• Title/Summary/Keyword: Oil refinery

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Analysis of selenium in oil refinery wastewater by hydride generation atomic absorption spectrometry (Hydride Generation Atomic Absorption Spectrometry를 이용한 석유정제폐수중의 selenium 분석)

  • Cheon, Mi-Hee;Kim, Chul;Lee, Hyun-Joo;Kang, Lim-Seok
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.399-406
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    • 2003
  • This study was conducted to find out the analysis condition of selenium(Se) in oil refinery wastewater with a high concentration of Se using the atomic absorption spectrometry with hydride generation system (HG-AAS). From various experiments that reduced Se(VI) to Se(IV), the optimum pretreatment condition was determined to be a sample volume of 10 mL, HCl 10 mL, with a 30 min heating time in a water bath. In oil refinery wastewater, as the concentration of organics and constitution became higher, the recovery rates of Se decreased. Therefore, three acid digestion methods ($HNO_3/HClO_4$ digestion, $KMnO_4$ digestion, and microwave acid digestion) were tested on the recovery rates of Se in reference to the digestion of organics, petroleum and oxidation from organic Se(org.), Se(IV) to Se(VI). The experiment results showed that the average recovery rate of Se was the highest in microwave acid digestion, although all of the digestions were more than 90%. In consequence, the pretreatment procedure of microwave digestion followed by HCl addition was the most suitable for selenium analysis in oil refinery wastewater by using HG-AAS.

WATER QUALITY OF THE CULTURE BEDS OF HARD CLAM AND ADJACENT SEA OF THE Y대녀 REFINERY OF HONAM OIL REFINERY CO. IN KWANG YANG BAY (광양만 백합양식장 수질에 미치는 영향에 대하여)

  • WON Jong Hun;GO Nam Pyo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.8 no.2
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    • pp.73-84
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    • 1975
  • The present study was conducted to evaluate the effects of oil spill from the wastewater of Yeosu Refinery on water quality of hard clam culture beds in Taein-Ri, Kwang Yang Bay. Wastewater and oil spill may reach to the culture beds in 6-8 hours by tidal current movement. Water quality is nearly normal as unpolluted sea water except the concentration of n-hexane extractive chemicals which shows higher than unpolluted sea water in period of September to October in 1973. It may be caused by wastewater of Yeosu Refinery.

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Non Conventional Energy Upgrading Process Technology (비재래형 에너지 고부가화 공정 기술)

  • Kim, Yong Heon;Bae, Ji Han
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.10-17
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    • 2013
  • Heavy oil residue upgrading process was being used in conventional refinery process. Recently, as the importance of non conventional energy development is growing up, the commercial projects of heavy oil upgrading are getting more active than before. For having competitive business model in the resource competition, non conventional energy development should be considered as an important business strategy. In developing oil sands, extra heavy oil, and shale gas, canadian oil sands and extra heavy oil have great importance in substitution of conventional oil consumption. In oil sands development, the bitumen, which is extracted from oil sands, has great value after upgrading or refining process. Similar process is being used current conventional refinery process. The bitumen is highly viscous hydrocarbon. This bitumen includes impurities which can not be treated in conventional refinery process. As this reason, specified process is needed in bitumen or extra heavy oil upgrading process. Moreover, there will be additional specified facilities in the process of production, transportation and marketing. In oil sands, there are various kinds of commercial upgrading process. Extraction, dilution, coking and cracking method were being used commercially.

The Meaning of the Oil Market Supply and Demand in three Northeast Asian Countries (동북아 3국의 석유수급 의미의 재검토 : 원유, 석유제품 생산과 수출입, 그리고 정제시설을 중심으로)

  • Ahn, II-Hwan;Doh, Hyun-Jae;Lee, Seung-Hoon;Sonn, Yang-Hoon;Kim, Suduk
    • Environmental and Resource Economics Review
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    • v.17 no.2
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    • pp.381-418
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    • 2008
  • This study revisits the meaning of energy security by examining the oil market supply and demand conditions of petroleum products and refinery capacity of three Northeast Asian countries(Korea, China, Japan). In 2006, 10.6 million bid of excess demand occurred and is expected to be 15~22 million bid by the year 2030 in this regional oil market. Different oil demand is caused mainly by the different demands for various petroleum products based on each country's economic structures. If the demands are ranked according to their petroleum products, Chinese case shows gasoil > gasoline > fuel oil> LPG > naphtha > Kero/jet and Japanese case shows gasoil > gasoline> naphtha> Kero/jet > fuel oil > LPG, while Korean case shows naphtha> gas oil > fuel oil > LPG > Kero/jet > gasoline, respectively. Total CDU(Crude Distillation Unit) capacity of three northeast asian countries also have been examined in this respect. This study points out the importance of the information on oil demand and supply, on petroleum products and refinery capacities of the three Northeast Asian countries to enhance the security of the oil market in this region.

