• 제목/요약/키워드: O3 effects

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$Sr(Zr, Ti)O_3$ 마이크로파 유전체에 첨가된 $Mn_2O_3, Y_2O_3$ 의 영향과 Mn의 산화상태 (Effects of $Mn_2O_3, Y_2O_3$ Additives and Valence State of Mn ion in $Sr(Zr, Ti)O_3$ Microwave Dielectrics)

  • 정하균;박도순;박윤창
    • 한국세라믹학회지
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    • 제34권6호
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    • pp.583-590
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    • 1997
  • The effects of Mn2O3 and Y2O3 additives on the microstructure and dielectric properties of Sr(Zr, Ti)O3 have been investigated. Powders with Sr(Zr1-xTix)O3(0$\leq$x$\leq$0.1) composition were prepared by the conventional solid state processing from commercial TiO2 and precipitation-processed ZrO2. The powders containing sintering additives of Mn2O3 and Y2O3 were compacted and then sintered at 1,55$0^{\circ}C$ for 4 h to get>97% relative density. Mn2O3 suppressed the grain growth and Y2O3 enhanced the density of sintered body. The oxidation state of Mn ions were determined by a chemical wet method and EPR spectroscopy. Mn ions were present as Mn2+ and Mn4+ in SrZrO3, while as Mn3+ and Mn4+ in Ti-substituted Sr(Zr, Ti)O3. With the substitution of Ti, the lattice parameters of SrZrO3 decreased and its dielectric constant increased with remarkable decrease in Q value. The dielectric constant of Sr(Zr, Ti)O3 was in the range of 30 to 40, Q values 1,200~5,400 at 6 GHz and temperature coefficient of resonant frequency -67~100 ppm/K.

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Flux가 Lithium Ferrite의 미세구조 및 메모리코어 특성에 미치는 영향 (The Effects of Flux on the Microstructure and Memory Core Characteristics of Lithium Ferrites)

  • 임호빈
    • 한국세라믹학회지
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    • 제16권1호
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    • pp.26-30
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    • 1979
  • The microstructures and memory core characteristics of substituted lithium ferrites with addition of $Bi_2O_3$, $V_2O_5$, $Nb_2O_3$, and $P_2O_5$ were investigated. The effects of composite flux on the sintering of the substituted lithium ferrites were also studied. The results show that the addition of $Bi_2O_3$, $V_2O_5$, and $Nb_2O_5$ enhances sintering whereas $Sb_2O_3$ and $P_2O_5$ inhibits it, and that the addition of $Nb_2O_5$ results in uniform grain size while the addition of $Bi_2O_3$ or $V_2O_5$ results in non-uniformity in grain size. When $P_2O_5$ was added with $V_2O_5$ or $Bi_2O_3$, however, it results in uniform grain size and improved memory core properties.

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ZTA계에서 첨가물($Cr_2O_3$, $HfO_2$)에 따른 물성 변화 및 기계적 성질이 마모성에 미치는 영향 (Characteristics and Effects for the Mechanical Properties on the Wearness of the ZTA System with $Cr_2O_3$ and $HfO_2$) as Additives)

  • 최성철;이응상
    • 한국세라믹학회지
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    • 제27권3호
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    • pp.369-382
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    • 1990
  • ZrO2-Toughened Alumina-Ceramics(ZTA) with Cr2O3 and HfO2 as addition were synthesized by assintering method for solid solution of Al2O3/Cr2O3 and ZrO2/HfO2, and were prepared by pressureless sintering at 1$600^{\circ}C$. The effects of Cr2O3 and HfO2 on the thermal and mechanical properties, the sintering mechanism, and the wearness between theory and experiment were investigated. Among three kinds of mechanisms such as stress-induced transformation, microcracking, and crack deflection it contributed to the ZTA system with a few exceptons according to composite. We show that wearness can be estimated sufficiently by HV and KIC through theory and experiment.

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Plasma-sprayed Coatings of Aluminium Oxide and Mulite

  • 소대화
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.336-339
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    • 2003
  • The present report is the investigation of the effects of the HIP treatment on plasma-sprayed ceramic coating of $Al_2O_3$, $Al_2O_3-SiO_2$ on the metal substrate. These effects were characterized by phase identification, Vickers hardness measurement, and tensile test before and after HIPing.

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HIP Effects on Mechanical Properties of Oxide Plasma-sprayed Coatings

  • Korobova, N.;Soh, Dea-Wha
    • 동굴
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    • 제76호
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    • pp.61-66
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    • 2006
  • The present report is the investigation of the effects of the HIP treatment on plasma-sprayed ceramic coating of $Al_2O_3$, $Al_2O_3-SiO_2$ on the metal substrate. These effects were characterized by phase identification, Vickers hardness measurement, and tensile test before and after HIPing.

