• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.19 no.6
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• pp.621-629
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• 2008

This paper presents a low temperature co-fire ceramics(LTCC) Upconverter for a Ka-band OBS satellite transponder in order for size reduction which is one of the most important requirement for satellite components. A S-band low-pass filter(LPF), a K-band band-pass filter(BPF), and an upconverting MMIC mixer are embedded in the multi-layer structure of the upconverter. All spurious can be selectively rejected by employing a modified Elliptic low pass filter with a multi-pole structure for the S-band LPF. Also an improved performance of out-of-band rejection can be obtained. At the K-band BPF design a layer coupled configuration is employed. The upconverting mixer is an MMIC diode mixer with a double-balanced configuration. Conversion loss and isolation of the upconverter are 9 dB and 51 dBc, respectively. The size of the LTCC upconverter is only $8{\times}7{\times}0.6mm^3$ which is one-third for the thin-film based upconverter.

• Steel and Composite Structures
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• v.12 no.5
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• pp.445-464
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• 2012

In order to evaluate the dynamic behavior of passive energy dissipation system, two steps need to be considered for prediction of structural response in the presence of ductile element in an off-centre bracing system. The first is a detailed analysis of the proposed ductile element and the second is the effect of this ductile element on an off-centre bracing system. The use of ductile bracing system is expanding in steel structures in order to increase the force reduction factor. Therefore, regarding the nonlinear behavior of steel material used in an off-centre bracing systems and using ductile element in OBS bracing systems, the seismic evaluation of the mentioned systems seems to be necessary. This paper aims to study linear and nonlinear behavior of steel frames with off-centre bracing system and ductile element, in order to get the best position of these bracing elements. To achieve this purpose, the modeling has been done with ANSYS software. The optimum eccentricity has been obtained by modeling three steel frames with different eccentricities and evaluating the results of them. The analytical results showed that the model OBS-C with 0.3 eccentricities has higher performance among the models.

• Bulletin of the Korean Chemical Society
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• v.26 no.12
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• pp.1981-1985
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• 2005

Kinetic studies have been performed for alkaline hydrolysis of a series of [(methoxy)(p-substituted styryl)carbene]pentacarbonyl chromium(0) complexes ($(CO)_5$Cr=$C(OCH_3)CH=CHC_6H_4X$, X = p-$OCH_3$, p-$CH_3$, H, p-Cl, p-$NO_2$). Second-order rate constants $(k_{{OH}^-})$ for the alkaline hydrolysis in 50% acetonitrile-water(v/v) were determined spectrophotometrically at various temperatures. At a low pH region (pH < 7.5), the observed rate constant $(k_{obs})$ remained constant with a small value, while in a high pH region (pH > 9.5), $k_{obs}$ increases linearly with increasing the pH of the medium. The second-order rate constants $(k_{{OH}^-})$ increase as the substituent X changes from a strong electron donating group to a strong electron withdrawing group. The Hammett plot obtained for the alkaline hydrolysis is consisted of two intersecting straight lines. The nonlinear Hammett plot might be interpreted as a change in the rate-determining step. However, the fact that the corresponding Yukawa-Tsuno plot is linear with $\rho$ and r values of 0.71 and 1.14, respectively indicates that the nonlinear Hammett plot is not due to a change in the rate-determing step but is due to ground-state stabilization through resonance interaction. The positive $\rho$ value suggests that nucleophilic attack by $OH^-$ to form a tetrahedral addition intermediate is the rate-determining step. The large negative ${\Delta}S^\neq$ value determined in the present system is consistent with the proposed mechanism.

• Journal of the Korean Chemical Society
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• v.27 no.2
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• pp.133-141
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• 1983

The kinetics of the acid-catalyzed hydrolysis of a series of 1-aryl-2-pyrrylideneaniline (3) have been studied in 20% MeOH solution using UV spectrophotometer. Substituents in 3 showed a relatively small effect, with hydrolysis facilitated by electron withdrawing group. By obtaing linear plots of $log k_{obs}$ against Hammett ${\sigma}$ constants, it was able to show that substituents had a considerable contribution to the aromaticity of pyrrole compounds. The small positive ${\rho}$ values were consistent with the rate-determining addition of water to the protonated schiff base in the buffer solution of pH 4 to 8, whereas the addition of water to the free imine seemed to be the rate-determining in the solution of acidities greater than pH 8.

