• Title/Summary/Keyword: Nylon 12

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Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin - (II) The Effects of Terpene Resin - (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능향상 - (II) 테르펜수지의 영향 -)

  • Chung, Kyung-Ho;Hong, Young-Keun;Chun, Young-Sik
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.226-231
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    • 1998
  • Hot melt adhesive which is solventless type has been widely used due to the possibility of automated adhesion process. The main purpose of this study is the development of polyamide based hot melt adhesive to improve the property of conventional ethylene-vinyl acetate hot melt adhesive, which has an inherent problem against heat resistance. In this study, it was found that the terpolymers of nylon 6, nylon 66, and nylon 12(CM831, 843P types) instead of nylon homopolymer were suitable base resins for hot melt adhesive, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. According to the results, the optimum adhesion property could be obtained by the using 75/25~50/50 weight radio of CM831/843P resin as a base resin. Terpene resin was used as tackifier to improve adhesion and wetting properties. The best result can be obtained with the 10 wt.% addition of terpene resin. The terpene resin acted as proper tackifier in this system which decreased the melt temperature and viscosity, but increased the mechanical strength of adhesive itself. Also, the rheological property of the adhesive changed from typical non-Newtonian behavior to Newtonian behavior as terpene resin was added.

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Assessment of Radiation Shielding Ability of Printing Materials Using 3D Printing Technology: FDM 3D Printing Technology (3D 프린팅 기술을 이용한 원료에 대한 방사선 차폐능 평가: FDM 방식의 3D 프린팅 기술을 중심으로)

  • Lee, Hongyeon;Kim, Donghyun
    • Journal of the Korean Society of Radiology
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    • v.12 no.7
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    • pp.909-917
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    • 2018
  • 3D printing technology is expected to be an innovative technology of the manufacturing industry during the 4th industrial revolution, and it is being used in various fields including biotechnology and medical field. In this study, we verified the printing materials through Monte Carlo simulation to evaluate the radiation shielding ability of the raw material using this 3D printing technology. In this paper, the printing materials were selected from the raw materials available in a general-purpose FDM-based 3D printer. Simulation of the ICRU phantom and the shielding system was carried out to evaluate the shielding effect by evaluating the particle fluence according to the type and energy of radiation. As a result, the shielding effect tended to decrease gradually with increasing energy in the case of photon beam, and the shielding effect of TPU, PLA, PVA, Nylon and ABS gradually decreased in order of materials. In the case of the neutron beam, the neutron intensity increases at a low thickness of 5 ~ 10 mm. However, the effective shielding effect is shown above a certain thickness. The shielding effect of printing material is gradually increased in the order of Nylon, PVA, ABS, PLA and TPU Respectively.

Rheology and Morphology of Ethylene-Vinyl Alcohol Copolymers/Nylons Blends (에틸렌-비닐알콜 공중합체와 나일론 블렌드의 유변학 및 형태학)

  • 김창기;김병규;정한모;허정도
    • The Korean Journal of Rheology
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    • v.1 no.1
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    • pp.20-28
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    • 1989
  • 비닐 알코올의 함량이 62(EVOH-62) 및 71(EVOH-71) mole%인 에틸렌 비닐알코올 공중합체와 나일론(나일론-6, 나일론-6/12 및 나일론-12)과의 블렌드를 이축압출기에서 제 조하였으며 이들블렌드의 형택학 및 유변학적 성질을 SEM, TEM 및 RDS로 측정하였다. EVOH-61/나일론-6 및 EVOH-7/나일론-6 블렌드는 나일론의 조성이 많은 영역에서는 균 일상을 EVOH 조성이 많은 영역에서는 미세한 상분리(약 0.2$\mu$)를 나타내었다. 한편 EVOH-71/나일론-6/12 및 EVOH-71/나일론-12 블렌드는 상분리가 뚜렸하였으며 EVOH조 성이 많은 영역에서는 피브릴화가 나타났다. 낮은 진동주파수 영역에서 점도 대 조성곡선은 전반적으로 양의 편차를 보였으나 Cole-Cole plot은 나일론-6과의 블렌드가 나일론-6/12나 나일론-12와의 블렌드에 배해 유변학적인 측면에서보다 상용성이 우수함을보였다.

