• Title/Summary/Keyword: Oil behavior

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Research on the Rheological Properties of Aqueous Film Forming Foam to Respond to Ship Oil Fires (함정 유류화재 대응을 위한 수성막포의 유변학적 특성 연구)

  • Kil-Song Jeon;Hwi-Seong Kim;Jung-Hoon You;Yong-Ho Yoo;Jin-Ouk Park
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.603-607
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    • 2023
  • Aqueous film forming foam (AFFF) is a critical fire suppression agent used in combating hydrocarbon fires. This type of fire suppressant is highly effective due to its ability to form a protective film, dissipate heat, inhibit combustion, and utilize a blend of chemical substances to extinguish fires. While these properties offer significant advantages in responding to hydrocarbon fires, AFFF is distinct in its deployment as it is dispensed in the form of foam. Therefore, the rheological analysis of AFFF foam using a rheometer plays a crucial role in predicting the spray characteristics of AFFF for combating hydrocarbon fires, and this is closely associated with effective fire suppression. In this study, we conducted rheometer experiments to confirm the non-Newtonian behavior (shear-thinning) of AFFF foam and obtained data on the form's stability. These experimental data are expected to contribute to enhancing the efficiency of fire suppression systems utilizing AFFF.

Tethers tension force effect in the response of a squared tension leg platform subjected to ocean waves

  • El-gamal, Amr R.;Essa, Ashraf;Ismail, Ayman
    • Ocean Systems Engineering
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    • v.4 no.4
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    • pp.327-342
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    • 2014
  • The tension leg platform (TLP) is one of the compliant structures which are generally used for deep water oil exploration. With respect to the horizontal degrees of freedom, it behaves like a floating structure moored by vertical tethers which are pretension due to the excess buoyancy of the platform, whereas with respect to the vertical degrees of freedom, it is stiff and resembles a fixed structure and is not allowed to float freely. In the current study, a numerical study for square TLP using modified Morison equation was carried out in the time domain with water particle kinematics using Airy's linear wave theory to investigate the effect of changing the tether tension force on the stiffness matrix of TLP's, the dynamic behavior of TLP's; and on the fatigue stresses in the cables. The effect was investigated for different parameters of the hydrodynamic forces such as wave periods, and wave heights. The numerical study takes into consideration the effect of coupling between various degrees of freedom. The stiffness of the TLP was derived from a combination of hydrostatic restoring forces and restoring forces due to cables. Nonlinear equation was solved using Newmark's beta integration method. Only uni-directional waves in the surge direction was considered in the analysis. It was found that for short wave periods (i.e., 10 sec.), the surge response consisted of small amplitude oscillations about a displaced position that is significantly dependent on tether tension force, wave height; whereas for longer wave periods, the surge response showed high amplitude oscillations that is significantly dependent on wave height, and that special attention should be given to tethers fatigue because of their high tensile static and dynamic stress.

Safety, Efficacy, and Physicochemical Characterization of Tinospora crispa Ointment: A Community-Based Formulation against Pediculus humanus capitis

  • Torre, Gerwin Louis Tapan Dela;Ponsaran, Kerstin Mariae Gonzales;de Guzman, Angelica Louise Dela Pena;Manalo, Richelle Ann Mallapre;Arollado, Erna Custodio
    • Parasites, Hosts and Diseases
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    • v.55 no.4
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    • pp.409-416
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    • 2017
  • The high prevalence of pediculosis capitis, commonly known as head lice (Pediculus humanus capitis) infestation, has led to the preparation of a community-based pediculicidal ointment, which is made of common household items and the extract of Tinospora crispa stem. The present study aimed to evaluate the safety, efficacy, and physicochemical characteristics of the T. crispa pediculicidal ointment. The physicochemical properties of the ointment were characterized, and safety was determined using acute dermal irritation test (OECD 404), while the efficacy was assessed using an in vitro pediculicidal assay. Furthermore, the chemical compounds present in T. crispa were identified using liquid-liquid extraction followed by ultra-performance liquid chromatography quadruple time-of-flight mass spectrometric (UPLC-qTOF/MS) analysis. The community-based ointment formulation was light yellow in color, homogeneous, smooth, with distinct aromatic odor and pH of $6.92{\pm}0.09$. It has spreadability value of $15.04{\pm}0.98g{\cdot}cm/sec$ and has thixotropic behavior. It was also found to be non-irritant, with a primary irritation index value of 0.15. Moreover, it was comparable to the pediculicidal activity of the positive control $Kwell^{(R)}$, a commercially available 1% permethrin shampoo (P>0.05), and was significantly different to the activity of the negative control ointment, a mixture of palm oil and candle wax (P<0.05). These findings suggested that the community-based T. crispa pediculicidal ointment is safe and effective, having acceptable physicochemical characteristics. Its activity can be attributed to the presence of compounds moupinamide and physalin I.

