• Title/Summary/Keyword: Oil separation

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Study on Materials and Process Systems for $CO_2$ separation from Combustion of Fossil Fuels (배기가스에서 이산화탄소 분리를 위한 재료 및 공정에 대한 이론적 고찰)

  • Han, Sang-Il;Hwang, Kyu-Suk
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.375-386
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    • 2014
  • Carbon dioxide ($CO_2$) is a green-house gas which causes the global warming problems. Anthropogenic emissionspredominantly from the combustion of coal, oil, and natural gas in electricity generations are expected to increase continuously in the future, resulting in increased $CO_2$ concentration in the atmosphere. In this study, we investigated materials properties and process systems for $CO_2$ separation with an emphasis of the post-combustion process.

Study on the Application of Cleaner Production using Life Cycle Assessment in the Can Industry (캔 산업의 전과정평가를 통한 청정생산 적용에 관한 연구)

  • Koo, H.J.;Chung, C.K.
    • Clean Technology
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    • v.8 no.4
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    • pp.205-215
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    • 2002
  • Can industry has grown up with growth of packing industry and its recycling activation in recent years. But profit has became low by oversupply. Therefore, can industry needs a reduction of environmental load and official loss by an optimization of process in order to maintain its competitiveness. In this study, the main issues of aluminium can production was investigated by life cycle assessment. As a result of LCA, it examined closely by main issues that reduce defective cans and remove tramp oil. In the present work, it was recommended that setup of R/O system, sterillizing tramp oil separation, and heating system of DI water. The ROI investigated 6.4 months. The operating cost with the advanced processes could be reduced annually by 300 million won.

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The Effects of Operation Variables of Supercritical Fluid on the Distribution Coefficients of Fatty Acid Esters (초임계유체의 작동변수가 지방산 에스터의 분배계수에 미치는 영향)

  • Heo, Byeong-Gi;No, Deok-U;U, Dong-Jin
    • KSBB Journal
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    • v.14 no.5
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    • pp.633-637
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    • 1999
  • Supercritical fluid of carbon dioxide was used to investigate the effects of its temperature and density on the distribuion coefficients of fatty-acid esters composing fish oil. The distribution coefficient of fatty acid ester was greatly different from each other according to the temperature and density of the supercritical fluid. The possibility of separation of a certain fatty acid from the mixture of fatty acids was tested. The density of the supercritical fluid showing the great differences ofthe distribution coefficients among the fatty acid esters ranged from 0.3 g/mL to 0.4 g/mL. The retrograde condensation took place at high densities of the supercritical fluid.

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An experimental study on the characteristics of transverse jet into a supersonic flow field (초음속 유동장에서의 충돌제트 특성에 대한 실험적 연구)

  • 박종호;김경련;신필권;박순종;길경섭
    • Journal of the Korea Institute of Military Science and Technology
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    • v.6 no.4
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    • pp.124-131
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    • 2003
  • When a secondary gaseous flow is injected vertically into a supersonic flow through circular nozzle, a complicated structure of flow field is produced around the injection area. The interaction between the two streams produces a strong bow shock wane on the upstream side of the side-jet. The results show that bow shock wave and turbulent boundary layer interaction induces the boundary layer separation in front of the side-jet. This study is to analyze the structure of flow fields and distribution of surface pressure on the flat plate according to total pressure ratio using a supersonic cold-flow system and also to study the control force of affected side-jet. The nozzle of main flow was designed to have Mach 2.88 at the exit. The injector has a sonic nozzle with 4mm diameter at the exit of the side-jet. In experiments, The oil flow visualization using a silicone oil and ink was conducted in order to analyze the structure of flow fields around the side-jet. The flow fields are visualized using the schlieren method. In this study, a computational fluid dynamic solution is also compared with experimental results.

Functionalized magnetite / silica nanocomposite for oily wastewater treatment

  • Hakimabadi, Seyfollah Gilak;Ahmadpour, Ali;Mosavian, Mohammad T. Hamed;Bastami, Tahereh Rohani
    • Advances in environmental research
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    • v.4 no.2
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    • pp.69-81
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    • 2015
  • A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.

Photodegradation stability study of PVDF- and PEI-based membranes for oily wastewater treatment process

  • Ong, C.S.;Lau, W.J.;Al-anzi, B.;Ismail, A.F.
    • Membrane and Water Treatment
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    • v.8 no.3
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    • pp.211-223
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    • 2017
  • In this work, an attempt was made to compare the effects of UV irradiation on the intrinsic and separation properties of membranes made of two different polymeric materials, i.e., polyvinylidene fluoride (PVDF) and polyetherimide (PEI). The changes on membrane structural morphologies and chemical characteristics upon UV-A exposure (up to 60 h) were studied by FESEM and FTIR, respectively. It was found that cracks and fractures were detected on the PVDF-based membrane surface when the membrane was exposed directly to UV light for up to 60 h. Furthermore, the mechanical strength and thermal stability of irradiated PVDF-based membrane was reported to decrease with increasing UV exposure time. The PEI membrane surface meanwhile remained almost intact throughout the entire UV irradiation process. Filtration experiments showed that the permeate flux of UV-irradiated PVDF membrane was significantly increased from approximately 11 to $16L/m^2.h$ with increasing UV exposure time from zero to 60 h. Oil rejection meanwhile was decreased from 98 to 85%. For the PEI-based membrane, oil rejection of >97% was recorded and its overall structural integrity was marginally affected throughout the entire UV irradiation process. The findings of this work showed that the PEI-based membrane should be considered as the host for photocatalyts incorporation if the membrane was to be used for UV-assisted wastewater treatment process.

