• Title/Summary/Keyword: O$_2$ concentration

Search Result 6,545, Processing Time 0.033 seconds

Study on the Elution Behaviors of Molybdate and Tungstate in Both Hydrochloric and Perchloric Acid by Anion Exchange Chromatograpphy

  • Cha, Ki-Won;Choi, Jae-Sung;Park, Kee-Chae
    • Bulletin of the Korean Chemical Society
    • /
    • v.2 no.2
    • /
    • pp.37-41
    • /
    • 1981
  • The elution behaviors of molybdate and tungstate through anion exchange column have been investigated in the various concentration of hydrochloric and perchloric acid. A discussion is made to evaluate the existing these equilibrium and constant according to acidity. In both acids of 0.01-2.0 M concentration range, the existing equilibrium for molybdate and its constant calculated at $20^{\circ}C$ is $10^{18.9}$ for $Mo_8O_2^{4-} + 20H^+ {\rightleftharpoons} 8MoO_2^{2+} + 10H_2O$. In the 3-3.5 M hydrochloric acid it is 0.16 for $MoO_2Cl_2 + Cl^- {\rightleftharpoons} MoO_2Cl^{3-}$ and for the case of tungstate, in the both acids of 0.01-1.0 M concentration range $10^{6.6}$ for $W_{12}O_{39}^{6-} + 6H^+ {\rightleftharpoons} 12WO_3{\cdot}3H_2O$. In higher concentration than 1.0 M both acids the following equilibrium seems to be existed. $12WO_3{\cdot}3H_2O {\rightleftharpoons} 12WO_3 + 3H_2O$

Boron Diffusion of Low Concentration through Poly $Poly{\cdot}Si-SiO_2$ ($Poly{\cdot}Si-SiO_2$를 통한 저농도 붕소확산)

  • Kim, Jung-Hoe;Ju, Byeong-Kwon;Kim, Chul-Ju
    • Journal of the Korean Institute of Telematics and Electronics
    • /
    • v.24 no.2
    • /
    • pp.248-253
    • /
    • 1987
  • Boron diffusion into silicon through poly\ulcorneri-SiO2 was carried out for the diffusion with low concentration using CVD-BN. The result of direct boron diffusion from BN into silicon and that of boron diffusion through SiO2 from BN into silicon was compared with the result of boron diffusion through poly-Si-SiO2 from BN into silicon. In the case of boron diffusion through poly Si-SiO2, the low concentration diffusion was obtained, that is the boron surface concentration in silicon Cs=10**16 Cm**-3, and the glassy compounds were not seen.

  • PDF

Evaluation of Microstructure and Electrical Properties in (Na,K)NbO3-Based Pb-free Piezoelectrics Doped with Various Cu2O Concentration ((Na,K)NbO3계 무연 압전체에서 Cu2O 첨가물의 농도 변화에 따른 미세구조 및 전기적 특성 평가)

  • Lee, Youn-Ki;Ryu, Sung-Lim;Kweon, Soon-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.24 no.11
    • /
    • pp.870-875
    • /
    • 2011
  • The $(Na_{0.52}K_{0.44})(Nb_{0.9}Sb_{0.06})O_3-0.04dLiTaO_3$ (NKNS-LT) ceramics with various $Cu_2O$ concentration were prepared by the conventional solid state reaction method. The $Cu_2O$ content was varied in the range of 0.1~0.4 wt%. The effects of Cu on microstructure, crystallographic phase transition, and piezoelectric properties were investigated. The material with perovskite structure had a tetragonal phase (T1) when $Cu_2O$ concentration was less than 0.3 wt% and it transformed to another tetragonal phase (T2) when the $Cu_2O$ amount was greater than 0.3 wt%. The phase boundary between T1 and T2 phases appeared at around 0.3 wt% of $Cu_2O$ concentration. The piezoelectric properties were shown the maximum values at the composition of the phase boundary. The electro-mechanical coupling factor ($k_p$) was 0.42 and the piezoelectric charge constant ($d_{33}$) was 245 pC/N at the 0.3 wt% of $Cu_2O$ concentration.

