• 제목/요약/키워드: Odor threshold

검색결과 53건 처리시간 0.023초

악취기여도평가를 이용한 악취원인물질 연구 - 오창과학산업단지를 중심으로 - (A Study on the Odor Compounds Emitted using Odor Contribution Analysis - Focus on the Ochang Scientific Industrial Complex Area -)

  • 정지선;김덕철;이한철;연승원;연익준
    • 한국환경과학회지
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    • 제25권9호
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    • pp.1329-1339
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    • 2016
  • The purpose of this study was to obtain the basic data needed to identify the impact of the odor, emitted from the Ochang Scientific Industrial Complex area on the surrounding residential areas by measuring and confirming odor compounds. The analysis showed that complex odors were diluted from around 4 to 1. The offensive odor measurement results showed that among the sites, site 1 was highest in sulfur compounds, site 2 was highest in toluene, site 3 was highest in trimethylamine, and site 4 was highest in buthylaldehyde. It cannot be decided to be odor-causing compounds for higher odor concentration because each odor substance has a different odor threshold value. According to the odor contribution analysis for each site, site 1, site 2, and site 4 contained high buthylaldehyde concentrations, and site 3 had a high level of trimethylamine. It could be determined that highly evaluated substances were main causes to result in substance for each site.

Piggery Slurry Composting Using Batch Operating Autothermal Thermophilic Aerobic Digestion System

  • Ahn, Hee K.;Choi, Hong L.
    • Asian-Australasian Journal of Animal Sciences
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    • 제19권2호
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    • pp.273-279
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    • 2006
  • The performance of an autothermal thermophilic aerobic digestion (ATAD) system was studied to determine if nitrogen loss, as ammonia, was affected by an exhaust gas condenser. The system was run with and without a condenser while treating $8m^3$ of piggery slurry for 8 days. The system with a condenser (SWC) maintained the reactor temperatures above $40^{\circ}C$ for 2 days during the 8 days run, while the system without a condenser (SWOC) remained above $40^{\circ}C$ for 6 days. The SWC maintained the reactor temperatures mostly at mesophilic conditions while the SWOC at thermophilc conditions. Differences in operation conditions for the two runs were mainly caused by differences in atmospheric temperatures. Soluble chemical oxygen demand (SCOD) and volatile solids (VS) removal efficiencies of the SWC (SCOD: 62%, VS: 41%) were higher than those of the SWOC (SCOD: 40%, VS: 20%). The total Kjeldal nitrogen (TKN) removal efficiency of the SWC (7%) was less than that of the SWOC (25%). The concentration of total volatile fatty acids (VFA) in the SWC was observed to be lower than the threshold value of 0.23 g total VFA/L after 6 days, while the SWOC progressed below the threshold value after 3 days. No offensive odor emissions were observed in either run, which suggest that the use of the ATAD system may be a good odor removal strategy.

생활폐기물 자동집하시설의 악취물질 배출특성 (Emission Characteristics of Odor Compounds from Pneumatic Waste Collection Plants)

  • 윤용경;김대근
    • 대한환경공학회지
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    • 제34권8호
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    • pp.541-548
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    • 2012
  • 본 연구에서는 생활폐기물 자동집하시설에서의 악취물질 배출특성을 파악하고자 2개소(A시설, B시설)의 시설을 선정하여 공기관로 내의 이송가스와 최종배출가스를 대상으로 복합악취와 22종의 지정악취물질을 조사하였다. 생활폐기물 자동집하시설에서 배출되는 주된 악취물질은 암모니아, 황 화합물, 아세트알데하이드이었으며, 악취처리공정의 종류에 따라 최종배출구의 악취 배출특성이 상이하였다. 이송가스를 대상으로 한 악취기여도 평가에서는 A시설의 경우, 디메틸설파이드 26%, 아세트알데하이드 18%, 메틸머캅탄 14%의 악취기여도를 보였으며, B시설의 경우에는 메틸머캅탄 56%, 황화수소와 디메틸설파이드가 각각 15%이었다.

