• Nuclear Engineering and Technology
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• v.26 no.4
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• pp.453-460
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• 1994

The migration equation is modified for a three-member decay chain in the fracture and porous matrix Analytical solutions are obtained by utilizing Laplace transform the initial conditions of Delta function and Bateman equation. The concentrations for each nuclide of Np$^{237}$ -U$^{233}$ -Th$^{229}$ and U$^{234}$ -Th$^{230}$ -Ra$^{226}$ chains selected from the 4n＋1 and 4n＋2 chains are plotted by utilizing analytical solutions in the fracture. Retardation coefficient of the nuclides are obtained using those of the granite. The results indicate that the daughter nuclides such as U$^{233}$ , Th$^{229}$ , Th$^{230}$ and Ra$^{226}$ become important at the far field from the repository though there is very small initial inventory in the waste solid or spent fuel, for they are produced by the mother nuclides decayed in the fracture and porous matrix.

• Nuclear Engineering and Technology
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• v.52 no.9
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• pp.2130-2137
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• 2020

The standard method for calculating anti-neutrino emissions from a reactor involves knowing the fractional fission rates for the most important fissioning nuclides in the reactor. To calculate these rates requires detailed reactor physics calculations based upon the reactor design, fuel design, burnup dependent fuel composition, location of specific fuel assemblies in the core and detailed operational data from the reactor. This has only been published for a few reactors during specific time periods, whereas to be of practical use for anti-neutrino reactor monitoring it is necessary to be able to predict these on the publicly available information from any reactor, especially if using these data to subtract the anti-neutrino signal from other reactors to identify an undeclared reactor and monitor its operation. This paper proposes a method to estimate the fission fractions for a specific reactor based upon publicly available information and provides a database based upon a series of spent fuel inventory calculations using the FISPIN10 code and its associated data libraries.

• Nuclear Engineering and Technology
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• v.53 no.9
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• pp.2830-2838
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• 2021

This work deals with the assessment of the burnup capabilities of the Serpent Monte Carlo code to predict spent nuclear fuel (SNF) isotopic concentrations for low-enriched uranium (LEU) fuel at different burnup levels up to 47 MWd/kgU. The irradiation of six UO₂ experimental samples in three different VVER-1000 reactor units has been simulated and the predicted concentrations of actinides up to ²⁴⁴Cm have been compared with the corresponding measured values. The results show a global good agreement between calculated and experimental concentrations, in several cases within the margins of the nuclear data uncertainties and in a few cases even within the reported experimental uncertainties. The differences in the performances of the JEFF3.1.1, ENDF/B-VII.1 and ENDF/B-VIII.0 nuclear data libraries (NDLs) have also been assessed and the use of the newly released ENDF/B-VIII.0 library has shown an increased accuracy in the prediction of the C/E's for some of the actinides considered, particularly for the plutonium isotopes. This work represents a step forward towards the validation of advanced simulation tools against post irradiation experimental data and the obtained results provide an evidence of the capabilities of the Serpent Monte-Carlo code with the associated modern NDLs to accurately compute SNF nuclide inventory concentrations for VVER-1000 type reactors.

• Journal of the Korean institute of surface engineering
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• v.56 no.1
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• pp.84-93
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• 2023

The spent nuclear fuel is burned during the planned cycle in the plant and then generates elements such as actinide series, fission products, and plutonium with a long half-life. An 'interim storage' step is needed to manage the high radioactivity and heat emitted by nuclides until permanent-disposal. In the case of Korea, there is no space to dispose of high-level radioactive waste after use, so there is a need for a period of time using interim storage. Therefore, the intensity of neutrons and gamma-ray must be determined to ensure the integrity of spent nuclear fuel during interim storage. In particular, the most important thing in spent nuclear fuel is burnup evaluation, estimation of the source term of neutrons and gamma-ray is regarded as a reference measurement of the burnup evaluation. In this study, an analysis of spent nuclear fuel was conducted by setting up a virtual fuel burnup case based on CE16×16 fuel to check the total amount and spectrum of neutron, gamma radiation produced. The correlation between BU (burnup), IE (enrichment), and CT (cooling time) will be identified through spent nuclear fuel burnup calculation. In addition, the composition of nuclide inventory, actinide and fission products can be identified.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.3
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• pp.265-279
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• 2017

The Gyeongju underground silo type disposal facility, approved for use in December 2014, is in operation for the disposal of low and very low-level radioactive wastes, excluding intermediate-level waste. That is why the existing low-level radioactive waste level has been subdivided and the concentration limit value for intermediate-level waste has been changed in accordance with Nuclear Safety Commission Notice 2014-003. For the safe disposal of intermediate-level wastes, new optimization methodology for calculating the concentration limit of intermediate radioactive level wastes at an underground silo type disposal facility was developed. According to the developed optimization methodology, concentration limits of intermediate-level wastes were derived and the inventory of radioactive nuclides was evaluated. The operation and post closure scenarios were evaluated for the derived radioactive nuclide inventory and the results of all scenarios were confirmed to meet the regulatory limit. However, in case of $^{14}C$, it was confirmed that additional radioactivity limitation through a well scenario was needed in addition to the limit of disposal concentration. It was confirmed that the derived intermediate concentration limit of radioactive waste can be used as the intermediate-level waste concentration limit for the underground disposal facility. For the safe disposal of intermediate-level wastes, KORAD plans to acquire additional data from the radioactive waste generator and manage the cumulative radioactivity of $^{14}C$.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.3
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• pp.257-265
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• 2007

