• KSBB Journal
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• v.27 no.1
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• pp.61-66
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• 2012

In the screening process of organic solvent tolerant bacteria showing good growth in media containing several kinds of organic solvents, one strain was isolated and identified as Bacillus sp. BCNU 5006. The strain was able to tolerate many organic solvents including benzene, toluene, xylene, octane, dodecane, butanol and ethylbenzene. Likewise, it could also utilize these solvents as the sole source of carbon with significant enzyme production. The lipolytic enzyme stability of Bacillus sp. BCNU 5006 was studied in the presence of several kinds of solvents at a 25% (v/v) concentration. The highest enzyme stability was observed in the presence of octane (107%), followed by ethylbenzene (88%), decane (86%), and chloroform (85%). Especially, BCNU 5006 lipase was determined to be more stable than immobilized enzyme (Novozyme 435) in the presence of octane, chloroform and xylene. This organic solvent tolerant Bacillus sp. BCNU 5006 could be expected as a potential bioremediation agent and biocatalyst for biodegradation and provide on organic-solvent-based enzymatic synthetic method in industrial chemical processes.

• Membrane and Water Treatment
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• v.10 no.5
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• pp.361-372
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• 2019

Effect of different alkane based solvents on the stability of emulsion liquid membrane was investigated using normal alkanes (n-hexane, n-heptane, n-octane and n-decane) under various operating parameters of surfactant concentration, emulsification time, internal phase concentration, volume ratio of internal phase to organic phase, volume ratio of emulsion phase to external phase and stirring speed. Results of stability revealed that emulsion liquid membrane containing n-octane as solvent and span-80 (5 % (w/w)) as emulsifying agent presented the highest amount of emulsion stability (the lowest breakage) compared with other solvents; however, operating parameters (surfactant concentration (5% (w/w)), emulsification time (6 min), internal phase concentration (0.05 M), volume ratio of internal phase to organic phase (1/1), volume ratio of emulsion phase to external phase (1/5) and stirring speed (300 rpm)) were also influential on improving the stability (about 0.2% breakage) and on achieving the most stable emulsion. The membrane with the highest stability was employed to extract acridine orange with various concentrations (10, 20 and 40 ppm) from water. The emulsion liquid membrane prepared with n-octane as the best solvent almost removed 99.5% of acridine orange from water. Also, the prepared liquid membrane eliminated completely (100%) other cationic dyes (methylene blue, methyl violet and crystal violet) from water demonstrating the efficacy of prepared emulsion liquid membrane in treatment of dye polluted waters.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.291-300
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• 2008

Catalytic cracking of n-octane was carried out over H-ZSM-5 zeolite catalysts after calcination with air and steaming with 100% steam in the temperature range of $550-750^{\circ}C$ for 24 h and compared with the results of thermal cracking. The increase of calcination and steaming temperature resulted in the decrease of surface area, pore volume, and strong acid sites, which was mainly caused by the dealumination of H-ZSM-5 framework. It was found by $^{27}Al$ and $^{29}Si$ MAS NMR that the dealumination was proceeded through the transformation process of tetrahedral framework Al${\rightarrow}$penta-cordinated Al ${\rightarrow}$ octahedral framework Al and the phenomena was much more severe in steaming conditions than that of calcination. In the catalytic cracking of n-octane, as the temperatures of calcination and steaming were increased, the conversion of n-octane, the selectivity of light olefins and ethylene to propylene ratio were decreased due to the dealumination of framework aluminum resulting the loss of acidic strengths. The conversion, selectivity of light olefins and ethylene to propylene ratio reached almost to the level of thermal cracking after steaming at $750^{\circ}C$ for 24 h.