The influence of $O_2$ concentration on the generation of $NO_2$ by using the wire-plate reactor (선대 평판형 반응기에서 $NO_2$ 생성에 미치는 $O_2$의 영향)

  • Park, Jae-Youn;Kim, Sung-Jin;Kim, Jong-Dal;Lee, Sun-Jae;Ha, Sang-Tae;Han, Sang-Bo;Lee, Dong-Hoon
    • Proceedings of the KIEE Conference
    • /
    • 2000.07c
    • /
    • pp.2050-2052
    • /
    • 2000
  • In this paper, the effect of $O_2$ concentration on NO removal and $NO_2$ generation by corona discharge from simulated flue gas was measured and estimated for the wire-plate reactor. $NO_2$ removal rate was 0$\sim$30[%] under about 3.4[%] of oxygen concentration, however, it was difficult to remove NOx over 3.4[%] of oxygen concentration. It may be due to generate $NO_2$ from $N_2$ and $O_2$ molecules and converse NO to $NO_2$ by 0 and $O_3$. Magnetic field applied to electric field in plasma was very effective for NOx removal under 2[%] of $O_2$ concentration.

  • PDF

Characteristic of Photodegradation of MTBE Using TiO2/UV Process (TiO2/UV공정을 이용한 수중 MTBE의 광분해 특성)

  • Ryu, Seong Pil;Kim, Seong Su;O, Yun Geun
    • Journal of Environmental Science International
    • /
    • v.13 no.3
    • /
    • pp.289-295
    • /
    • 2004
  • The objective of this study is to delineate removal efficiency of the MTBE in solution by $TiO_2$ photocatalytic degradation as a function of the following different experimental conditions: Initial concentration of MTBE, air flow rate in solution, $H_2O_2$ dosage and pH of the solution. Photodegradation rate was increased with decreasing initial concentration of MTBE. The removal efficiency was 82% after 180 min in the case of MTBE concentration of 100 mg/L but 100% after 180 min in the case of 20 mg/L. Removal efficiency was increased with increasing pH, $H_2O_2$ dosage and air flow rate in solution.

Determination of Physiological Changes according to Nitrous Concentration and Application Method (아산화질소 농도 및 적용방법에 따른 생리학적 변화)

  • Lee, Daewoo;Han, Jihoon;Yang, Yeonmi
    • Journal of the korean academy of Pediatric Dentistry
    • /
    • v.43 no.4
    • /
    • pp.435-442
    • /
    • 2016
  • The aim of this study was to analyze physiological changes, clinical and subjective symptoms by different $N_2O$ concentrations and administration method. This study surveyed 65 men and women ages 19 to 35 and all subjects were healthy volunteers, with no contraindication for use of $N_2O$ sedation. The $N_2O$ sedation was carried out in a way that increases by 10 percent to one-minute interval or increases at once the desired level. Each method was required to reach 30 or 50 percent $N_2O$ concentration. The way to gradually raise the $N_2O$ concentration can reduce the risk by decreasing the pulse reduction rate at the same $N_2O$ concentration. $SpO_2$ has no statistical significance according to $N_2O$ concentration and method of administration. Pulse rate reduced significantly when 50% $N_2O$ increase at once during sedation and 100% $O_2$ after 5 minutes. The way to gradually raise the $N_2O$ concentration is safe for reducing pulse rate.