Spent filter wastes of about 1,000 units (200 L) have been stored in the waste storage facility of the Korea Atomic Energy Research Institute since its operation. At the moment, to secure space in a waste storage facility as well as to efficiently manage spent filter wastes, it is necessary to conduct a compaction treatment of these spent filters, and finally, to repack the compacted spent filters into a 200 liter drum. To do that, the spent filter wastes were first classified according to their generation facilities, their generation date and their surface dose rate by investigating the inventory of the spent filters. In order to repack a compacted spent filter in a 200 liter drum, it is first necessary to conduct a radionuclide assessment of a spent filter before compacting it. Therefore, after taking a representative sample from a spent filter without a dismantlement, the nuclide analysis for it will be conducted. And then, after putting a spent filter into a regular drum by conducting the columnar shaping of the hexahedral form of a spent filter, the compaction treatment of the shaped spent filter will be conducted by vertically compacting it.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.4
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• pp.343-356
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• 2016

The Korea Radioactive Waste Agency (KORAD) has developed a dual-purpose metal cask for the dry storage of spent nuclear fuel that has been generated by domestic light-water reactors. The metal cask was designed in compliance with international and domestic technology standards, and safety was the most important consideration in developing the design. It was designed to maintain its integrity for 50 years in terms of major safety factors. The metal cask ensures the minimization of waste generated by maintenance activities during the storage period as well as the safe management of the waste. An activation evaluation of the main body, which includes internal and external components of metal casks whose design lifetime has expired, provides quantitative data on their radioactive inventory. The radioactive inventory of the main body and the components of the metal cask were calculated by applying the MCNP5 ORIGEN-2 evaluation system and by considering each component's chemical composition, neutron flux distribution, and reaction rate, as well as the duration of neutron irradiation during the storage period. The evaluation results revealed that 10 years after the end of the cask's design life, $^{60}Co$ had greater radioactivity than other nuclides among the metal materials. In the case of the neutron shield, nuclides that emit high-energy gamma rays such as $^{28}Al$ and $^{24}Na$ had greater radioactivity immediately after the design lifetime. However, their radioactivity level became negligible after six months due to their short half-life. The surface exposure dose rates of the canister and the main body of the metal cask from which the spent nuclear fuel had been removed with expiration of the design lifetime were determined to be at very low levels, and the radiation exposure doses to which radiation workers were subjected during the decommissioning process appeared to be at insignificant levels. The evaluations of this study strongly suggest that the nuclide inventory of a spent nuclear fuel metal cask can be utilized as basic data when decommissioning of a metal cask is planned, for example, for the development of a decommissioning plan, the determination of a decommissioning method, the estimation of radiation exposure to workers engaged in decommissioning operations, the management/reuse of radioactive wastes, etc.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.2
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• pp.155-162
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• 2008

Inventories to be disposed of, reference turnup, and source terms for CANDU spent fuel were evaluated for geological disposal system design. The historical and projected inventory by 2040 is expected to be 14,600 MtU under the condition of 30-year lifetime for unit 1 and 40-year lifetime for other units in Wolsong site. As a result of statistical analysis for discharge burnup of the spent fuels generated by 2007, average and stand deviation revealed 6,987 MWD/MtU and 1,167, respectively. From this result, the reference burnup was determined as 8,100 MWD/MtU which covers 84% of spent fuels in total. Source terms such as nuclide concentration for a long-term safety analysis, decay heat, thermo-mechanical analysis, and radiation intenity and spectrum was characterized by using ORIGEN-ARP containing conservativeness in the aspect of decay heat up to several thousand years. The results from this study will be useful for the design of storage and disposal facilities.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.1
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• pp.1-7
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• 2009

This study has been focused on determining the chemical composition of $^{14}C$ - in terms of both organic and inorganic $^{14}C$ contents - in reactor coolant from 3 different PWR's reactor type. The purpose was to evaluate the characteristic of $^{14}C$ that can serve as a basis for reliable estimation of the environmental release at domestic PWR sites. $^{14}C$ is the most important nuclide in the inventory, since it contributes one of the main dose contributors in future release scenarios. The reason for this is its high mobility in the environment, biological availability and long half-life(5730yr). More recent studies - where a more detailed investigation of organic $^{14}C$ species believed to be formed in the coolant under reducing conditions have been made - show that the organic compounds not only are limited to hydrocarbons and CO. Possible organic compounds formed including formaldehyde, formic acid and acetic acid, etc. Under oxidizing conditions shows the oxidized carbon forms, possibly mainly carbon dioxide and bicarbonate forms. Measurements of organic and inorganic $^{14}C$ in various water systems were also performed. The $^{14}C$ inventory in the reactor water was found to be 3.1 GBq/kg in PWR of which less than 10% was in inorganic form. Generally, the $^{14}C$ activity in the water was divided equally between the gas- and water- phase. Even though organic $^{14}C$ compound shows that dominant species during the reactor operation, But during the releasing of $^{14}C$ from the plant stack, chemical forms of $^{14}C$ shows the different composition due to the operation conditions such as temperature, pH, volume control tank venting and shut down chemistry.