mortar has also been studied.

An Experimental Study on the Properties of High Volume Fly Ash Concrete (플라이애시를 대량 사용한 콘크리트의 특성에 관한 실험적 연구)

  • Choi, Se-Jin;Jang, Jong-Ho;Choi, Sung-Woo;Choi, Hee-Yong;Park, Sun-Gyu;Kim, Moo-Han
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.549-554
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    • 2000
  • Generally, it is indicated that concrete using fly ash as a part of cement content has lower early strength, and faster carbonation velocity. To improve these problems and provide useful information for high volume fly ash concrete, the properties of concrete - those include slump, bleeding, setting time, compressive strength and carbonation depth etc. - which contained large amount of fly ash as a part of fine aggregate were investigated experimentally. According to test results, it was found that the compressive strength of the concrete increased in early age as well as in long term age with the increase of the fly ash content. And the carbonation depth of concrete using fly ash as a part of fine aggregate was lower than that of plain concrete(FA 0kg/ $\textrm{m}^3$).

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Mechanical and Durability Performance of Roller-Compacted Concrete with Fly Ash for Dam Applications

  • Park, Chan-Gi;Yoon, Jong-Whan;Kim, Wan-Young;Won, Jong-Pil
    • International Journal of Concrete Structures and Materials
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    • v.1 no.1
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    • pp.57-61
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    • 2007
  • This study investigated the mechanical and durability performance of roller-compacted concrete (RCC) with fly ash for dam applications. A test program studied the effects on the properties of fresh and hardened RCC with fly ash replacement ratio, as well as the long-term durability of the resulting mixture. Fly ash replaced 20, 30, 40, and 50% by mass of the cement. Laboratory tests of the compressive strength, splitting tensile strength, shear strength, chloride ion permeability, abrasion, and drying shrinkage were conducted. The test results demonstrated that 30% fly ash replacement is an optimum level, and that this mixture has excellent mechanical and durability properties.

A Scheme of Introducing Class C Fly Ash to the Korean industrial Standard (C급 플라이애쉬에 대한 KS규준 도입방안)

  • 이상수;권영호;안재현;김무한;박칠림
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.129-135
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    • 1997
  • Recently, discarding of reuse of fly ashes produced from combined heat power plant of thermal power plant as a by-product causes several problems. Esepecially, the fly ash from Ulsan Pertrochemical Serviec Co, classified as class C is the first by-product to be reused or discarded. For the reuse of the class C fly ash, it is necessary to prepare and provide domestic specifications because there is no specifications on the fly ash of class C from combined heat power plant. Therefore, this study dealt with a scheme of introducing class C fly ash to the korean industrial standard.

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Mechanical Characteristics of Recycled Structural Concrete with Fly Ash (Fly Ash를 사용한 구조용 재생 콘크리트의 역학적 특성)

  • 김진영;김장우;이봉학;박제선
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.229-234
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    • 1994
  • Various of batches of recycled concretes were produced with different rations of recycled aggregate (20% and 50%) and admixtures based on workable range of slump value and using a fixed w/c ration. Mechanical characteristics of the recycled concretes were evaluated. Test results showed that, in general, relatively high strength recycled concrete could be obtained using a plasticiser. The concrete using fly ash showed somewhat reduced strength, lower elastic modulus and relatively high strain, in general. However, the strength reduction ratio of the recycled concrete due to adding fly ash was relatively minor, compared with normal concrete. Since it has been known that the fly ash is used in place of cement and gives an improved long term strength, a further study may be warranted for a possibility of using fly ash without degrading the strength required.

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Physico-chemical Characteristics of Ammonia Adsorbed Fly Ash (AAFA)

