• 제목/요약/키워드: Off-gas

검색결과 898건 처리시간 0.025초

흑연 씰의 비마모율 예측에 관한 수학적 모델 개발 (Development of Mathematical Model to Predict Specific Wear Rates of Graphite Seal)

  • 김연욱;김재훈;박성한;이환규;김범근;이성범;곽재수
    • 한국추진공학회지
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    • 제18권4호
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    • pp.67-73
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    • 2014
  • 고온고압의 밸브에서 연소가스의 유입을 방지하는 흑연 씰은 밸브 축의 구동으로 인한 마찰 및 마모에 노출된다. 흑연 씰의 마모로 인해 고온 가스 제어가 불가능해지기 때문에 씰의 마모 특성을 예측하는 것은 매우 중요하다. 본 논문은 비마모율을 마모 특성에 대한 척도로 설정하고 접촉하중, 미끄럼 속도, 온도 등을 변수로 하여 흑연의 왕복동 마모 시험을 수행하였다. 반응표면분석법에 근거하여 실험계획을 정립하고 시험 결과에 대하여 분산분석법을 통하여 유효한 수학적 모델을 제시하였다. 또한, 마모된 표면의 SEM 분석을 통해 특정 조건에서의 마모 메커니즘을 분석하고 비교하였다.

Etch Characteristics of $SiO_2$ by using Pulse-Time Modulation in the Dual-Frequency Capacitive Coupled Plasma

  • 전민환;강세구;박종윤;염근영
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.472-472
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    • 2011
  • The capacitive coupled plasma (CCP) has been extensively used in the semiconductor industry because it has not only good uniformity, but also low electron temperature. But CCP source has some problems, such as difficulty in varying the ion bombardment energy separately, low plasma density, and high processing pressure, etc. In this reason, dual frequency CCP has been investigated with a separate substrate biasing to control the plasma parameters and to obtain high etch rate with high etch selectivity. Especially, in this study, we studied on the etching of $SiO_2$ by using the pulse-time modulation in the dual-frequency CCP source composed of 60 MHz/ 2 MHz rf power. By using the combination of high /low rf powers, the differences in the gas dissociation, plasma density, and etch characteristics were investigated. Also, as the size of the semiconductor device is decreased to nano-scale, the etching of contact hole which has nano-scale higher aspect ratio is required. For the nano-scale contact hole etching by using continuous plasma, several etch problems such as bowing, sidewall taper, twist, mask faceting, erosion, distortions etc. occurs. To resolve these problems, etching in low process pressure, more sidewall passivation by using fluorocarbon-based plasma with high carbon ratio, low temperature processing, charge effect breaking, power modulation are needed. Therefore, in this study, to resolve these problems, we used the pulse-time modulated dual-frequency CCP system. Pulse plasma is generated by periodical turning the RF power On and Off state. We measured the etch rate, etch selectivity and etch profile by using a step profilometer and SEM. Also the X-ray photoelectron spectroscopic analysis on the surfaces etched by different duty ratio conditions correlate with the results above.

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TMCP강을 적용한 해상용 풍력타워의 용접 공정에 따른 기계적 물성 평가 (Evaluation on Mechanical Properties with Welding Processes for Off Shore Wind Tower Application)

  • 지창욱;최철영;남대근;김형찬;장재호;김기혁;박영도
    • Journal of Welding and Joining
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    • 제32권1호
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    • pp.15-21
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    • 2014
  • FCAW(Flux Cored Arc Welding), SAW(Submerged Arc Welding), EGW(Electro Gas Welding), and three-pole SAW are applicable in manufacturing the offshore wind tower. In this paper, mechanical properties of these welded-joints for TMCP steels were evaluated in all above welding processes. The tensile strength of welded-joints for all the welding methods satisfied the standard guideline (KS D 3515). No cracking on weldment was found after the bending test. Changes of weldedments hardness with welding processes were observed. In a weld HAZ (heat-affected zone), a softened HAZ-zone was formed with high heat input welding processes (SAW and EGW). However, the welded-joint fractures were found in the base metal for all cases and small decrease in welded-joint strength was caused by a softened zone. The multi-pole SAW welds exhibited similar mechanical properties comparing to the one with one-pole SAW process.

