• Journal of the Korea Convergence Society
• /
• v.11 no.4
• /
• pp.11-16
• /
• 2020

As a plan for oil spill accidents, research to collect and analyze optimal equipment assignments is essential. However, studies that have diversified and analyzed the optimal equipment assignments for responding to oil spill accidents have not been preceded. In response to the need for analyzing optimal equipment assignments study, we devised a genetic algorithm for optimal equipment assignments. The designed genetic algorithm yielded 10,000 optimal equipment assignments. We clustered using the k-means algorithm. As a result, the two clusters of Yeosu, Daesan, and Ulsan, which are expected to be the largest spills, were clearly identified. We also projected 16-dimensional data in two dimensions via Sammon's mapping. The projected data were analyzed for distribution. We confirmed that results of the simulation were better than those of optimal equipment assignments included in the cluster.In the future, it will be possible to implement an approximate model with excellent performance based on this study.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.15 no.3
• /
• pp.213-216
• /
• 2009

Since adopting 1969 CLC and 1971 FC, IMO increased maximum amount of compensation by adopting protocols of 1969 CLC and 1971 FC. Recently IMO adopted 2003 Supplementary Fund by which the compensation limits increased dramatically to 750 million SDR. Korea government has only entered 1992CLC/FC. However, since the Hebei Spirit incident in 2007, there have been strong claims that Korea government should enter 2003 Supplementary Fund. In this article, feasibility study was carried out to help Korea government decide whether or not entering the Convention. The quantitative analysis has been carried out using data of the past oil spill accidents and contribution fee to IOPC Fund and showed that the benefit was much bigger than costs. The qualitative analysis in relation to resources fix compensation to victims, benefits of consignee, and the status of Korea in IMO also showed that Korea should ratify the 2003 SF.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.18 no.1
• /
• pp.33-39
• /
• 2012

Official Development Assistance(ODA) Project is initiated to assist a developing country economically and to promote its welfare. Support on training and information system development are the primary elements in the maritime safety field. The maritime safety information system(MSIS) of ODA projects deals with maritime safety information of developing nations and ensures an inter-operability between other systems. Therefore, it is required to develop MSIS based on the Universal Hydrographic Data Model(UHDM) of International Hydrographic Organization(IHO). In this paper, we have analyzed the current status and operational process of UHDM established by IHO. Oil spill response system was selected as an example of MSIS project and, also, considered the application results to the maritime safety field of UHDM.

• Journal of Applied Biological Chemistry
• /
• v.62 no.1
• /
• pp.73-79
• /
• 2019

A novel esterase gene (est7S) was cloned from an enriched metagenomic library derived from an oil-spill area. The gene encoded a protein of 505 amino acids, and the molecular mass of the Est7S was estimated to be 54,512 Da with no signal peptide. Est7S showed the highest identity of 40% to an esterase from a sludge metagenome compared to the characterized enzymes with their properties, although it showed 99% identity to a carboxylesterase in the genome sequence of Alcanivorax borkumensis SK2. Est7S had catalytic triad residues, Ser183, Glu312, and His420, and the GESAG motif in most family VII lipolytic enzymes. Est7S was purified from the crude extract of clone SM7 using Sephacryl S-200 HR and HiTrap Q column chromatographies. The purified Est7S was optimally active at $50^{\circ}C$ and pH 10.0. Est7S showed a high specific activity of 366.7 U/mg protein. It preferred short length esters, particularly p-nitrophenyl acetate, efficiently hydrolyzed R- and S-enantiomers of methyl-3-hydroxy-2-methylpropionate, and glyceryl tributyrate. These properties of Est7S may provide potential merits in biotechnological applications such as detergent and paper processing under alkaline conditions.

• Proceedings of KOSOMES biannual meeting
• /
• 2006.11a
• /
• pp.169-174
• /
• 2006

A distinctive difference of hydrocarbon in crude oil and petroleum products exists. Depending on the origin where it comes from, crude oil shows its own unique pattern which is different from petroleum products containing characteristics according to their operating process and production period. A process of mixing behavior in a tank containing residual amounts of oil draws its own pattern when analysis is conducted. The analytical process described above is named oil fingerprint method. This study investigates an effectiveness of the method for comparing data sets produced by conventional gas chromatography with mass spectrometer (GC/MS) and comprehensive two-dimensional gas chromatography (GC X GC) which is known as powerful new technology for chemical analysis.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.11 no.2 s.23
• /
• pp.41-49
• /
• 2005

In general, the criminal responsibility of seaman should always be directly assumed by the seamen, according to the principle of self-incrimination. Therefore, the only possible countermeasures for the criminal responsibility of seamen may be to reduce the responsibility by using criminal procedures (ex. the warrant substance examination system, the review system of legality for confinement as much as possible. Another possibility is to reduce the penalty through the revision of the law. In detail, concerning the problem of fine, the maximum fine for oil spill accidents by criminal negligence is KRW 30,000,000 under the current Ocean Pollution Prevention Act, and when an oil spill occurs, the maximum fine tends to be levied regardless of the amount of the spilled oil; thus, it is judged that grading the fine according to the amount of spilled oil may be worth considering. Regarding P & I's payment of fine, contrary to general belief, it is only possible to make up the loss when P & I takes up the legal responsibility or acknowledges its payment. In order to solve the problem, it is possible to consider the option of introducing new collective insurance program or mutual aid system. Also, as seamen are not specialists in legal issues, the ship owners' association or the marine afficers' association need to develop some program through which they can receive systematic assistance from legal specialists including lawyers when they encounter any legal problems (ex. free legal aid programs for farmers and fishermen). Finally, it may be possible to establish enact new laws or revise the existing Act on Special cases Concerning the Settlement of Traffic Accidents to insert a new section on marine accidents.

