• Title/Summary/Keyword: Nuclear reaction models

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Detonation cell size model based on deep neural network for hydrogen, methane and propane mixtures with air and oxygen

  • Malik, Konrad;Zbikowski, Mateusz;Teodorczyk, Andrzej
    • Nuclear Engineering and Technology
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    • v.51 no.2
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    • pp.424-431
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    • 2019
  • The aim of the present study was to develop model for detonation cell sizes prediction based on a deep artificial neural network of hydrogen, methane and propane mixtures with air and oxygen. The discussion about the currently available algorithms compared existing solutions and resulted in a conclusion that there is a need for a new model, free from uncertainty of the effective activation energy and the reaction length definitions. The model offers a better and more feasible alternative to the existing ones. Resulting predictions were validated against experimental data obtained during the investigation of detonation parameters, as well as with data collected from the literature. Additionally, separate models for individual mixtures were created and compared with the main model. The comparison showed no drawbacks caused by fitting one model to many mixtures. Moreover, it was demonstrated that the model may be easily extended by including more independent variables. As an example, dependency on pressure was examined. The preparation of experimental data for deep neural network training was described in detail to allow reproducing the results obtained and extending the model to different mixtures and initial conditions. The source code of ready to use models is also provided.

Electrical fire simulation in control room of an AGN reactor

  • Jyung, Jae-Min;Chang, Yoon-Suk
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.466-473
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    • 2021
  • Fire protection is one of important issues to ensure safety and reduce risks of nuclear power plants (NPPs). While robust programs to shut down commercial reactors in any fires have been successfully maintained, the concept and associated regulatory requirements are constantly changing or strengthening by lessons learned from operating experiences and information all over the world. As part of this context, it is necessary not only to establish specific fire hazard assessment methods reflecting the characteristics of research reactors and educational reactors but also to make decisions based on advancement encompassing numerical analyses and experiments. The objectives of this study are to address fire simulation in the control room of an educational reactor and to discuss integrity of digital console in charge of main operation as well as analysis results through comparison. Three electrical fire scenarios were postulated and twenty-four thermal analyses were carried out taking into account two turbulence models, two cable materials and two ventilation conditions. Twelve supplementary thermal analyses and six subsequent structural analyses were also conducted for further examination on the temperature and heat flux of cable and von Mises stress of digital console, respectively. As consequences, effects of each parameter were quantified in detail and future applicability was briefly discussed. On the whole, higher profiles were obtained when Deardorff turbulence model was employed or polyvinyl chloride material and larger ventilation condition were considered. All the maximum values considered in this study met the allowable criteria so that safety action seems available by sustained integrity of the cable linked to digital console within operators' reaction time of 300 s.

Application of CFD model for passive autocatalytic recombiners to formulate an empirical correlation for integral containment analysis

  • Vikram Shukla;Bhuvaneshwar Gera;Sunil Ganju;Salil Varma;N.K. Maheshwari;P.K. Guchhait;S. Sengupta
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4159-4169
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    • 2022
  • Hydrogen mitigation using Passive Autocatalytic Recombiners (PARs) has been widely accepted methodology inside reactor containment of accident struck Nuclear Power Plants. They reduce hydrogen concentration inside reactor containment by recombining it with oxygen from containment air on catalyst surfaces at ambient temperatures. Exothermic heat of reaction drives the product steam upwards, establishing natural convection around PAR, thus invoking homogenisation inside containment. CFD models resolving individual catalyst plate channels of PAR provide good insight about temperature and hydrogen recombination. But very thin catalyst plates compared to large dimensions of the enclosures involved result in intensive calculations. Hence, empirical correlations specific to PARs being modelled are often used in integral containment studies. In this work, an experimentally validated CFD model of PAR has been employed for developing an empirical correlation for Indian PAR. For this purpose, detailed parametric study involving different gas mixture variables at PAR inlet has been performed. For each case, respective values of gas mixture variables at recombiner outlet have been tabulated. The obtained data matrix has then been processed using regression analysis to obtain a set of correlations between inlet and outlet variables. The empirical correlation thus developed, can be easily plugged into commercially available CFD software.