Evaluating the Headspace Volatolome, Primary Metabolites, and Aroma Characteristics of Koji Fermented with Bacillus amyloliquefaciens and Aspergillus oryzae

  • Seo, Han Sol;Lee, Sunmin;Singh, Digar;Park, Min Kyung;Kim, Young-Suk;Shin, Hye Won;Cho, Sun A;Lee, Choong Hwan
    • Journal of Microbiology and Biotechnology
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    • 제28권8호
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    • pp.1260-1269
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    • 2018
  • Production of good Koji primarily depends upon the selection of substrate materials and fermentative microflora, which together influence the characteristic flavor and aroma. Herein, we performed comparative metabolomic analyses of volatile organic compounds (VOCs) and primary metabolites for Koji samples fermented individually with Bacillus amyloliquefaciens and Aspergillus oryzae. The VOCs and primary metabolites were analyzed using headspace solid phase microextraction (HS-SPME) followed by gas chromatography time-of-flight mass spectrometry (GC-TOF-MS). In particular, alcohols, ketones, and furans were mainly detected in Bacillus-fermented Koji (Bacillus Koji, BK), potentially due to the increased levels of lipid oxidation. A cheesy and rancid flavor was characteristic of Bacillus Koji, which is attributable to high content of typical 'off-flavor' compounds. Furthermore, the umami taste engendered by 2-methoxyphenol, (E,E)-2,4-decadienal, and glutamic acid was primarily detected in Bacillus Koji. Alternatively, malty flavor compounds (2-methylpropanal, 2-methylbutanal, 3-methylbutanal) and sweet flavor compounds (monosaccharides and maltol) were relatively abundant in Aspergillus-fermented Koji (Aspergillus Koji, AK). Hence, we argue that the VOC profile of Koji is largely determined by the rational choice of inocula, which modifies the primary metabolomes in Koji substrates, potentially shaping its volatolome as well as the aroma characteristics.

국산 버터 중의 유리지방산에 관한 연구 (Studies on the Free Fatty Acids of Domestic Butter)

  • 송근섭;권용주;양희천;이태규
    • 한국식품과학회지
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    • 제22권5호
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    • pp.526-529
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    • 1990
  • 국내에서 생산되고 있는 버터의 유리지방산 조성을 분석하기 위하여 silicic acid column chromatography 방법을 이용하여 버터로부터 직접 유리지방산을 분리 용출시켜 농축한 후 GLC로 분석하였다. 국산 버터 2종류 제품을 분석한 결과, 버터 A의 유리지방산 조성에 있어서는 $C_{18}$ 유리지방산$(C_{18_0},\;C_{18:1},\;C_{18:2}\;및\;C_{18:3})$ 함량이 52.83%로 가장 높았고, 그 다음으로 palmitic acid가 29.39%, myristic acid가 11.85% 함유되어 있었으며, 버터 B의 경우에는 $C_{18}$ 유리지방산이 47.50%, palmitic acid가 30.52%, myristic acid가 13.76% 함유되어 있었고, 그 외의 유리지방산은 소량씩 함유되어 있었다. 한편 함량면에서는 적지만 버터의 풍미에 중요한 영향을 미치는 것으로 알려진 butyric, caproic, capric 및 lauric acid의 농도를 분석한 결과, 버터 A에서는 각각 35, 10, 48, 60ppm, 버터 B에서는 각각 56, 11, 70, 126ppm이었다.

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국내 일반공항에서 항공기에 의한 대기오염물질과 온실가스의 배출량 산정 및 특성 분석 (Emissions of Air Pollutants and Greenhouse Gases from Aircraft Activities at the Small Scale Airports)

  • 손장호;송상근;윤태경;이강춘
    • 한국환경과학회지
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    • 제22권7호
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    • pp.823-836
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    • 2013
  • Emissions of air pollutants and greenhouse gases (GHGs) from aircraft activities at 11 small-scale airports were investigated using the emissions and dispersion modeling system (EDMS) version 5.1.3 during the two year period of 2009~2010. The number of landing and take-off (LTO) at these airports was dominant for the aircraft type B737, accounting for more than 60% of the total LTOs. Out of the 11 small-scale airports, Gwangju (GJ, RKJJ) airport was the largest emitter of air pollutants and GHGs, whereas Yangyang (YY, RKNY) airport was the smallest emitter. The emissions of $NO_x$ and VOCs in 2010 at the 11 airports ranged from 1.9 to 83 ton/y and 0.1 to 17 ton/y, respectively. In 2010, the emissions of $CO_2$ ranged from 394 to 21,217 ton/y. The emissions of most air pollutants (except for $NO_x$ and $PM_{10}$) and GHGs were estimated to be the highest in taxi-out mode. The highest emissions of $NO_x$ and $PM_{10}$ were emitted from climb-out and approach modes, respectively. In addition, the total LTOs at the 11 small-scale airports accounted for the range of 9.3~9.9% of those at four major international airports in Korea. The total emissions of air pollutants and GHGs at the 11 airports ranged from 4.8 to 12% of those at the four major airports.