반월.시화공단 주변 주거지역의 악취현황 및 황화합물의 체감도 (The Concentrations of Sulfur Compounds and Sensation of Odor in the Residential Area Around Banwol-Sihwa Industrial Complex)

  • 김종보;정상진;송일석
    • 한국대기환경학회지
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    • 제23권2호
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    • pp.147-157
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    • 2007
  • This study was carried out to investigate the characteristics of fourteen odor compounds from a total of 10 sampling sites in residential areas around Banwol-Sihwa industrial complex. The measurement data are analyzed and compared with sensation of odor unit. Only a hydrogen sulfide out of four sulfur compounds was quantified above the detection limit (0.06 ppb) in the residential area around Banwol industrial complex with leather companies and a sewage treatment plant. The concentrations of VOCs were higher than those measured from a big city, and styrene showed the relatively high concentration from all sampling sites ($2.1{\sim}37.8\;ppb$). In the case of carbonyl compounds, acetaldehyde was found most frequently with the mean of 3.97 ppb, and its concentration difference was not significant between Banwol and Sihwa industrial complex. Of the nitrogen compounds, ammonia was measured at the relatively high concentration from all the sampling sites ($12{\sim}707\;ppb$), and a trimethylamine was found at the odor threshold level (0.1 ppb). The concentrations of styrene and ammonia showed relatively seasonal variation, the concentration of styrene in summer was five times higher than that in autumn, the concentration of ammonia in autumn was two times higher than that in summer. However other odorous compounds did not show such strong seasonal variation. Odor-concentration relationship between odor unit and $H_{2}S$ concentrations from industrial sources was examined and used as odor sensation evaluation, and thus the neighbourhood odor complaints maybe caused during the four seasons from the results.

수종 생약 수증기 증류물의 탈취작용 (Deodorizing Responses of the Steam Distillate from Some Medicinal Plants)

  • 신국현;이은방;송영진;김운자
    • 생약학회지
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    • 제23권3호
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    • pp.153-157
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    • 1992
  • The deodorizing responses of the steam distillate from some medicinal plants(G-3) on three representative malodors were evaluated by estimating the best estimate threshold(BET) of odor responses. With a single spray of G-3, the BETs of malodors such as ammonia, acetic acid, and ethyl acetate were found to increase 4.11, 32.6 and 13.1 fold, respectively, which indicated G-3 possessed a potent deodorizing activity. The deodorizing potency of G-3 was also demonstrated to be as high as and even higher than those of the commercial deodorizing agents.

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제지슬러지 발산악취의 화학적 제거 방법에 관한 연구 (A Study on the Chemical Odor Reduction Methodology of Paper-mill Sludge)

  • 노태목;김학민;이승현;김선태
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.217-218
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    • 1999
  • 최근 들어 경제의 발전과 생활수준이 향상됨에 따라 악취는 소음과 함께 환경분야에 많은 민원을 야기하고 대기오염물질의 하나로 인식되고 있다. 특히 유황계 화합물을 대표하는 악취물질인 황화수소는 무색의 기체로써 부패한 계란 냄새가 나고 역치농도(Threshold Odor Value)가 0.00047ppm$_{v}$ 로 매우 낮은 농도에서도 취기를 감지할 수 있는 것으로 알려져 있다. 이러한 성질을 갖는 황화수소는 석유 화학공업이나 제지공업, 폐수처리장 그리고 폐기물 처리장 등에서 많이 발생하고 있다.(중략)

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약주(藥酒) 향기성분(香氣成分)의 역치와 쾌감도(快感度) (Odor Threshold and Agreeability of Aroma Components of Yakju)

  • 정지흔;정순택
    • Applied Biological Chemistry
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    • 제30권3호
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    • pp.272-277
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    • 1987
  • 약주(藥酒)의 향기성분(香氣成分)인 formaldehyde, acetaldehyde, ethyl acetate, acetone, diacetyl, n-propanol, iso-butanol, iso-amyl alcohol, dimethylsulfide, ethanol의 역치를 유사(類似) 약주(藥酒)와 18% ethanol 액(液) 및 $20^{\circ}C$$50^{\circ}C$의 증류수중에서 측정(測定)하고 이들 성분(成分)의 각농도(各濃度)에서의 쾌감도(快感度)를 측정(測定)하였다. 유사약주(類似藥酒)에서의 역치는 각각 5,20,30,7,0.2,20,80,10,2ppm 및 5g/l이었으며 $20^{\circ}C$ 증류수중에서의 역치는 각각(各各) 5,10,20,7,0.15,75,7.5,2ppm 및 5g/l 이었고 iso-amyl alcohol은 $80{\sim}350ppm$에서 최고 쾌감(快感)을 나타낸 후 520ppm 이상에선 불쾌감(不快感)을 나타냈다. Ethanol은 $10^5ppm$, n-propanol은 50ppm까지는 쾌감(快感)을 나타냈으며 iso-butanol은 220ppm, diacetyl은 1ppm을 초과하면 불쾌감(不快感)을 나타냈으며 iso-butanol은 260ppm 초과의 경우 극도의 불쾌감(不快感)을 나타냈다. Ethyl acetate는 함량(含量)이 증가함에 따라 쾌감(快感)이 좋았으나 250ppm이 초과하면 쾌감(快感)이 감소(感少)하는 경향이었으며 acetaldehyde는 110ppm에서 최고(最高) 쾌감(快感)을 보였다.

