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Studies on Physical Properties of Sulfonpolyimide for Fuel Cell (연료전지용 술폰폴리이미드의 물성 연구)

  • Ko, Jae-Churl;Ahn, Bum-Jong;Park, Young-Goo
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.2
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    • pp.151-156
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    • 2005
  • Many researchers have been focused on polymer electrolyte membrane (PEM) to improve performance of a fuel cell. Sulfonpolyimide with hydrocarbon was synthesized from ODA (4,4-diaminodiphenyl ether), ODADS (4,4-diaminodiphenyl ether-2,2-disulfonic acid), NTDA (1,4,5,8-naphthalenetetracarboxylicdianhydride) and CSA (chlorosulfonic acid). In order to estimate the feasibility as a fuel cell, the performance of sulfonpolyimide was analyzed through a swelling degree, IEC (ion exchange capacity), ion conductivity and TEM (transmission electron microscope). As the results of this performance test, swelling degree, IEC and ion conductivity were 37%, 0.06 meq/g and 0.08 S/cm respectively, when the CSA concentration was 0.4 M. It was thought that sulfonpolyimide could be used as a fuel cell through improvement of electrolyte membrane.

A Study on the Strategy of Technical Education Project for Underdeveloped Country (개도국 기술교육사업 지원전략에 관한 연구)

  • Ryu, Gil Ha
    • The Journal of Korean Institute for Practical Engineering Education
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    • v.4 no.1
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    • pp.156-164
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    • 2012
  • Education support programs in underdeveloped countries are important parts of Korea Official Development Assistance (ODA). Even though Education aid for underdeveloped country is increasing every year, expectations of underdeveloped countries for educational cooperation is not enough. Korea's remarkable economic growth is essential to technical education and training that has been investing in fact. Currently, in the underdeveloped country it is needed human resources development for poverty reduction and national economic development. The purpose of this study is to suggest a strategic approach method for technical education support maximizing the effectiveness in the economic development of recipient countries.

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Ectopic Expression of Mitochondria Endonuclease Pnu1p from Schizosaccharomyces pombe Induces Cell Death of the Yeast

  • Oda, Kaoru;Kawasaki, Nami;Fukuyama, Masashi;Ikeda, Shogo
    • BMB Reports
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    • v.40 no.6
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    • pp.1095-1099
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    • 2007
  • Endonuclease G (EndoG) is a mitochondrial non-specific nuclease that is highly conserved among the eukaryotes. Although the precise role of EndoG in mitochondria is not yet known, the enzyme is released from the mitochondria and digests nuclear DNA during apoptosis in mammalian cells. Schizosaccharomyces pombe has an EndoG homolog Pnu1p (previously named SpNuc1) that is produced as a precursor protein with a mitochondrial targeting sequence. During the sorting into mitochondria the signal sequence is cleaved to yield the functionally active endonuclease. From the analogy to EndoG, active extramitochondrial Pnu1p may trigger cell killing by degrading nuclear DNA. Here, we tested this possibility by expressing a truncated Pnu1p lacking the signal sequence in the extramitochondrial region of pnu1-deleted cells. The truncated Pnu1p was localized in the cytosol and nuclei of yeast cells. And ectopic expression of active Pnu1p led to cell death with fragmentation of nuclear DNA. This suggests that the Pnu1p is possibly involved in a certain type of yeast cell death via DNA fragmentation. Although expression of human Bak in S. pombe was lethal, Pnu1p nuclease is not necessary for hBak-induced cell death.

An Analysis of High Speed Forming Using the Explicit Time Integration Finite Element Method(II) - Application to High Speed Rolling - (엑스플리시트 시간 적분 유한 요소법을 이용한 고속 성형 해석(II) - 고속 압연 해석)