Current Situation and Overview of Biodiesel over the Global View (글로벌 측면에서 본 바이오디젤의 현황과 전망)

  • Lee, Moon-Yong;Lee, Jin-Hui;Kwak, Jung-Min;Kim, Jae-Kon
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.3
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    • pp.528-539
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    • 2013
  • Biodiesel is one of the most important renewable energy, since it is one of the most important alternative and eco-friendly energy source compared to fossil energy, especially for diesel engineequipped vehicles. It is now coming up for preparation of biodiesel as the alternative that applies the hetrogeneous catalyst, super critical state and various methods used in order to reduce the stages of the processes be converted and separation stages started from oil and fat which are originated from animals and wastes, and those new methods bring eco-friendly as well, though some of those are stand on research step so far. It is necessary that nation provides the tax exemption program for the supplier and strengthen the research system for the farming crops relate to fat and oil. It can improve the development of biodiesel which sustains stability against oxidation and keeps good mobility over the low temperatures in the winter season by new additives and develops new processes to show good harmony with diesel engine.

Cementing failure of the casing-cement-rock interfaces during hydraulic fracturing

  • Zhu, Hai Y.;Deng, Jin G.;Zhao, Jun;Zhao, Hu;Liu, Hai L.;Wang, Teng
    • Computers and Concrete
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    • v.14 no.1
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    • pp.91-107
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    • 2014
  • Using the principle of damage mechanics, zero-thickness pore pressure cohesive elements (PPCE) are used to simulate the casing-cement interface (CCI) and cement-rock interface (CRI). The traction-separation law describes the emergence and propagation of the PPCE. Mohr-coulomb criteria determines the elastic and plastic condition of cement sheath and rock. The finite element model (FEM) of delamination fractures emergence and propagation along the casing-cement-rock (CCR) interfaces during hydraulic fracturing is established, and the emergence and propagation of fractures along the wellbore axial and circumferential direction are simulated. Regadless of the perforation angle (the angle between the perforation and the max. horizontal principle stress), mirco-annulus will be produced alonge the wellbore circumferential direction when the cementation strength of the CCI and the CRI is less than the rock tensile strength; the delamination fractures are hard to propagate along the horizontal wellbore axial direction; emergence and propagation of delamination fractures are most likely produced on the shallow formation when the in-situ stresses are lower; the failure mode of cement sheath in the deep well is mainly interfaces seperation and body damange caused by cement expansion and contraction, or pressure testing and well shut-in operations.

Experimental Study on the Calculation of Stremlines Around a ShipHull of Chine Form (Chine형 선체주위의 유선계산에 관한 실험적 고찰)

  • 이근무
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.32 no.3
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    • pp.273-285
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    • 1996
  • Generally, the flow around the ship's hull often appear 3-dimensional separation at the bow and stem, and the vortex by this flow affects greatly the resistance propulsive efficiency and maneuverability of the ship. This study is compared the calculated result based on the streamlines calculation method with the experimental result by oil fIlm method to analyze the patterns and characteristics of the flows around the ship's hull of chine form. DTMB Series 62, 4667-1 vessel was selected as a sample ship of chine form and model ship was painted with the mixture of oil-color, paint, and poly wax at the surface of the vessel and tested in the model towing tank of Inha University. The results obtained in this study are listed briefly as follows ; 1. For the single chine form, after $4\frac{1}{2}$ station the streamlines are crossed at the chine line and the streamlines are converted to the vortex follow the chine line. 2. For the single chine form, the vortex appered increases and severely in and arround the stern. 3. The approximate streamlines for the ship's hull of chine form can be assigned by the use of the Watanabe's basic transformation formular.

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Preparation and Characterization of PP-g-Poloxamer Membranes by UV Irradiation Methods and their Solutes Permeation Behaviors

  • Lee, S. H.;Shim, J. K.;Lee, Y. M.;Ahn, S. H.;Yoo, I. K.;Baek, K. H.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.97-98
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    • 1998
  • 1. Introduction : Polypropylene(PP) membrane is widely used in the field of microfiltration and ultrafiltration. However, the hydrophobicity of PP causes the adsorption of hydrophobic and amphoteric solutes in the feed. Surface modification techniques of membrane through the treatment of hydrophilizing agents, coating of hydrophilic compounds, UV, plasma and high energy irradiation, etc. can have a great effect on propensities to prevent the protein from staining membranes. Among them, the modification to hydophilize membrane surface using UV is very simple and effective. Recently many studies for more effective surface modification have been conducted. Iwata et al. prepared membranes by grafting polyethylene glycol diacrylate macromer(PEGDA) onto polysulfone with plasma using a glow discharge reactor which prevent the oil from staining the membrane. The primary mechanism contributing to the membranes is preventing the oil from directly contacting the surface of the membrane as the PEGDA chains dissolved into emulsion. To evaluate their feasibility for use as a anti-fouling separation membrane, we prepared hydrophilic membranes by UV irradiation method and investigated their characteristics.

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