The Sanitation Level and Culinary Environment of Using Fishery Products for the Housewives in the Seoul Metropolitan Area

  • Rha, Young-Ah;Lee, Woo-Sik;Hong, Sang-Pyo;Kwon, Woo-Taeg
    • Culinary science and hospitality research
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    • v.20 no.5
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    • pp.43-51
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    • 2014
  • The purpose of this study is to assess the sanitation level and purchase behavior of fishery products, and to identify management conditions of bad smell from cooking fish at home as perceived by housewives in a metropolitan area. Frequency analysis, descriptive analysis, and cross-tabulation analysis were employed as statistical techniques for current study. Total 270 were collected from housewives. The statistical variables included the kinds of cooking oil and the age of housewives, the types of hoods for fish roasting, the types of covers for fish grills, the number of family, the ventilation methods, and the maintenance of kitchen utensils based on family incomes, and they showed statistically significant differences(p<.05). Furthermore, the housewives whose sanitary cognition level for fishery products was high, the housewives whose level of purchase attitude was relatively high, and the housewives who utilized specialized kitchen utensils demonstrated statistically significant differences(p<.05). It resulted from the assessment of such actual conditions as difference of culinary environment according to the sanitation level of fishery products, the level of purchase attitude, and whether the housewives utilized special kitchen utensils or not. The more efforts were proved from those who had the intentions for improvement of an amenable culinary environment at homes, according to the higher income obtainers, the smaller nuclear family, the younger generation, whether the housewives utilized special kitchen utensils or not, and those who had the higher sanitary cognition level of fishery products. The above results were derived from an individual lifestyle or a dietary lifestyle, but eventually this seems to be related with the propensity and values hierarchy of individuals.

The Relationship between Divorce Rates and Socioeconomic and Demographical Factors (사회경제, 인구학적 요인과 이혼율과의 관계)

  • Chung, Hyun-Sook
    • Journal of Families and Better Life
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    • v.26 no.1
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    • pp.51-67
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    • 2008
  • The study analyzes divorce rates in Korea and makes suggestions for the future research of divorce rates. Based on the data from Korea Statistical Information System (KOSIS) of the National Statistics Organization, trends for divorce rates change and the relations between divorce rates and macro environmental factors are analyzed. Macro environmental factors include socioeconomic factors such as, Korean War, Vietnam War, oil shock, IMP economic crisis and gross national income (GNI), whereas demographical factors include population structure, rates of female labor participation, and geographical location. The principle characteristics of divorce rates are as follows: 1) the Crude divorce rates (CDR) and the number of divorced had been increased from 1970 to 2004, then the trend changed to a decrease; 2) the slope of the change were the highest during 1998 to 2004 after the IMP economic crisis. The relations between socioeconomic factors are as follows: 1) during the war there was a small increase of CDR for a short period of time; 2) the economic crisis of the nation tend to increase the CDR, while the IMP economic crisis had a strong impact on an increase of CDR because of the interaction effect among the population structure, women's sex role changes as well as the level of standard of living. The increase in CDR from 1990 to 2000 can be explained partly by the population of baby Boomers passing through their marriage and divorce process. The number of population residing in the rural area and the middle class households, and the mobility of population also had an impact on the divorce rates changes. The recommendations for the future research were as follows: 1) the need to develop new divorce statistics that are based on a marriage cohort or a birth cohort because family behavior is a mixture of personal, social and political responses, and because CDR is not an accurate measure of divorce rate since it was influenced by population structure; 2) the need to include micro personal factors as well as macro social factors in a model to find an interaction effect between those variables.

Combustion and NOx Emission Characteristics of the Gas Turbine Combustor Burning Medium-Btu Gas as Alternative Fuel (중발열량 가스 대체 시 가스터빈 연소기의 연소 및 NOx 배출 특성)

  • Lee, Chan;Seo, Je-Young
    • Journal of Energy Engineering
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    • v.12 no.4
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    • pp.320-327
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    • 2003
  • A CFD (Computational fluid Dynamics) research is conducted for the investigation of the fuel alteration of MBTU (medium-Btu) gas in IGCC gas turbine combustor. The computational analysis method of the gas turbine combustor is constructed by incorporating MBTU gas reaction and fuel NOx models into commercial CFD code. With the use of the present analysis method, comparisons are made on the flow velocity, the chemical species and the temperature distributions, and on the flame shape and behavior of gas turbine combustor firing natural gas and MBTU gases (coal gas, heavy residue oil gas). Furthermore, the NOx formation characteristics and the turbine matching condition of the combustor are analyzed. Based on the computed analysis results, the present study provides the directions for the redesign and the design modification of IGCC gas turbine combustor firing MBTU gas as alternative fuel.