  • Kim, Jae-kwan;Park, Seok-un;Hong, Jin-pyo
    • KEPCO Journal on Electric Power and Energy
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    • v.4 no.1
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    • pp.39-45
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    • 2018
  • Ammonia Adsorbed Fly Ash (AAFA) samples produced from coal fired plants equipped with SNCR (Selective Non-Catalytic Reduction) of nitrogen oxides with urea have been chemically analyzed, and their physical and dissolution properties have been investigated. XRD results for the ammonia component in AAFA ascertained that ABS (ammonium bisulfate) and AS (ammonium sulfate) were deposited on fly ash as $SO_3$ reacted with unreacted ammonia at SNCR. SEM and EDS images showed that fine ashes on large fly ash surface of sphere type were agglomerated, due to adhesive role of ammonium salts attached fly ashes. Dissolution test results of ammonium salts absorbed on AAFA in distilled water or sea water showed that the proportion of un-ionized $NH_3$ to $NH_4{^+}$ were primarily a function of pH and temperature. Increasing pH and temperature causes an increase in the fraction of un-ionized $NH_3$. At pHs of 9.6 and 10.7, un-ionized $NH_3$ and $NH_4{^+}$ ions are present in equal amounts at distilled water and sea water, respectively.

Efficacy of supplementary cementitious material and hybrid fiber to develop the ultra high performance hybrid fiber reinforced concrete

  • Sharma, Raju;Bansal, Prem Pal
    • Advances in concrete construction
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    • v.8 no.1
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    • pp.21-31
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    • 2019
  • The rich recipe of ultra high performance concrete (UHPC) offers the higher mechanical, durability and dense microstructure property. The variable like cement/sand ratio, amount of supplementary cementitious material, water/binder ratio, amount of fiber etc. alters the UHPC hardened properties to any extent. Therefore, to understand the effects of these variables on the performance of UHPC, inevitably a stage-wise development is required. In the present experimental study, the effect of sand/cement ratio, the addition of finer material (fly ash and quartz powder) and, hybrid fiber on the fresh, compressive and microstructural property of UHPC is evaluated. The experiment is conducted in three phases; the first phase evaluates the flow value and strength attainment of ingredients, the second phase evaluates the efficiency of finer materials (fly ash and quartz powder) to develop the UHPC and the third phase evaluate the effect of hybrid fiber on the flow value and strength of ultra high performance hybrid fiber reinforced concrete (UHP-HFRC). It has been seen that the addition of fly ash improves the flow value and compressive strength of UHPC as compared to quartz powder. Further, the usage of hybrid fiber in fly ash contained matrix decreases the flow value and improves the strength of the UHP-HFRC matrix. The dense interface between matrix and fiber and, a higher amount of calcium silicate hydrate (CSH) in fly ash contained UHP-HFRC is revealed by SEM and XRD respectively. The dense interface (bond between the fiber and the UHPC matrix) and the higher CSH formation are the reason for the improvement in the compressive strength of fly ash based UHP-HFRC. The differential thermal analysis (DTA/TGA) shows the similar type of mass loss pattern, however, the amount of mass loss differs in fly ash and quartz powder contained UHP-HFRC.

Impacts of Saudi Arabian fly ash on the structural, physical, and radiation shielding properties of clay bricks rich vermiculite mineral

  • Aljawhara H. Almuqrin;Abd Allh M. Abd El-Hamid;M.I. Sayyed;K.A. Mahmoud
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.2324-2331
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    • 2024
  • The current study investigated Saudi Arabian oil fly ash impacts on Egyptian clay bricks' structural and radiation shielding properties. To produce the required bricks, crushed clay minerals from the Hafafit area were mixed with 0, 10, 20, 30, and 40 % wt.% Saudi Arabian oil fly ash and pressed at a pressure rate of 68.55 MPa. Identification of the minerals in the chosen clay was achieved via X-ray diffraction. Additionally, the material's morphology and chemical composition were determined through scanning electron microscope and energy-dispersive X-ray. The fabricated bricks' density was reduced by 36.3 % through increasing the concentration of fly ash from 0 to 40 wt%. Then, the fly ash addition's influence on the fabricated clay bricks' γ-ray shielding properties was investigated by Monte Carlo simulation, which found a reduction in the fabricated bricks' linear attenuation coefficient (LAC) by 41.2, 36.0, 33.8, and 33.8 % at the 0.059, 0.103, 0.662, and 1.252 MeV γ-ray energies, respectively. The LAC reduction caused an increase in the fabricated bricks' half-value thickness, transmission factor, and the equivalent thickness of the lead. Moreover, the thicker fabricated sample thicknesses were found to have high γ-ray shielding capacity and can thus be used in radiation shielding applications.