• Title/Summary/Keyword: OH value

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Using Design of Mixture Experiments to Select the Ratio of a Three-Component Electrode for Optimal Generation of Hydroxyl Radicals (혼합물 실험계획법을 이용한 OH라디칼 최적 생성을 위한 삼성분 전극의 비율 선정)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.29 no.8
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    • pp.793-800
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    • 2020
  • The conventional development of multi-component electrodes is based on the researcher's experience and is based on trial and error. Therefore, there is a need for a scientific method to reduce the time and economic losses thereof and systematize the mixing of electrode components. In this study, we use design of mixture experiments (DOME)- in particular a simplex lattice design with Design Expert program- to attempt to find an optimum mixing ratio for a three-component electrode for the high RNO degradation; RNO is an indictor of OH radical formation. The experiment included 12 experimental points with 2 center replicates for 3 different independent variables (with the molar ratio of Ru, Ti, Ir). As the Prob > F value of the 'Quadratic' model is 0.0026, the secondary model was found to be suitable. Applying the molar ratio of the electrode components to the corrected response model results is an RNO removal efficiency (%) = 59.89 × [Ru] + 9.78 × [Ti] + 67.03 × [Ir] + 66.38 × [Ru] × [Ir] + 132.86 × [Ti] × [Ir]. The R2 value of the equation is 0.9374 after the error term is excluded. The optimized formulation of the ternary electrode for an high RNO degradation was acquired when the molar ratio of Ru 0.100, Ti 0.200, Ir 0.700 (desirability d value, 1).

A Rapid COD Test Procedure for Alkaline Permanganate Value Determination (알칼리성 $100^{\circ}C$에서 화학적 산소요구량 신속정량법)

  • Czae, Myung-Zoon;Ly, Suw-Young;Kim, Mi-Kyung
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.167-170
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    • 1995
  • A simple and rapid permanganate value test procedure for the estimation of COD, based on the photometric measurement of the remained permanganate after the color bleaching by oxygen demand organics during digestion, has been described. Optimized conditions were 1% NaOH, 0.6mM $KMnO_4$, with a closed reflux in the boiling water bath for 90 sec using sample size of 5mL.

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Examining the Relationship between Shopping Style and Consumption Value of Apparel Products (의류상품 유형별 쇼핑스타일과 소비가치 관계 연구)

  • Oh, Hyun-Jeong
    • Journal of the Korean Home Economics Association
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    • v.48 no.1
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    • pp.27-40
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    • 2010
  • The objectives of this study were to investigate differences in shopping style and consumption value of apparel product type, and to establish the effects of consumption value on shopping style. A questionnaire was used to collect data from 263 women aged between 20 to 49 in Gwangju on their shopping style and consumption value according to formal and casual product type. Collected data were subjected to frequency analysis, factor analysis, ANOVA, t-test and multiple regression analysis using statistical program SPSS(version 17.0). Results showed that shopping style could be influenced by six factors: fashion-recreational, quality-brand, impulsive, confused, brand-loyal, and price conscious consumer. Clothing consumption value was influenced by five factors: emotional, functional, epistemic, social, and situational value. Shopping style and clothing consumption value were significantly different between a formal product purchaser and a casual product purchaser. Consumption value had a significant influence on shopping style of the formal product purchaser and also the casual product purchaser.

Neuroprotective Effects of Ginsenoside Rg3 against 24-OH-cholesterol-induced Cytotoxicity in Cortical Neurons

  • Roh, Yoon-Seok;Kim, Hyoung-Bae;Kang, Chang-Won;Kim, Bum-Seok;Nah, Seung-Yeol;Kim, Jong-Hoon
    • Journal of Ginseng Research
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    • v.34 no.3
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    • pp.246-253
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    • 2010
  • Ginsenoside $Rg_3$ ($Rg_3$), one of the active ingredients in Panax ginseng, attenuates NMDA receptor-mediated currents in vitro and antagonizes NMDA receptors through a glycine modulatory site in rat cultured hippocampal neurons. In the present study, we examined the neuroprotective effects of $Rg_3$ on 24-hydroxycholesterol (24-OH-chol)-induced cytotoxicity in vitro. The results showed that $Rg_3$ treatment significantly and dose-dependently inhibited 24-OH-chol-induced cell death in rat cultured cortical neurons, with an $IC_{50}$ value of $28.7{\pm}7.5\;{\mu}m$. Furthermore, the $Rg_3$ treatment not only significantly reduced DNA damage, but also dose-dependently attenuated 24-OH-chol-induced caspase-3 activity. To study the mechanisms underlying the in vitro neuroprotective effects of $Rg_3$ against 25-OH-chol-induced cytotoxicity, we also examined the effect of $Rg_3$ on intracellular $Ca^{2+}$ elevations in cultured neurons and found that $Rg_3$ treatment dose-dependently inhibited increases in intracellular $Ca^{2+}$, with an $IC_{50}$ value of $40.37{\pm}12.88\;{\mu}m$. Additionally, $Rg_3$ treatment dose-dependently inhibited apoptosis with an $IC_{50}$ of $47.3{\pm}14.2\;{\mu}m$. Finally, after confirming the protective effect of $Rg_3$ using a terminal deoxynucleotidyl transferase-mediated dUTP nick end-labeling assay, we found that $Rg_3$ is an active component in ginseng-mediated neuroprotection. These results collectively indicate that $Rg_3$-induced neuroprotection against 24-OH-chol in rat cortical neurons might be achieved via inhibition of a 24-OH-chol-mediated $Ca^{2+}$ channel. This is the first report to employ cortical neurons to study the neuroprotective effects of $Rg_3$ against 24-OH-chol. In conclusion, $Rg_3$ was effective for protecting cells against 24-OH-chol-induced cytotoxicity in rat cortical neurons. This protective ability makes $Rg_3$ a promising agent in pathologies implicating neurodegeneration such as apoptosis or neuronal cell death.

