• Geosciences Journal
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• v.22 no.6
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• pp.881-889
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• 2018

The Geodo skarn deposit is located in the Taebaeksan Basin, central eastern Korean Peninsula. The geology of the deposit consists of Cambrian to Ordovician calcareous sedimentary rocks and the Cretaceous Eopyeong granitoids. The skarns at Geodo occur around the Eopyeong granitoids, which consist, from early to late, of magnetite-bearing equigranular quartz monzodiorite, granodiorite, and dykes. These dykes emanated randomly from equigranular granodiorite and some of dykes spatially accompany skarns. Skarn Fe mineralization, referred as Prospect I and II in this study, is newly discovered beyond previously known skarns adjacent to the quartz monzodiorite. These discoveries show a vertical and lateral variation of skarn facies, grading from massive reddish-brown garnet-quartz in a lower and proximal zone to banded in an upper and distal zone, reflecting changes in lithofacies of the host rocks. Skarn veins in distal locations are parallel to sedimentary laminae, suggesting that lithologic control is important although proximal skarn has totally obliterated primary structures, due to intense retrograde alteration. Skarns at Geodo are systematically zoned relative to the causative dykes. Skarn zonation comprises proximal garnet, distal pyroxene, and vesuvianite (only in Prospect I) at the contact between skarn and marble. Retrograde alteration is intensely developed adjacent to the contact with dykes and occurs as modification of the pre-existing assemblages and progressive destruction such as brecciation of the prograde assemblages. The retrograde alteration assemblages consist predominantly of epidote, K-feldspar, amphibole, chlorite, and calcite. Most of the magnetite (the main ore mineral), replaces calc-silicate minerals such as garnet in the lower proximal exoskarn, whereas it occurs massive in distal pyroxene and amphibole in the upper and distal exoskarn. The emanation of dykes from the equigranular granodiorite has provided channelways for ascent of skarn-forming fluids from a deep source, whereas the style and nature of skarns suggest that originally structurally-controlled skarn-forming fluids may migrate long distances laterally to produce skarn in calcareous sedimentary rocks.

• Economic and Environmental Geology
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• v.52 no.5
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• pp.323-336
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• 2019

The Mesozoic activity on the Korean Peninsula is mainly represented by the Triassic post-collisional, Jurassic orogenic, and Cretaceous post-orogenic igneous activities. The diversity of mineralization by each geological period came from various geothermal systems derived from the geochemical characteristics of magma with different emplacement depth. The Cretaceous metallic mineralization has been carried out over a wide range of time periods from ca. 115 to 45 Ma (main stage; ca. 100 to 60 Ma) related to post-orogenic igneous activity, and spatial distribution patterns of most metal deposits are concentrated along small granitic stocks. The late Cretaceous metal deposits in the Gyeonggi and Yeongnam massifs are generally distributed along the boundary among the Gongju-Eumseong fault system and the Yeongdong-Gwangju fault system and the Gyeongsang Basin, most of them are in the form of a distal epithermal~mesothermal Au-Ag vein or a transitional mesothermal Zn-Pb-Cu vein. On the other hand, diverse metal commodities in the Taebaeg Basin, the Okcheon metamorphic belt and the Gyeongsang Basin are produced from various deposit types such as skarn, carbonate-replacement, vein, porphyry, breccia pipe, and Carlin type. In the late Cretaceous metallic mineralization, various mineral deposits and commodities were induced not only by the pathway of the hydrothermal solution, but also by the diversity of precipitation environment in the proximity difference of the granitic rocks. The diversity of these types of Cretaceous deposits is fundamentally dependent on the geochemical characteristics such as degree of differentiation and oxidation state of related igneous rocks, and ore-forming fluids generally exhibit the evolutionary characteristics of intermediate- to low-sulfur hydrothermal fluids.

• Nuclear Engineering and Technology
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• v.26 no.4
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• pp.471-483
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• 1994

A sodium fire facility with a test chamber of 1.7㎥ volume was constructed and operated to carry out experiments of sodium fires such as pool, spray, and columnar fires which might take place in sodium-related facilities. The experimental results of pool fires showed that the increase of temperature and pressure in the test chamber was much smaller than that of spray and columnar fires even though their amount of sodium injection in the chamber was much larger compared to other types of fires. And it was found in pool fires that the temperatures of sodium pool and the gas temperature in the test chamber had been maintained much longer than other types of fires, and that the chamber pressure had come to vacuum due to depletion of the oxygen for a large amount of sodium injection in the chamber. The experimental results of spray fires showed that sprayed sodium of small particles instantly reacted with oxygen, and that its reaction heat increased gas temperature and pressure of the test chamber rapidly and decreased them shortly. And the maximum gas temperature and pressure of the test chamber in spray fires ore greatly changed according to the inlet sodium temperature in the test chamber. The characteristics of the columnar fires were almost similar to those of spray fires, but the maximum temperature and pressure of the test chamber were much smaller even for a large amount of sodium injection. And it was shown in spray and columnar fires that the temperatures at each measurement position in the test chamber were quite different due to the instantaneous sodium oxidation in comparision with pool fires. Finally, the graphex powder was proved to be a very effective extinguisher against sodium pool fires.

