• Title/Summary/Keyword: Oil absorption rate

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Effect of rheological properties on chemical absorption of carbon dioxide with MEA

  • Park, Sang-Wook;Kim, Tae-Young;Park, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.16 no.1
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    • pp.35-45
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    • 2004
  • Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.

Optimization of Headspace Analysis of Volatile Compounds from Oxidized Fish Oil

  • Shin, Eui-Cheol;Jang, Hae-Jin;Lee, Hyung-Il;An, Hae-Jung;Lee, Yang-Bong
    • Preventive Nutrition and Food Science
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    • v.8 no.4
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    • pp.315-320
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    • 2003
  • Headspace volatile compounds of oxidized fish oil were analyzed by the combination of hexane solvent or solid phase microextraction, gas chromatography and mass selective detector. The optimum condition of headspace analysis by hexane trapping was 23 min absorption time, 96$^{\circ}C$ sample temperature and 20 mL/min air flow rate. The numbers of volatile compounds identified by solvent trapping and SPME were 35 and 14, respectively. Groups having the largest amount and many kinds were hydrocarbons and aldehydes, respectively. The numbers of aldehydes were 15 and 6 for solvent trap and SPME, respectively. These basic data could be used as indicators for the quality changes of fish oil.

Properties of Acylated Mungbean Whole Globulin (Acyl화에 의한 녹두 Whole Globulin의 특성에 관한 연구)

  • Kim, Yong-Hwan;Song, Jong-Seon;Kim, Gwang-Su
    • The Korean Journal of Food And Nutrition
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    • v.2 no.1
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    • pp.18-26
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    • 1989
  • The objective of this study was to improved the limited functional characteristics of mungbean whole globulin. The mungbean whole globulin was acylated with succinic and acetic anhydride, and the functional properties of acylated protein were investigated, The results obtained ware as follows. 1. The UV-absorption spectra of acylated whole globulins with that of the succinylated 74% whole globulin as large blue shift of the absorption maximum and minimum wavelength from 275 nm to 269 nm, respectively. 2. The mobility of acylated whole globulin were increased on PAGE pattern, and degree of mobility was particularly remarkable in case of succinylation, 3. The water absorption capacity of whole globulin was increased by acylation. The most increased rate of whole globulin was 174,02% from succinylated 74%. The oil absorption capacity of whole globulin was increased by acylation The most increased rate of whole globulin was 165.41% from acetylated 81.77%. 4. The bulk density of whole globulin was decreased by acylation. and the greater the extent of acylation, the smaller the bulk density. 5. The foaming capacity and stability of whole globulin was increased by acylation, and remarkably high in 74% succinylated whole globulin. In contrast, however, the foaming capacity and stability of native and acylated whole globulin were decreased by heat treatment.

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The Intestinal Absorption of Lysino-Methylene-Ampicillin in Rat (Lysino-Methylene-Ampicillin의 Rat 소장흡수(小腸吸收)에 관한 연구(硏究))

  • Chin, Kum-Sup;Kim, Jong-Kap;Kim, Jae-Baek
    • Journal of Pharmaceutical Investigation
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    • v.9 no.1
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    • pp.15-19
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    • 1979
  • The absorption rate of lysino-methylene-ampicillin from the rat small intestine, compared with ampicillin, was determined in vitro and in situ to establish the biopharmaceutical properties of lysino-methylene-ampicillin which is one of the new penicillinase-resistance antibiotics. The half of administered dose was absorbed rapidly within thirty minutes. The water-oil distribution coefficient of lysino-methylene-ampicillin was 0.03 in chloroform versus buffer system with $Na_{2}HPO_{4}-citric$ acid of pH5.2 at $37^{\circ}C$, and its dissolution rate reached the plateau in an hour and then represented 0.6 percent of equilibrium solubility

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A Study on Formulation Optimization for Improving Skin Absorption of Glabridin-Containing Nanoemulsion Using Response Surface Methodology (반응표면분석법을 활용한 Glabridin 함유 나노에멀젼의 피부흡수 향상을 위한 제형 최적화 연구)

