• Journal of the Korean Chemical Society
• /
• v.17 no.4
• /
• pp.306-313
• /
• 1973

With the intention of obtaining technical data for the industrial production of ${\gamma}-MnO_2$ for dry cell depolarizer by electrolytic oxidation of acidic manganese sulfate solution made from domestic rhodochrosite, optimum conditions of ore leaching, purification of leached solution and electrolytic oxidation of divalent manganes to tetravalent were investigated using simulated micro pilot plant having a production capacity of 4 kg of $MnSO_4$ per day. The nature and quality of the products were investigated by means of chemical analysis, DTA, X-ray diffraction and electron microscopy. The cell activity of $MnO_2$were examined by cell discharging character measurements. The optimum electrolysis conditions were as follow: Temperature of the electrolyte, above $90^{\circ}C$; current density, 0.7${\sim}A/dm^2$; anode materials, graphite or lead ; concentration of electrolyte, $MnSO_4 50{\sim}150g/l $ g/l and $H_2SO_4/MnSO_4 = 0.15{\sim}0.25$. Under the best condition the current efficiency was 99% and the products were almost pure ${\gamma}-MnO_2$. The cell discharging character were good and almost the same as that of regular grade commercial electrolytic manganese dioxide.

• Journal of the Korean Society of Food Culture
• /
• v.19 no.2
• /
• pp.209-216
• /
• 2004

To investigate physico-chemical changes of mashed red repper and red pepper powder during frozen storage, we analyzed the quality of samples after mashing, mashing and blanching, mashing and addition of vitamin C, mashing and addition of NaCl. The most important quality factor of red pepper is red color. $\alpha$ value of red pepper powder of Pochungchun was 31.51. These results showed that those processing methods were effective to preserve red color. Capsanthin contents of mashed red pepper treated with vitamin C were decreased 1.8% after 180 days of frozen storage. This decrease was the least, showing that addition of vitamin C helped retaining capsanthin contents. Capsaicin and dihydrocapsaicin contents in Pochungchun powder ore decreased 11.9 and 18.3% during frozen storage respectively. These results showed that capsaicin was more stable than dihycrocapsaicin during frozen storage. Generally capsaicin and dihydrocapsaicin in the Pochungchun red pepper frozen-stored after mashing were less decreased than red pepper powder, and addition of vitamin C to the mashed red pepper was the most effective to retain capsicin and dihydrocapsaicin than others. The content of vitamin C in the red pepper frozen-stored after masking and blanching was 12.0 mg/100g, compared with 44.0 mg/100g in the sample stored after only mashing. This suggested that blanching process destroyed vitamin C in the mashed red pepper. Addition of salt in the mashed red pepper showed the same inclination. But, addition of vitamin C to the mashed red pepper was decreased 32.9% compared with 69.0% in the mashed red repper during frozen storage. Theser results indicated that addition of vitamin C could retain vitamin C in the mashed red lopper.

• Journal of the Mineralogical Society of Korea
• /
• v.28 no.4
• /
• pp.299-308
• /
• 2015

The six natural zeolites collected in Pohang area, Kyungsangbuk-do, Korea, were characterized by XRD, XRF, DTA, TGA, and CEC analysis. The primary species of these zeolite are modenite, albite, and quarts in Kuryongpo-A (Ku-A), Kuryongpo-B (Ku-B), Kuryongpo-C (Ku-C), Donghae-A (Dh-A), Donghae-B (Dh-B), and Donghae-C (Dh-C) samples. The XRF analysis showed that the six zeolites contain Si, Al, Na, K, Mg, Ca, and Fe. Cation exchange capacity of Kuryongpo-C (Ku-C) zeolite was the highest compared to other zeolites. The capabilities of removing heavy metal ions such as $Pb^{2+}$, $Cd^{2+}$ and $Cu^{2+}$ were compared. The effect of reaction time in removing heavy metal ions was studied. The experimental results showed that the efficiency of removal was low for $Pb^{2+}$, $Cd^{2+}$ and $Cu^{2+}$ ions. These may be caused by the low content of zeolite in the six natural zeolites. This indicates that the adsorption capacity roughly tends to depend on the zeoite contents, ie., the grade of zeolite ore.

