• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.344-347
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• 2005

The purpose of the study for the development of the technologies of water quality monitoring and contamination protection at water resource aquifer is to secure the groundwater as potable water resources. The results of water analysis as a basis of potable water criteria showed that 30 groundwater samples among 138 samples of small water supply system (21.7%) were exceeded the water criteria. The concentrations of Cl, $NO_3$ and Na for granite area are higher than those of gneiss and metasedimentary rocks of Ogcheon belt area and they are caused by the high vulnerability of groundwater at granite region where the residential area and cultivated land are concentrated. The spatial distribution of components indicated the close relationships between water quality and geology, land use, and topography. The multivariate statistical results showed that the water samples are divided into three groups by geology.

• The Journal of Engineering Geology
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• v.13 no.4
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• pp.429-444
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• 2003

Domestic marbles are mostly distributed in Gyeonggi and Yeongnam Massifs, southwest and northeast Ogcheon Belts, which belong to Precambrian, age-unknown, Cambrian-Ordovician ages, respectively. The former marbles occur as interbedded rocks in metasediments and xenoliths in granitic gneisses. Age-unknown ones occur as interbedded in the formations of Hyangsanri, Gyeomyeongsan, Hwajeonri and Munjuri, and some in metasedimentary rocks. The latter ones occur as interbedded in Pungchon Limestone, and in Jeongseon Limestone, Hwacheonri Formation and Great Limestone Group, respectively. Among physical properties, porosity shows irregular patterns to density and compressive strength, respectively. Absorption ratio has a linear pattern of positive trend to porosity, and compressive strength mostly shows a positive trend to tensile strength. Compressive strengths of the marbles are as follows : Precambrian $1,106{\;}kg/\textrm{cm}^2$, age-unknown $935{\;}kg/\textrm{cm}^2$. Cambrian $1,162{\;}kg/\textrm{cm}^2$ and Ordovician $1,560{\;}kg/\textrm{cm}^2$, respectively. Tensile strengths have decreasing trends as the above order of geologic age. In diagrams of major elements, $Al_2O_3,{\;}Fe_2O_{3(t)}{\;}and{\;}Na_2O+K_2O$ generally show positive trends with increasing $v_2$. MgO/CaO of Precambrian and age-unknown marbles have much higher values than Cambrian and Ordovician marbles as follows, Precambrian 0.31, age-unknown 0.30, Cambrian 0.03 and Ordovician 0.08. And MgO shows a negative trend with increasing CaO, which nay be caused by dolomitization. By MgO contents they can be classified into calcitic dolomite, dolomitic limestone, limestone and dolomitic limestone, respectively.

• The Journal of the Petrological Society of Korea
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• v.4 no.1
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• pp.20-30
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• 1995

We report major element chemistry of the Chuncheon amphibolite in the Precambrian Kyonggi massif and discuss its origin. On the basis of areal distribution and chemical difference, the Chuncheon amphibolite can be divided into the Gubongsan arnphibolite in the Gubongsan Group east of Chuncheon city and the Sangguli amphibolite in the Yongduri gneiss complex occurring to the southeast of the Gubongsan Group. Overall major element characteristics of the Chuncheon amphibolite indicate an igneous precursor, although it shows concordant relationship with metasedimentary rocks in many cases. The parental rock of the amphibolite has tholeiitic composition with 45-53wt% $SiO_2$. The Sangguli amphibolite has lower MgO than the Gubongsan one. The difference in $TiO_2$/P_2O_5 ratio between the two amphibolites suggests that they are not genetically related. In MgO variation diagrams, $Na_2O$, $Fe_2O_3$ and $Al_2O_3$ show scattered pattern, while MgO has positive correlation with CaO and negative one with $SiO_2$, $TiO_2$, $P-2O_5$ and $K_2O$. These variations can be interpreted as the result of differentiation of basaltic magma with fractionation of olivine, pyroxene, and plagioclase. Tectonic discrimination using major elements generally suggest withinplate environment for the Chuncheon amphibolite which is similar to that of the amphibolite in the Ogcheon belt.

• Economic and Environmental Geology
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• v.45 no.4
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• pp.385-396
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• 2012

The geochemical high-grade uranium anormal zone has been reported in the Shinbo mine and its eastern areas, Jinan-gun, Jeollabuk-do located in the southwestern part of Ogcheon metamorphic zone, Korea. In this paper is reported the time-relationship between deformation and growth of metamorphic minerals in the eastern area of Shinbo mine, which consists of the Precambrian metasedimentary rocks (quartzite, metapelite, metapsammite) and the age-unknown pegmatite and Cretaceous porphyry which intrude them, and is considered the relative mineralization time on the basis of the previous research's result. The D1 deformation formed the straight-type Si internal foliation which is defined mainly as the arrangement of elongate quartz, biotite, opaque mineral in andalusite porphyroblast. The D2 deformation, which is defined by the microfolding of Si foliation, formed S2 crenulation cleavage. It can be divided into two sub-phases, early crenulation and late crenulation. The former occurs as the curvetype Si foliation in the mantle part of andalusite. The latter occurs as S1-2 composite foliation which warps around the andalusite. The andalusite porphyroblast began to grow under non-deformation condition after the formation of S1 foliation which corresponds to the straight-type Si foliation. It continued to grow before the late crenulation phase. The age-unknown pegmatite intruded after the D2 deformation and grew the fibrous sillimanite which random masks the S1-2 composite foliation. The D3 deformation formed F3 fold which folded the S1-2 composite foliation, D2 crenulation, fibrous sillimanite. It means that the intrusion of pegmatite related to the growth of the fibrous sillimanite took place during the inter-tectonic phase of D2 and D3 deformations. The retrograde metamorphism is recognized by the chloritization of biotite and two-way cleavage lamellae which is parallel to the S1-2 composite foliation and the F3 fold axial surface in the andalusite porphyroblast. It occurred during the D2 late crenulation phase and D3 deformation. In considering of the previous research's result inferring the most likely candidate for the uranium source rock as pegamatite, it indicates that the age-unknown pegmatite intruded during the inter-tectonic phase of D2 and D3 deformations, i.e. during the retrograde metamorphism related to the uplifting of crust, and formed the uranium ore zone around the Shinbo mine.