  • 유요한;정동택
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.5
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    • pp.1551-1562
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    • 1991
  • 최근까지 발표된 유한 요소법을 이용한 압연 해석 관련 주요 논문들을 정리해 보면 다음과 같다. Li와 Kobayashil는 강소성 유한 요소법(rigidplastic finite element method)을 여러가지 마찰조건에 대하여 해석하였다. 이때 압연롤은 강체 (rigid body)로 시편은 가공경화(workhardening)를 동반한 강소성체로 모델링하였다. Hwang과 Kobayashi는 강소성 유한 요소법을 이용한 평면 변형 압연에서 재료 손실을 최소화하는 예비 성형체(preform)의 설계에 대한 연구를 수행하였다. 이 경우에도 역시 압연롤은 강체로 시편은 가공 경화를 동반한 강소성체와 완전 소성체로 모델링 되었으나, 고착(sticking) 마찰 조건에 대해서만 해석을 수행하였다. Mori와 Osak- ada 그리고 Oda는 약간 압축성이 있는 재료의 평면 변형 압연에 대하여 연구하였다. 이때 압연롤은 강체로 시편은 가공 경화를 동반한 강소성체로 모델링 되었으며 경계 면에서는 Coulomb 마찰을 고려하였다. 이밖에도 오일러(Eulerian) 수식화를 이용한 Dawson과 Thompson, Berman의 해석 결과가 있으며, 또 폭 방향의 변형까지를 고려한 Li와 Kobayashi, Mori와 Osakada의 3차원 해석 결과가 있다.

Study on Reactive Non-thermal Plasma Process combined with Metal Oxide Catalyst for Removal of Dilute Trichloroethylene

  • Han Sang-Bo;Oda Tetsuji;Park Jae-Youn;Park Sang-Hyun;Koh Hee-Seok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.292-300
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    • 2006
  • In order to improve energy efficiency in the dilute trichloroethylene removal using the nonthermal plasma process, the barrier discharge treatment combined with manganese dioxide was experimentally studied. Reaction kinetics in this process was studied on the basis of final byproducts distribution. Decomposition efficiency was improved to about $99\;\%$ at the specific energy of 40 J/L with passing through manganese dioxide. C=C ${\pi}$ bond cleavage of TCE substances gave DCAC, which has the single bond of C-C through oxidation reaction during the barrier discharge plasma treatment. Those DCAC were broken easily in the subsequent catalytic reaction due to the weak bonding energy about $3{\sim}4\;eV$ compared with the double bonding energy in TCE molecules. Oxidation byproducts of DCAC and TCAA from TCE decomposition are generated from the barrier discharge plasma treatment and catalytic surface chemical reaction, respectively. Complete oxidation of TCE into COx is required to about 400 J/L, but $CO_2$ selectivity remains about $60\;\%$.

High sensitivity humidity sensors using polyimide films without fluorinated group (플루오르 그룹을 배제시킨 폴리이미드를 이용한 고감도 습도 센서)

  • Shim, Jae-Hun;Lee, Jun-Young;Kim, Jung-Hyun;Choa, Sung-Hoon;Kim, Yong-Jun
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1997-1999
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    • 2002
  • 고분자 주쇄(Main chain)의 소수성을 가지는 플루오르 그룹을 배제시킨 습도 민감성 폴리이미드를 합성 및 이미드화 하였고, 이를 이용한 초고참도 습도 센서를 제작 및 측정하였다. 사용된 폴리이미드는 다이아민계로 Oxydianyline(ODA)와 다이안하이드라이드계로 Pyromellitic dianhydried(PMDA)를 유기용매 Dimethyla cetamide(DMAc) 하에서 폴리이미드 전구체 (Polyamic acid)를 합성하였으며, 진공 및 승온 조건에서 유기용매를 제거하여 이미드화(Imidization) 반응을 진행시켜 제조하였다. 본 습도 센서는 정전용량형 고감도 습도 센서로 디자인되었으며 실리콘 웨이퍼상에서 일반적인 반도체 공정을 이용하여 구현하였다. 본 습도 센서는 센서 크기와 유효면적, 감습층의 두께를 주요 변수로 설정하였으며 이에 따른 습도 민감성 효과를 평가 및 분석하였다. 측정 결과 유효면적 70%, 감습층 두께 $1.1{\mu}m$ 로 제작된 습도 센서는 상대숨도$20%{\sim}90%$ 영역에서 캐패시턴스와 선형적 상관관계를 보여주고 있으며, 습도 민감도는 3.9 pF/%RH 클 얻을 수 있었다.