• Journal of Environmental Science International
• /
• v.7 no.2
• /
• pp.149-156
• /
• 1998

Enoronmental problems caused by certain geologic conditions Include pollution of soil by heavy metal, acidization of souls , acid mine drainage, Pound-water pollution, and natural radioactivity, as well as zoo-logical hazards such as landslide and subsidence. The acrid mine drainage contains large amount of heavy metals nO, therefore. cause serious pollution onto the nearby drainage systems and soils. In spite of this prospective environmental danger, few studies have been done on the acid mine drainage derived from non-metallic ore deposits such as pyrophyllitefNapseok) deposits. The sudo-bearing pyrophyllite ores, alteration zones, and mine talllngs of pyrophylllte deposits produce acrid mine drainage by the okidation of weathering. Compared to the fresh host rocks, the ores and altered rocks of pyrophyllite deposits produce acidic solution which contain higher amount of heavy metals because of OeP lower buffering capacity to acrid solution. The pus of urine water and nearby stream water of pyrophyllite deposits are 2.1~3.7, which are strong- ly acidic and much lower than that (6.2~7.2) of upstream water and than that (6.8~7.6) of the stream water derived from the non-mineralized area. This study reveals that this acrid mine drainage can affect the downstream area which is 8km far from the pyrophyllite deposits, even though the drain Is diluted with abundant non-contaminated river water This suggmists that not only acid mine drainage but also the sulfide-bearing sediments originated from the pyrophyllite deposits move downstream and form acidic water through continuous oxidation reaction. The heavy metals such as Pb, Zn, Cu, Cd, Nl, Mn and Fe are enriched In the mine water of low pH, and their contents decrease as the pH of mine water Increases because of the Influx of fresh stream wainer. SoUs of the Pyrophyulte deposits are characterized by high contents of heavy metals. The stream sediments containing the yellowish brown precipitates formed by neutralization of acid mine drainage occur in all parts of the stream derived from the pyrophyllite deposits, and the sediments also contain high amounts of heavy metals. In summary, the acid mine drainage of the pyrophyllite deposits is located in the upstream part of Hoidong water reservoir in Pusan contains large amounts of heavy metals and flows into the Holdong water reservoir without any purification process. To protect the water of Holdong reservoir, the acid mine drainage should be treated with a proper purification process.

• Resources Recycling
• /
• v.1 no.1
• /
• pp.69-77
• /
• 1992

In this study, a talc flotation was fundamentally carried out with dolomite origin talc ore produced in Dong Yang Talc Mine at Chung-Ju. This ores are mainly composed with talc as a valuable mineral, dolomite as a gangue mineral and other minor minerals of hornblende, tremolite, actinolite, chlorite, calcite, epidote and iron oxide. In order to obtain some of fundamental data for the talc flotation from low grade dolomitic talc tailings which were abandoned -25mm +17 mm size, after the treatment of crude talc ores by screening and hand -picking at the mine, flotation characteristics of the pure talc and dolomite in this ores were first investigated by measuring floatability of the minerals at some experiment conditions. Furthermore, Several times of batch flotations for talc were performed experimentally to recover talc from the low grade dolomitic talc tailings. From the results obtained in this experiment, the conclusions can be summarized as follows ; 1) In the flotation of pure talc, the use of Dowfroth 250 as frother was the most effective in various kinds of frother and the proper addition amount was about 50 mg/${\ulcorner}$(200g/t) at the condition of this experiment. 2) In the flotation of pure talc, the use of kerosene as collector was not adequate, at the addition over 50mg/l of Dowfroth 250. 3) The adequate pH of pulp ranged from pH6 to pH9 in the talc flotation using Dowfroth 250 as frother. 4) The use of Quebracho as depressant for dolomite was not adequate for the recovery of talc, and more selective depressant was required. 5) In the talc flotation on D sample(dolomitic talc tailing), the suitable number of cleaning time was about 3. 6) At this experimental conditions for the talc flotation on D sample, the talc flotation concentrates of 1. 40% CaO and 84.5 whiteness could be recovered with the talc recovery of about 53%.