A Development of a Transient Hydrogen Generation Model for Metal-Water Interactions

  • Lee, Jin-Yong;Park, Goon-Cherl;Lee, Byung-Chul
    • Nuclear Engineering and Technology
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    • v.32 no.6
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    • pp.549-558
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    • 2000
  • A transient model for hydrogen generation in molten metal-water interactions was developed with separate models for two stages of coarse mixing and stratification. The model selves the mechanistic equations (heat and mass transfer correlation, heat conduction equation and the concentration diffusion equation) of each stage with non-zero boundary conditions. Using this model, numerical simulations were performed for single droplet experiments in the Argonne National Laboratory tests and for FITS tests that simulated dynamic fragmentation and stratification. The calculation results of hydrogen generation showed better agreement to the experiment data than those of previous works. It was found from the analyses that the steam concentration to be reached at the reaction front might be the main constraint to the extent of the metal droplet oxidized. Also, the hydrogen generation rate in the coarse mixing stage was the higher than that in the stratification stage. The particle size was the most important factor in the coarse mixing stage to predict the amount of hydrogen generation.

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A Study on the Migration Characteristics of Cs-137 in a Packed Column (충전층에서의 세슘-137의 이동특성에 관한 연구)

  • Lee, Jae-Owan;Cho, Won-Jin;Han, Kyung-Won;Park, Hun-Hwee
    • Nuclear Engineering and Technology
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    • v.22 no.1
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    • pp.20-28
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    • 1990
  • In this study the migration experiment using packed column with crushed tuff was conducted as a basic research to develop migration model of radionuclides through geologic media. The main emphasis was put on evaluating the validity of migration models. For this, two models were introduced: one is the model which is based on the assumption of instantaneous equilibrium reaction and the other the model based on kinetic process such as intraparticle diffusion. The coefficient of hydrodynamic dispersion in packed column was determined using iodine as nonsorbing tracer. The hydrodynamic dispersion coefficient, D$_{L}$ was shown to be 0.11$\times$10$^{-2}$ $\textrm{cm}^2$/min under the condition of the column porosity of 0.483 and the average water velocity of 0.915$\times$10$^{-2}$ cm/min. The distribution coefficient, Kd of Cs-137 on crushed tuff was 11.3 cc/g at the concentration of 2$\times$10$^{-6}$ M and the temperature of 2$0^{\circ}C$. The breakthrough curve of Cs-137 through packed column was shown to have an asymmetric curve in which long trailing tail appears at the end part of the curve. The results obtained from the comparison of introduced models with experimental data indicated that the mass transfer model with intraparticle diffusion as rate-controlling step simulated the behaviors of Cs-137 migration more adequately, when compared with the bulk reaction model in which the assumption of instantaneous equilibrium reaction was maded. Consequently, the intraparticle diffusion was found to be an important factor in the migration of Cs-137 through packed column.n.

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Antianaphylactic Effect of Sinpo-tang by Anal Therapy (肛腸療法에 의한 辛蒲湯의 抗아나필락시 效果)

  • Lee, Jong-Beom;Mun, Seok-Jae;Mun, Gu;Won, Jin-Hui;Kim, Tae-Gyun;Bae, Nam-Gyu
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.14 no.1
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    • pp.240-249
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    • 2001
  • Objective : Anal Therapy is another way of taking medicine and applies to each field of clinical treatment extensively. Sinpo-tang(SPT) has been used for the treatment of a allergic rhinitis. In this study, the auther investigated the anti anaphylactic action of Sinpo-tang by anal therapy was investigated on cutaneous allergic reaction models. Methods : Results : 1. Sinpo-tang (0,001-0.1 g/kg) dose-dependently inhibited the compound 48/80-induced ear swelling response in mice. Inhibitory effect of Sinpo-tang was significant (P < 0.05) at the doses of 0.01, 0.1 g/kg. 2. Sinpo-tang (0.001-0.1 g/kg) inhibited the cutaneous allergic reaction activated by anti-dinitrophenyl IgE in rats. Of special note, Sinpo-tang (0.1 g/kg) inhibited the cutaneous allergic reaction by $68\%$. 3. This inhibitory effect of Sinpo-tang was confirmed by observation of alcian blue/nuclear fast red stained-mast cells in the cutaneous tissue. 4. Sinpo-tang (0.01-1 g/L) dose-dependently inhibited the compound 48/80-induced histamine release from the peritoneal mast cells. Conclusions :These results indicate that anal therapy of Sinpo-tang may be beneficial in the treatment of mast cell-mediated anaphylaxis by inhibition of histamine release from mast cells in vivo and in vitro.

