• Title/Summary/Keyword: OIL

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Lifetime Prediction and Aging Behaviors of Nitrile Butadiene Rubber under Operating Environment of Transformer

  • Qian, Yi-hua;Xiao, Hong-zhao;Nie, Ming-hao;Zhao, Yao-hong;Luo, Yun-bai;Gong, Shu-ling
    • Journal of Electrical Engineering and Technology
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    • v.13 no.2
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    • pp.918-927
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    • 2018
  • Based on the actual operating environment of transformer, the aging tests of nitrile butadiene rubber (NBR) were conducted systematically under four conditions: in air, in transform oil, under compression in air and under compression in transform oil to studythe effect of high temperature, transform oil and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber and predict the lifetime. The effects of liquid media and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber were studied by using characterization methods such as IR spectrosc-opy, thermogravimetric measurements, Differential Scanning Calorimetry (DSC) measurements and mechanical property measurements. The changes in physical properties during the aging process were analyzed and compared. Different aging conditions yielded materials with different properties. Aging at $70^{\circ}C$ under compression stress in oil, the change in elongation at break was lower than that aging in oil, but larger than that aging under compression in air. The compression set or elongation at break as evaluation indexes, 50% as critical value, the lifetime of NBR at $25^{\circ}C$ was predicted and compared. When aging under compression in oil, the prediction lifetime was lower than in air and under compression in air, and in oil. It was clear that when predicting the service lifetime of NBR in oil sealing application, compression and media liquid should be involved simultaneously. Under compression in oil, compression set as the evaluation index, the prediction lifetime of NBR was shorter than that of elongation at break as the evaluation index. For the life prediction of NBR, we should take into account of the performance trends of NBR under actual operating conditions to select the appropriate evaluation index.

Influence of Blend Mode of Extender Oil on the Properties of EPDM/PP-Based Thermoplastic Vulcanizates (이피디엠/폴리프로필렌 열가소성 경화물에서 오일의 블렌드 방식이 경화물의 물성에 미치는 영향)

  • Na, Sung-Su;Song, Ki-Chan;Kim, Su-Kyung
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.315-322
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    • 2009
  • Influence of blend mode of extender oil on the properties of thermoplastic vulcanizates (TPVs), based on an ethylene-propylene-diene copolymer (EPDM) and a polypropylene (PP), was studied. The EPDM/PP TPVs were prepared in an open roll mill using two different modes in blending sequence of paraffinic oil and phenolic curative, i.e., Oil-Cure and Cure-Oil modes. Degree of cross-linking by gel fraction and properties such as hardness, tensile strength, elongation at break, and melt flow rate were investigated as a function of extender oil content for the two modes. Little influence of the blend mode of extender oil on the degree of cross-linking and mechanical behaviors was observed. However, the use of Cure-Oil mode in the preparation of EPDM/PP TPVs resulted in a marked increase in the level of processability as reflected by melt flow index, as compared to the use of Oil-Cure mode.

Acaricidal activity and chemical composition of essential oil derived from the Albizziae julibrissin barks

  • Park, Jun-Hwan;Lee, Sang-Guei;Kim, Jeong-Moon;Lee, Hoi-Seon
    • Journal of Applied Biological Chemistry
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    • v.59 no.2
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    • pp.125-128
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    • 2016
  • The chemical compositions of the essential oil extracted from Albizziae julibrissin barks were analyzed by Gas chromatography-Mass spectrometry spectrometry. Fourteen components were identified, representing 89.23 % of the total oil composition. The analysis of the essential oil revealed that the essential oil contains 14 compounds, accounting for 89.23 % of the total oil. Hexanoic acid was the principal component (41.43 %) of the essential oil, followed by 4,4,6-trimethyl-cyclohex-2-en-1-ol (11.16 %), palmitic acid (9.00 %), 2-pentylfuran (5.66 %), 2-butyl-2-octenal (4.12 %), linoleic acid (3.10%), amyl hexanoate (3.01%), (E,E)-2,4-decadienal (2.49 %), 2-hexylthiophene (2.47 %), caprylic acid (2.13 %), ${\delta}-undecalactone$ (1.52 %), heptanoic acid (1.27 %), 3,5-octadien-2-ol (0.99 %), and 2-octenal (0.88 %). The acaricidal activity of the A. julibrissin oil was tested against Dermatophagoides farina, D. pteronyssinus and Tyrophagus putrescentiae by the fumigant bioassay. Based on the $LD_{50}$ values, the essential oil exhibited strong acaricidal activities against D. farinae ($LD_{50}$, $4.88{\mu}g/cm^3$), D. pteronyssinus ($2.44{\mu}g/cm^3$), and T. putrescentiae ($1.22{\mu}g/cm^3$). These results indicate that A. julibrissin oil could be a source of acaricidal agents for mite control.