• Journal of the Korean Society of Groundwater Environment
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• v.6 no.4
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• pp.194-205
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• 1999

Hydrogeochemical variation and environmental isotope at the some abandoned metal mine (Sanggok, Keumsil, Jangpung and Samdeok) creeks of the Hwanggangri mining district were carried out based upon the physicochemical properties for surface water collected of February in 1998. Hydrogeochemical composition of the all water samples are characterized by the relatively significant enrichment of Ca$^{2}$, alkaline ions, N $O_3$$^{－}$ and Cl$^{－}$ in normal surface water, whereas the surface waters near the mining area are relatively enriched in Ca$^{2+$, Mg$^{2＋}$, heavy metals. HC $O_3$$^{－}$ and S $O_4$$^{2－}$. Surface waters of the mining creek have low pH, high EC and extremely high concentrations of TDS compared with surface water of the non-mining creeks. The range of $\delta$D and $\delta$$^{18}$O values (SMOW) in the waters are shown in －65.0 to－71.2$\textperthousand$ and －9.1 to－10.2$\textperthousand$. The d($\delta$D－$\delta$$^{18}$O) value with those of water samples ranged from 7.3 to 10.9. These $\delta$D and $\delta$$^{18/}$ of the acid mine water are more heavy values than those of surface water. The values have revealed the positive correlation between isotopic compositions and major elements, because those $\delta$D and $\delta$$^{18}$O values increase with increasing TDS. HC $O_3$$^{－}$ , S $O_4$$^{2－}$ and Ca$^{2＋}$ concentration. Using WATEQ4F, saturation index of albite calcite, dolomite and mostly clay minerals in water of the mining area show undersaturated and progressively evolved toward the equilibrium condition due to fresh water mixing, however, surface waters of the non-mining area are nearly saturated and/or supersaturated. Geochemical modeling showed that mostly toxic heavy metals within water in the mining creek may exist largely in the from of metal-sulfate (MS $O_4$$^{2－}$), free metal (M$^{2＋}$/), C $O_3$$^{－}$ and/or OH$^{－}$ complex ions. Based on the geology, water chemistry and environmental istopic data the water compositions from the Sanggok and Keumsil mine creek (consist mainly of Cambro-Ordovician carbonate rocks of the Cho-seon Supergroup) show higher PH, Ca$^{2＋}$, Mg$^{2＋}$ , HC $O_3$$^{－}$ and more heavy $\delta$D and $\delta$$^{18}$O values than those from the Jangpung and Samdeok mine creek (consist of age -unknown metasedimentary rocks of the Ogcheon Supergroup and/or Jurassic grani-toids), but each of these waters represents a similar hydrogeochemical evolution path by the mine water mixing.

• Economic and Environmental Geology
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• v.20 no.1
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• pp.35-60
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• 1987

The geochemical characteristics including minerals, major and trace elements chemistries of the Proterozoic, Jurassic and Cretaceous granites in Korea are systematically summarized and intended to decipher the origin and crystallization process in connection with the tectonic evolution. The granites in Korea are classified into three different ages of the granites with their own distinctive geochemical patterns: 1) Proterozoic granitoids; 2) Jurassic granites(cratonic and mobile belt); 3) Cretaceous-Tertiary granites. The Proterozoic granite gneisses (I-type and ilmenite-series) formed by metamorphism of the geochemically evolved granite protolith. The Proterozoic granites (S-type and ilmenite-series) produced by remobilization of sialic crust. The Jurassic granites (S-type and ilmenite-series) were mainly formed by partial melting of crustal materials, possibly metasedimentary rocks. The Cretaceous granites (I-type and magnetite-series) formed by fractional crystallization of parental magmas from the igneous protolith in the lower crust or upper mantle. The low temperature ($315{\sim}430^{\circ}C$) and small temperature variations (${\pm}20{\sim}30^{\circ}C$) in the cessation of exsolution of perthites for the Proterozoic and Jurassic granites might have been caused by slow cooling of the granites under regional metamorphic regime. The high ($520^{\circ}C$) and large temperature variations (${\pm}110^{\circ}C$) of perthites for the Cretaceous granites postulate that the rapid cooling of the granitic magma. In terms of the oxygen fugacity during the feldspar crystallization in the granite magmas, the Jurassic mobile belt granites were crystallized in the lowest oxygen fugacity condition among the Korean granites, whereas the Cretaceous granites in the Gyeongsang basin at the high oxygen fugacity condition. The Jurassic mobile belt granites are located at the Ogcheon Fold Belt, resulting by closing-collision situation such as compressional tectonic setting, and emplaced into a Kata-Mesozonal ductile crust. The Jurassic cratonic granites might be more evolved either during intrusion through thick crust or owing to lower degree of partial melting in comparison with the mobile belt granites. The Cretaceous granites are possibly comparable with a continental margin of Andinotype. Subduction of the Kula-Pacific ridge provided sufficient heat and water to trigger remelting at various subcrustal and lower crustal igneous protoliths.