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DETERMINATION OF THE APPARENT ILEAL DIGESTIBILITY OF PROTEIN AND AMINO ACIDS IN FEEDSTUFFS AND MIXED DIETS FOR GROWIG-FINSHING PIGS WITH THE MOBILE NYLON BAG TECHNIQUE

  • Yin, Y.L.;Zhong, H.Y.;Huang, R.L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.8 no.5
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    • pp.433-441
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    • 1995
  • A series of experiments was conducted to determine the influence of various pepsin-HCL pretreatment factor, hereby the factors of duration of washing for the retrieved bags, inherent to the mobile nylon bag technique (MNBT), on apparent ileal digestibility of crude protein (AIDCP) and apparent ileal digestibility of dry matter (AIDDM). At last, the AIDCP and apparent ileal digestibility of amino acids (AIDAA) in maize, barley, wheat, rapeseed meal, cottonseed meal and three mixed diets were determined with the MNBT and ileo-rectal anastomis pigs (IRAT). For the MNBT techniques, bag measuring $25{\times}40$ MM and containing 0.75 g feedstuff samples, after pre-digestion in vitro, were introduced into the ileo-rectal anastomis pigs (IRAT) gastrointestinal tract through a duodenal cannula and recovered in the ileal digesta between 6 and 12 h. later. 1. The apparent ileal digestibility of dry matter (AIDDM) and crude protein (AIDCP) of the tested samples, with the exception of fish meal, determined by MNBT were not affected by the different pepsin-HCL pretreatment times in vitro between 2.5 h. and 4 h. 2. There was no significant (p > 0.05) difference of the AIDCP and AIDDM of maize determined by the MNBT among different pepsin concentration (0.03%, 0.07% and 0.1 %) treatment in vitro. 3. The AIDCP determined with the MNBT was affected by the washed and unwashed recovered bags from the ileal digesta. 4. The AIDCP and AID amino acids (AIDAA) of maize, barley, wheat, rapeseed meal, soya-bean meal, cottonseed meal and three mixed diets from the MNBT, with a solution of 0.01N HCL (PH 2) and 0.1% of pepsin concentration, a pepsin-HCL pretreatment time in vitro or 4h. and a washing time of the recovered bag from the ileal digesta compared well with those from the IRAT. The linear regression analysis showed a significant correlation (p < 0.01) of AIDCP and AIDDA between the IRAT and MNBT.

Dynamic Fracture Properties of Nylon Thermoplastic Material Depending on Notch Angle with Charpy Impact Machine and Finite Element Method (유한요소법과 샤피충격시험기에 의한 노치각도에 따른 나일론 열가소성 플라스틱 재료의 파괴특성)

  • Park, Myung-Kyun;Lee, Jung-Won;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
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    • v.12 no.1
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    • pp.1-6
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    • 2008
  • The notched Charpy impact test is one of the most prevalent techniques used to characterize the effect of high impulse loads on polymeric materials. In this study, a method of analysis in nylon plastic materials is suggested to evaluate the critical strain energy release rate for variation of notch angles from the Charpy impact energy measurement. Instrumented Charpy impact tester was used to extract ancillary information concerning fracture parameters in addition to total fracture properties and maximum critical load. The dynamic stress intensity factor of nylon plastic material was calculated for the ASTM Charpy specimen from the obtained maximum critical load. Also, the finite element model was developed to figure out the stress distributions for Charpy specimen with different notch angles subject to 3 point bending load which is equivalent to the load applied in the experiment.

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Dyeing Properties and Ultraviolet-cut Ability of Fabrics Dyed with Coffee Bean Extracts (커피 추출액에 의한 직물의 염색성과 자외선 차단성)

  • Choi, In-Ryu;Joen, Mi-Sun
    • The Research Journal of the Costume Culture
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    • v.17 no.4
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    • pp.575-582
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    • 2009
  • The coffee has been used as drink in the world and it has been using not only food but also dyeing. It can be used for four seasons in our normal living and it can be taken friendly everywhere. The coffee consists of about 8${\sim}$10% phenol(chlorogenic acid) that related to antioxidant and antimicrobial activity. However, its exact components and the dyeing property effects has not been well known yet. Therefore, the purpose of this study was to investigate the dyeing property and ultraviolet-cut ability of silk and nylon fabrics that was dyed variously with coffee extracts. Coffee extracts were done by boiling coffee with distilled water at $100^{\circ}C$ for 2 hours. As mordanting agent, we used $AlK(SO_4)_2$ $12H_2O$, $CuSO_4$ $5H_2O$, $FeCl_2$ $4H_2O$. As the result of the dyeing properties and ultraviolet-cut ability of fabrics dyed with coffee bean extracts, we can find that the optimum dyeing temperature and dyeing time of the silk and nylon fabrics dyed with coffee bean extracts was $90^{\circ}C$, 60 min. and the colorfastness of washing and dry-cleaning was improved by using mordanting agent(4${\sim}$5 grade). Ultraviolet-cut ability was showed more 90% in dyed nylon fabrics.