  • Se-Yeon Kim;Won Hyung Kim;Kyung-Sup Yoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.3
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    • pp.231-245
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    • 2023
  • In the cosmetics industry, it is important to develop new materials for functional cosmetics such as whitening, wrinkles, anti-oxidation, and anti-aging, as well as technology to increase absorption when applied to the skin. Therefore, in this study, we tried to optimize the nanoemulsion formulation by utilizing response surface methodology (RSM), an experimental design method. A nanoemulsion was prepared by a high-pressure emulsification method using Glabridin as an active ingredient, and finally, the optimized skin absorption rate of the nanoemulsion was evaluated. Nanoemulsions were prepared by varying the surfactant content, cholesterol content, oil content, polyol content, high-pressure homogenization pressure, and cycling number of high-pressure homogenization as RSM factors. Among them, surfactant content, oil content, high-pressure homogenization pressure, and cycling number of high-pressure homogenization, which are factors that have the greatest influence on particle size, were used as independent variables, and particle size and skin absorption rate of nanoemulsion were used as response variables. A total of 29 experiments were conducted at random, including 5 repetitions of the center point, and the particle size and skin absorption of the prepared nanoemulsion were measured. Based on the results, the formulation with the minimum particle size and maximum skin absorption was optimized, and the surfactant content of 5.0 wt%, oil content of 2.0 wt%, high-pressure homogenization pressure of 1,000 bar, and the cycling number of high-pressure homogenization of 4 pass were derived as the optimal conditions. As the physical properties of the nanoemulsion prepared under optimal conditions, the particle size was 111.6 ± 0.2 nm, the PDI was 0.247 ± 0.014, and the zeta potential was -56.7 ± 1.2 mV. The skin absorption rate of the nanoemulsion was compared with emulsion as a control. As a result of the nanoemulsion and general emulsion skin absorption test, the cumulative absorption of the nanoemulsion was 79.53 ± 0.23%, and the cumulative absorption of the emulsion as a control was 66.54 ± 1.45% after 24 h, which was 13% higher than the emulsion.

The Study on the Mechanical Characteristics of Hydrogen Embrittlement for the Weld Zone of Ferrite Stainless Steel (페라이트 스테인리스강 용접부에 대한 수소취성의 기계적 특성에 관한 연구)

  • Choi, Byung-Il;Lim, Uh-Joh
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.11-16
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    • 2005
  • In this paper, the hydrogen osmosis test and the mechanical tensile test were carried out to examine hydrogen cracking behavior of STS444 with welding conditions. In $0.5MH_2SO_4+0.001M \;As_2O_3$ solution, the hydrogen embrittlement characteristics of weld zone of STS444 added to load of $1,400 kg/cm^2$ together with hydrogen osmosis by current of $30mA/cm^2$ for 60 min. was considered. As a result of study on the hydrogen embrittlement and mechanical characteristics of STS444외와 with welding conditions the tensile stress and elongation of STS444 get lower by the absorption of oil or water before welding. Also, the reduction rate of tensile stress and elongation of STS444 is larger because of hydrogen embrittlement by the absorption of oil or water. STS444 by the absorption of water before welding is more sensitive to hydrogen embrittlement than oil.

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Analysis of selenium in oil refinery wastewater by hydride generation atomic absorption spectrometry (Hydride Generation Atomic Absorption Spectrometry를 이용한 석유정제폐수중의 selenium 분석)

  • Cheon, Mi-Hee;Kim, Chul;Lee, Hyun-Joo;Kang, Lim-Seok
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.399-406
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    • 2003
  • This study was conducted to find out the analysis condition of selenium(Se) in oil refinery wastewater with a high concentration of Se using the atomic absorption spectrometry with hydride generation system (HG-AAS). From various experiments that reduced Se(VI) to Se(IV), the optimum pretreatment condition was determined to be a sample volume of 10 mL, HCl 10 mL, with a 30 min heating time in a water bath. In oil refinery wastewater, as the concentration of organics and constitution became higher, the recovery rates of Se decreased. Therefore, three acid digestion methods ($HNO_3/HClO_4$ digestion, $KMnO_4$ digestion, and microwave acid digestion) were tested on the recovery rates of Se in reference to the digestion of organics, petroleum and oxidation from organic Se(org.), Se(IV) to Se(VI). The experiment results showed that the average recovery rate of Se was the highest in microwave acid digestion, although all of the digestions were more than 90%. In consequence, the pretreatment procedure of microwave digestion followed by HCl addition was the most suitable for selenium analysis in oil refinery wastewater by using HG-AAS.