A Study on Economic Operation for Liner-Fleet by Fluctuation of Fuel Oil Price (연료유 가격변동에 따른 컨테이너선대의 경제적 운영방안)

  • Lee, Soo-Dong;Shin, Jeong-Hoon;Kim, Chul-Hyun;Chang, Myung-Hee
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2009.06a
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    • pp.173-174
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    • 2009
  • For container shipping company, fuel oil prise is a considerable expense. In the last 3 years, fuel oil prises have risen considerably. An increasing fuel oil prise in container shipping, in the short term, is only partially compensated through surcharges and will therefore affect earnings negatively. This paper deals with the impact of increasing fuel oil price and capital costs for vessels on the number of vessels on the Asia-Europe trade. As per result of 'H' carrier's operation in 2008, there were no cost difference between 8 and 9 vessels operation in case the fuel oil price is USD 169/tons while adopt USD 31,818 as fixed cost. We can expect that the fuel oil price will not be decreased under USD 200 $/Ton on the basis of current high oil price phenomenon. When the fuel oil price is over USD 200 $/ton, therefore, 9 vessels operation is more economic than 8 vessel operation even if the fixed cost is over USD 35,000.

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Characteristics of Iodine Values and Viscosities by blending of Waste Vegetable Oil and Diesel Oil (폐식용유와 디젤유 블렌딩을 통한 요오드가 및 점도 특성)

  • Jeong, Dong-Seok;Nam, Byeong-Uk;Jeong, Yong-Ju
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.7
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    • pp.1648-1653
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    • 2009
  • Fossil fuel causes the greenhouse effect by emitting $CO_2$, and an estimated amount of oil deposits are also limited. Therefore, people have been interested in alternative energies. Vegetable oil which is one of the alternative energies is eco-friendly renewable energy source and has similar properties like diesel oil with high efficiency. Also, vegetable oil has been well recognized as one of solutions to reduce the greenhouse effect caused by $CO_2$release. In this study, we chose Waste vegetable oil(WVO) to solve the problems of high price of grain and lack of food. Impurities and sediments from WVO were removed by separation process using sieves of $15{\mu}m$pore size. Blending was performed in Homo-mixer by 5000 rpm for 10 min. We investigated viscosities and Iodine values in different compositions of WVO and diesel oil blends. Finally, we could find out blended oils have some possibility to be used in the diesel engine.

Assessment of Potential Utility of Subcritical Water for Remediation of Crude Oil Contaminated Soil (원유오염토양의 아임계수를 통한 정화 가능성 평가)

  • Jeong, Yeon-Jae;Jo, Young-Tae;Islam, Mohammad Nazrul;Park, Seong-Jae;Jung, Sun-Kook;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.22 no.6
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    • pp.48-56
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    • 2017
  • Although various methods have been investigated for treatment of crude oil contaminated soil, more researches are still required to preserve soil environment. This study investigated the potential utility of subcritical water in remediation of crude oil contaminated soil under various experimental conditions including temperature ($150-300^{\circ}C$), flow rate (1.0-2.0 mL/min) and extraction time (60-120 min). The removal rate of crude oil gradually increased with increasing temperature and time. After treatment at $200^{\circ}C$ and $300^{\circ}C$ for 60 min, the remaining concentration of crude oil met the Kuwait standard clean-up level (10,000 mg/kg) and the Korean standard level (2,000 mg/kg), respectively. The removal efficiency of crude oil increased from 77.8% to 88.4% with increasing extraction time from 60 to 120 min at $250^{\circ}C$. A decreasing rate of oil removal was observed as flow rate increased, possibly due to channeling flow occurred within the soil body at higher flow rate condition. Overall, the results revealed that subcritical water extraction process could be feasible for remediation of crude oil contaminated soil, and the relative effect of parameters on the oil removal was in the order of temperature > time > flow rate.

사료중 어유가 급성기 반응중인 육계 병아리에서 에너지 대사와 항산화효소 활성에 미치는 영향

  • 박인경;김재환;임진택;이성일;고태송
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2003.11a
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    • pp.73-74
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    • 2003
  • Three experiment were designed to determine the effects of dietary(n-3) fatty acids on the growth-suppressive effects of the inflammatory response and anti-oxidant enzyme activity and balances of nitrogen and energy. Day-old chicks were fed diets containing 1.0 % soybean oil in experiment 1, or diets containing 1.0 % of fish oil in experiment 2, and then on 7-d of age chicks were fed diets containing 1.0 % of either soybean oil or fish oil. In experiment 3, day-old chicks were fed on diets containing 1.0 % of either soybean oil or fish oil. In chicks of half pens within each dietary treatments of each experiments, the acute phase response were induced by injecting with Salmonella typhymurium lipopolysaccaride(LPS) i.p. 3 times at 8, 10 and 12-d of age. During acute phase response, chicks fed dietary fish oil from 1-d of age enhanced energy balances and did not give negative effect on nitrogen balance and uric acid excretion, but elevated MnSOD and Cu/ZnSOD activity In liver and erythrocyte cytosols compared with those fed dietary soybean oil. The results indicated that enhanced daily gain and metabolizable energy value of diet in birds fed fish oil from one-d of age seems due to change on the antioxidants systems during acute phase response.