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Fractal kinetic characteristics of uranium leaching from low permeability uranium-bearing sandstone

  • Zeng, Sheng;Shen, Yuan;Sun, Bing;Tan, Kaixuan;Zhang, Shuwen;Ye, Wenhao
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1175-1184
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    • 2022
  • The pore structure of uranium-bearing sandstone is one of the critical factors that affect the uranium leaching performance. In this article, uranium-bearing sandstone from the Yili Basin, Xinjiang, China, was taken as the research object. The fractal characteristics of the pore structure of the uranium-bearing sandstone were studied using mercury intrusion experiments and fractal theory, and the fractal dimension of the uranium-bearing sandstone was calculated. In addition, the effect of the fractal characteristics of the pore structure of the uranium-bearing sandstone on the uranium leaching kinetics was studied. Then, the kinetics was analyzed using a shrinking nuclear model, and it was determined that the rate of uranium leaching is mainly controlled by the diffusion reaction, and the dissolution rate constant (K) is linearly related to the pore specific surface fractal dimension (DS) and the pore volume fractal dimension (DV). Eventually, fractal kinetic models for predicting the in-situ leaching kinetics were established using the unreacted shrinking core model, and the linear relationship between the fractal dimension of the sample's pore structure and the dissolution rate during the leaching was fitted.

Thermodynamic Analysis of Vapor Explosion Phenomena (증기폭발 현상의 열역학적 해석)

  • Bang, Kwang-Hyun
    • Nuclear Engineering and Technology
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    • v.25 no.2
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    • pp.265-275
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    • 1993
  • A vapor explosion has been a concern in nuclear reactor safety due to its potential for a destructive mechanical energy release. In order to properly assess the hazard of a vapor explosion, it is necessary to accurately estimate the conversion efficiency of the thermal energy to mechanical energy. In the absence of a complete model to determine the explosive energy yield, one may have to rely on a simpler upper bound estimate such as a thermodynamic model. This paper discusses various thermodynamic models and presents a clarification of each model in their mathematical formulation and the thermodynamic work conversion. It is shown that the work release in the shock adiabatic model of Board and Hall is essentially equal to that of Hicks-Menzies thermodynamic model. The effect of coolant void fraction on the explosion efficiency is also predicted based on these thermodynamic models. Finally, the Hicks-Menzies model is modified to account for the chemical reaction between a metallic fuel and water and the resultant effects on the explosion expansion work are discussed.

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Mathematical Modeling for Leaching and dissolution of Solidified Radioactive Waste in a Geologic Reposiory (지하 처분장에서의 방사성폐기물 고화체의 용출 및 용해에 대한 수학적 모형 분석)

  • Kim, Chang-Lak;Park, Kwang-Sub;Cho, Chan-Hee;Kim, Jhinwung;Suh, In-Suk
    • Nuclear Engineering and Technology
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    • v.20 no.2
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    • pp.120-131
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    • 1988
  • A souce term model describes mathematically the source of radionuclides as they begin slow migration and decay in deep groundwater. Various source term models based on mass-transfer analysis and measurement-based source term models are reviewed. Ganerally, two processes are involved in leaching or dissolution: (1) chemical reactions and (2) mass transfer by diffusion. The chemical reaction controls the dissolution rates only during the early stage of exposure to groundwater. The exterior-field mass transfer may control the long term dissolution rates from the waste solid in a geologic repository. Mass-transfer analyses re3y on detailed and careful application of the governing equations that describe the mechanistic processes of transport of material between and within phases. If used correctly, source term models based on mass-transfer theory are valuable and necessary tools for developing reliable predictions.

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Characterization of the Purified Ca-type Bentonil-WRK Montmorillonite and Its Sorption Thermodynamics With Cs(I) and Sr(II)

  • Seonggyu Choi;Bong-Ju Kim;Surin Seo;Jae-Kwang Lee;Jang-Soon Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.4
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    • pp.427-438
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    • 2023
  • Thermodynamic sorption modeling can enhance confidence in assessing and demonstrating the radionuclide sorption phenomena onto various mineral adsorbents. In this work, Ca-montmorillonite was successfully purified from Bentonil-WRK bentonite by performing the sequential physical and chemical treatments, and its geochemical properties were characterized using X-ray diffraction, Brunauer-Emmett-Teller analysis, cesium-saturation method, and controlled continuous acid-base titration. Further, batch experiments were conducted to evaluate the adsorption properties of Cs(I) and Sr(II) onto the homoionic Ca-montmorillonite under ambient conditions, and the diffuse double layer model-based inverse analysis of sorption data was performed to establish the relevant surface reaction models and obtain corresponding thermodynamic constants. Two types of surface reactions were identified as responsible for the sorption of Cs(I) and Sr(II) onto Ca-montmorillonite: cation exchange at interlayer site and complexation with edge silanol functionality. The thermodynamic sorption modeling provides acceptable representations of the experimental data, and the species distributions calculated using the resulting reaction constants accounts for the predominance of cation exchange mechanism of Cs(I) and Sr(II) under the ambient aqueous conditions. The surface complexation of cationic fission products with silanol group slightly facilitates their sorption at pH > 8.