• The Korean Journal of Vision Science
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• v.20 no.4
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• pp.461-468
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• 2018

Purpose : Tourmaline, a natural ore material, was applied to the entire eyeglasses to observe changes in intraocular pressure (IOP), one of the factors related to human ocular metabolism. Methods : After making eyeglass frames by mixing TR-90, which is the main material of eyeglass frames and 7wt% of tourmaline, The changes of intraocular pressure before and after wearing of tourmaline spectacle frames were divided into low, middle and high groups according to the intraocular pressure in 90 normal subjects (46 men and 44 women) in their 20s. Results : Total intraocular pressure was a significantly decreased to -4.14% (p<0.000) in the right eye after wearing tourmaline frames, and significantly decreased to -6.39 % (p<0.000) and -4.64 % (p<0.017) in the High and Middle groups, respectively. Total intraocular pressure was a significantly decreased to -2.74 % (p<0.004) in the left eye, and -4.58 % (p<0.000) in the High group only showed statically significant value. Conclusion : In this study, the spectacle frame containing 7wt% tourmaline was used and it was confirmed that the intraocular pressure was significantly decreased after wearing the spectacle frame, and it became close to the average value of the normal intraocular pressure range. The results of this study showed that tourmaline, which has the effect of promoting the metabolism and blood circulation of the body, has an effect on the normalization of the intraocular pressure by attaching it to the spectacle frame.

• Journal of the Korean earth science society
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• v.40 no.2
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• pp.163-176
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• 2019

The Potosinian geological basement in central Mexico is comprised of the Upper Paleozoic metamorphic rocks, which crop out on the Sierra de Catorce nucleus located in the northeastern part of the state. The sedimentary sequence that covers unconformably the Paelozoic basement is represented by an Upper Triassic marine sedimentary sequence, correlating to the Zacatecas Formation and the Upper Triassic continental Huizachal Formation red beds, which in turn are covered either by La Joja Formation Jurassic red beds or by Upper Jurassic marine sediments. This sequence is overlain by the conformable Cretaceous calcareous marine sedimentary rocks in all the state of San Luis Potosi. The Cenozoic sequence unconformably covers some of the aforementioned rocks and is represented by undifferentiated volcanic rocks as well as by marine clastic rocks. The existing intrusive igneous rocks are felsic to intermediate composition, and they intrude the metamorphic basement and sedimentary rocks. Conglomerates with evaporitic sediments were deposited during the Pleistocene. The Quaternary sequence includes basalt flows, piedmont deposits, alluvium, and occasionally evaporites and caliche layers. In the state of San Luis Potosi, a great diversity of mineral deposit types is known as both metallic and nonmetallic. The host rocks of these deposits vary from one another including formations that represent from Paleozoic up to Tertiary. The mineralization age corresponds approximately to Tertiary (75%), and is mainly epigenetic. Conclusively, the data on geology and mineralization in San Luis Potosi, Mexico are helpful to predict a hidden ore body and select promising mineralized zone(s) when the domestic company makes inroads in the mining sector of Mexico.

• Economic and Environmental Geology
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• v.51 no.6
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• pp.521-529
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• 2018

This study was conducted to investigate the natural origin of fluorine contained in the rocks within the Eulwangsan area via petrological and mineralogical analyses. The main geology of the Yongyudo Eulwangsan area is Triassic biotite granite. Biotite granite and mylonite are the major rock types containing fluorine at high levels (up to 1,700 and 2,400 mg/kg for biotite granite and mylonite, respectively). In the case of the biotite granite, a high concentration of fluorine can be contributed to fluorite, and the results of microscopic analyses show that the fluorite was observed as small veinlets filling cleavages and micro-fractures within alkali-feldspars and plagioclases, or observed together with quartz in ore veins, indicating the secondary formation of fluorite by hydrothermal fluids. In mylonite, on the other hand, a high fluorine concentration is attributable to sericite. Microscopic analyses revealed that the boundary between sericite and surrounding quartz was not clear, the sericite occurred filling the micro-fractures of quartz and encapsulating small quartz cataclasts. These results indicate that the sericite was also formed as a result of hydrothermal alteration. Consequently, it is speculated that the high fluorine level in the rocks of the Eulwangsan area of Yongyudo is of natural origin due to hydrothermal processes.