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An Experimental Study on Characteristics of Engine Oil Diluted by a Bio-Alcohol Mixture Fuel (바이오알코올 혼합연료의 엔진오일 희석특성에 대한 실험적 연구)

  • Kim, HyunJun;Lee, HoKil;Oh, SeDoo;Kim, Shin
    • Tribology and Lubricants
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    • v.32 no.6
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    • pp.183-188
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    • 2016
  • Engine oil plays an important role in the mechanical lubrication and cooling of a vehicle engine. Recently, engine development has focused on the adoption of gasoline direct injection (GDI) and turbocharging methodology to achieve high-power and high-speed performance. However, oil dilution is a problem for GDI engines. Oil dilution occurs owing to high-pressure fuel injection into the combustion chamber when the engine is cold. The chemical components of engine oil are currently developed to accommodate gasoline fuel; however, bio-alcohol mixtures have become a recent trend in fuel development. Bio-alcohol fuels are alternatives to fossil fuels that can reduce vehicle emissions levels and greenhouse gas pollution. Therefore, the chemical components of engine oil should be improved to accommodate bio-alcohol fuels. This study employs a 2.0 L turbo-gas direct injection (T-GDI) engine in an experiment that dilutes oil with fuel. The experiment utilizes a variety of fuels, including sub-octane gasoline fuel (E0) and a bio-alcohol fuel mixture (Ethanol E3~E7). The results show that the lowest amount of oil dilution occurs when using E3 fuel. Analyzing the diluted engine oil by measuring density and moisture with respect to kinematic viscosity shows that the lowest values of these parameters occur when testing E3 fuel. The reason is confirmed to influence the vapor pressure of the low concentration bio-alcohol-fuel mixture.

Changes in the Physicochemical Characteristics of Sancho Oil according to the Purification Process (산초유 정제공정에 따른 물리화학적 변화)

  • Kang, Seung Mi;Kim, Hak Gon;Yang, Woo Hyeong;Yong, Seong Hyeon;Park, Dong Jin;Park, Jun Ho;Enukwa, Ettagbor Hans;Choi, Myung Suk
    • Korean Journal of Medicinal Crop Science
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    • v.25 no.5
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    • pp.296-304
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    • 2017
  • Background: Sancho oil extracted from Zanthoxylum schinifolium (Siebold & Zucc) is a useful edible oil that has been in use for a long time, but it is known to be susceptible to rancidity. Sancho oil purification can remove impurities to prevent rancidity. This study was performed in order to improve the quality of sancho oil and enhance its availability throughout the purification process. Methods and Results: Sancho oil extracted in Hadong, Korea was refined via the degumming and deoxygenation processes, following which we examined the changes in the polyphenol content, fatty acid content and antioxidant activity of the oil. Acetic acid was effective for deoxygenation of sancho oil and 2 N NaOH was effective for its deoxidation. The polyphenol content and antioxidant activity were reduced by the purification process. Saturated fatty acids contents did not vary with the degumming and deoxygenation processes, however the content of unsaturated fatty acids were slightly reduced. Conclusions: This study suggests that the process of sancho oil purification used in this study will contribute to the increased use and storage of sancho oil.

Phytochemical Screening and Antibacterial Activity Coix lacryma-jobi Oil

  • Diningrat, Diky Setya;Risfandi, Marsal;Harahap, Novita Sari;Sari, Ayu Nirmala;Kusdianti, Kusdianti;Siregar, Henny Kharina
    • Journal of Plant Biotechnology
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    • v.47 no.1
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    • pp.100-106
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    • 2020
  • Coix lacryma-jobi (Hanjeli) is known to posses anti-microbial properties. Therefore, phytochemical compounds of C. lacryma-jobi have been studied to produce novel antimicrobial agents as treatments against antibiotic-resistant bacteria.The objective of this study was to determine the phytochemical composition and antibacterial activity of the C. lacryma-jobi oil against Escherichia coli, Staphylococcus aureus, and Bacillus subtilis. The phytochemical composition of the oil was determined via gas chromatography mass spectrophotometry (GC-MS). Moreover, agar disk and agar well diffusion were employed to screen the antibacterial activity of the oil. An agar well diffusion test was implemented to determinate MIC's (minimum inhibitory concentrations). Dodecanoic acid, tetradecanoic acid, 2,3-dihydroxypropylester, 1,3-dioctanoin, N-methoxy-N-methyl-3,4-dihydro-2H-thiopyran6-carboxamide, propanamide, 5-Amino-1-(quinolin-8-yl)-1,2,3-triazole-4-carboxamide, and pyridine were identified in the C. lacryma-jobi oil. The MIC value of the oil was 0.031 g/L and the MBC of the oil was 0.125 g/L effective in all test bacteria. Dodecanoic acid displayed inhibitory activity against gram-positive and gram-negative bacteria. Therefore, our research demonstrated C. lacryma-jobi (Hanjeli) oil exhibited antibacterial activity against E. coli, S. aureus, and B. subtilis. These research suggest that C. lacryma-jobi root oil could be used for medicinal purposes; however clinical and in vivo tests must be performed to evaluate its potential as an antibacterial agent.