Chemical Reaction of Carbon Dioxide with AMP in w/o Emulsion Membrane (W/O 에멀션액막에서 이산화탄소와 AMP의 화학반응)

  • Park Sang-Wook;Choi Byoung-Sik;Kim Seong-Soo;Lee Jae-Wook
    • Membrane Journal
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    • v.14 no.4
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    • pp.275-288
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    • 2004
  • Carbon dioxide was absorbed into water-in-oil (w/o) emulsion composed of aqueous 2-amino-2-methyl-1-propanol (AMP) droplets as a dispersed phase and benzene solutions of polybutene and polyisobutylene as a continuous phase in a flat-stirred vessel to investigate the effect of non-Newtonian rheological behavior on the rate of chemical absorption of $CO_2$, where the reaction between $CO_2$ and AMP in the aqueous phase was assumed to be a pseudo-first-order reaction. It was expressed that PIB with elastic property made the rate of chemical absorption of $CO_2$ accelerated by comparison of mass transfer coefficient of $CO_2$ in the non-Newtonian liquid with that in the Newtonian liquid.

Effect of Medium and Long Chain Triglyceride Diet on the Serum Lipids of Rats Fed with Cholesterol (중쇄(中鎖)와 장쇄지방(長鎖脂肪) 식이(食餌)가 Cholesterol급여(給與) 흰쥐의 혈청지질(血淸脂質)에 미치는 영향(影響))

  • Lee, Eun-Sook;Cho, Jeong-Soon
    • Journal of the Korean Applied Science and Technology
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    • v.4 no.1
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    • pp.91-97
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    • 1987
  • Because of its more complete hydrolysis and rapid absorption, MCT is expected its usefulness in the diets of patients with malabsorption syndrom. Also, several authors reported that serum cholesterol level was lower after MCT feedings. In this study, rate of each experimental group were fed for 4weeks with 20% MCT, 20% corn oil, mixed diet of 10% MCT and 10% corn oil, mixed diet of 17% corn oil and 3% shortening. After experimental diet, it was measured to growth rate and serum cholesterol, triglyceride and phospholipid level. The results were as follows; 1. The body weight gain was the lowest in MCT group and others were lower than control group. 2. Serum total cholesterol level was the lowest in corn oil group and others were significantly lower than control group. Free cholesterol level was lower in all experimental groups than control group too. 3. Serum HDL-cholesterol level was significantly higher in all experimental groups than control group. 4. The ratio of VLDL, LDL-Cholesterol to HDL-Cholesterol was significantly lower in all experimental groups than control group. 5. Serum triglyceride level was higher in all experimental groups than control group. Serum phospholipid level was significantly in only mixed diet group of corn oil and shortening than control group. 6. The ratio of total cholesterol to phospholipid was significantly lower in corn oil diet group than control group.

Study on Damping Characteristics of Hydropneumatic Suspension Unit of Tracked Vehicle

  • Cho, Jin-Rae;Lee, Hong-Woo;Yoo, Wan-Suk;Lee, Jin-Kyu
    • Journal of Mechanical Science and Technology
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    • v.18 no.2
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    • pp.262-271
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    • 2004
  • Hydropneumatic suspension unit is an important part of tracked vehicles to absorb external impact load exerted from the non-paved road and the cannon discharge. Its absorption performance is strongly influenced by both damping and spring forces of the unit. In this paper, we numerically analyze the damping characteristics of the in-arm-type hydropneumatic suspension unit (ISU) by considering four distinct dynamic modes of the ISU damper: jounce-loading, jounce-unloading, rebound-loading and rebound-unloading. The flow rate coefficients determining the oil flow rate through the damper orifice are decided with the help of independent experiments. The wheel reaction force, the flow rate at cracking and the damping energy are parametrically investigated with respect to the orifice diameter and the wheel motion frequency.