• Fire Science and Engineering
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• v.25 no.3
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• pp.113-118
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• 2011

The flash point is an important indicator of the flammability of a chemical. The minimum flash point behaviour (MFPB) is exhibited when the flash point of a mixture is below the flash points of the individual components. The identification of this behaviour is critical, because a hazardous situation results from taking the lowest component flash point value as the mixture flash point. In this study, the flash points for the n-butanol + n-decane and n-octane + n-propanol systems which exhibit MFPB, were measured by Tag open-cup apparatus. The experimental data were compared with the alues calculated by the Raoult's law, the van Laar equation and the Wilson equation. The calculated values based on the van Laar and Wilson equations were found to be better than those based on the Raoult's law. It was concluded that the van Laar and Wilson equations were more effective than the Raoult' law at describing the activity coefficients for non-ideal solution such as the n-butanol + n-decane and n-octane + n-propanol systems. The predictive curve of the flash point prediction model based on the Wilson equation described the experimentally-derived data more effectively than was the case when the prediction model was based upon the van Laar equation.

• Bulletin of the Korean Chemical Society
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• v.17 no.11
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• pp.980-981
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• 1996

• Bulletin of the Korean Chemical Society
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• v.14 no.3
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• pp.324-325
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• 1993

• Journal of Mechanical Science and Technology
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• v.20 no.9
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• pp.1449-1458
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• 2006

Controlled Auto-ignition (CAI) combustion processes can be broadly divided between a CAI process that is applied to four-cycle engines and a CAI process that is applied to two-cycle engines. The former process is generally referred to as Homogeneous Charge Compression Ignition (HCCI) combustion and the later process as Active Thermo-Atmosphere Combustion (ATAC) The region of stable engine operation differs greatly between these two processes, and it is thought that the elucidation of their differences and similarities could provide useful information for expanding the operation region of HCCI combustion. In this research, the same two-cycle engine was operated under both the ATAC and HCCI combustion processes to compare their respective combustion characteristics. The results indicated that the ignition timing was less likely to change in the ATAC process in relation to changes in the fuel octane number than it was in the HCCI combustion process.

• Journal of the Korean Applied Science and Technology
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• v.28 no.3
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• pp.374-378
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• 2011

The studied results of the gasohol, which is the mixture of gasoline and ethanol, were investigated for the promotion of applications on commercially by gasoline vehicle referring to octane number, minimum water contents be involved, and separation inhibitors for protecting phase separation etc. especially for the E10 and E20. The results showed that octane number will be revised by higher value as the ethanol is added more, and it's more effect in case of be added as a mixture than individually when inhibition agents is added for the inhibition of separation. and it's reasonable for the water contents of less than 1% by comparing with experimental results and in view of regulations of various countries.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.109.1-109.1
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• 2011

This study is a part of the project that investigates a possibility of using methyl/ethyl butyrate as an alternative material of MTBE. To investigate characteristics of the two materials, a 2.0L 4-cylinders SI engine that was coupled to an 160kw EC engine dynamometer was used and operated several conditions. Two exhaust gas analyzer was used to measure CO, NOx and THC of after and before of a catalyst. Also, to compare combustion characteristics of the fuels a combustion analyzer was used for measuring pressure of inside of a cylinder. The results show no special difference between MTBE and the two materials from the emission and combustion characteristics aspect.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2126-2130
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• 2008

Gasoline engine have proved its utility in light, medium and heavy duty vehicle in every sector of the world community. The concern about long term availability of petroleum and the increasing threat for the environment by the increasing load of vehicular emission, compel the technology to upgrade itself for meeting the challenges. CNG is environmentally clean alternative to the existing SI Engines with out much change in the hardware. Many researchers have found this as a potential substitute to meet the energy requirement. Higher octane number and higher self ignition temperature make it a good gaseous fuel. Although power output is slightly lesser than the gasoline it's thermal efficiency is better than the gasoline for the same SI Engine. Results showed that reduced CO, hydrocarbon emissions is a favorable outcome, with slight increase in $NO_x$ emission when compared with gasoline fuel to dual fuel mode in the existing SI Engines.