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Distribution of T and B lymphocytes in peripheral blood and lymphoid tissues of bovine (소의 순환혈액 및 림프조직내 T 및 B 림프구 분포)

  • Yoon, Chang-yong;Kim, Tae-Joong;Chai, Hyo-seok;Kim, Jong-Myeog;Song, Hee-jong
    • Korean Journal of Veterinary Research
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    • v.31 no.1
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    • pp.71-75
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    • 1991
  • This study was undertaken to identify the distribution of T and B lymphocytes in bovine peripheral blood and various lymphoid tissues by the method of ABPC using RABTS, $BLT_1$ and $_6E_{12}$ as primary antibodies. RABTS, $BLT_1$ and $_6E_{12}$ positive cells in PB-MNCs were 70.9${\pm}5.5%$, $59.0{\pm}8.7%$ and $23.0{\pm}8.7%$, respectively. $BLT_1$ and $_6E_{12}$ positive cells in nylon wool nonadherent cells of PB-MNCs were $91.6{\pm}1.0%$ and $9.6{\pm}0.8%$, respectively. In the lymphoid tissues such as inguinal lymph node, mesenteric lymph node, spleen and thymus, positive cells of RABTS were $76.3{\pm}3.4%$, $74.2{\pm}8.2%$, $73.6{\pm}5.5%$ and $95.6{\pm}2.8%$, those of $BLT_1$ were $56.4{\pm}6.2%$, $55.6{\pm}7.7%$, $48.6{\pm}5.1%$ and $23.0{\pm}4.8%$ and those of $_6E_{12}$ were $45.3{\pm}7.4%$, $42.3{\pm}5.8%$, $48.5{\pm}6.2%$ and $5.6{\pm}2.1%$, in order. These results are indicating that nylon wool column method is effective for separation of bovine ocytes.

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Evaluation of Ground-Water Sampling Techniques for Analysis of Chlorofluorocarbons (지하수의 CFCs(Chlorofluorocarbons) 조사를 위한 시료 채취 방법의 평가)

  • 고동찬;이대하
    • Journal of Soil and Groundwater Environment
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    • v.8 no.2
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    • pp.1-8
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    • 2003
  • Two types of ground-water sampling techniques for CFCs (chlorofluorocarbons) analysis, the cold-welded copper tube method and flame-sealed borosilicate glass ampule method, were compared and evaluated. CFCs concentrations by the copper tube method showed a poor reproducibility among triplicates whereas those by the glass ampule method showed a good agreement and relative standard deviations of triplicates were less than 5%. The poor reproducibility of the copper tube method appears to be attributed to the incomplete sealing in connection between faucets of wellhead and the sampling apparatus. The copper tube method also showed higher CFCs concentrations than the glass ampule method, which is more pronounced for CFC-11 than for CFC-12. The plastic tubings and rubber gasket of faucets in case of the copper tube method possibly contaminated the samples with CFC-11 and CFC-12. The potential of CFCs contamination for the glass ampule method was eliminated by using stainless steel and Nylon only and by connecting the sampling equipment directly to the main discharge pipe of wellhead. The validity of the glass ampule method were also verified by detecting very low level of CFCs for the ground-water sample which is old enough to have negligible CFCs.

Coloring Analysis of Digital Textile Printing According to the Type of Fiber (섬유 종류에 따른 디지털 텍스타일 프린팅의 발색성 비교 분석)

  • Lee, Youn-Soon;Eum, Ji-Eun
    • Journal of the Korea Fashion and Costume Design Association
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    • v.12 no.2
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    • pp.67-73
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    • 2010
  • Whole process of textile printing is made by computer and it remarkably improves environment problem. This digital textile printing is becoming next step environment friendly textile printing method. But, still now range of textile possible for digital textile printing is limited, and also color analysis according to fiber types is not completed. The ink printed on the fabrics through DTP printer can be absorbed and fixed into textile without any blots by pre-treatment using suitable media solution for fabrics types. The chemical formulation of media solution used in the pre-treatment process varies according to the types of textiles and inks for DTP products. First, I studied reference books or articles about color analysis of digital textile printing. Second, I recorded pre-process, printing, post-process and coloring of silk, wool, nylon at same condition. After that, I analyzed $L^*\;a^*\;b^*$, Total K/S, ${\Delta}E$ and studied color intensity and coloring. According to this study, I suggested particular textile special for coloring and manual for affective coloring control. It showed that the performance of the digital printing on the Silk, Wool and Nylon blend fabrics treated by the media solution developed in this study was better than the one treated by the previous media solution for each single inks.

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