• Nuclear Engineering and Technology
• /
• v.27 no.4
• /
• pp.544-554
• /
• 1995

Pool boiling of dilute aqueous solutions of polyethylene oxide polymer has been experimentally investigated for the purpose of understanding the physical mechanisms of the suppression of vapor explosions in this polymer solution. Tn solid spheres of 22.2mm and 9.5mm-diameter ore heat-ed and quenched in the polymer solutions of various concentrations at 3$0^{\circ}C$. The results showed that minimum film boiling temperature($\Delta$ $T_{MFB}$) in this highly-subcooled liquid rapidly decreased from over $700^{\circ}C$ for pure water to about 15$0^{\circ}C$ as the polymer concentration was increased up to 300ppm for 22.2mm sphere, and it decreased to 35$0^{\circ}C$ for 9.5mm sphere. This large decrease of minimum film boiling temperature in this aqueous polymer solution may explain its ability to suppress spontaneous vapor explosions. Also, tests with applying a pressure wave showed that the vapor film behaved more stable against an external disturbance at higher polymer concentrations. These observations together with the experimental evidences of vapor explosion suppression in dilute polymer solutions suggest that the application of polymeric additives such as polyethylene oxide as low as 300ppm to reactor emergency coolant be considered to prevent or mitigate energetic fuel-coolant interactions during severe reactor accidents.s.

• Nuclear Engineering and Technology
• /
• v.27 no.4
• /
• pp.453-462
• /
• 1995

In connection with the safe storage of high level nuclear waste, effect of $H_2O$$_2$ on the corrosion behavior of 304L stainless steel was examined. Open circuit potentials and polarization curves were measured with and without $H_2O$$_2$. The experimental results show that $H_2O$$_2$ increased corrosion potential and decreased pitting potential. The passive range, therefore, decreased as $H_2O$$_2$ concentration increased, indicating that pitting resistance was decreased by the existence of $H_2O$$_2$ in the electrolyte. These effect of $H_2O$$_2$ on corrosion of 304L stainless steel are considered to be similar to those of ${\gamma}$-irradiation. To compare the effects of $H_2O$$_2$ with those of $O_2$, cathodic and anodic polarization curves ore made in three types of electrolyte such as aerated, deaerated, and stirred electrolyte. The experimental results show that the effects of $H_2O$$_2$ on the corrosion behavior were tory similar to those of $O_2$ such as increase of corrosion potential, decrease of pitting resistance, and increase of repassivation potential. In acid and alkaline media, the corrosion potential shifts by $H_2O$$_2$ were restricted by the large current density of proton reduction and by the le Chatelier's principle respectively.y.

• Journal of the Mineralogical Society of Korea
• /
• v.30 no.4
• /
• pp.137-147
• /
• 2017

Sericite is a clay mineral that has a wide applications in the industry, depending on its purity. To maintain sericite's purity as high as possible it is necessary to remove its gangue minerals or control their contents prior to use for high value-added products and applications. In this study, the wet beneficiation of sericite by applying selective grinding and sedimentation techniques, were investigated. The ore mineral was composed mainly of sericite, quartz and calcite. Analysis showed that the content of sericite increased along with the particle size decrease, but the contents of impurity minerals as quartz and calcite were tended to decrease relatively with particle size decrease. The results of liberation tests using an attrition scrubber showed that the increase in residence time and slurry density have increased the generation of fine particles in -325 mesh size range. It was observed, however, that the contents of impurities such as quartz and calcite in such fine particles also increased during prolonged scrubbing. In the dispersed form without breaking, the yield of the recovered concentrate was 15.4 wt% and the $K_2O$ content was 9.84 wt%, after the dispersed slurry was allowed to settle for 20 minutes. On the other hand, the concentrate yield was increased to 23.4 wt% after 10 minute attrition scrubbing and 40 minute sedimentation, while its $K_2O$ content was decreased to 9.71 wt%. Most of final products were observed as platelet-shaped particles containing Si, Al and K which are main component of sericite.

