• Title/Summary/Keyword: On bipolar cell

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Numerical analysis of the shape effect on PEMFC's Performace (연료전지 성능에 영향을 미치는 채널형상에 대한 연구)

  • Kim, K.J.;Jeon, Yu-Taek;Kim, Hyo-Gyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.59-62
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    • 2006
  • Formability is requested to successfully develop of a metal bipolar plate for mass production. From this point of view, wider channel and land width is more helpful to improve formability. But the performance of the fuel cell can be affected by its channel and land shape. So it is very important to select proper channel and land shape not to deteriorate the fuel cell performance. In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of channel and land width on the fuel cell performance. 3 types of straight channel were selected for the numerical simulation. The simulation results reveal that wide channel and land width lower fuel cell performance and decrease voltage at a high current density region. Water activity, temperature, oxygen concentration distributions were investigated to find the reasons of performance degradation. The results show that wide channel and land width give an bad effect on fuel cell performance because of low cool ins efficiency and lack of oxygen gas under the land.

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Effect of SUS316L Bipolar Plate Corrosion on Contact Resistance and PEMFC Performance (SUS316L 분리판 부식에 의한 접촉저항 및 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.664-670
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    • 2021
  • Stainless steel was applied as bipolar plate (BP) of polymer electrolyte membrane fuel cell (PEMFC) due to high mechanical strength, electrical conductivity, and good machinability. However, stainless steel was corroded and increased contact resistance resulting PEMFC performance decrease. Although the corrosion resistance could be improved by surface treatment such as noble metal coating, there is a disadvantage of cost increase. The stainless steel corrosion behavior and passive layer influence on PEMFC performance should be studied to improve durability and economics of metal bipolar plate. In this study, SUS316L bipolar plate of 25 cm2 active area was manufactured, and experiments were conducted for corrosion behavior at an anode and cathode. The influence of SUS316L BP corrosion on fuel cell performance was measured using the polarization curve, impedance, and contact resistance. The metal ion concentration in drained water was analyzed during fuel cell operation with SUS316L BP. It was confirmed that the corrosion occurs more severely at the anode than at the cathode for SUS316L BP. The contact resistance was increased due to the passivation of SUS316L during fuel cell operation, and metal ions continuously dissolved even after the passive layer formation.

Development of Thermoplastic Carbon Composite Hybrid Bipolar Plate for Vanadium Redox Flow Batteries (VRFB) (바나듐 레독스 흐름전지용 열가소성 탄소 복합재료 하이브리드 분리판 개발)

  • Jun Woo Lim
    • Composites Research
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    • v.36 no.6
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    • pp.422-428
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    • 2023
  • The electrical contact resistance between the bipolar plate (BP) and the carbon felt electrode (CFE), which are in contact by the stack clamping pressure, has a great impact on the stack efficiency because of the relatively low clamping pressure of the vanadium redox flow battery (VRFB) stack. In this study, a polyethylene (PE) composite-CFE hybrid bipolar plate structure is developed through a local heat welding process to reduce such contact resistance and improve cell performance. The PE matrix of the carbon fiber composite BP is locally melted to create a direct contact structure between the carbon fibers of CFE and the carbon fibers of BP, thereby reducing the electrical contact resistance. Area specific resistance (ASR) and gas permeability are measured to evaluate the performance of the PE composite-CFE hybrid bipolar plate. In addition, an acid aging test is performed to measure stack reliability. Finally, a VFRB unit cell charge/discharge test is performed to compare and analyze the performance of the developed PE composite-CFE hybrid BP and the conventional BP.

Numerical Study on Flow Distribution in PEMFC with Metal foam Bipolar Plate (다공성 분리판을 적용한 고분자 전해질 연료전지의 유동 분포에 관한 전산해석 연구)

  • SONG, MYEONGHO;KIM, KYOUNGYOUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.1
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    • pp.29-35
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    • 2016
  • It is important to uniformly supply the fuel gas into the reaction activity area in polymer electrolyte membrane fuel cell (PEMFC). Recent studies have shown that the cell performance can be significantly improved by employing metal foam gas distributor as compared with the conventional bipolar plate types. The metal foam gas distributor has been reported to be more efficient to fuel transport. In this study, three-dimensional computational fluid dynamics (CFD) simulations have been performed to examine the effects of metal foam flow field design on the fuel supply to the reaction site. Darcy's law is used for the flow in the porous media. By solving additional advection equation for fluid particle trajectory, the gas transport has been visualized and examined for various geometrical configuration of metal foam gas distributor.

Thermal and Flow Analysis in a Proton Exchange Membrane Fuel Cell

  • Jung, Hye-Mi;Koo, Ja-Ye
    • Journal of Mechanical Science and Technology
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    • v.17 no.9
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    • pp.1358-1370
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    • 2003
  • The effects of anode, cathode, and cooling channels for a Proton Exchange Membrane Fuel Cell (PEMFC) on flow fields have been investigated numerically. Continuous open-faced fluid flow channels formed in the surface of the bipolar plates traverse the central area of the plate surface in a plurality of passes such as a serpentine manner. The pressure distributions and velocity profiles of the hydrogen, air and water channels on bipolar plates of the PEMFC are analyzed using a two-dimensional simulation. The conservation equations of mass, momentum, and energy in the three-dimensional flow solver are modified to include electro-chemical characteristics of the fuel cell. In our three-dimensional numerical simulations, the operation of electro-chemical in Membrane Electrolyte Assembly (MEA) is assumed to be steady-state, involving multi-species. Supplied gases are consumed by chemical reaction. The distributions of oxygen and hydrogen concentration with constant humidity are calculated. The concentration of hydrogen is the highest at the center region of the active area, while the concentration of oxygen is the highest at the inlet region. The flow and thermal profiles are evaluated to determine the flow patterns of gas supplied and cooling plates for an optimal fuel cell stack design.