Artificial Spawning Behavior and Development of Eggs, Larvae and Juveniles of the Red Spotted Grouper, Epinephelus akaara in Korea

  • Park, Jong Youn;Cho, Jae Kwon;Son, Maeng Hyun;Kim, Kyong Min;Han, Kyeong Ho;Park, Jae Min
    • Development and Reproduction
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    • v.20 no.1
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    • pp.31-40
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    • 2016
  • This study was conducted in order to examine the egg development in red spotted grouper, Epinephelus akaara and the morphological development of its larvae and juveniles, and to obtain data for taxonomic research. This study was conducted in June 2013, and 50 male and female fish were used for the study. One hundred ${\mu}g/kg$ of LHRHa was injected into the body of the fish for inducing spawning, and the fish were kept in a small-sized fish holder ($2{\times}2{\times}2m$). Eggs were colorless transparent free pelagic eggs, 0.71-0.77 mm large (mean $0.74{\pm}0.02mm$, n=30), and had an oil globule. Hatching started within 27 h after fertilization. Pre-larvae that emerged just after hatching were 2.02-2.17 mm in total length (mean $2.10{\pm}0.11mm$), their mouth and anus were not opened yet, and the whole body was covered with a membrane fin. Post-larvae that emerged 15 days post hatching were 3.88-4.07 mm in total length (mean $3.98{\pm}0.13mm$), and had a ventral fin with two rays and a caudal fin with eight rays. Juveniles that were formed at 55 d post hatching, were 31.9-35.2 mm in total length (mean $33.6{\pm}2.33mm$), with red color deposited over the entire body, and black chromophores deposited in a spotted pattern. The number of fin rays, body color, and shape were the same as that in the adult fish.

Initiation and Growth Behavior of Small Fatigue Cracks in the Degraded 2 1/4 Cr-1 Mo Steel (2 1/4 Cr-1 Mo강 劣化材의 微小 疲勞龜裂의 발생 및 진전거동)

  • 곽상국;장재영;권재도;최선호;장순식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.1
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    • pp.53-62
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    • 1992
  • Material can be degraded by using it for a long service under the high temperature and pressure circumstances, Therefore, material degradation can affect the strength of mechanical structures. At present, the life prediction of the degraded structures is considered as an important technical problem. In this paper, the degraded 21/4Cr-lMo steel is the material used for about 10 years around 400.deg. C in an oil refinery plant. The recovered one was prepared out of the above degraded steel by heat treatment for one hour at 650.deg. C. The degradation effect was investigated through the tension test, Hardness test and Charpy impact test. On the smooth surface material, the fatigue crack initiation, growth and coalescence stages of the distributed small cracks were investigated with photographs, and the crack length and density were measured. The measuring results were analyzed by quantative and statistical methods.

Mixing Analysis of Floating Pollutant Using Lagrangian Particle Tracking Model (Lagrangian 입자추적모형을 이용한 부유성 오염물질의 혼합해석)

  • Seo, Il Won;Park, Inhwan;Kim, Young Do;Han, Eun Jin;Choo, Min Ho;Mun, Hyun Saing
    • Journal of Korean Society on Water Environment
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    • v.29 no.3
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    • pp.383-392
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    • 2013
  • In this research, mixing behavior of the floating pollutant such as oil spill accidents was analyzed by studying the advection-diffusion of GPS floaters at water surface. The LPT (Lagrangian Particle Tracking) model of EFDC (Environmental Fluid Dynamics Computer Code) was used to simulate the motion of the GPS floater tracer. In the field experiment, 35 GPS floaters were injected at the Samun Bridge of Nakdong River. GPS floaters traveled to downstream about 700 m for 90 minutes. The field data by the GPS floater experiments were compared with the simulation in order to calibrate the parameter of LPT model. The turbulent diffusion coefficient of LPT model was determined as $K_H/hu^*$ = 0.17 from the scatter diagram. The arrival time of peak concentration and transverse diffusion from the simulation results were similar with the experiments from the concentration curves. Numerical experiments for anticipation of damage from floating pollutant were conducted in the same reach of the Nakdong River and the results show that the pollutant cloud transported to the left bank where the Hwawon pumping station is located. For this reason, it is suggested that the proper action should be needed to maintain the safety of the water withdrawal at the Hwawon pumping station.

The Study on the Electrochemical Polarization Characteristics of Hydrogen Embrittlement for Ferrite Stainless Steel with Welding Conditions (용접조건에 따른 페라이트 스테인리스강에 대한 수소취성의 전기화학적 분극특성에 관한 연구)

  • Choi, Byung-Il;Lim, Uh-Joh
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.30-35
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    • 2005
  • In order to examine the electrochemical polarization characteristics of hydrogen embrittlement far STS444 with welding conditions, this paper carried out the accelerated hydrogen osmosis test and the electrochemical polarization test. That is, in $0.5M\; H_2SO_4+0.001M\;As_2O_3$ solution, the hydrogen embrittlement behavior of STS444 added to load of $1,400kg/cm^2$ together with hydrogen osmosis by current of $30mA/cm^2$ far 60 min. was considered. In researching the electrochemical polarization characteristics of hydrogen embrittlement for STS444 with welding conditions, the previous study clarified that tensile strength or elongation became low influenced by absorption of oil or water before welding. In this paper, we proposed the advanced mechanism of hydrogen embrittlement that integrated electrochemical corrosion with the existing mechanism of hydrogen embrirtlement.

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