고온용 연료전지 미반응 가스를 이용한 촉매연소-개질 통합 반응기의 성능 비교 (Performance Comparison of Integrated Reactor with Steam Reforming and Catalytic Combustion using Anode Off-Gas for High Temperature Fuel Cells)

  • 강태규;성해정;이상민;안국영;김용모
    • 한국수소및신에너지학회논문집
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    • 제22권6호
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    • pp.800-809
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    • 2011
  • The reaction characteristics of an integrated reactor with steam reformer and catalytic combustor using anode offgas for high temperature fuel cells such as MCFC and SOFC have been experimentally investigated in the present study. The coupled reactor had a coaxial cylindrical shape, and the inner and the outer tube was packed with combustion catalysts and reforming catalysts, respectively. Thus, the endothermic steam reforming could proceed by absorbing heat from catalytic combustion of anode offgas. Results show that increasing inlet temperature and decreasing excess air ratio increased the reformer temperature, which led to the increase in $H_2$ yield. The reforming performance for SOFC conditions was better than that for MCFC conditions since the composition of flammable components became smaller for MCFC cases. Measured reformate composition under various test conditions correlated well with thermal equilibrium composition.

무인항공기용 150W급 연료전지 동력원 개발 및 실증 (Development and Demonstration of 150W Fuel Cell Propulsion System for Unmanned Aerial Vehicle (UAV))

  • 양철남;김양도
    • 한국수소및신에너지학회논문집
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    • 제23권4호
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    • pp.300-309
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    • 2012
  • Long endurance is a key issue in the application of unmanned aerial vehicles. This study presents feasibility test results when fuel cell system as an alternative to the conventional engine is applied for the power of the UAV after the 150W fuel cell system is developed and packaged to the 1/4 scale super cub airplane. Fuel cell system is operated by dead-end method in the anode part and periodically purged to remove the water droplet in flow field during the operation. Oxygen in the air is supplied to the stack by the two air blowers. And fuel cell stack is water cooled by cooling circuit to dissipate the heat generated during the fuel cell operation. Weight balance is considered to integrate the stack and balance of plant (BOP) in package layout. In flight performance test, we demonstrated 4 times standalone take-off and landing. In the laboratory test simulating the flight condition to quantify the energy flow, the system is analyzed in detail. Sankey diagram shows that electric efficiency of the fuel cell system is 39.2%, heat loss 50.1%, parasitic loss 8.96%, and unreacted purged gas 1.67%, respectively compared to the total hydrogen input energy. Feasibility test results show that fuel cell system is high efficient and appropriate for the power of UAV.

시동/정지 반복에 의한 데드엔드형 고분자전해질 연료전지의 성능 감소 (Performance Degradation of Dead-end Type PEMFC by Startup and Shutdown Cycles)

  • 정재현;정재진;송명현;정회범;나일채;이호;박권필
    • Korean Chemical Engineering Research
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    • 제51권5호
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    • pp.540-544
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    • 2013
  • 고분자전해질연료전지(PEMFC)는 시동/정지과정에서 성능과 수명이 감소한다. 본 연구에서는 캐소드가스로 산소를 사용하는 데드엔드 형 PEMFC의 시동/정지 과정의 영향을 분극곡선, 임피던스(EIS), SEM과 TEM을 사용해 연구하였다. 시동/정지 과정에서 PEMFC 성능감소를 막기 위해서는 더미 로드를 사용해야 함을 보였다. 시동/정지 반복과정 중 50% 상대습도(RH)에서 캐소드 카본지지체의 부식에 의한 열화가 100% RH보다 심했다. 데드엔드 형 PEMFC의 정지과정에서 PEMFC에 물을 공급해줌으로써 50% RH에서 열화속도를 감소시켰다.

남면지역(南面地域) 농어촌(農魚村) 현대화(現代化) 시범학교(始範學校) 종합시설(宗合施設) 기본계획(基本計劃) 연구(硏究) (A Study on the Architectural Design for Nammyun Rural Pilot School Project)

  • 임창복;최병관;박영숙
    • 교육시설
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    • 제6권2호
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    • pp.24-40
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    • 1999
  • The purpose of this study is planning a representative model of a modernized school with rearrangement of existing two primary schools(Nammyun and Namjin) and a middle school(Seonam) in Nammyun distric. Nammyun district, which is adjacent to Tae-an national ocean park, is the Place where gas a natural advantage. However, in the result of the rural exodus follwed by industrialization, the population in this province are decreased rapidly and it still be on the process of the rural exodus. Hence, the total number of students, each school is under 100 at the moment and the number will be less in the future. Under this consequences, the rearrangement of these school is inevitable. For the new modernized school plan Narnmyun district, estimate the scale of school on the basis of decreased number of students, the analysis the 7th education plan and the questionnaire and face-to-face interview investigation, which is a resident-orented investigation, were carried out preferentially. The major research contents are as follows; o Expansion of schools facility and space for operating the 7th education plan(classified level schools level and subject-based class school plan) o Over-all improvement of educational environment to take all-out advantages of school, social and home education. o The school which can take a part of an educational center of a rural community in schools off-time-after school and summer and winter vocation. o The school which is related to the local cultural, sports and entertainment utility, On the basis of this research, the basic concept and purpose of a new school model model plan in Nammyun will be established and the new school plan represented for the result of this research.

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