• Tunnel and Underground Space
• /
• v.23 no.3
• /
• pp.180-191
• /
• 2013

The purpose of this research was to find an optimal quarrying for marble by analyzing the applicability and the work efficiency of a chain saw machine newly introduced in the underground Baekwoon mine. From the test results of the physical properties of Baekwoon marble, which affects the efficiency of rock cutting, it was found to have similar physical characteristics as the ones which are now being produced in the other areas in Korea. And especially it shows isotropic property, which can be thought to be advantageous as a dimensional stone. To check the long-term quality of the marble as a stone material, several tests such as corrosion resistance test and abrasion test were carried out. It was found to be vulnerable to acid rain with decrease of weight and seismic wave velocity after applying artificial rain at pH 5.6 for 50 times. The percentage of wear from abrasion test was 22.67%. The working time and cutting speed of the chain saw machine were recorded and analyzed during the test-run at the quarry. The overall work cycle was assorted into 9 unit operations and the operating time per each unit was drawn. The operating times for the two cutting patterns, which could be possibly applicable to the work site, were compared. The results indicated that the pattern B, that the cutting sequence was set to minimize the movement of the machine, showed 6% less working hours than the pattern A, which first cuts the outer boundary. With cutting pattern analysis, the ore body in the Baekwoon mine was 3 dimensionally modeled and a quarrying plan considering the existing conditions of the marble was suggested.

• Economic and Environmental Geology
• /
• v.32 no.6
• /
• pp.611-631
• /
• 1999

Enviromental geochemisty and heary metal contamination at the Kongjueil mine creek were underaken on the basis of physicohemical properties and mineralogy for various kinds of water (surface, mine and ground water),soil, precipitate and sediment collected of April and December in 1998. Hydrgeochemical composition of the water samples are characterized by relatively significant enricant of Ca+Na, alkiali ions $NO_3$ and Cl inground and surfore water, wheras the mine waters are relatively eneripheral water of the mining creek have the characteristics of the (Ca+Mg)-$(HCO_3+SO_4)$type. The pH of the mine water is high acidity (3.24)and high EC (613$\mu$S/cm)compared with those of surface and ground water. The range of $\delta$D and $\delta^{18}O$ values (relative to SMOW) in the waters are shpwn in -50.2 to -61.6% and -7.0 to -8.6$\textperthousand$(d value=5.8 to 8.7). Using computer program, saturation index of albite, calcite, dolomite in mine water are nearly saturated. The gibbiste, kaolinite and smectite are superaturated in the surface and ground water, respectively. Calculated water-mineral reaction and stabilities suggest that weathing of silicate minerals may be stable kaolinite owing to the continuous water-rock reaction. Geochemical modeling showed that mostly toxic heavy metals may exist larfely in the from of metal-sulfate $(MSO_4\;^2)$and free metal $(M^{2+})$ in nmine water. These metals in the ground and surface water could be formed of $CO_3$ and OH complex ions. The average enrichment indices of water samples are 2.72 of the groundwater, 2.26 of the surface water and 14.15 of the acid mine water, normalizing by surface water composition at the non-mining creek, repectively. Characteristics of some major, minor and rate earth elements (Al/Na, K/Na, V/Ni, Cr/V, Ni/Co, La/Ce, Th/Yb, $La_N/Yb_N$, Co/Th, La/Sc and Sc/Th) in soil and sediment are revealed a narrow range and homogeneous compositions may be explained by acidic to intermediate igneous rocks. And these suggested that sediment source of host granitic gneiss colud be due to rocks of high grade metamorphism originated by sedimentary rocks. Maximum concentrations of environmentally toxic elements in sediment and soil are Fe=53.80 wt.% As=660, Cd=4, Cr=175, Cu=158, Mn=1010, Pb=2933, Sb=4 and Zn=3740 ppm, and extremely high concentrations are found are found in the subsurface soil near the ore dump and precipitates. Normalizing by composition of host granitic gneiss, the average enerichment indices are 3.72 of the sediments, 3.48 of the soils, 10.40 of the precipitates of acid mine drainage and 6.25 of the soils near the main adit. The level of enerichment was very severe in mining drainage sediments, while it was not so great in the soils. mineral composition of soil and sediment near the mining area were partly variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. reddish variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. Reddish brown precipitation mineral in the acid mine drainage identifies by schwertmanite. From the separated mineralgy, soil and sediment are composed of some pyrite, arsenopyite, chalcopyrite, sphalerite, galena, malachite, goethite and various kinds of hydroxied minerals.