용융염 합성법에 의한 반도성 $BaTiO_3$의 PTCR 효과 (PTCR Effects in Molten Salt System Synthesized Semiconductive $BaTiO_3$)

  • 윤기현;오기영
    • 한국세라믹학회지
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    • 제22권3호
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    • pp.13-18
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    • 1985
  • Semiconductive $Ba_{0.9}Sr_{0.1}TiO_3$ was prepared by both the Calcining of mixed Oxides (C. M. O) and the Molten Salt Synthesis(M.S.S) methods to investigate the PTCR effects. In the Molten Salt Synthesis method the temperature of calcination for Synthesis of $BaTiO_3$ could be lowered from 110$0^{\circ}C$ to 80$0^{\circ}C$. The M.S.S Specimens had smaller grain size and more homogeneous size distribution at the same sintering temperature as compared with the C. M. O specimens. The M. S. S. specimens showed greater PTCR effects and current variations in the time vs. current charac-teristics than those of C. M. O Specimens.

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ZnO 바리스터 제조시 소결후 열처리 조건에 따른 미세구조 및 전기적 특성에 관한 연구 (Effects of Annealing on the Microstructure and Electrical Properties of ZnO Varistor)

  • 소진중;한세원;김형식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1679-1681
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    • 1996
  • ZnO varistor with composition of 89wt%-ZnO, 3.0wt%-$Bi_{2}O_{3}$, 3.6wt%-$Sb_{2}O_{3}$, 1.16wt%-CoO, 0.88wt%-NiO, 0.71wt%-$MnO_2$, 0.93wt%-$Cr_{2}O_{3}$, 0.013wt%-$Al_{2}O_{3}$ was fabricated by sintering methods. The effects of annealing on the J-E characteristics of ZnO varistors were investigated. These changes of electric properties were found to be caused by the variation of grains and grain boundary related to annealing. And the conductive mechanism and micostructure of ZnO varistor were researched using I-V meter, SEM and XRD.

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Al$_2$O$_3$-SiC-C 내화물의 특성에 미치는 MgO의 첨가효과 (Effects of MgO Addition on the Properties of $Al_2$O$_3$-SiC-C Refractory)

  • 조문규;정두화;이석근
    • 한국세라믹학회지
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    • 제35권2호
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    • pp.129-136
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    • 1998
  • The effects of MgO on the resistance to corrosion and oxidation of Al2O3-SiC-C refractory have been in-vestigated. The resistance to oxidation was improved as the amount of MgO increased. The resistance to corrosion was enhanced until 2 wt% MgO content but degraded over that content. From the dependence of temperatuer on the oxidation resistance oxidation was suppressed by the microstructural densification caused by spinel formation over 1200~130$0^{\circ}C$and the formation MgO-Al2O3-SiO2 liguid-phase over 130$0^{\circ}C$ The weight loss of specimens containing MgO with various purity at range of 95 to 99% and par-ticle size of -0.045 mm to -0.074 mm was examined. The oxidation resistance was not changed signficantly with the particle size and purity of MgO powders.

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The Oxide Coating Effects on the Magnetic Properties of Amorphous Alloys

  • 배영제;Jang, Ho G.;Chae, Hee K.
    • Bulletin of the Korean Chemical Society
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    • 제17권7호
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    • pp.621-625
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    • 1996
  • A variety of metal oxides were coated by sol-gel process from their metal alkoxides on the ribbons of Co-based and Fe-based amorphous alloys, and the effects of surface oxide coating on the magnetic properties of the alloy are investigated. The core loss is found to be reduced significantly by the oxide coating, the loss reduction becoming more prominent at higher frequencies. The shape of the hystersis loop is also dependent upon the kind of the coated metal oxide. The coatings of MgO, SiO2, MgO·SiO2 and MgO·Al2O3 induce tensile stress into the Fe-based ribbon whereas those of BaO, Al2O3, CaO·Al2O3, SrO·Al2O3 and BaO·Al2O3 induce compressive stress. These results may be explained by the modification of domain structures via magnetoelastic interactions with the shrinkage stress induced by the sol-gel coating.

The Effects of Using O2O Fashion Mobile Commerce on Consumers' Attitudes and Intentions -Focused on the characteristics of consumers and O2O mobile commerce-

  • Ko, Takhwan;Yeom, Sunyoung;Lee, MiYoung
    • 패션비즈니스
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    • 제21권3호
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    • pp.67-79
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    • 2017
  • This study investigated consumers' enjoyment, perceived risks, expected values, and innovativeness factors and the effects of the convenience and personalization of "online to offline" (O2O) fashion mobile commerce on its perceived usefulness, perceived ease of use, and consumers' attitudes and intention to use O2O mobile commerce. A research model was developed using the Technology Acceptance Model (TAM). A mobile survey was conducted through smartphone messengers and SNSs targeting male and female college students in their 20s who are living in the Seoul Metropolitan Area. A total of 192 questionnaire responses were used in the analysis. "Among the consumer characteristics, only enjoyment and expected values were found to make consumers feel that the O2O fashion mobile commerce is useful and easy to use. Among the mobile commerce characteristics, only convenience was found to have significant effects on consumers' perceived usefulness and ease of use regarding O2O fashion mobile commerce. Perceived usefulness was found to have the effects on attitudes as well as intention to use toward O2O mobile commerce. It was shown that positive attitudes toward O2O mobile commerce led to positive use intention toward O2O mobile commerce.