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A Study on Diesel Engine NOx and Soot Emission Characteristics using Different Fuel Oils

  • Nam, Jeong-Gil;Kang, Dae-Sun
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.7
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    • pp.1080-1088
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    • 2008
  • This paper addresses some concerns faced by the shipping industry nowadays. Initially, the environmental issues were resolved and stricter regulations are now being implemented with regards to the exhaust gas, specifically nitrogen oxides (NOx) and sulfur oxides (SOx), emitted from ships. Secondly, with the increasing and unstable cost of fuel oils in the world market, it has become almost a necessity to explore on a new alternative fuel. Hence, this study was conducted. An experiment was carried-out on a fishing survey vessel with the main engine (M/E) and generator engine (G/E) operated on expensive marine gas oil (MGO). During the experiment, two pre-refinery systems were installed and different fuel oil samples were employed for the M/E and the G/E. Furthermore, the NOx emission and soot concentration were monitored and verified. The results confirmed the compatibility of some fuel oil types to the engines and meeting the emission standards. MDO, MF15 and Bunker A can be used in place of MGO for the engines(M/E, G/E).

Degradation of Phenanthrene by Bacterial Strains Isolated from Soil in Oil Refinery Fields in Korea

  • KIM JEONG DONG;SHIM SU HYEUN;LEE CHOUL GYUN
    • Journal of Microbiology and Biotechnology
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    • v.15 no.2
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    • pp.337-345
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    • 2005
  • The degradation of phenanthrene, a model PAH compound, by microorganisms either in the mixed culture or individual strain, isolated from oil-contaminated soil in oil refmery vicinity sites, was examined. The effects of pH, temperature, initial concentration of phenanthrene, and the addition of carbon sources on biodegradation potential were also investigated. Results showed that soil samples collected from four oil refinery sites in Korea had different degrees of PAH contamination and different indigenous phenanthrene-degrading microorganisms. The optimal conditions for phenanthrene biodegradation were determined to be 30$^{circ}C$ and pH 7.0. A significantly positive relationship was observed between the microbial growth and the rate of phenanthrene degradation. However, the phenanthrene biodegradation capability of the mixed culture was not related to the degree of PAH contamination in soil. In low phenanthrene concentration, the growth and biodegradation rates of the mixed cultures did not increase over those of the individual strain, especially IC10. High concentration of phenanthrene inhibited the growth of microbial strains and biodegradation of phenanthrene, but was less inhibitory on the mixed culture. Finally, when non-ionic surfactants such as Brij 30 and Brij 35 were present at the level above critical micelle concentrations (CMCs), phenanthrene degradation was completely inhibited and delayed by the addition of Triton X100 and Triton N101.

A Study on the Analysis of the Relative Efficiency of Northeast Asian Country's oil Refinery Facilities (동북아시아 국가의 석유정제설비의 상대적 효율성 분석)

  • Lee, Choong-Bae;Kim, Jeong-Hwan;Kang, Hyo-Won
    • International Commerce and Information Review
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    • v.14 no.3
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    • pp.209-227
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    • 2012
  • Northeast Asia where is an epicenter of the global financial crisis's conquest is traditional imbalanced region of oil production and consumption. In recent years, the region has been suffered by the shortage of oil storage and transportation facilities due to surging oil trading and necessity in strategic reserves. Therefore, since independent petroleum logistics with the storage facilities and oil trading hub is required to form efficient oil market in this region. In this study, we analyzed the efficiency of refinery facilities by country that is of importance in being a logistics hub in Northeast Asia by employing non-static and dynamic efficiency analysis, which are a part of DEA(Data Envelopment Analysis) and then policy implications have been drawn. The result illustrates Korea's is the highest country in terms of efficiency of oil refining facilities in Northeast Asia. It implies that Korea has strong position to be the oil hub in Northeast Asia.

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Advanced Treatment for Reuse of Oil Refinery Process Wastewater using UF/RO Processes (UF/RO 공정을 이용한 정유공장 방류수의 재활용을 위한 고도처리)

  • 이광현
    • Membrane Journal
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    • v.10 no.4
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    • pp.220-229
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    • 2000
  • Deionized water and wastewater flux were discussed using module set 1-7 composed of ultrafiltration hollow fiber type modules and reverse osmosis spiral wound type modules. The separation characteristics of ultrafiltration and reverse osmosis membranes were discussed with the variation of applied pressure and temperature. Turbidity and SS were removed effectively from ultrafiltration mem¬brane, and removal efficiency of COD, T-N, and TDS using reverse osmosis membrane was very efficient. Permeate flux increased linearly with the increase of applied pressures and temperature. It was shown that ultrafiltration and reverse osmosis membranes were suitable Lo the advanced treatment and reuse of oil refinery process effluent.

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