• Economic and Environmental Geology
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• v.51 no.6
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• pp.493-507
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• 2018

The Wooseok deposit in Jecheon belongs to the Hwanggangri Mineralized Distict of the northeastern Ogcheon Metamorphic Belt. Its geology consists mostly of limestone of the Choseon Supergroup and the Cretaceous Muamsa granite intruded at the eastern area of the deposit. The deposit shows vertical occurrence of skarn and hydrothermal vein ores with W-Mo-Fe and Cu-Pb-Zn mineralization and skarn is developed only at lower levels of the deposit. Skarn minerals are replaced or cut by ore minerals in paragenetic sequence of magnetite-hematite, molybdenite-scheelite-wollframite, and higher abundances of pyrrhotite-chalcopyrite-pyrite-sphalerite-galena. Garnet has chemical compositions of $Ad_{65.9-97.8}Gr_{0.3-32.0}Pyr_{0.9-3.0}$, corresponding to andradite series, and pyroxene compositions are $Hd_{4.5-49.7}Di_{42.3-93.9}Jo_{0.5-7.9}$, prevailing in diopside compositions, both of which suggest oxidized conditions of skarnization. On the FeS-MnS-CdS ternary diagram, FeS contents of sphalerite in vein ores decrease with increasing MnS contents from bottom to top levels, possibly relating to W mineralization in deep and Pb-Zn mineralization in shallow level. Sulfur isotope values of sulfide minerals range from 5.1 to 6.8‰, reflecting magmatic sulfur affected by host rocks. W-Mo skarn and Pb-Zn vein mineralization in the Wooseok deposit were established by spatio-temporal variation of decreasing temperature and oxygen fugacity with increasing sulfur fugacity from bottom to top levels.

• Korean Journal of Heritage: History & Science
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• v.48 no.1
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• pp.148-165
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• 2015

Iron was one of the most influential factors for formation and development of ancient countries. The diffusion of ironware had increased agricultural productivity and brought about military technical revolution. Needless to say, the rise and fall of the countries depended on the possession of stable iron production. Raw materials and fuels are the key factors for mass production of iron and a transportation route is essential to supply the goods. Jungwon area satisfies the three factors. There are many iron manufacture sites such as Jincheon Seokjang-ri Gusan-ri, and Chunju Chilgeum-dong Tangeumdae earthen ramparts in the Jungwon area. In order to study the ancient iron manufacture technique, reconstitution experiment was carried out using restored furnace which was made based on the Jincheon Seokjang-ri B-23 furnace. Some notable results were identified with the experiment as in the followings. Firstly, a roasting process has a connection with the decrease of hardness of the iron ore. Secondly, melting of the blast pipe as well as the formation of product within the furnace had a crucial effect on the cessation of the experiment. Thirdly, reduced iron in various locations within the furnace prove that there was enough reducing environment during the working. Not only melting point but also properties of iron can vary depending on the carbon contents. For the reason, formation of approximate environment in which iron can react to the chalcoal is the most important factor in terms of iron manufacture.

• Korean Journal of Heritage: History & Science
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• v.48 no.4
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• pp.138-153
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• 2015

A Jincheon Seokjangri B23 furnace was reconstructed and iron smelting experiment was performed to investigate an ancient Baekjae iron production process. The work mainly described in this paper is the $1^{st}$ and $2^{nd}$ experiments among the several experiments carried out at Jungwon National Research Institute of Cultural Heritage. Iron ore(magnetite) and oak charcoal were used as a source and a foot bellow was used for air supply. Common results of the experiments are masses of iron, slag and charcoal formed in the furnace. Most iron lumps were formed nearby the tuyere rather than the area of tapping hole. Metallographic and chemical analysis shows that the iron lumps can be used for either forge or cast depending on their carbon content. Low Fe content and glassy texture of the inner slags suggest that the operation environment was quite reducing. Based on the results of the iron smelting experiments, measurements and analysis, various information was obtained regarding physical-chemical and metallurgical processes of the ancient iron smelting process. It is firmly believed that its undisclosed contents can be revealed more in depth with continual reconstitution experiments.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.1
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• pp.69-81
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• 2021

The exposed rocks in the Zacatecas state include mainly Mesozoic sedimentary and volcanic, Cenozoic volcanic and plutonic rocks. Paleozoic metamorphic rocks found in the northwestern portion of the state are considered as the most ancient rocks. These rocks correspond to the Caopas Formation which underlays the Later Paleozoic Rodeo Formation. The Mesozoic sequences are represented by a marine sedimentary sequence of the Later Triassic and the red beds of the Triassic-Jurassic Nazas Formation. The marine sediments of the Upper Jurassic overlay the Nazas Formation or metamorphic rocks from the Paleozoic. The Cretaceous sequences comprises marine sedimentary rocks in the north and northeast, and a volcanosedimentary set in the center and southeast. The Cenozoic is represented by volcanic nondifferentiated rocks, intrusive igneous rocks of acid and intermediate composition, and continental conglomerates with evaporitic sediments. The Quarternary sequences includes basalts, piedmont deposits, alluviums and occasionally, layers of evaporites and saltpeter. Furthermore, a great diversity of mineral deposits of both metallic and nonmetallic types occur in Zacatecas state. The rocks composing these deposits are extremely varied and include formations from Paleozoic to Tertiary. The mineralization age of ore deposits corresponds to the Tertiary in approximately 90%, and their genesis is mainly considered as epigenetic.