A Study on Comparison and Evaluation Standard of Photocatalytic Activity for Commercial TiO2 (광촉매 TiO2의 반응활성 비교 . 평가 기준에 관한 연구)

  • Lee, Sang-Jin;Hong, Sung-Chang
    • Journal of Environmental Science International
    • /
    • v.17 no.7
    • /
    • pp.801-808
    • /
    • 2008
  • This study was investigated experimental condition which is able to evaluate photocatalytic activity of various commercial $TiO_2$. The experiments were performed for three representative substances (ethanol, phenol and methylene blue) and four kinds of commercial $TiO_2$, under the experimental conditions such as pH, reactant concentration, amount of $TiO_2$, reaction time and UV intensity. The optimum experimental conditions to evaluate photocatalytic activity were as follows : for ethanol, the initial concentration 1000 ppm, initial pH 8, $TiO_2$ loadings 0.1 wt%, and reaction time 90 minutes: for phenol, the initial concentration 200 ppm, initial pH 8, $TiO_2$ loadings 1 wt%, and reaction time 60 minutes: for methylene blue, the initial concentration 200 ppm, initial pH 4, $TiO_2$ loadings 0.5 wt%, and reaction time 30 minutes.

Effects of Water on the Electrical Conductivity of Magnesium Metaphosphate Glasses (MgO.$P_2O_5$ 유리의 전기전도도에 미치는 수분의 영향)

  • 강은태;박용완
    • Journal of the Korean Ceramic Society
    • /
    • v.23 no.4
    • /
    • pp.85-89
    • /
    • 1986
  • Electrical conductivity have been measured as function of temperature in MgO.$P_2O_5$ glasses containing small amounts of water. Conduction was due to the contribution of $H^+$ and the mobility of protons in the glass increased linearly with increasing its concentration. The conductivity was pro-portional to the square of the proton concentration and the activation energy decreased linerly with increasing logarithm of the proton concentration, And $$\sigma$_0$ and $A_0$ was independent of the proton concentration but not on glass compositions.

  • PDF

Preparation and Photoluminescence of Mn-Doped $ZnGa_2O_4$ Phosphors (Mn 도핑한 $ZnGa_2O_4$ 형광체의 제조 및 빛발광 특성)

  • 류호진;박희동
    • Journal of the Korean Ceramic Society
    • /
    • v.33 no.5
    • /
    • pp.531-535
    • /
    • 1996
  • ZnGa2O4 and Mn-doped ZnGa2O4 were synthesized using the state reaction method to investigate their photoluminescence characteristics depending on Mn concentration. Under 254nm excitation, ZnGa2O4 exhibited a broad-band emission extending from 330 nm to 610 nm peaking at 450nm. On the other hand Mn-doped ZnGa2O4 showed a new strong narrow-band emission peaking at 504 nm and maximum intensity at the doping concentration of 0.006 mole Mn.

  • PDF

Catalytic Oxidation of VOCs using Photocatalysis (광촉매반응을 이용한 VOCs의 촉매산화)

  • 이승범;이재동
    • Journal of environmental and Sanitary engineering
    • /
    • v.18 no.2
    • /
    • pp.52-59
    • /
    • 2003
  • This study was progressed in photocatalysis of VOCs using $UV/TiO_2$ which was a benign process environmentally. The experiments were peformed to know photodegradation characteristics as crystalline structure of $TiO_2$ which had anatase, rutile and P-25 (anatase : rutile = 70 : 30). The main purpose of this study was to identify photocatalytic characteristics as inlet concentration of reactants, $H_2O$, and residence time. The inlet concentration of VOCs was changed 50, 100 and 200 ppmv, and amount of $H_2O$ was changed 0, 500 and $1000{\;}mg/m^3$, respectively. The deep conversion was increased as the inlet concentration decreased, and the amount of $H_2O$ increased. The deep conversion of benzene had the highest value at $1000{\;}mg/m^3${\;}H_2O$ and 50 ppmv of inlet concentration. The reactivity of reactants was decreased in order benzene > toluene > m-xylene. Also, the photocatalytic deep conversion was increased as residence time increased, because the contact time between reactants and catalyst was increased. In this study, intermediates had not found by GC/MSD analysis. Therefore, the reactants were completely converted to $H_2O{\;}and{\;}CO_2$.