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Hydration Characteristics of Coal-Fly Ash Containing High CaO Compound (CaO 화합물이 다량 함유된 비산재의 수화 특성에 관한 연구)

  • Sim, Jun-Soo;Lee, Ki-Gang;Kim, Yu-Taek;Kang, Seung-Ku
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.185-190
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    • 2012
  • The purpose of this study was to examine a possibility that fly ash could be used as raw material for carbonation by conducting the experiment on magnetic separation and hydration of fly ash that contained a large amount of CaO composite. Wet magnetic separation experiment was performed to remove the component of magnetic substance that contained fly ash, which aimed at increasing the content of CaO in the non-magnetic domain. The selected fly ash was used for hydration experiment before the TG-DTA, XRF and XRD analyses were made to confirm the Ca component that could be carbonated. Then, the fly ash was turned to a hydrate that was favorable to dissociation of $Ca^{2+}$ ion. As a result, the magnetic separation enabled detecting the content of CaO component by up to 61 wt% in the non-magnetic domain. Since the hydrate was confirmed, it is believed that the fly ash can be used as raw material for carbonation.

Bond behavior between high volume fly ash concrete and steel rebars

  • Liang, Jiong-Feng;Hu, Ming-Hua;Gu, Lian-Sheng;Xue, Kai-Xi
    • Computers and Concrete
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    • v.19 no.6
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    • pp.625-630
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    • 2017
  • In this paper, 54 pull-out specimens and 36 cubic specimens with different replacement ratios of fly ash in the concrete (i.e., 0%, 20%, 30%, 40%, 50%, 60%) were fabricated to evaluate the bond at the interface between fly ash concrete and steel rebar. The results showed that the general shape of the bond-slip curve between fly ash concrete and steel rebar was similar to that for the normal concrete and steel rebar. The bond strength between fly ash concrete and the steel rebar was closer to each other at the same rebar diameter, irrespective of the fly ash replacement percentage. On the basis of a regression analysis of the experimental data, a revised bond strength mode and bond-slip relationship model were proposed to predict the bond-slip behaviour of high volume fly ash concrete and steel rebar.

An Experimental Study on the Setting of Antiwashout Underwater concrete Using Fly Ash (플라이애쉬를 사용한 수중불분리성 콘크리트의 응결에 관한 실험적 연구)

  • 권중현;김봉익
    • Journal of Ocean Engineering and Technology
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    • v.15 no.4
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    • pp.120-125
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    • 2001
  • This paper describes the effect of fly ash replacement on the setting time of antiwashout underwater concrete, where cement was replaced by 0% to 50%. Experimental work was performed on the condition of sea water and in air to find out the characteristics of setting time between the concretes that were cast in air and cast in 15$^{\circ}C$ of sea water. The experimental results show that the setting time of underwater concrete with 50% replacement was delayed about 10 hours than normal concrete. And it can be concluded that, at the case of underseawater concrete addicted with fly ash, the delayed final setting times are shown as the function Tf=0.069F+7.69, where Tf is the delayed final setting time and F is quantity of fly ash, respectively. These results confirm that the setting time underseawater concrete could be prolonged.

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A Study on the Quality of the Domestic Fly Ash as an Additive for Concrete (콘크리트용 혼화재(混和材)로서 국산 플라이애쉬의 품질에 관한 실험적 연구)

  • Moon, Han Young;Seo, Joung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.213-221
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    • 1987
  • To use fly ash as an additive for concrete, authors collected 15 kinds of domestic fly ashes and tested the chemical compositions and physical properties of the fly ashes. Fluidity of the fly ash paste was also investigated. The result shows that the chemical compositions of the fly ashes were in the range of regulation of Korean Industrial Standards except ignition loss and the following relationships in fly ash were studied; specific surface and residue in standard sieve, specific surface and unit weight, residue in standard sieve and ignition loss. For the given flow properties, fly ash paste required higher water-binder ratio than cement paste.

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Effect of Industrial Wastes as a Bulking Agent on the Composting of Swine Manure (산업폐기물의 수분조절재 대체가 양돈분뇨의 퇴비화에 미치는 영향)

  • 김두환
    • Journal of Animal Environmental Science
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    • v.3 no.1
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    • pp.19-26
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    • 1997
  • Composting has recently become popular as a means of recycling swine manure into products for sale off the farm, but bulking agent(usually sawdust) are expensive and availability is limited. This experiment was conducted to investigate the effect of fly ash as a bulking agent on the composting of swine manure and to analyze the effective substitution rate of fly ash mixed with swine manure for sawdust. Fly ash was able to be substituted for sawdust and the most effective substitution rate are 50% of sawdust. According to the results the advanced research and development are required, the effect of swine manure with fly ash on the soil properties, forage composition and animal performance.

Utilization of Fly ash as a Source of Mineral Fertilizers II. Potassium availability for soybean (Fly ash 비료화(肥料化) 연구(硏究) II. 대두(大豆)에 대한 Fly ash의 가리효과(加里效果))

  • Shin, Jae-Sung;Lim, Dong-Kyu;Seong, Ki-Seog
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.3
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    • pp.204-207
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    • 1990
  • This study was conducted to evaluate the potassium availability of soybean grown on potted soil amended with 20% by weight of fly ash for two years of which the second year was done on its residual effect. Soybean growth was normal with incorporation of 20% fly ash. The increase in yield was accompanied by an increase in the potassium contents of plant and soil.