• Journal of the Korean Chemical Society
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• v.33 no.3
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• pp.273-280
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• 1989

The spectra of the $Co^{II}CyDTA$(CyDTA: cyclohexyldiaminetetraacetic acid) complex have been measured in aqueous solution of pH = 6-13.2. The red shift of the spectrum in the more basic solution was ascribed to the transformation of $CoCyDTA^{2-}$ into $CoCyDTA(OH)^{3-}$. The equilibrium constant, $K_{OH} = [CoCyDTA(OH)^{3-}]/[CoCyDTA^{2-}][OH^-]$ was $75M^{-1}$ at $40^{\circ}C$. The electron transfer reactions of $CoCyDTA^{2-}$ and $CoCyDTA(OH)^{3-}$ with $Fe(CN)_6^{3-}$ have been studied using spectrophotometric technique in the range of pH applied to the determination of equilibrium constant. The pseudo first-order rate constants observed ($k_{obs}$) were not changed upto pH = 10.8, but increased with increasing pH in the range of pH = $10.8{\sim}13.0$. The rate law reduced in the range of pH = 6-13 was $k_{obs} = (k_3[CoCyDTA^{2-}] + k_4[CoCyDTA(OH)^{3-}])/(1+K_1[CoCyDTA^{2-}])$. The rate constants of the reactions (3a) and (3b), $k_3$ and $k_4$ respectively have been determined to be 0.529 and $4.500M^{-1}sec^{-1}$ at $40^{\circ}C$. The activation entropies (147{\pm}1.1JK^{-1} mol^{-1}$ at pH = 10.8) and activation volumes $(6.25cm^3mol^{-1}, pH = 10.8)$ increased with increasing pH, while the activation enthalpy (12.44 ${\pm}$ 0.20 kcal/mole) was independent of pH. Using the pH effect on the rate constants, the activation entropies and the activation volumes, the mechanism of the electron transfer reaction for $Co^{II}-Fe^{III}$ system was discussed.

• Journal of the Korean Chemical Society
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• v.32 no.6
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• pp.528-535
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• 1988

The rates of oxygen ring formation of $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ have been investigated spectrophotometric method in binary aqueous mixtures. Temperature was $20^{\circ}C$ to $40^{\circ}C$ and pressure was varied up to 1500 bar. The observed rate constants are increased by hydrogen ion and decreased by thiocyanate. The more increasing of co-solvents dielectric constant, the more stable intermediate is formed. The observed rate constant is given by, $k_{obs}^{-1} = k^{-1} (1 + K^{-1}[H_2O]^{-1}) All activation parameters are positive values. The oxygen ring formation of [Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ is believed to be a interchange-dissociative mechanism..

• Journal of the Korean GEO-environmental Society
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• v.17 no.11
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• pp.5-14
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• 2016

The main objective of this study was to evaluate the removal properties of Cu from existing exfoliated vermiculite (EV) coated with a mixed solution of sulfuric acid and glycerol on the $580^{\circ}C$ in heating, which uses coated with glycerol of copper ions can be removed more effectively. Serial batch kinetic tests and batch sorption tests were conducted to determine the removal characteristics for Cu in aqueous solution. The result of batch kinetic test shows that removal rate, $K_{obs}$ (1/hr), of Cu are 0.579, 0.878, 3.459, and 6.578 for MEV weight 1 g (25 g/L), 2 g (50 g/L), 3 g (75 g/L), 4 g (100 g/L), respectively. In this case the initial pH of the solution was 3.26. The removal experiment according to the concentration, $K_{obs}$ (1/hr), of Cu are 1.96, 0.878, 1.25, and 1.04 for the initial concentration of 3 mg/L, 5 mg/L, 8 mg/L, 10 mg/L, and the initial pH of the solution are 3.46, 3.26, 3.10, 2.96, respectively. Influence of initial pHs on Cu removal were tested under 1g of MEV with 5 mg/L of Cu solution. $K_{obs}$ (1/hr) were increased from 0.263 (pH 3) to 0.525 (pH 5). It leads to the conclusion that the removal rates are inversely proportional to the initial Cu concentration and are increased proportional to the initial pHs. Sorption capacity of MEV was determined by batch sorption tests. The maximum sorption capacity ($Q_{max}$) obtained from Langmuir was 0.761 mg/g, Linear and Freundlich partition coefficients were 0.494 L/g and 0.729 L/g (1/n = 0.476). These results show that the MEV could be used as an excellent adsorbent for copper contained in various types of aqueous solutions.