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하수관거에 퇴적된 유기물에 의한 악취 발생과 산화전리시스템을 이용한 악취 저감 (Odor Emission from Sediments in Sewer Systems and Odor Removal using an Electrolytic Oxidation Process)

  • 안해영;신승규;송지현
    • 한국대기환경학회지
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    • 제27권6호
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    • pp.703-710
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    • 2011
  • Odor emission from domestic sewer systems has become a serious environmental problem. An investigation on a sewer manhole revealed that anaerobic decay of sediment organic matters (SOMs) and related declines of oxidation reduction potential (ORP) in the sediment layer were the main reason of the production of volatile sulfur compounds. In addition, as the anaerobic decaying period continued, the odor intensity rapidly increased with increasing concentrations of $H_2S$ and dimethyl sulfide. As a feasible method to control SOMs and to minimize odor emission potentials, an electrolytic oxidation process has been employed to the sediment sludge phase. In this study, voltages applied to the electrolytic oxidation process were varied as a main system parameter, and its effects on odor removal efficiencies and reaction characteristics were investigated. At the applied voltages greater than 20 V, the system efficiently oxidized the organic matter, and the ORP in the sludge phase increased rapidly. As a consequence, the removal efficiency of hydrogen sulfide was found to be >99% within 60 minutes of the electrolytic oxidation. Overall, the electrolytic oxidation process can be an alternative to control odor emission from sewer systems, and a threshold input energy needs to be determined to achieve effective operation of the process.

부영양호 원수의 냄새유발 물질 탈기 특성 (Air stripping of odor causing materials from eutrophic lake water)

  • 박노백;송용효;나광주;박상민;전항배
    • 상하수도학회지
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    • 제22권5호
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    • pp.523-529
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    • 2008
  • Algal blooms in a local eutrophic lake often produces the musty and earthy taste & odor problems. Since the odor causing compounds(OCCs) including geosmin and 2-MIB have their own volatility, the OCCs can be removed from water by air stripping methods. Removal of TON(threshold odor number) as an index for OCCs could be fitted well with the first order equations($R^2=0.9$ above), where the air stripping coefficient of TON, k was in the range between 0.0055 and 0.0097 according to the aeration time. k within 30min aeration tests was 0.0097, while it was 0.0055 where the aeration time extended to 150min. With 15 mg/L of PAC, removal of TON was not simulated with 1st order equation within 30min aeration. Within 30min aeration, OCCs rather than geosmin and/or 2-MIB could be removed easily by air stripping or PAC adsorption, while OCCs such as geosmin and/or 2-MIB could be removed slowly by air stripping after 30min aeration. Geosmin and 2-MIB were not readily removed by air stripping(k of them were 0.0018~0.0047 and 0.0018~0.0034, respectively at different air flow rates). Geosmin could be removed by air stripping a little better than 2-MIB.

GC/FPD에 의한 대기 중 황화합물 농도분포에 관한 연구 (A Study on the Distribution of Atmospheric Concentrations of Sulfur Compounds by GC/FPD)

  • 양성봉;유미선;황희찬
    • 분석과학
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    • 제16권3호
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    • pp.240-248
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    • 2003
  • 공업지역에서 악취원인물질로 잘 알려진 황화물은 매우 낮은 최소 후각감지농도를 나타낸다. 여러 악취발생원 주변의 대기 중 미량의 황화합물을 아르곤에서 농축시켜 선택성과 감도가 우수한 불꽃 광도 검출기 (FPD)가 장착된 가스크로마토그래프를 이용하여 측정하였다. 25% ${\beta}$,${\beta}$-Oxydipropionitrile, 60/80 Chromosob W가 저온농축을 위한 흡착제로 되었으며 이를 충전 유리컬럼의 충전제로도 사용하였다. 악취시료의 농축량은 0.1~3.0L 범위에서 채취장소에 따라 달리하였다. 주거지역과 사업장 부지경계선상에서의 공기 및 하수처리장과 같은 공업지역 내 사업장의 배출구 가스 중의 휘발성 황화합물의 농도를 측정하였다.