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Present State of Membrane Structures in Japan

  • Oda, Kenshi
    • Journal of Korean Association for Spatial Structures
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    • v.2 no.2 s.4
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    • pp.11-15
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    • 2002
  • Formerly, it was called a tent and now, it is called membrane structure. If saying a tent, it imagines the tent of Bedouin, Mongolia and North American Indian. It became clear from the excavated wall painting that have been covered with the retractable roof of the canvas on the auditorium at the amphitheater in Pompeii and became a topic. These tents were made of the animal skins or fabric woven with the flax plants, and these tents are still used. However, if saying membrane material at present, it says the one to have applied a coating resin to the textile. Because the base fabric of membrane material is a woven fabric, the relation between the stress and the strain is different to the direction of the weaving thread. Moreover, the tensile force must always occur in the membrane surface. From these reasons, because the membrane structure corresponds to the particular building material and the construction method about the Building Standard Law, it must be examined specially that the membrane structural building have the same or any more safety as the provisions which was set to the Building Standard Law. Therefore, the technical standards about the membrane structural building became indispensable. In the paper, the kinds of the membrane materials, which are used for the membrane structural buildings, and technical standards process of the creating for the membrane structure buildings are introduced. Lastly, some of the soccer stadiums for 2002 FIFA World Cup KOREA/JAPAN which be covered with the roof of the membrane structures are presented.

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CONTINUUM RADIATION EMITTED FROM THIN CARBON FOILS BY LIGHT ION BOMBARDMENTS

  • Park, Jang-Sick;Nishimura, Fumio;Ichimori, Toshihiro;Kobayashi, Hiso;Oda, Nobuo
    • Proceedings of the Korean Vacuum Society Conference
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    • 1994.06a
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    • pp.92-92
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    • 1994
  • Relative intensities of photons emitted from tilted carbon foils have been measured in the wavelength region 300800 nm by 0,6-2,4 MeV $H^{+}\;and\;He^{+}$ ion impacts, Ions were directed onto target surfaces at tilt angles with respect to the sllrface normal, Experimental results support the model that the observed continuum radiation is emitted from the exited carbon foil itself. At each incident projectile energy, the photon intensities of continuum spectra for tilted carbon foi Is were compatred to the stoppi ng powers of carbon for $H^{+}\;and\;He^{+}$ ions, It was found that the photon emission intensity for $H^{+}$ ion is linearly proportional to the stopping power, whereas that for $He^{+}$ ions is proportional to a higher power of the stopping power, and that this tendency increases wi th decreasing velocity of the projectiIes[1, 2].[1, 2].

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The Impact of Foreign Direct Investment, Aid and Exports on Economic Growth in Vietnam

  • NGUYEN, Cung Huu
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.10
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    • pp.581-589
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    • 2020
  • Foreign factors play an important role in the socio-economic development of each country, in which foreign direct investment (FDI), foreign aid and exports of goods and services are always given top priority in undeveloped countries as well as developing countries. The purpose of this study is to examine the relationship between the various factors such as FDI, foreign aid, exports and economic growth in Vietnam. The empirical method employed secondary time-series data set during the period 1997-2018 to determine the impact of FDI, foreign aid and exports on economic growth in Vietnam by using a linear approach. For this study, data is collected from the World Bank and relevant agencies in Vietnam. An empirical model is built with a correlation and regression analysis between economic growth (GDP, current) and three independent variables (FDI, aid, exports of goods and services). The results show that the relationship between FDI (net inflows), aid, exports and GDP (current) has a positive effect at a 1% significance level. Based on these findings, the article recommends that Vietnam continues to seek effective solutions to maintain high economic growth rates by attracting FDI inflows, official development assistance (ODA), and increasing exports of goods and services.

Conversion Process of Amorphous Si-Al-C-O Fiber into Nearly Stoichiometric SiC Polycrystalline Fiber

  • Usukawa, Ryutaro;Oda, Hiroshi;Ishikawa, Toshihiro
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.610-614
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    • 2016
  • Tyranno SA (SiC-polycrystalline fiber, Ube Industries Ltd.) shows excellent heat-resistance up to $2000^{\circ}C$ with relatively high mechanical strength. This fiber is produced by the conversion process from a raw material (amorphous Si-Al-C-O fiber) into SiC-polycrystalline fiber at very high temperatures over $1500^{\circ}C$ in argon. In this conversion process, the degradation reaction of the amorphous Si-Al-C-O fiber accompanied by a release of CO gas for obtaining a stoichiometric composition and the subsequent sintering of the degraded fiber proceed. Furthermore, vaporization of gaseous SiO, phase transformation and active diffusion of the components of the Si-Al-C-O fiber competitively occur. Of these changes, vaporization of the gaseous SiO during the conversion process results in an abnormal SiC-grain growth and also leads to the non-stoichiometric composition. However, using a modified Si-Al-C-O fiber with an oxygen-rich surface, vaporization of the gaseous SiO was effectively prevented, and then consequently a nearly stoichiometric SiC composition could be obtained.