• Applied Chemistry for Engineering
• /
• v.28 no.1
• /
• pp.1-7
• /
• 2017

Polydimethylsiloxane (PDMS) can be deposited on various substrates using chemical vapor deposition process, which results in the formation of PDMS thin films with thickness below 5 nm. PDMS layers can be evenly deposited on surfaces of nanoparticles composed of various chemical compositions such as $SiO_2$, $TiO_2$, ZnO, C, Ni, and NiO, and the PDMS-coated surface becomes completely hydrophobic. These hydrophobic layers are highly resistant towards degradation under acidic and basic environments and UV-exposures. Nanoparticles coated with PDMS can be used in various environmental applications: hydrophobic silica nanoparticles can selectively interact with oil from oil/water mixture, suppressing fast diffusion of spill-oil on water and allowing more facile physical separation of spill-oil from the water. Upon heat-treatments of PDMS-coated $TiO_2$ under vacuum conditions, $TiO_2$ surface becomes completely hydrophilic, accompanying formation oxygen vacancies responsible for visible-light absorption. The post-annealed $PDMS-TiO_2$ shows enhanced photocatalytic activity with respect to the bare $TiO_2$ for decomposition of organic dyes in water under visible light illumination. We show that the simple PDMS-coating process presented here can be useful in a variety of field of environmental science and technology.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.4
• /
• pp.679-688
• /
• 2000

Dispersants, which are used to break water-in-oil emulsions and to remediate oil-spills, are another water pollutants. In this study, magnetic separation technology was applied to remove dispersants from the sea. Magnetite and maghemite were used as magnetic sorbents and SDDBS, an anionic surfactant and Triton X-100, a nonionic surfactant, were employed as dispersants. Batch experiments were undertaken to study the sorption capacity and sorption equilibrium, and water-bath experiments were conducted to simulate the real situation and to describe the recovery of magnetic particles by the permanent magnet or electromagnet. Maghemite has rather constant removal efficiency for dispersants, regardless of surfactant species. On the other hand, removal efficiency by magnetite is higher for anionic surfactant than maghemite and is higher in distilled water than in seawater which contains more ions. The sorption of dispersants to magnetite is explained by electrostatic attraction and that of maghemite is described not only by electrostatic attraction, but also by structural characteristics that provide high sorption ability and surface condition. Water bath experimental results showed that recovery efficiency of magnetic particle after sorption for dispersants is nearly 100%. It is suggested that this magnetic separation technology is an effective way of dispersant removal because of short operating time, high sorption capacity, and high recovery efficiency of sorbents.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.23 no.6
• /
• pp.603-612
• /
• 2017

Accidents associated with hazardous materials, including oil and HNS, in maritime transportation show increasing trend. Therefore, preventive countermeasures for such accidents should be provided. The purpose of this study is to analyze level of risk on human loss and potential damage to environment, using data on domestic marine accidents carrying hazardous materials (2002~2014), and identify high-risk accident types for urgent risk management which needs findings of accident causes and proper mitigation measures. High-risks on human loss are explosion and suffocation, occurred in process of ship maintenance and tank cleaning. On the other hand, high-risk on environmental damage is spill caused by ship accidents (collision, grounding and etc.). Especially, spill occurs during loading operation of oil and HNS onboard a ship. Strict operation supervision/management and safety education/training on a regular basis could prevent accidents, because human factors such as not wearing safety gear and careless cargo handling cause most of the marine accidents.

• Proceedings of KOSOMES biannual meeting
• /
• 2006.11a
• /
• pp.175-179
• /
• 2006

With the rapid development of oil and chemical industry in the late 20C, massive transportation of oil by oil tanker vessel has grown and it caused the big oil pollution accidents. When oil spill from the oil tanker, damages reach into the astronomical figures in economically and damages affect wide area and many people with break the balance of ecosystem. Recently in Korea, the oil pollution accidents has occurred frequently as growing of oil consumption and it caused large-scale damages to the victim. Oil pollution in Korean offshore takes not only korean fishermen from their life ground and break the ecosystem but it takes too much time and money to recover. To minimize oil pollution damages, it is necessary to make pre-caution effort as a ship owner and relevant government bodies should endeavor to prevent from more damages. But once oil pollution accidents occurs in territorial sea, compensation for victim fishermen is very important. But it is true that compensation is not paid to victim smoothly. So this study aims at the problems of oil pollution compensation to the Korean victim and find the best way to get reasonable compensation.