Effect of FTO coated on stainless steel bipolar plate for PEM fuel cells

  • Park, Ji-Hun;Jang, Won-Yeong;Byeon, Dong-Jin;Lee, Jung-Gi
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.55.2-55.2
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    • 2009
  • A polymer electrolyte membrane (PEM) fuel cell has been getting large interest as a typical issue in useful applications. The PEMFC is composed of a membrane, catalyst and the bipolar plate. SnOx:F films on SUS316 stainless steel were prepared as a function of substrate with using electron cyclotron resonance-metal organic chemical vapor deposition (ECR-MOCVD) in order to achieve the corrosion-resistant and low contact resistance bipolar plates for PEM fuel cells. The SnOx:F films coated on SUS316 substrate at surface plasma treatment for excellent stability, before/after heat treatment for good crystalline structure and microwave power for were characterized by X-ray diffraction (XRD), auger electron microscopy (AES) and field emission-scanning electron microscopy (FE-SEM). The SnOx:F film coated on SUS316 substrate with various process parameters were able to observe optimum interfacial contact resistance (ICR) and corrosion resistance. It can be concluded that fluorine-doping content plays an important function in electrical property and characteristic of corrosion-protective film.

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A study on the channel design of bipolar plate of electrolytic cell of hydrogen gas generation system by flow dynamic simulation (수소가스발생 장치의 전해조 분라판의 유로설계에 관한 전산모사 연구)

  • Jo, Hyeon-Hak;Jang, Bong-Jae;Song, Ju-Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.152-156
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    • 2010
  • This study is focused on the channel design of bipolar plate in the electrode of hydrogen gas generator. The characteristics of hydrogen gas generation was studied in view of efficiency of hydrogen gas generation rate and a tendency of gas flow through the riv design of electrode. Since the flow rate of generated gas is the most crucial in determining the efficiency of hydrogen gas generator, we adopted the commercial analytical program of COMSOL $Multiphysics^{TM}$ to calculate the theoretical flow rate of hydrogen gas from the outlet of gas generator.

The Effect of Contact Resistance and Electric Conductivity on PEMFC Performance (접촉저항 및 전기전도도가 연료전지 성능에 미치는 영향)

  • Kim, Ki-Jung;Yun, Yong-Sik;Jeon, Yu-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.133-136
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    • 2007
  • In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of contact resistance and electric conductivity of GDL on the fuel cell performance. For numerical simulation contact resistance of Carbon and Stainless steel was measured. The simulation results reveal that 10 times change of electric conductivity leads only 6.5% decrease of PEMFC performance. But stainless steel which has high contact resistance decrease fuel cell performance over 25% at a high current density region than carbon. This results show that suitable Surface treatment technology is needed for metal bipolar plate, especially stainless steel.

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A study on the channel design of bipolar plate of electrolytic cell by flow dynamic simulation in the two phase flow system (2상 흐름계에서 유로설계에 따른 전해조 분리판의 전산모사 연구)

  • Jo, Hyeon-Hak;Jang, Bong-Jae;Song, Ju-Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.415-420
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    • 2010
  • This study is focused on the channel design of bipolar plate in the electrode of hydrogen gas generator. The characteristics of hydrogen gas generation was studied in view of efficiency of hydrogen gas generation rate and a tendency of gas flow through the riv design of electrode. Since the flow rate and flow pattern of generated gas in the two phase flow system are the most crucial in determining the efficiency of hydrogen gas generator, we adopted the commercial analytical program of COMSOL MultiphysicsTM to calculate the theoretical flow rate of hydrogen gas from the outlet of gas generator and flow pattern of two phase fluid in the electrode. In this study, liquid electrolyte flows into the bipolar plate and decomposed into gas phase, two phase flow simulation is applied to measure the efficiency of hydrogen gas generation.

Numerical Study on the Thermal and Flow Characteristics of Manifold Feed-Stream in Polymer Electrolyte Fuel Cells (고분자 전해질 연료전지 매니폴드의 열유동 특성에 관한 수치적 연구)

  • Jung Hye-Mi;Um Sukkee;Sohn Young-Jun;Park Jungsun;Lee Won-Yong;Kim Chang-Soo
    • New & Renewable Energy
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    • v.1 no.2 s.2
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    • pp.41-52
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    • 2005
  • The effects of internal manifold designs on the reactants feed-stream in Polymer Electrolyte Fuel Cells [PEFCs] is studied to figure out flow and thermal distribution patterns over an entire fuel cell stack. Reactants flows are modeled either laminar of turbulent depending on regions and the open channels in the bipolar plates are simulated by porous media where permeability should be pre-deter-mined for computational analysis. In this work, numerical models for reactants feed-stream In the PEFC manifolds are classified Into two major flow patterns: Z-shape and U-shape. Several types of manifold geometries are analyzed to find the optimal manifold configurations. The effect of heat generation in PEFC on the flow distribution is also Investigated applying a simplified heat transfer model in the stack level (i.e. multi-cell electrochemical power-generation unit). This modeling technique Is well suited for many large scale problems and this scheme can be used not only to account for the manifold flow pattern but also to obtain Information on the optimal design and operation of PEFC systems.

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