• Journal of Environmental Science International
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• v.26 no.10
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• pp.1167-1180
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• 2017

Numerical Weather Prediction (NWP) models such as the Weather Research and Forecasting (WRF) model are essential for forecasting one-day-ahead solar irradiance. In order to evaluate the performance of the WRF in forecasting solar irradiance over the Korean Peninsula, we compared WRF prediction data from 2008 to 2010 corresponding to weather observation data (OBS) from the Korean Meteorological Administration (KMA). The WRF model showed poor performance at polluted regions such as Seoul and Suwon where the relative Root Mean Square Error (rRMSE) is over 30%. Predictions by the WRF model alone had a large amount of potential error because of the lack of actual aerosol radiative feedbacks. For the purpose of reducing this error induced by atmospheric particles, i.e., aerosols, the WRF model was coupled with the Community Multiscale Air Quality (CMAQ) model. The coupled system makes it possible to estimate the radiative feedbacks of aerosols on the solar irradiance. As a result, the solar irradiance estimated by the coupled system showed a strong dependence on both the aerosol spatial distributions and the associated optical properties. In the NF (No Feedback) case, which refers to the WRF-only stimulated system without aerosol feedbacks, the GHI was overestimated by $50-200W\;m^{-2}$ compared with OBS derived values at each site. In the YF (Yes Feedback) case, in contrast, which refers to the WRF-CMAQ two-way coupled system, the rRMSE was significantly improved by 3.1-3.7% at Suwon and Seoul where the Particulate Matter (PM) concentrations, specifically, those related to the $PM_{10}$ size fraction, were over $100{\mu}g\;m^{-3}$. Thus, the coupled system showed promise for acquiring more accurate solar irradiance forecasts.

• Economic and Environmental Geology
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• v.44 no.3
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• pp.229-238
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• 2011

S-wave, which provides lithology and pore fluid information, plays a key role in estimating gas-hydrate saturation. In general, P- and S-wave velocities increase in the presence of gas-hydrate and the P-wave velocity decreases in the presence of free gas under the gas-hydrate layer. Whereas there are very small changes, even slightly increases, in the S-wave velocity in the free gas layer because S-wave is not affected by the pore fluid when propagating in the free gas layer. To verify those velocity properties of the BSR (bottom-simulating reflector) depth in the gas-hydrate prospect area in the Ulleung Basin, P- and S-wave velocity profiles were derived from multi-component ocean-bottom seismic data which were acquired by Korea Institute of Geoscience and Mineral Resources (KIGAM) in May 2009. OBS (ocean-bottom seismometer) hydrophone component data were modeled and inverted first through the traveltime inversion method to derive P-wave velocity and depth model of survey area. 2-D multichannel stacked data were incorporated as an initial model. Two horizontal geophone component data, then, were polarization filtered and rotated to make radial component section. Traveltimes of main S-wave events were picked and used for forward modeling incorporating Poisson's ratio. This modeling provides S-wave profiles and Poisson's ratio profiles at every OBS site. The results shows that P-wave velocities in most OBS sites decrease beneath the BSR, whereas S-wave velocities slightly increase. Consequently, Poisson's ratio decreased strongly beneath the BSR indicating the presence of a free gas layer under the BSR.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.66.2-66.2
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• 2014

We carried out photometric observations of Maria family asteroids during 134 nights spanning from July 2008 to May 2013, and derived synodic rotational periods for 51 objects including obtained periods of 34 asteroids for the first time. In this study, we found that there is a significant excess of fast and slow rotators. The one-sample Kolmogorov-Smirnov test confirms that the spin rate distribution is not consistent with the Maxwellian at a 92% confidence level. From the correlations between rotational period, amplitude of lightcurve, and size, we conclude that rotational properties of Maria family have been changed considerably by the non-gravitational force such as the Yarkovsky and the YORP effect. Using the lightcurve inversion method, we successfully determined the pole orientation for the 13 Maria members, and found the excess of prograde objects versus retrograde with a ratio ($N_p/N_r$) of 3. This implies that retrograde rotators could have been ejected by the 3:1 resonance to the inner Solar System since the generation of Maria family. We estimate that approximately 37 - 75 kilometer-sized Maria asteroids have entered to near-Earth space every 100 Myr.