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Reaction Characteristics of Elemental and Oxidized Mercury with Fly Ash Components (비산재 성분과 원소 및 산화수은의 반응특성)

  • Lee, Sang-Sup;Kim, Kwang-Yul;Oh, Kwang-Joong;Jeon, Jun-Min;Kang, Dong-Chang
    • Clean Technology
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    • v.19 no.4
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    • pp.453-458
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    • 2013
  • Fly ash has capacity to oxidize or adsorb mercury in a flue gas. Mercury oxidation and adsorption efficiencies of fly ash vary depending on the properties of fly ash. This study was designed to understand reaction characteristics of mercury with fly ash components. The fly ash components were tested to determine their oxidation and adsorption capabilities for elemental mercury and oxidized mercury. A sample was synthesized with fly ash components and tested. The test results were compared with those of the fly ash sample obtained from a coal-fired power plant. $Fe_2O_3$, CuO and carbon black showed higher oxidation or adsorption efficiency for elemental mercury while CaO, MgO, CuO and carbon black showed higher adsorption efficiency for mercury chloride. In addition, the synthesized sample showed comparable mercury oxidation and adsorption efficiencies to the fly ash sample.

The non-shrinkage grout to use ground fly ash as admixture

  • Kim, Yoo;Chu, Yong-Sik;Seo, Sung-Kwan;Kim, Jang-ho Jay
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.509-513
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    • 2018
  • This study uses fly ash for non-shrinkage grout in order to develop strength of grout and improve its durability. We grind fly ash to the extent of $7,000cm^2/g$ and use ground fly ash and raw fly ash respectively at the proportion of 10%, 20%, 30% instead of OPC and compare the results drawn on the condition of each proportion. As a mixed material of grout, EVA and water-reducing agent is added in order to prevent bleeding and improve segregation resistance, CSA is added with a view to preventing drying shrinkage and improving early strength property. In regard to flow and flow time test for analyzing and evaluating workability, it is revealed that grouts of all mix proportions except raw fly ash 30% mix proportion satisfy all performance criteria. With regard to length change rate, grout with no admixture shows the highest shrinkage rate, but the rate is 0.0005%, extremely insignificant rate. As material age increases, compressive strength of two grouts, that is to say ground fly ash 10% and 20%-used grouts, exceed that of grout with no admixture or show high-level compressive strength.

An Experimental Study on The Development of fly-ash Cement Mortal Permanent (플라이애쉬 시멘트 모르터를 사용한 비탈형 영구거푸집 개발에 관한 실험적연구)

  • 김형남;김우재;김성식;김영희;정상진
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.481-486
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    • 1999
  • According to results of this research Fly-ash Cement permanent-form production was found to be possible by fly-ash mortal. The compress strength 350kg/$\textrm{cm}^2$, banding strength 120kg/$\textrm{cm}^2$ were possible material separting and bleeding by excessive W/C rate was decreased permanent-form made by polymer solved high price of polymer by fly-ash. Model material was made by result of first research. There were no minute-crack on beam form and out surface of form was very smooth, So filling degree seemed desirable length of form after steaming curing was maintained as expected. with these results production of form seemed possible. In the banding load test, fly-ash showed increase of maxim load 12% than RC. in the case of minute-crack, comparing with RC, fly-ash showed no crack at connect. at the first stage under continuing loading size of crack increased. These phenomena seemed to be based on contribution of stress of inner bars in permanent-form. in the test of defection, fly-ash shower about 10% beam load increase than RC. in the case of beam defection, RC showed sudden decrease of tolerance at maxim load and total breaking, but permanent-form showed breaking of bending maintaining defection with contribution of steel stress ($\Phi$6 wire-mash). There phenomenic seemed to be attributed to increase of surface and steel tolerance of form. According to construction explacemaion, it was guessed that each panel was constructed by conner-steels in form edge. so cohesiveness was small. on these bases. keeping width of horizontal band 30cm, form-panel of 20mm width was found to be of use. Permanent-form was found to be efficient in compressibleness, defection, safety and use of Fly-ash mortal.

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Capacitance Characteristics of Fly Ash for Monitoring the Unburned Carbon Contained in Fly Ash (석탄회 미연탄소함량 동시측정을 위한 석탄회 정전용량 분석에 관한 연구)

  • 이재근;김장우;구재현;신진혁;김성찬;신희수;황유진
    • Journal of Energy Engineering
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    • v.11 no.1
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    • pp.67-73
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    • 2002
  • The carbon-in-ash system for simultaneously monitoring the unburned carbon in fly ash produced in a coal-fired power plan is designed and evaluated using the domestic fly ash produced in the coal-fired power plant. Real time monitoring is very important to control the combustion of the boiler in the coal-fired power plant and the purification system for fly ash recycling. The carbon-in-ash system based on the capacitance measurement consists of a LCR meter, a duct collector and an electrode cell. The capacitance of fly ash increases linearly with increasing fly ash carbon contents. The water content in fly ash plays an important role on the ash capacitance. The empirical equation for predicting the content of unburned carbon in fly ash produced in the domestic Boryung, Hadong and Samchenpo coal-fired power plants can be derived in the range of carbon content 0-20%.