A Study on Polyester Fabric treated with Quarternary Ammonium Salt and Alkali (사급암모늄염/수산화나트륨용액에서 폴리에스테르 직물의 알칼리처리에 관한 연구)

  • 류효선
    • Journal of the Korean Home Economics Association
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    • v.25 no.4
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    • pp.9-18
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    • 1987
  • This study is conducted to investigate the influence of addition of quarternary ammonium salt(cetyl trimethyl ammonium bromide: CTAB) when polyester(PET) fabric is treated with sodium hydroxide(NaOH), depending on experimental variables such as CTAB concentration, NaOH concentration, time & temperature, and the change in physical & chemical properties of alkaline-hydrolyzed PET fabrics depending on their weight loss. The results are as follows: 1. By adding CTAB in aqueous NaOH, the weight loss of PET fabric is increased remarkably and until the concentration of CTAB is reached at its cmc, and the higher the concentration of CTAB are, the more weight loss on PET fibrics are. 2. The addition of CTAB in aqueous NaOH is most effective at lower NaON concentration(2%) among various NaOH concentration, on increasing the amount of weight loss, while there are almost similar results through various treatment time and temperature. 3. As the amount of weight of weight loss on PET fabric is increased, the increase of void space in the PET yarn, of softness & dyeability of PET fabric and the decrease of tensile strength are found. On the other hand, the moisture regain shows a little increase by alkaline-hydrolysis on PET fabric while vertical absorption test & water retention value are not sufficiently sensitive to distinguish between the hydrophillicity of untreated and treated PET fabric. The shrinkage of PET fabric is induced by swelling in hot aqueous NaOH regardless of NaOH concentration & addition of CTAB.

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Effect of NCO/OH ratio and binder content with micro-AP on HTPB/AP/Al-based propellants mechanical properties

  • Zulfam Adnan;Nurul Musfirah Mazlan
    • Advances in materials Research
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    • v.13 no.2
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    • pp.129-140
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    • 2024
  • This study evaluates the ratio of Toluene di-isocyanate (TDI) functional group isocyanate (NCO) to the binder functional hydroxyl group (OH) in HTPB/AP/Al-based propellants on their mechanical properties, flow rate, and viscosity to determine the limitations of NCO/OH in the composition of solid propellants. The propellants consisted of hydroxyl-terminated polybutadiene (HTPB) polyurethane (PU), aluminum (Al) and tri-modal ammonium perchlorate (AP). The tri-modal AP consisted of 30% of coarse AP, 30% of medium AP, and 8% of fine AP. The ratio of NCO/OH varies from 0.73 to 0.85, with two binder percentages of 10.5% and 12%. An increase in NCO/OH ratio with 10.5% binder provided 20%, 95%, and 8 to 9% increments in UTS, modulus, and hardness, respectively. However, the propellant elongation, density, and flow rate decreased by 170%, 0.2%, and 11-12%, respectively. Viscosity increased 20% based on initial hour reading. The 12% binder provides 27%, 47%, and 5~6% an increment of UTS, modulus and hardness respectively. However, the propellant elongation, density, and flow rate decreased by 47%, 0.17% and 27%, respectively. The viscosity increased 30% based on initial hour reading. This study suggests the NCO/OH value of 0.77 and 10.5~11% binder content in propellant based on the mechanical properties, flow rate, and viscosity for better processing and pot life.

Methodology for Selecting Traffic Safety Warning Messages using Analytical Hierarchical Process(AHP)-based Multi-Criteria Value Function (AHP기반 다기준 가치함수를 이용한 교통안전 경고정보 메시지 선정기법)

  • Kim, Tai-Jin;Oh, Cheol;Oh, Ju-Taek
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.9 no.2
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    • pp.1-11
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    • 2010
  • The provision of warning information on upcoming hazards leading to potential crash occurrence is a significant countermeasure to prevent crashes on the highway. This study presents a methodology for selecting more effective warning messages using a multi-criteria value function. The understandability, preference level, and message reading time were used as measures of effectiveness (MOE) for messages. Expert judgements were incorporated into the value function by analytical hierarchical process (AHP) technique. Field experiments to evaluate the warning messages were conducted in a testbed section on the Jungboo-Naeryuk freeway. The proposed methodology would be a useful tool to support the design of various traffic information messages.